{"id":25608,"date":"2016-07-09T08:00:40","date_gmt":"2016-07-09T00:00:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=25608"},"modified":"2016-07-09T16:55:02","modified_gmt":"2016-07-09T08:55:02","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81jacs-6%e6%9c%88%e5%8d%81%e5%a4%a7%e7%b2%be%e9%80%89%e7%a7%91%e7%a0%94%e6%88%90%e6%9e%9c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=25608","title":{"rendered":"\u9876\u520a\u52a8\u6001\uff5cJACS\uff1a6\u6708\u6750\u6599\u524d\u6cbf\u5341\u5927\u7cbe\u9009\u79d1\u7814\u6210\u679c"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-25697\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/11-7.jpg\" alt=\"Journal of the American Chemical Society\" width=\"700\" height=\"177\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/11-7.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/11-7-300x76.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" 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2016\u5e746\u6708\u524d\u6cbf\u7cbe\u9009\u79d1\u7814\u6210\u679c\uff1a<strong>\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240<\/strong>\u2014\u2014\u5229\u7528Diels-Alder\u53cd\u5e94\u6210\u529f\u5b9e\u73b0\u5bf9\u77f3\u58a8\u70ef\u7684\u5b9a\u70b9\u56fe\u6848\u5316\u4fee\u9970\uff1b<strong>\u52a0\u5229\u798f\u5c3c\u4e9a\u5927\u5b66<\/strong>\u2014\u2014\u62a5\u9053\u4e86\u4e00\u79cd\u5229\u7528\u5206\u5b50\u8868\u9762\u529f\u80fd\u5316\u7684\u65b9\u6cd5\u6765\u8c03\u8282\u7eb3\u7c73\u91d1\u9897\u7c92\u7535\u50ac\u5316\u5242\u7528\u4e8e\u5c06CO<sub>2<\/sub>\u8fd8\u539f\u6210CO\u7684\u6280\u672f\uff1b<strong>\u829d\u52a0\u54e5\u5927\u5b66<\/strong>\u2014\u2014\u4eceCdCl<sub>3<\/sub><sup>&#8211;<\/sup>\u5305\u8986\u7684CdTe\u7eb3\u7c73\u6676\u6eb6\u6db2\u4e2d\u5904\u7406\u5f97\u5230\u8d85\u8584\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\uff0c\u5e76\u5bf9\u5176\u4e2dCdCl<sub>3<\/sub><sup>&#8211;<\/sup>\u914d\u4f53\u7684\u589e\u5f3a\u4f5c\u7528\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\uff1b<strong>\u9999\u6e2f\u4e2d\u6587\u5927\u5b66<\/strong>\u2014\u2014\u63ed\u793a\u4e86\u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\u5728\u6291\u5236\u9502-\u6c27\u7535\u6c60\u5145\u7535\u4e0d\u7a33\u5b9a\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\uff1b<strong>\u829d\u52a0\u54e5\u5927\u5b66<\/strong>\u2014\u2014\u901a\u8fc7\u5408\u7406\u8bbe\u8ba1\u5236\u5907\u4e86\u4e00\u7c7b\u591a\u5b54\u5171\u8f6d\u7684\u805a\u5408\u7269\uff08PCP\uff09\u5e76\u5b9e\u73b0\u4e86\u5149\u89e3\u6c34\u5236\u6c22\uff1b<strong>\u5251\u6865\u5927\u5b66<\/strong>\u2014\u2014\u5bf9\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u751f\u957f\u4ee5\u53ca\u7845\u7535\u6781\u4e2d\u5bb9\u91cf\u635f\u5931\u7684\u7814\u7a76\uff1b<strong>\u592a\u5e73\u6d0b\u897f\u5317\u56fd\u5bb6\u5b9e\u9a8c\u5ba4<\/strong>\u2014\u2014\u5bf9\u7528\u4e8e\u7535\u50ac\u5316\u5236\u6c22\u7684\u77ac\u6001\u94b4\u6c22\u5316\u7269\u4e2d\u95f4\u4f53\u7684\u7