{"id":256451,"date":"2023-12-09T06:42:47","date_gmt":"2023-12-08T22:42:47","guid":{"rendered":"\/\/m.iemloyee.com\/?p=256451"},"modified":"2023-12-08T21:47:32","modified_gmt":"2023-12-08T13:47:32","slug":"%e4%b8%ad%e7%a7%91%e5%a4%a7%e9%99%88%e7%bb%b4%e3%80%81%e8%8b%8f%e5%a4%a7%e8%83%a5%e7%87%95%e3%80%81%e5%bc%a0%e6%85%8e%e7%a5%a5jacs-angew-%e5%9f%ba%e4%ba%8e%e6%9c%89%e6%9c%ba%e5%a4%9a%e5%ad%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=256451","title":{"rendered":"\u4e2d\u79d1\u5927\u9648\u7ef4\u3001\u82cf\u5927\u80e5\u71d5\u3001\u5f20\u614e\u7965JACS & Angew: \u57fa\u4e8e\u6709\u673a\u591a\u5b54\u6750\u6599\u7eb3\u7c73\u9650\u57df\u4f5c\u7528\u7684\u53ef\u5145\u7535\u9502-\u6c2f\u6c14\u7535\u6c60"},"content":{"rendered":"
2023\u5e7412\u67085\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u9648\u7ef4\u6559\u6388\u8054\u5408\u82cf\u5dde\u5927\u5b66\u5f20\u614e\u7965\u526f\u6559\u6388\uff0c\u5728J. Am. Chem. Soc. \u548cAngew. Chem. Inter. Ed.\u671f\u520a\u4e0a\u540c\u65e5\u53d1\u8868\u9898\u4e3a Enrichment of Chlorine in Porous Organic Nanocages for High-Performance Rechargeable Lithium\u2013Chlorine Batteries\u548cOrganocatalytic Lithium Chloride Oxidation by Covalent Organic Frameworks for Rechargeable Lithium\u2013Chlorine Batteries\u7684\u7814\u7a76\u8bba\u6587\u3002\u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u4e86\u4e24\u79cd\u529f\u80fd\u5316\u7684\u6709\u673a\u591a\u5b54\u6750\u6599\u4f5c\u7535\u6781\uff0c\u501f\u52a9\u6709\u673a\u591a\u5b54\u6750\u6599\u7684\u7eb3\u7c73\u9650\u57df\u4f5c\u7528\uff0c\u5b9e\u73b0\u4e86\u9502-\u6c2f\u6c14\u4e8c\u6b21\u7535\u6c60\u7684\u9ad8\u6bd4\u5bb9\u91cf\uff08\uff1e3500 mAh\/g\uff09\u3001\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u4f4e\u6e29\u5de5\u4f5c\u7b49\u6027\u80fd\u3002<\/p>\n
<\/p>\n
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\u53ef\u5145\u7535Li-Cl2<\/sub>\u7535\u6c60\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u5bbd\u5de5\u4f5c\u6e29\u5ea6\u8303\u56f4\u548c\u9ad8\u5b89\u5168\u6027\u7b49\u4f18\u52bf\uff0c\u662f\u6781\u5177\u53d1\u5c55\u6f5c\u529b\u7684\u65b0\u578b\u7535\u6c60\u4f53\u7cfb\u3002\u7136\u800c\uff0cLi-Cl2<\/sub>\u7535\u6c60\u9762\u4e34\u4e00\u4e9b\u91cd\u8981\u6311\u6218\uff0c\u4e00\u662f\u7535\u6781\u6750\u6599\u5bf9Cl2<\/sub>\u7684\u4f5c\u7528\u529b\u6bd4\u8f83\u5f31\uff0c\u5bfc\u81f4\u653e\u7535\u8fc7\u7a0b\u4e2dCl2<\/sub>\u4f9b\u5e94\u4e0d\u8db3\uff0c\u7535\u6c60\u653e\u7535\u6bd4\u5bb9\u91cf\u964d\u4f4e\uff1b\u53e6\u5916\uff0c\u672a\u7ed3\u5408\u7684Cl2<\/sub>\u7684\u7a7f\u68ad\u6548\u5e94\u4f1a\u5bfc\u81f4\u7535\u6c60\u5bb9\u91cf\u8870\u51cf\uff1b\u4e8c\u662f\u5728\u518d\u5145\u7535\u8fc7\u7a0b\u4e2d\u4ece\u56fa\u4f53LiCl\u5230\u6c14\u6001Cl2<\/sub>\u7684\u6c27\u5316\u8fc7\u7a0b\u975e\u5e38\u7f13\u6162\uff0c\u8fdb\u800c\u5f15\u8d77\u7535\u89e3\u6db2\u53d1\u751f\u5206\u89e3\u7b49\u526f\u53cd\u5e94\uff0c\u964d\u4f4e\u7535\u6c60\u53ef\u9006\u6027\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u80fd\u591f\u6355\u83b7Cl2<\/sub>\u5206\u5b50\uff0c\u50ac\u5316LiCl\u5206\u89e3\u7684\u6b63\u6781\u6750\u6599\u5bf9\u4e8e\u5b9e\u73b0\u9ad8\u6027\u80fd\u9502-\u6c2f\u6c14\u4e8c\u6b21\u7535\u6c60\u81f3\u5173\u91cd\u8981\u3002<\/p>\n \u4e3a\u4e86\u63d0\u5347Li-Cl2<\/sub>\u7535\u6c60\u7684\u653e\u7535\u6bd4\u5bb9\u91cf\u548c\u5e93\u4f26\u6548\u7387\uff0c\u7814\u7a76\u4eba\u5458\u9996\u5148\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4e00\u79cd\u4e9a\u80fa\u529f\u80fd\u5316\u591a\u5b54\u6709\u673a\u7eb3\u7c73\u7b3c\uff08POC\uff09\u6765\u5bcc\u96c6Cl2<\/sub>\u5206\u5b50\u3002\u57fa\u4e8e\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff0cPOC\u4e2d\u7684\u4e9a\u80fa\u57fa\u56e2\u4f4d\u70b9\u4e0eCl2<\/sub>\u5206\u5b50\u5f3a\u70c8\u76f8\u4e92\u4f5c\u7528\uff0c\u4fc3\u8fdbCl2<\/sub>\u7684\u5feb\u901f\u6355\u83b7\u5e76\u5c01\u88c5\u5728\u7eb3\u7c73\u7b3c\u4e2d\u3002\u5f97\u76ca\u4e8ePOC\u5bf9Cl2<\/sub>\u5206\u5b50\u7684\u7eb3\u7c73\u9650\u57df\u4f5c\u7528\uff0c\u4f7f\u7528POC\u7684Li-Cl2<\/sub>\u7535\u6c60\u7684\u8f93\u51fa\u6bd4\u5bb9\u91cf\u663e\u8457\u63d0\u9ad8\uff0c\u57284000 mAh\/g\u7684\u8d85\u9ad8\u653e\u7535\u6bd4\u5bb9\u91cf\u4e0b\u80fd\u5b9e\u73b0\u63a5\u8fd1100% \u5e93\u4f26\u6548\u7387\uff08\u56fe2\uff09\u3002<\/p>\n \u56fe2. \u4e9a\u80fa\u529f\u80fd\u5316\u591a\u5b54\u6709\u673a\u7eb3\u7c73\u7b3c\uff08POC\uff09\u7684\u8868\u5f81\u53ca\u7535\u6c60\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n \u8fdb\u4e00\u6b65\uff0c\u89e3\u51b3LiCl\u6c27\u5316\u8fc7\u7a0b\u7f13\u6162\u95ee\u9898\u5bf9\u4e8e\u63d0\u9ad8Li-Cl2<\/sub>\u7535\u6c60\u7684\u53ef\u9006\u6027\u81f3\u5173\u91cd\u8981\u3002\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u4eba\u5458\u81f4\u529b\u4e8e\u5f15\u5165\u6709\u673a\u50ac\u5316\u5242\u6765\u4fc3\u8fdbCl–<\/sup>\u5230Cl2<\/sub>\u7684\u6c27\u5316\u3002\u4f8b\u5982\uff0c\u674e\u4e9a\u680b\u9662\u58eb\u56e2\u961f\u8bbe\u8ba1\u4e86\u4e00\u79cd\u5177\u6709\u9170\u80fa\u5b98\u80fd\u56e2\u7684\u6709\u673a\u50ac\u5316\u5242\uff0c\u572810 kA\/m2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u2009\uff0cCl–<\/sup>\u7684\u6c27\u5316\u8fc7\u7535\u4f4d\u4ec5\u4e3a89\u2009mV\uff0c\u4e3a\u5f00\u53d1\u6709\u673a\u50ac\u5316\u5242\u6765\u964d\u4f4eCl–<\/sup>\u5230Cl2<\/sub>\u7684\u6c27\u5316\u80fd\u5792\u63d0\u4f9b\u7406\u8bba\u6307\u5bfc\uff08Nature, 2023, 617, 519\uff09\u3002\u5728\u6b64\uff0c\u4f5c\u8005\u63a2\u7d22\u4e86\u57fa\u4e8e\u6709\u673a\u50ac\u5316\u4f5c\u7528\u7684COF\u7535\u6781\u6750\u6599\uff0c\u901a\u8fc7\u5728COF\u5b54\u9053\u7684\u9650\u57df\u7a7a\u95f4\u5185\uff0c\u52a0\u901fLiCl\u5411Cl2<\/sub>\u7684\u6c27\u5316\u52a8\u529b\u5b66\u6765\u589e\u5f3aLi-Cl2<\/sub>\u7535\u6c60\u7684\u53ef\u9006\u6027\u3002<\/p>\n \u7814\u7a76\u4eba\u5458\u53c8\u8bbe\u8ba1\u4e86\u4e00\u79cd\u6c28\u57fa\u529f\u80fd\u5316\u7684COF\u7eb3\u7c73\u6750\u6599\uff08COF-NH2<\/sub>\uff09\uff0c\u5e76\u5c06\u5176\u5e94\u7528\u4e8eLi-Cl2<\/sub>\u7535\u6c60\uff08\u56fe3\uff09\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\u5f15\u5165COF-NH2<\/sub>\u663e\u8457\u964d\u4f4e\u4e86LiCl\u7684\u5206\u89e3\u52bf\u5792\u3002\u4e3a\u4e86\u63a2\u7a76\u6709\u673a\u50ac\u5316\u5242\u7684\u76ca\u5904\uff0c\u91c7\u7528COF-NH2<\/sub>\u7ec4\u88c5\u7684Li-Cl2<\/sub>\u7535\u6c60\u57281500 mA\/g\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8fc7\u7535\u4f4d\u964d\u4f4e\u4e860.21 V\uff0c\u653e\u7535\u5bb9\u91cf\u63d0\u9ad8\u52303500 mAh\/g\uff0cLiCl\u7684\u5229\u7528\u7387\u63d0\u9ad8\u523081.4%\uff0c\u6bd4\u76ee\u524d\u6587\u732e\u6700\u9ad8\u62a5\u9053\u503c\u9ad8\u51fa18.4 %\uff08\u56fe4\uff09\u3002\u540c\u65f6\uff0c\u8be5\u7535\u6c60\u5728-20 \u2103\u4f4e\u6e29\u4e0b\u4f9d\u7136\u53ef\u4ee5\u7a33\u5b9a\u5de5\u4f5c\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u52a0\u901fLiCl\u7684\u6c27\u5316\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6548\u7684\u6709\u673a\u50ac\u5316\u5242\uff0c\u5e76\u4e3a\u5f00\u53d1\u9ad8\u6027\u80fdLi-Cl2<\/sub>\u7535\u6c60\u63d0\u4f9b\u4e86\u65b0\u7684\u89c1\u89e3\u3002<\/p>\n \u56fe3. COF-NH2<\/sub>\u6750\u6599\u7684\u7ed3\u6784\u8868\u5f81\u53ca\u6709\u673a\u50ac\u5316\u673a\u7406\u3002<\/p>\n \u56fe4. \u91c7\u7528COF-NH2<\/sub>\u7ec4\u88c5\u7684Li-Cl2<\/sub>\u7535\u6c60\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n \u82cf\u5dde\u5927\u5b66\u80fd\u6e90\u5b66\u9662\u8bb2\u5e08\u80e5\u71d5\u535a\u58eb\u4e3a\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662\u9648\u7ef4\u6559\u6388\u548c\u82cf\u5dde\u5927\u5b66\u6750\u5316\u90e8\u5f20\u614e\u7965\u526f\u6559\u6388\u4e3a\u8be5\u8bba\u6587\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u79d1\u6280\u90e8\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u4e2d\u592e\u9ad8\u6821\u57fa\u672c\u79d1\u7814\u4e1a\u52a1\u8d39\u4e13\u9879\u8d44\u91d1\u7684\u8d44\u52a9\u3002<\/p>\n \u8bba\u6587\u4fe1\u606f\uff1a<\/strong><\/p>\n 1.Enrichment of Chlorine in Porous Organic Nanocages for High-Performance Rechargeable Lithium\u2013Chlorine Batteries ,Yan Xu, Shenxiang Zhang*, Mingming Wang, Yahan Meng, Zehui Xie, Lidong Sun, Cheng Huang, and Wei Chen*, J.Chem. Soc. DOI: 10.1021\/jacs.3c11726<\/p>\n https:\/\/doi.org\/10.1021\/jacs.3c11726<\/a><\/p>\n 2.Organocatalytic Lithium Chloride Oxidation by Covalent Organic Frameworks for Rechargeable Lithium\u2013Chlorine Batteries, Yan Xu, Mingming Wang, Muhammad Sajid, Yahan Meng, Zehui Xie, Lidong Sun, Jian Jin, Wei Chen*<\/sup>, Shenxiang Zhang*<\/sup>, Angew. Chem. Inter. Ed. DOI: 10.1002\/anie.202315931<\/p>\n https:\/\/doi.org\/10.1002\/anie.202315931<\/a><\/p>\n \u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n \u9648\u7ef4<\/strong>\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5e94\u7528\u5316\u5b66\u7cfb\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u5408\u80a5\u5fae\u5c3a\u5ea6\u7269\u8d28\u79d1\u5b66\u56fd\u5bb6\u7814\u7a76\u4e2d\u5fc3\u6559\u6388\u30022008\u5e74\u4e8e\u5317\u4eac\u79d1\u6280\u5927\u5b66\u83b7\u6750\u6599\u7269\u7406\u5b66\u58eb\u5b66\u4f4d\uff1b2013\u5e74\u4e8e\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66\u83b7\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u535a\u58eb\u5b66\u4f4d\uff1b2014-2018\u5e74\u4e8e\u65af\u5766\u798f\u5927\u5b66\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff1b2018-2019\u5e74\u5728EEnotech\u516c\u53f8\u62c5\u4efb\u79d1\u5b66\u5bb6\uff1b2019\u5e747\u6708\u5165\u804c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\uff0c\u4e13\u6ce8\u4e8e\u5927\u89c4\u6a21\u50a8\u80fd\u7535\u6c60\u3001\u7535\u50ac\u5316\u7b49\u7814\u7a76\u3002\u72ec\u7acb\u5efa\u7ec4\u4ee5\u6765\uff0c\u4f5c\u4e3a(\u5171\u540c)\u901a\u8baf\u4f5c\u8005\u5728Chemical Reviews, Nature Communications (2), Joule, Journal of the American Chemical Society (3), Angewandte Chemie International Edition (4), Advanced Materials (3), Energy & Environmental Science, Advanced Energy Materials (4), Advanced Functional Materials, Nano Letters (9), ACS Nano, ACS Catalysis, eScience (2), Energy Storage Materials (6) \u7b49\u56fd\u9645\u671f\u520a\u53d1\u8868\u5b66\u672f\u8bba\u658750\u4f59\u7bc7\uff0c\u8bba\u6587\u603b\u88ab\u5f1511000\u4f59\u6b21\uff0cH\u56e0\u5b5051\u3002\u7814\u7a76\u6210\u679c\u83b7\u5f97\u7f8e\u56fd\u4e13\u52295\u9879\uff0c\u4e2d\u56fd\u53d1\u660e\u4e13\u522920\u4f59\u9879\u3002\u62c5\u4efbeScience, Nano Research Energy, Energy Materials Advances\u7b49\u591a\u4e2a\u6742\u5fd7\u7684\u9752\u5e74\u7f16\u59d4\u3002<\/p>\n \u9648\u7ef4\u8bfe\u9898\u7ec4\u7f51\u9875\uff1a<\/strong>http:\/\/staff.ustc.edu.cn\/~weichen1<\/a><\/p>\n \u3010\u56e2\u961f\u62db\u8058\u3011<\/strong><\/p>\n \u9648\u7ef4\u8bfe\u9898\u7ec4\u76ee\u524d\u62df\u62db\u65361\u4f4d\u7279\u4efb\u526f\u7814\u7a76\u5458\uff0c2-3\u4f4d\u535a\u58eb\u540e\uff0c1-2\u4f4d\u535a\u58eb\u751f\uff0c1\u4f4d\u7855\u58eb\u751f\u548c\u82e5\u5e72\u4f4d\u5de5\u7a0b\u5e08\uff08\u5b66\u5386\u4e0d\u9650\uff09\u3002\u8bf7\u7533\u8bf7\u8005\u5c06\u4e2a\u4eba\u7b80\u5386\u7b49\u6750\u6599\u53d1\u9001\u7ed9\u9648\u7ef4\u8001\u5e08\uff08weichen1@ustc.edu.cn<\/a>\uff09\uff0c\u90ae\u4ef6\u4ee5\u201c\u804c\u4f4d\u7533\u8bf7+\u59d3\u540d\u201d\u547d\u540d\u3002<\/p>\n","protected":false},"excerpt":{"rendered":" 2023\u5e7412\u67085\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u9648\u7ef4\u6559\u6388\u8054\u5408\u82cf\u5dde\u5927\u5b66\u5f20\u614e\u7965\u526f\u6559\u6388\uff0c\u5728J. Am. Chem. Soc. \u548cAngew. Chem. Inter. 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