{"id":256472,"date":"2023-12-11T06:29:00","date_gmt":"2023-12-10T22:29:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=256472"},"modified":"2023-12-10T23:29:10","modified_gmt":"2023-12-10T15:29:10","slug":"edward-h-sargent%e9%99%a2%e5%a3%abnature-nanotechnology%ef%bc%9a%e9%ab%98%e6%95%88%e9%85%b8%e6%80%a7co2rr%e4%b8%b2%e8%81%94%e7%94%b5%e5%82%ac%e5%8c%96%ef%bc%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=256472","title":{"rendered":"Edward H. Sargent\u9662\u58ebNature Nanotechnology\uff1a\u9ad8\u6548\u9178\u6027CO2RR\u4e32\u8054\u7535\u50ac\u5316\uff01"},"content":{"rendered":"
\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u78b1\u6027\u548c\u4e2d\u6027\u7535\u89e3\u8d28\u6291\u5236\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\uff0c\u4fc3\u8fdb\u7535\u5316\u5b66CO2<\/sub>\u8fd8\u539f\u53cd\u5e94\uff08CO2<\/sub>RR\uff09\u4e2d\u7684C-C\u8026\u5408\u3002\u7136\u800c\uff0c\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0c\u7531\u4e8e\u9634\u6781\u5c40\u90e8\u78b1\u5ea6\u8f83\u9ad8\uff0c\u8d85\u8fc775%\u7684\u8f93\u5165CO2<\/sub>\u901a\u8fc7\u4e0e\u6c22\u6c27\u6839\u79bb\u5b50\uff08OH–<\/sup>\uff09\u53cd\u5e94\u5f62\u6210\u78b3\u9178\u6c22\u76d0\uff0c\u8fdb\u800c\u4ee5\u5316\u5b66\u65b9\u5f0f\u635f\u5931\u3002\u8fd9\u4f1a\u964d\u4f4eCO2<\/sub>\u7684\u5355\u7a0b\u8f6c\u5316\u6548\u7387\uff08SPCE\uff09\uff0c\u5e76\u4e3a\u56de\u6536\u635f\u5931\u7684CO2<\/sub>\u53cd\u5e94\u7269\u5e26\u6765\u80fd\u91cf\u635f\u5931\u3002\u5728CO2<\/sub>RR\u4e2d\u4f7f\u7528\u9178\u6027\u7535\u89e3\u8d28\u53ef\u4ee5\u901a\u8fc7\u51cf\u5c11\u78b3\u9178\u6c22\u76d0\u7684\u5f62\u6210\u548cCO2<\/sub>\u4ea4\u53c9\u6765\u63d0\u9ad8CO2<\/sub>\u7684\u5229\u7528\u7387\uff0c\u4f46\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\uff0c\u52a8\u529b\u5b66\u4e0a\u66f4\u5bb9\u6613\u53d1\u751fHER\uff0c\u5bfc\u81f4CO2<\/sub>RR\u9009\u62e9\u6027\u8f83\u5dee\u3002\u56e0\u6b64\u9700\u8981\u5bfb\u6c42\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u4fc3\u8fdb\u9009\u62e9\u6027\u5f62\u6210C2+<\/sub>\u7684\u7b56\u7565\u3002<\/p>\n \u00a0<\/strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n \u6709\u89c2\u70b9\u8ba4\u4e3a\u9ad8CO\u8986\u76d6\u7387\u6709\u52a9\u4e8eC-C\u5076\u8054\u3002\u57fa\u4e8e\u6b64\uff0c\u52a0\u62ff\u5927\u591a\u4f26\u591a\u5927\u5b66<\/strong>Edward