535\u5316\u5b66\u68c0\u6d4b\u7814\u7a76\uff1b<strong>\u6b66\u6c49\u5927\u5b66<\/strong>\u2014\u2014\u6210\u529f\u5408\u6210\u51fa\u4e86\u4e16\u754c\u4e0a\u7b2c\u4e00\u4e2a\u4e8c\u7ef4\u8d85\u6709\u5e8f\u7ed3\u6784\u6750\u6599\uff082DSOS\uff09\uff1b<strong>\u4e2d\u56fd\u79d1\u5b66\u9662\u534a\u5bfc\u4f53\u7814\u7a76\u6240<\/strong>\u2014\u2014\u5bf9\u57fa\u4e8eTiO<sub>2<\/sub>\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u5feb\u7535\u5b50\u4f20\u8f93\u7684\u539f\u7406\u63ed\u793a\uff1b<strong>\u5fb7\u514b\u8428\u65af\u5927\u5b66<\/strong>\u2014\u2014\u57fa\u4e8e\u7eb3\u7c73\u626b\u63cf\u7535\u5316\u5b66\u663e\u5fae\u955c\u7684\u5355\u94c2\u7eb3\u7c73\u7c92\u5b50\u7535\u50ac\u5316\u6d3b\u6027\u7814\u7a76\u3002<\/p>\n<p><strong>1\u3001\u5229\u7528<\/strong><strong>Diels-Alder<\/strong><strong>\u53cd\u5e94\u5bf9\u77f3\u58a8\u70ef\u8fdb\u884c\u5b9a\u70b9\u56fe\u6848\u5316\u4fee\u9970<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-25610 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/01.jpg\" alt=\"01\" width=\"500\" height=\"471\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/01.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/01-300x283.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe1\u00a0\u77f3\u58a8\u70ef\u5b9a\u70b9\u56fe\u6848\u5316\u4fee\u9970\u539f\u7406\u793a\u610f\u56fe<\/strong><\/p>\n<p>\u5229\u7528\u5316\u5b66\u6cd5\u4fee\u9970\u77f3\u58a8\u70ef\u8868\u9762\u4ece\u800c\u5f97\u5230\u5177\u6709\u7279\u6b8a\u6027\u80fd\u7684\u77f3\u58a8\u70ef\u662f\u4e00\u79cd\u975e\u5e38\u5177\u6709\u524d\u666f\u7684\u4fee\u9970\u65b9\u6cd5\u3002<\/p>\n<p>\u4e2d\u79d1\u9662\u5316\u5b66\u7814\u7a76\u6240\u4e07\u7acb\u9a8f\u9662\u58eb\uff08\u901a\u8baf\u4f5c\u8005\uff09\u3001\u738b\u680b\u7814\u7a76\u5458\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u9648\u4f20\u5cf0\u7814\u7a76\u5458\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7684\u56e2\u961f\u8bbe\u8ba1\u4e86\u4e00\u79cd\u8fd0\u7528Diels-Alder\u5b9a\u70b9\u70b9\u51fb\u53cd\u5e94\u7ed3\u5408\u5177\u6709\u4e24\u4e2a\u4e8c\u6c22\u8418\u9aa8\u67b6\u7684\u987a\u5f0f\u70ef\u70c3\u6765\u5b9e\u73b0\u77f3\u58a8\u70ef\u7684\u8868\u9762\u4fee\u9970\u3002\u800c\u5c06\u4e8c\u70ef\u57fa\u8054\u7ed3\u5230\u975e\u5e73\u9762\u5206\u5b50\u7ed3\u6784\u4e2d\u5f97\u5230\u7684\u987a\u5f0f\u6784\u50cf\u5219\u53ef\u4ee5\u5b9e\u73b0\u77f3\u58a8\u70ef\u4e0e\u70ef\u57fa\u4e4b\u95f4\u5feb\u901f\uff08\u6307\u7684\u662f\u7ea65 min\uff09\u5730\u53d1\u751fDiels-Alder\u53cd\u5e94\u3002\u56fe\u6848\u5316\u7684\u77f3\u58a8\u70ef\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u901a\u8fc7\u5ba4\u6e29\u4e0b\u5728\u7f9f\u57fa\u53d6\u4ee3\u7684\u987a\u5f0f\u4e8c\u70ef\u6eb6\u6db2\u4e2d\u6d78\u6ce1\u7532\u57fa\u4e19\u70ef\u9178\u7532\u916f\uff08PMMA\uff09\u4fee\u9970\u7684\u77f3\u58a8\u70ef\u6765\u5b9e\u73b0\u3002\u800c\u5176\u4e2d\u4fee\u9970\u7684\u7a0b\u5ea6\uff0c\u53ef\u4ee5\u8fdb\u4e00\u6b65\u901a\u8fc7\u63a7\u5236\u8f93\u51fa\u66f4\u9ad8\u7684\u53cd\u5e94\u6e29\u5ea6\u6765\u63a7\u5236\u3002\u6700\u65b0\u7684\u7814\u7a76\u6210\u679c\u63ed\u793a\u4e86\u77f3\u58a8\u70ef\u4fee\u9970\u8fc7\u7a0b\u4e2d\u5206\u5b50\u6784\u8c61\u6548\u5e94\u7684\u91cd\u8981\u8bc1\u636e\uff0c\u5e76\u4e14\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b80\u5355\u800c\u6709\u6548\u7684\u77f3\u58a8\u70ef\u529f\u80fd\u5316\u65b9\u6cd5\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b02209\" target=\"_blank\">Click and Patterned Functionalization of Graphene by Diels-Alder Reaction<\/a> \uff08Journal of the American Chemical Society\uff0c2016\uff0c DOI: 10.1021\/jacs.6b02209\uff09<\/p>\n<p><strong style=\"line-height: 1.5;\">2\u3001<\/strong><strong style=\"line-height: 1.5;\">\u4e00\u79cd\u5206\u5b50\u8868\u9762\u529f\u80fd\u5316\u7684\u65b9\u6cd5\u7528\u4e8e\u7535\u50ac\u5316\u5242\u7684\u8c03\u8282\u4f7f\u5176\u5177\u6709<\/strong><strong style=\"line-height: 1.5;\">CO<sub>2<\/sub><\/strong><strong style=\"line-height: 1.5;\">\u50ac\u5316\u8fd8\u539f\u6d3b\u6027<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-25614 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/02-01-1.jpg\" alt=\"02-01\" width=\"500\" height=\"158\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/02-01-1.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/02-01-1-300x95.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2\u00a0Au\u8868\u660e\u529f\u80fd\u5316\u7684\u539f\u7406\u793a\u610f\u56fe\u4ee5\u53ca\u50ac\u5316\u8fd8\u539fCO<sub>2<\/sub>\u7684\u793a\u610f\u56fe<\/strong><\/p>\n<p>\u5728\u53ef\u6301\u7eed\u80fd\u6e90\u7814\u7a76\u4e2d\uff0c\u5c06\u6e29\u5ba4\u6c14\u4f53\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e3a\u589e\u503c\u4ea7\u54c1\u662f\u4e00\u4e2a\u91cd\u8981\u7684\u6311\u6218\uff0c\u6b64\u5916\uff0c\u7eb3\u7c73\u6750\u6599\u4e2d\u5b58\u5728\u591a\u79cd\u591a\u6837\u6027\u80fd\u4e0d\u4e00\u7684\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u4e3a\u8be5\u79cd\u8f6c\u5316\u63d0\u4f9b\u6280\u672f\u652f\u6301\u3002<\/p>\n<p>\u52a0\u5229\u798f\u5c3c\u4e9a\u5927\u5b66\u7684\u6768\u57f9\u4e1c\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548cChristopher J. Chang\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u5229\u7528\u5206\u5b50\u8868\u9762\u529f\u80fd\u5316\u7684\u65b9\u6cd5\u6765\u8c03\u8282\u7eb3\u7c73\u91d1\u9897\u7c92\u7535\u50ac\u5316\u5242\u7528\u4e8e\u5c06CO<sub>2<\/sub>\u8fd8\u539f\u6210CO\u7684\u6280\u672f\u3002\u76f8\u5bf9\u4e8e\u7eaf\u7cb9\u7684\u7eb3\u7c73\u91d1\u9897\u7c92\u50ac\u5316\u5242\u5728\u540c\u6837\u7684\u4e2d\u6027\u6c34\u73af\u5883\u4e0b53%\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff0cN-\u6742\u73af\u5361\u5bbe\uff08NHC\uff09\u4fee\u9970\u7684\u7eb3\u7c73\u91d1\u9897\u7c92\u50ac\u5316\u5242\u5177\u6709\u5c06CO<sub>2<\/sub>\u8f6c\u5316\u6210CO\u66f4\u9ad8\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff0c\u5176\u6570\u503c\u9ad8\u8fbe83%\uff0c\u5e76\u4e14\u4fee\u9970\u540e\u6240\u80fd\u627f\u8f7d\u7684\u8fc7\u7535\u4f4d\u9ad8\u8fbe0.46V\uff0c\u662f\u539f\u6765\u7684\u7eb3\u7c73\u91d1\u9897\u7c92\u76847.6\u500d\u3002\u5728\u5854\u83f2\u5c14\u56fe\u5bf9\u4e8e\u6539\u53d8\u76f8\u5e94\u6570\u91cf\u7ea7\u7684\u7535\u6d41\u5bc6\u5ea6\u9700\u8981\u6539\u53d8\u7684\u7535\u4f4d\u7684\u6bd4\u8f83\u4e0a\uff0cNHC\u5361\u5bbe\u4fee\u9970\u7684\u7eb3\u7c73\u91d1\u9897\u7c92\u4e3a72 