H. Sargent<\/strong>\u9662\u58eb<\/strong>\u56e2\u961f\u62a5\u9053\u4e86\u5c06CO2<\/sub>\u8f6c\u5316\u4e3aC2+<\/sub>\u53cd\u5e94\u89e3\u8026\u4e3a\u4e24\u4e2a\u6b65\u9aa4\uff0c\u5373CO2<\/sub>\u8f6c\u5316\u4e3aCO\u548cCO\u8f6c\u5316\u4e3aC2+<\/sub>\uff0c\u901a\u8fc7\u4e24\u4e2a\u4e0d\u540c\u7684\u50ac\u5316\u5242\u5c42\u4e32\u8054\u64cd\u4f5c\u6765\u5b9e\u73b0\u6240\u9700\u7684\u8f6c\u5316\u3002\u7b2c\u4e00\u79cd\u50ac\u5316\u5242\u662f\u539f\u5b50\u5206\u6563\u7684\u915e\u83c1\u94b4\uff08CoPc\uff09\uff0c\u5176\u4ee5\u9ad8\u9009\u62e9\u6027\u5c06CO2<\/sub>\u8fd8\u539f\u4e3aCO\u3002\u8be5\u8fc7\u7a0b\u589e\u52a0\u4e86\u5c40\u90e8CO\u7684\u53ef\u7528\u6027\uff0c\u4ee5\u589e\u5f3a\u7b2c\u4e8c\u50ac\u5316\u5242\u5c42\u4e0a\u7684C-C\u5076\u8054\u6b65\u9aa4\u3002\u7b2c\u4e8c\u5c42\u50ac\u5316\u5242\u662f\u5177\u6709Cu-\u79bb\u805a\u7269\u754c\u9762\u7684Cu\u7eb3\u7c73\u50ac\u5316\u5242\u3002\u4f18\u5316\u540e\u7684\u4e32\u8054\u7535\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a800 mA cm-2<\/sup>\u4e0b\uff0c\u572825\u2103\u6761\u4ef6\u4e0b\u5b9e\u73b061%\u7684C2<\/sub>H4<\/sub> FE\u548c82%\u7684C2+<\/sub> FE\u3002\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a800 mA cm-2<\/sup>\u548c2 ml min-1<\/sup>\u7684CO2<\/sub>\u6d41\u901f\u4e0b\uff0c\u7cfb\u7edf\u7684\u5355\u7a0b\u78b3\u6548\u7387\u4e3a90\u00b13%\uff0cC2<\/sub>H4<\/sub> FE\u4e3a55\u00b13%\uff0c\u603bC2+<\/sub> FE\u4e3a76\u00b12%\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cEfficient multicarbon formation in acidic CO2<\/sub> reduction via tandem electrocatalysis<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aNature Nanotechnology<\/em><\/strong>\u4e0a<\/em><\/strong>\u3002<\/p>\n \u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n 1\u3001\u901a\u8fc7\u4e24\u4e2a\u4e0d\u540c\u7684\u50ac\u5316\u5242\u5c42\u4e32\u8054\u64cd\u4f5c\u6765\u5b9e\u73b0\u5c06CO2<\/sub>-to-C2+<\/sub>\u53cd\u5e94\u89e3\u8026\u4e3a\u4e24\u4e2a\u6b65\u9aa4\uff0c\u5373CO2<\/sub>-to-CO\u548cCO-to-C2+<\/sub>\u3002<\/p>\n 2\u3001\u572825\u00b0C\u548c800 mA cm-2<\/sup> \u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u4f18\u5316\u7684\u4e32\u8054\u7535\u6781\u53ef\u5b9e\u73b061% C2<\/sub>H4<\/sub> FE\u548c82% C2+<\/sub> FE\u3002<\/p>\n 3\u3001\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a800 mA cm-2<\/sup>\u548c2 ml