mV\/decade\u4e0e\u7eaf\u7cb9\u7684\u7eb3\u7c73\u91d1\u9897\u7c92\u4e3a138 mV\/decade\uff0c\u4e24\u8005\u76f8\u6bd4\uff0c\u8fdb\u4e00\u6b65\u8bf4\u660e\u4e86\u5206\u5b50\u914d\u4f53\u5bf9CO<sub>2<\/sub>\u8fd8\u539f\u673a\u5236\u7684\u5f71\u54cd\u3002\u8be5\u7814\u7a76\u6210\u679c\u8bf4\u660e\u4e86\u5206\u5b50\u8868\u9762\u529f\u80fd\u5316\u662f\u4f5c\u4e3a\u5bf9\u63a7\u5236\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u5c3a\u5bf8\u3001\u5f62\u72b6\u3001\u7ed3\u6784\u548c\u7f3a\u9677\u7684\u4e00\u79cd\u4e92\u8865\u673a\u5236\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b02878\" target=\"_blank\">A Molecular Surface Functionalization Approach to Tuning Nanoparticle Electrocatalysts for Carbon Dioxide Reduction<\/a> \uff08Journal of the American Chemical Society\uff0c 2016\uff0cDOI: 10.1021\/jacs.6b02209\uff09<\/p>\n<p><strong style=\"line-height: 1.5;\">3\u3001\u6e90\u4e8e<\/strong><strong style=\"line-height: 1.5;\">CdCl<sub>3<\/sub><sup>&#8211;<\/sup><\/strong><strong style=\"line-height: 1.5;\">\u5305\u8986\u7684<\/strong><strong style=\"line-height: 1.5;\">CdTe<\/strong><strong style=\"line-height: 1.5;\">\u7eb3\u7c73\u6676\u6eb6\u6db2\u7684\u8d85\u8584\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-25615 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/03-01.jpg\" alt=\"03-01\" width=\"500\" height=\"174\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/03-01.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/03-01-300x104.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>3 CdCl<sub>3<\/sub><sup>&#8211;<\/sup>\u5305\u8986\u7684CdTe\u7eb3\u7c73\u6676\u8584\u819c\u58a8\u6c34\u56fe\u53ca\u5176\u8f6c\u5316\u6548\u7387\u6d4b\u8bd5\u7ed3\u679c\u56fe<\/strong><\/p>\n<p>\u6eb6\u6db2\u8fc7\u7a0b\u7684CdTe\u592a\u9633\u80fd\u7535\u6c60\u4f7f\u7528CdTe\u7eb3\u7c73\u6676\u6d82\u8986\u5e94\u8be5\u53ef\u4ee5\u63d0\u4f9b\u66f4\u7ecf\u6d4e\u5b9e\u7528\u7684\u9014\u5f84\u5b9e\u73b0\u592a\u9633\u80fd\u7535\u6c60\u7684\u5927\u89c4\u6a21\u5236\u9020\u3002<\/p>\n<p>\u829d\u52a0\u54e5\u5927\u5b66\u7684Dmitri V. Talapin\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u5229\u7528CdCl<sub>3<\/sub><sup>&#8211;<\/sup>\u5305\u8986\u7684CdTe\u7eb3\u7c73\u6676\u58a8\u6c34\u4ece\u800c\u5f97\u5230\u4ee4\u4eba\u60ca\u5947\u7684\u8868\u660e\u5316\u5b66\u6027\u80fd\u3002\u5728\u8fd9\u79cd\u58a8\u6c34\u4e2d\uff0cCdCl<sub>3<\/sub><sup>&#8211;<\/sup>\u914d\u4f53\u5145\u5f53\u4e86\u8868\u9762\u914d\u4f53\u3001\u70e7\u7ed3\u52a9\u5242\u548c\u63ba\u6742\u5242\u7b49\u4e09\u79cd\u5c5e\u6027\u3002\u4ece\u8be5\u6eb6\u6db2\u4e2d\u5f97\u5230\u4e86\u9ad8\u8d28\u91cf\u7684\u8d85\u8584CdTe\u8fde\u7eed\u8584\u819c\uff0c\u800c\u8fd9\u5bf9\u4e8e\u4f20\u7edf\u7684\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6cd5\uff08CVD\uff09\u6765\u8bf4\u90fd\u662f\u4e00\u5927\u6311\u6218\u3002\u4e4b\u540e\uff0c\u4f7f\u7528\u826f\u6027\u6eb6\u5242\uff0c\u5728\u7a7a\u6c14\u4e2d\uff0c\u4ee5\u53ca\u6ca1\u6709CdCl<sub>2<\/sub>\u7684\u52a0\u5165\u4e0b\uff0c\u4ed6\u4eec\u4ece\u65b0\u7684\u58a8\u6c34\u4e2d\u5f97\u5230\u4e86\u4e00\u79cd\u70e7\u7ed3\u5b8c\u597d\u7684CdTe\u5438\u6536\u5c42\uff0c\u5e76\u4e14\u76f8\u5173\u6d4b\u8bd5\u8868\u660e\uff0c\u8be5\u79cd\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\u5177\u6709\u8d85\u8fc710%\u7684\u8f6c\u5316\u6548\u7387\uff0c\u6253\u7834\u4e86400 nm\u4ee5\u4e0b\u539a\u5ea6CdTe\u5438\u6536\u5c42\u8f6c\u5316\u6548\u7387\u7684\u8bb0\u5f55\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b03240\" target=\"_blank\">Solution-Processed, Ultrathin Solar Cells from CdCl<sub>3<\/sub><sup>&#8211;<\/sup> -capped CdTe Nanocrystals: The Multiple Roles of CdCl<sub>3<\/sub><sup>&#8211; <\/sup>Ligands<\/a> \uff08Journal of the American Chemical Society\uff0c2016\uff0cDOI: 10.1021\/jacs.6b03240\uff09<\/p>\n<p><strong style=\"line-height: 1.5;\">4\u3001<\/strong><strong style=\"line-height: 1.5;\">\u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\u5728\u6291\u5236\u9502<\/strong><strong style=\"line-height: 1.5;\">&#8211;<\/strong><strong style=\"line-height: 1.5;\">\u6c27\u7535\u6c60\u5145\u7535\u4e0d\u7a33\u5b9a\u4e0a\u7684\u91cd\u8981\u4f5c\u7528<\/strong><strong style=\"line-height: 1.5;\">\u00a0<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-25616 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/04-01.jpg\" alt=\"04-01\" width=\"500\" height=\"365\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/04-01.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/04-01-300x219.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>4 \u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\u8f6c\u5316\u8fc7\u7a0b\u539f\u7406\u56fe<\/strong><\/p>\n<p>\u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\u5df2\u7ecf\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u51cf\u5c11\u9502-\u6c27\uff08Li-O<sub>2<\/sub>\uff09\u7535\u6c60\u5145\u7535\u8fc7\u7a0b\u8fc7\u7535\u52bf\u3002<\/p>\n<p>\u9999\u6e2f\u4e2d\u6587\u5927\u5b66\u673a\u68b0\u4e0e\u81ea\u52a8\u5316\u7cfb\u7684\u5362\u6021\u541b\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u63ed\u793a\u4e86\u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\u5728\u6291\u5236\u9502-\u6c27\u7535\u6c60\u5145\u7535\u4e0d\u7a33\u5b9a\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\u3002\u5229\u7528\u5728\u7ebf\u6027\u7535\u5316\u5b66\u8d28\u8c31\u4e2d\u7684\u9ad8\u65f6\u95f4\u89e3\u51b3\u65b9\u6848\uff0c\u4ed6\u4eec\u8bc1\u5b9e\u4e86\u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\uff08\u5176\u4e2d\u5229\u7528\u6eb4