min-1<\/sup>\u7684CO2<\/sub>\u6d41\u901f\u4e0b\uff0c\u7cfb\u7edf\u7684\u5355\u7a0b\u78b3\u6548\u7387\u4e3a90\u00b13%\uff0cC2<\/sub>H4<\/sub> FE\u4e3a55\u00b13%\uff0c\u603bC2+<\/sub> FE\u4e3a76\u00b12%\u3002<\/p>\n \u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n \u00a0 \u56fe<\/strong>1\u00a0 <\/strong>\u4e32\u8054\u50ac\u5316\u9178\u6027<\/strong>CO2<\/sub>RR<\/strong>\u7684\u7a7a\u95f4\u89e3\u8026\u7b56\u7565<\/strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n \uff08a\uff09\u4e0d\u540cCO\u8986\u76d6\u7387\u4e0bCu\u8868\u9762H*\u4e2d\u95f4\u4f53\u5f62\u6210\u7684\u53cd\u5e94\u81ea\u7531\u80fd\u3002<\/p>\n \uff08b\uff09\u4e0d\u540cCO\u8986\u76d6\u7387\u4e0bCu\u8868\u9762CO\u4e8c\u805a\u7684\u521d\u59cb\u6001\u3001\u8fc7\u6e21\u6001\u548c\u6700\u7ec8\u6001\u7684\u80fd\u91cf\u5206\u5e03\u3002<\/p>\n \uff08c\uff09\u5728\u9178\u6027\u7f13\u51b2\u7535\u89e3\u6db2\u4e2d\uff0c\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0bCO2<\/sub>RR\u548cCORR\u4e2dCu\u7535\u6781\u4e0aH2<\/sub>\u3001C2<\/sub>H4<\/sub>\u548cC2+<\/sub>\u7684FE\u503c\u3002<\/p>\n \uff08d\uff09\u9178\u6027CO2<\/sub>RR\u7cfb\u7edf\u4e2d\u79bb\u5b50\u4f20\u8f93\u548c\u53cd\u5e94\u7684\u793a\u610f\u56fe\u3002<\/p>\n \uff08e\uff09\u9178\u6027CO2<\/sub>RR\u7cfb\u7edf\u4e2d\u901a\u8fc7\u4e32\u8054\u50ac\u5316\u5b9e\u73b0\u7a7a\u95f4\u89e3\u8026\u7b56\u7565\u7684\u793a\u610f\u56fe\uff0c\u663e\u793a\u4e86\u9178\u6027CO2<\/sub>RR\u7cfb\u7edf\u4e2d\u7684CO2<\/sub>\u4f20\u8f93\u3002<\/p>\n <\/p>\n \u56fe<\/strong>2\u00a0 <\/strong>\u539f\u5b50\u5206\u6563<\/strong> CoPc@HC <\/strong>\u7684\u5408\u6210\u4e0e\u7ed3\u6784\u5206\u6790<\/strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n \uff08a\uff09CoPc@HC\u7684\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n \uff08b\uff09CoPc@HC\u7684SEM\u56fe\u50cf\u3002<\/p>\n \uff08c\uff09CoPc@HC \u7684HAADF-STEM\u56fe\u50cf\u548c\u76f8\u5e94\u7684\u5143\u7d20mapping\u56fe\u3002<\/p>\n \uff08d\uff09CoPc@HC\u7684\u76f8\u5dee\u6821\u6b63HAADF-STEM\u56fe\u50cf\u3002<\/p>\n \uff08e\uff09CoPc@HC\u548c\u5bf9\u7167\u6837\u54c1\uff08Co\u7b94\u3001CoO\u3001Co3<\/sub>O4<\/sub>\u3001CoPc\uff09\u7684Co K-edge XANES\u5149\u8c31\u3002<\/p>\n \uff08f\uff09CoPc@HC\u548c\u5bf9\u7167\u6837\u54c1\u7684\u5085\u7acb\u53f6\u53d8\u6362Co K-edge EXAFS\u5149\u8c31\u3002<\/p>\n \uff08g\uff09\u572825\u2103\u7684\u6d41\u52a8\u6c60\u4e2d\uff0c\u5728\u9178\u6027\u7f13\u51b2\u7535\u89e3\u6db2\u4e2d\uff0cCoPc@HC\u7535\u6781\u4e0eCoPc\/C\u7535\u6781\u5728\u9178\u6027CO2<\/sub>RR\u4e0a\u7684CO FE\u6bd4\u8f83\u3002<\/p>\n <\/p>\n \u56fe<\/strong>3\u00a0 <\/strong>\u9178\u6027<\/strong>CO2<\/sub>RR<\/strong>\u6027\u80fd<\/strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n \uff08a\uff09CoPc@HC\/Cu\u4e32\u8054\u7535\u6781\u7684\u6a2a\u622a\u9762SEM\u56fe\u50cf\u3002<\/p>\n \uff08b-c\uff09\u4e0a\u5c42CoPc@HC\u50ac\u5316\u5242\u5c42\u7684TEM\u56fe\u50cf\u548c\u4e0b\u5c42\u94dc\u50ac\u5316\u5242\u5c42\u4e0e\u94dc-\u79bb\u805a\u7269\u754c\u9762\u7684SEM\u56fe\u50cf\u3002<\/p>\n \uff08d\uff09\u901a\u8fc7\u4e32\u8054\u50ac\u5316\u5b9e\u73b0\u7a7a\u95f4\u89e3\u8026\u7b56\u7565\u7684\u793a\u610f\u56fe\uff0c\u663e\u793a\u9178\u6027CO2<\/sub>RR\u4e2d\u7684\u7535\u5b50\uff08e–<\/sup>\uff09\u4f20\u8f93\u548c\u8d28\u91cf\u4f20\u8f93\u3002<\/p>\n \uff08e-f\uff09\u572825\u2103\u7684\u6d41\u52a8\u6c60\u4e2d\uff0c\u5728\u9178\u6027\u7f13\u51b2\u7535\u89e3\u6db2\u4e2d\uff0cCoPc@HC\/Cu\u4e32\u8054\u7535\u6781\u548c\u94dc\u7535\u6781\u4e0aCO2<\/sub>RR\u4ea7\u7269\u7684FE\u503c\u3002<\/p>\n \uff08g\uff09C2<\/sub>H4<\/sub>\u548cH2<\/sub>\u7684\u90e8\u5206\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n \uff08h\uff09\u5728\u9178\u6027\u7f13\u51b2\u7535\u89e3\u6db2\u4e2d\uff0c25\u2103\u3001800 mA cm-2<\/sup>\u6761\u4ef6\u4e0b\uff0cCoPc@HC\/Cu\u4e32\u8054\u7535\u6781\u4e0a\u7684CO2<\/sub>RR\u4ea7\u7269\u548cSPCE\u7684FE\u503c\u3002<\/p>\n \uff08i\uff09\u572825\u2103\u7684\u6d41\u52a8\u6c60\u4e2d\uff0c\u5728\u9178\u6027\u7f13\u51b2\u7535\u89e3\u6db2\u4e2d\uff0cCoPc@HC\/Cu\u4e32\u8054\u7535\u6781\u548c\u94dc\u7535\u6781\u4e0aCO2<\/sub>RR\u4ea7\u7269\u7684\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n \uff08j\uff09\u6700\u5148\u8fdb\u7535\u6781\u7684\u76f8\u6bd4\uff0cCoPc@HC\/(Cu+CoPc@HC)\u4e32\u8054\u7535\u6781\u7684SPCE\u3001FE\u548cC2+<\/sub>\u90e8\u5206\u7535\u6d41\u5bc6\u5ea6\u3001\u4e59\u70ef\u7684\u90e8\u5206\u7535\u6d41\u5bc6\u5ea6\u4ee5\u53caCO2<\/sub>\u5230\u4e59\u70ef\u7684\u8f6c\u5316\u7387\u3002<\/p>\n <\/p>\n \u56fe<\/strong>4\u00a0 DFT<\/strong>\u8ba1\u7b97\u548c\u539f\u4f4d\u62c9\u66fc\u6d4b\u91cf<\/strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n \uff08a\uff09\u5728CoN4<\/sub>-C\/Cu\u4e32\u8054\u7535\u6781\u548c\u94dc\u7535\u6781\u4e0a\u7684CO2<\/sub>RR\u81ea\u7531\u80fd\u56fe\u3002<\/p>\n \uff08b\uff09\u4ece\u4e00\u6c27\u5316\u78b3\u5230\u4e59\u70ef\u7684\u5173\u952e\u4e2d\u95f4\u4ea7\u7269\u7684\u76f8\u5e94\u539f\u5b50\u6784\u578b\u3002<\/p>\n \uff08c-d\uff0925\u2103\u4e0d\u540c\u7535\u4f4d\u4e0b\u94dc\u7535\u6781\u548cCoPc\/Cu\u4e32\u8054\u7535\u6781\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n \uff08e\uff0925\u2103\u65f6\u94dc\u8868\u9762\u9ad8CoPc\u8986\u76d6\u7387\u7684CoPc\/Cu\u4e32\u8054\u7535\u6781\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n \uff08f\uff09CoPc\/Cu\u4e32\u8054\u7535\u6781\u572825\u2103\u65f6\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\uff0c\u8868\u660eCoPc\u5728Cu\u8868\u9762\u6709\u56e2\u805a\u3002<\/p>\n <\/p>\n \u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n \u672c\u7814\u7a76\u63a2\u7a76\u4e86\u5982\u4f55\u5728\u94dc\u8868\u9762\u5bcc\u96c6CO\uff0c\u4ee5\u6291\u5236HER\u5e76\u4fc3\u8fdb\u9178\u6027CO2<\/sub>RR\u4e2d\u591a\u78b3\uff08C2+<\/sub>\uff09\u4ea7\u7269\u7684\u5f62\u6210\u3002\u5305\u62ec\u5c06CO2<\/sub>\u5230C2+<\/sub>\u7684\u603b\u53cd\u5e94\u89e3\u8026\u4e3a\u4e24\u4e2a\u6b65\u9aa4\uff0c\u5373CO2<\/sub>\u5230CO\u548cCO\u5230C2+<\/sub>\uff0c\u6bcf\u4e2a\u6b65\u9aa4\u90fd\u5728\u96c6\u6210\u4e32\u8054\u50ac\u5316\u5242\u4e2d\u5b9e\u73b0\u3002\u8fd9\u6837\uff0c\u5728800 mA cm-2<\/sup>\u7684\u6761\u4ef6\u4e0b\uff0cC2<\/sub>H4<\/sub> FE\u4e3a61%\uff0cC2+<\/sub> FE\u4e3a82%\uff0c\u540c\u65f6H2<\/sub> FE\u4fdd\u6301\u5728<10%\u5de6\u53f3\u3002\u8be5\u7cfb\u7edf\u7684C2<\/sub>H4<\/sub>\u80fd\u6548\u4e3a16%\uff0c\u6bd4\u4e4b\u524d\u62a5\u9053\u7684\u9178\u6027CO2<\/sub>\u5230C2<\/sub>H4<\/sub>\u7684\u9ad8\u6548\u7535\u5408\u6210\u63d0\u9ad8\u4e86\u4e24\u500d\u3002\u8be5\u4e32\u8054\u9178\u6027CO2<\/sub>RR\u7cfb\u7edf\u5728800 mA cm-2<\/sup>\u7684\u6761\u4ef6\u4e0b\uff0cSPCE\u8fbe\u523090%\uff0cC2<\/sub>H4<\/sub> FE \u8fbe\u523055%\uff0cC2+<\/sub>\u603bFE\u8fbe\u523076%\u3002\u5206\u6790\u8868\u660e\uff0c\u4e0e\u6700\u5148\u8fdb\u7684\u78b1\u6027\/\u4e2d\u6027\/\u9178\u6027\u7cfb\u7edf\u76f8\u6bd4\uff0c\u8be5\u4e32\u8054\u7cfb\u7edf\u5177\u6709\u8f83\u4f4e\u7684C2<\/sub>H4<\/sub>\u751f\u4ea7\u80fd\u8017\u6210\u672c\u3002<\/p>\n <\/p>\n<\/p>\n
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