\u5316\u9502\u4f5c\u4e3a\u4e00\u4e2a\u6a21\u578b\u7cfb\u7edf\uff09\u80fd\u591f\u6781\u5927\u5730\u51cf\u5c11\u6742\u8d28\u6c14\u4f53\u7684\u6325\u53d1\u5e76\u540c\u65f6\u63d0\u9ad8\u6c27\u6c14\u7684\u590d\u539f\u6548\u7387\u3002\u5229\u7528\u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\u5c06\u5145\u7535\u53cd\u5e94\u7684\u7535\u5316\u5b66\u8fc7\u7a0b\u8f6c\u4e3a\u5316\u5b66\u8fc7\u7a0b\uff0c\u53ef\u4ee5\u4e0d\u7ecf\u610f\u95f4\u7ed5\u8fc7\u8fc7\u6c27\u5316\u9502\uff08Li<sub>2<\/sub>O<sub>2<\/sub>\uff09\u8fc7\u7535\u6c27\u5316\u8fc7\u7a0b\u4e2d\u4ecb\u4f53\u95f4\u9ad8\u9891\u76f8\u4e92\u4f5c\u7528\u7684\u5f62\u6210\u3002\u8fd9\u79cd\u8f6c\u5316\u8fc7\u7a0b\u53ef\u4ee5\u51cf\u5c11\u9502-\u6c27\u7535\u6c60\u4e2d\u7535\u6781\u548c\u7535\u89e3\u8d28\u7684\u81ea\u653e\u5927\u964d\u89e3\u53cd\u5e94\u7684\u53d1\u751f\u3002\u4ed6\u4eec\u8fdb\u4e00\u6b65\u7684\u7814\u7a76\u8bc1\u5b9e\u4e86\u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\u5bf9\u8be5\u79cd\u7a33\u5b9a\u6027\u7684\u589e\u52a0\u5728\u9ad8\u9891\u5145\u7535\u60c5\u51b5\u4e0b\u53d8\u5f97\u66f4\u52a0\u5730\u660e\u663e\uff0c\u8fd9\u662f\u7531\u4e8e\u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\u7684\u5feb\u901f\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\u6240\u81f4\u3002\u540c\u65f6\uff0c\u4ed6\u4eec\u8fd8\u8bc1\u5b9e\u4e86\u5e94\u7528\u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\u4e0d\u4ec5\u53ef\u4ee5\u964d\u4f4e\u5145\u7535\u8fc7\u7a0b\u8fc7\u7535\u52bf\uff0c\u8fd8\u80fd\u6291\u5236\u9502-\u6c27\u7535\u6c60\u4e2d\u526f\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u4ece\u800c\u63d0\u9ad8\u5176\u5145\u7535\u6548\u7387\u3002\u4ed6\u4eec\u7684\u5de5\u4f5c\u8bc1\u660e\u4e86Li<sub>2<\/sub>O<sub>2<\/sub>\u7535\u6c27\u5316\u8fc7\u7a0b\u5411Li<sub>2<\/sub>O<sub>2<\/sub>\u6c27\u5316\u8fc7\u7a0b\u7684\u8f6c\u5316\u662f\u4e00\u79cd\u975e\u5e38\u6709\u5e94\u7528\u524d\u666f\u80fd\u591f\u540c\u65f6\u6291\u5236\u526f\u53cd\u5e94\uff0c\u5b9e\u73b0\u9502-\u6c27\u7535\u6c60\u4f4e\u7535\u4f4d\u5145\u7535\u7684\u65b9\u6848\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b01821\" target=\"_blank\">Critical role of redox mediator in suppressing charging instabilities of lithium-oxygen batteries<\/a> \uff08Journal of the American Chemical Society\uff0c2016\uff0c DOI: 10.1021\/jacs.6b01821\uff09<\/p>\n<p><strong>5\u3001\u00a0<\/strong><strong>\u5bf9\u591a\u5b54\u5171\u8f6d\u805a\u5408\u7269\u5149\u50ac\u5316\u5242\u7684\u5408\u7406\u8bbe\u8ba1\u53ca\u5176\u4e2d\u6b8b\u7559\u94af\u5728\u5149\u50ac\u5316\u5236\u6c22\u8fc7\u7a0b\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\u7814\u7a76<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-25617 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/05-01.jpg\" alt=\"05-01\" width=\"500\" height=\"440\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/05-01.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/05-01-300x264.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>5<\/strong> <strong>PCPs\u5149\u89e3\u6c34\u5236\u6c22\u539f\u7406\u793a\u610f\u56fe<\/strong><\/p>\n<p>\u53d1\u5c55\u9ad8\u6548\u50ac\u5316\u5242\u7528\u4e8e\u5149\u89e3\u6c34\u5236\u6c22\u662f\u4f20\u7edf\u592a\u9633\u80fd\u5e94\u7528\u8fd9\u4e00\u8bfe\u9898\u4e2d\u7684\u91cd\u5927\u6311\u6218\u3002<\/p>\n<p>\u829d\u52a0\u54e5\u5927\u5b66\u7684\u534e\u4eba\u79d1\u5b66\u5bb6\u4fde\u9646\u5e73\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u901a\u8fc7\u5408\u7406\u8bbe\u8ba1\u5236\u5907\u4e86\u4e00\u7c7b\u591a\u5b54\u5171\u8f6d\u7684\u805a\u5408\u7269\uff08PCP\uff09\u5e76\u5b9e\u73b0\u4e86\u5149\u89e3\u6c34\u5236\u6c22\u3002\u6b64\u79cd\u5177\u6709\u5171\u8f6d\u805a\u5408\u7269\u6210\u5206\u7684\u8bbe\u8ba1\u662f\u6a21\u4eff\u5929\u7136\u5149\u5408\u7cfb\u7edf\u7684\u6355\u5149\u673a\u5236\u540c\u65f6\u8fc7\u6e21\u91d1\u5c5e\u90e8\u5206\u662f\u4e3a\u4e86\u4fc3\u8fdb\u50ac\u5316\u5242\u7684\u6d3b\u6027\u3002\u7814\u7a76\u4eba\u5458\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u4e0d\u540c\u5149\u6355\u83b7\u80fd\u529b\u548c\u8fc7\u6e21\u91d1\u5c5e\u5421\u5576\u7ed3\u6d3b\u6027\u4f4d\u70b9\u7684PCPs\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u5177\u6709\u5421\u5576\u7ed3\u4f4d\u70b9\u7684PCPs\u7531\u4e8e\u53ef\u4ee5\u589e\u52a0\u5bf9\u5149\u7684\u5438\u6536\uff0c\u4ece\u800c\u5177\u6709\u66f4\u9ad8\u7684\u5149\u50ac\u5316\u6d3b\u6027\u3001\u66f4\u597d\u7684\u6da6\u6e7f\u6027\u3001\u66f4\u52a0\u6709\u5e8f\u7684\u5c40\u57df\u7ed3\u6784\u4ee5\u53ca\u6539\u8fdb\u7684\u7535\u8377\u5206\u79bb\u8fc7\u7a0b\u3002\u5176\u4e2d\uff0c\u5177\u6709\u5f3a\u5b8c\u5168\u5171\u8f6d\u7684\u7ed9\u4f53\u751f\u8272\u56e2DBD\u8868\u73b0\u51fa\u6700\u9ad8\u7684\u4ea7\u6c22\u6548\u7387\uff0c\u9ad8\u8fbe\u7ea633 \u03bcmol\/h\u3002\u8be5\u7ed3\u679c\u8868\u660e\uff0c\u5f3a\u7535\u5b50\u7ed9\u4f53\u548c\u5f31\u7535\u5b50\u53d7\u4f53\u4e4b\u95f4\u7684\u5171\u805a\u5165\u76f8\u540c\u7684\u805a\u5408\u7269\u94fe\uff0c\u5bf9\u53d1\u5c55\u9ad8\u6548\u5149\u50ac\u5316\u5242\u6765\u8bf4\u662f\u4e00\u79cd\u975e\u5e38\u6709\u7528\u7684\u65b9\u6848\u3002\u8fd9\u9879\u7814\u7a76\u540c\u65f6\u63ed\u793a\u4e86PCP\u7f51\u4e2d\u6b8b\u7559\u94af\u5176\u5b9e\u5728\u50ac\u5316\u6027\u80fd\u4e0a\u4e5f\u62c5\u5f53\u4e86\u975e\u5e38\u91cd\u8981\u7684\u89d2\u8272\u3002PCP\u5149\u50ac\u5316\u5242\u5236\u6c22\u7684\u6d3b\u6027\u53ef\u4ee5\u901a\u8fc7\u8d1f\u8f7d2wt%\u8d28\u91cf\u5206\u6570\u7684\u989d\u5916\u94af\u52a9\u50ac\u5316\u5242\uff0c\u4ece\u800c\u5728350 nm\u6ce2\u957f\u4e0b\u660e\u663e\u63d0\u9ad81.8%\u7684\u91cf\u5b50\u4ea7\u7387\uff0c\u8fdb\u4e00\u6b65\u5c06\u5236\u6c22\u6548\u7387\u63d0\u9ad8\u5230164 \u03bcmol\/h\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b03472\" target=\"_blank\">Rational Design of Porous Conjugated Polymers and Roles of Residual Palladium for Photocatalytic Hydrogen Production<\/a> \uff08Journal of the American Chemical Society\uff0c 2016\uff0c DOI: 10.1021\/jacs.6b03472\uff09<strong>\u00a0<\/strong><\/p>\n<p><strong style=\"line-height: 1.5;\">6\u3001<\/strong><strong style=\"line-height: 1.5;\">\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u751f\u957f\u4ee5\u53ca\u7845\u7535\u6781\u4e2d\u5bb9\u91cf\u635f\u5931\u7684\u7814\u7a76<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-25618 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/06-01.jpg\" alt=\"06-01\" width=\"500\" height=\"207\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/06-01.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/06-01-300x124.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>6 \u7535\u5316\u5b66\u591a\u5708\u6570\u5faa\u73af\u56fa\u6001\u6838\u78c1\u5171\u632f\u5149\u8c31\u6d4b\u8bd5\u6d4b\u8bd5\u7ed3\u679c<\/strong><\/p>\n<p>\u9ad8\u5bb9\u91cf\u9633\u6781\u6750\u6599Si\u7684\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u6027\u80fd\u53ef\u4ee5\u901a\u8fc7\u7535\u5316\u5b66\u591a\u5708\u6570\u5faa\u73af\u56fa\u6001\u6838\u78c1\u5171\u632f\u5149\u8c31\u6d4b\u8bd5\u76f8\u5e94\u7684Li\u3001F\u4ee5\u53caC\u8c31\u8fdb\u884c\u76d1\u6d4b\uff0c\u5176\u4e2dSEI\u53d7\u5230\u6709\u673a\u7269\u652f\u914d\u3002\u540c\u6838\u76f8\u5173\u6027\u5b9e\u9a8c\u88ab\u7528\u6765\u786e\u8ba4\u6709\u673a\u7269\u7247\u6bb5\uff0c\u5305\u62ec\u2212OCH<sub>2<\/sub>CH<sub>2<\/sub>O\u2212\u3001\u2212OCH<sub>2<\/sub>CH<sub>2<\/sub>\u2212\u3001\u2212OCH2CH<sub>3<\/sub>\u2212\u548c\u2212CH<sub>2<\/sub>CH<sub>3<\/sub>\u7b49\u4f4e\u805a\u7269\u4ee5\u53ca\u9502\u7684\u534a\u78b3\u9178\u76d0ROCO<sub>2<\/sub>Li\u548cRCO<sub>2<\/sub>Li\u7b49\u3002SEI\u7684\u751f\u957f\u4e0e\u589e\u52a0\u7535\u6781\u7684\u5f2f\u66f2\u7a0b\u5ea6\u6709\u5173\uff0c\u901a\u8fc7\u4f7f\u7528\u805a\u7126\u79bb\u5b50\u675f\u548c\u626b\u9762\u7535\u5b50\u663e\u5fae\u955c\u53ef\u4ee5\u89c2\u6d4b\u3002<\/p>\n<p>\u5251\u6865\u5927\u5b66Clare P. Grey\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u5efa\u7acb\u4e86\u4e00\u4e2a2\u9636\u7684\u5d4c\u9502\u5bb9\u91cf\u635f\u5931\u6a21\u578b\uff0c\u901a\u8fc7\u7814\u7a76\u53d1\u73b0\uff1a\u6700\u521d\uff0c\u5d4c\u9502\u5bb9\u91cf\u7a33\u5b9a\u5730\u51cf\u5c11\uff0cLi<sup>+<\/sup>\u4ee5\u4e00\u4e2a\u7a33\u5b9a\u7684\u901f\u7387\u88ab\u4e0d\u53ef\u9006\u5730\u6d88\u8017\uff0c\u540c\u65f6\uff0c\u53ef\u4ee5\u660e\u663e\u5730\u53d1\u73b0SEI\u7684\u751f\u957f\uff1b\u4e4b\u540e\uff0c\u5d4c\u9502\u5bb9\u91cf\u4f4e\u4e8e\u6700\u521d\u5bb9\u91cf\u768450%\uff0cSi\u7535\u6781\u4e2dLi\u7684\u51cf\u5c11\u5bfc\u81f4\u66f4\u5c11\u7684\u4f53\u79ef\u81a8\u80c0\u4e0e\u6536\u7f29\uff0c\u6700\u7ec8\u7a33\u5b9a\u5728Li<sup>+<\/sup>\u4e0d\u53ef\u9006\u6d88\u8017\u7684\u901f\u7387\u89e6\u5e95\uff0cSi\u7684SEI\u539a\u5ea6\u8d8b\u4e8e\u4fdd\u6301\u7a33\u5b9a\u3002\u7814\u7a76\u6210\u679c\u8868\u660e\uff0c\u5d4c\u9502\u5bb9\u91cf\u7684\u51cf\u5c11\u662f\u52a8\u529b\u5b66\u7684\u7ed3\u679c\uff0c\u7535\u6781\u5f2f\u66f2\u7a0b\u5ea6\u7684\u589e\u52a0\u6216\u591a\u6216\u5c11\u80fd\u591f\u9650\u5236\u7535\u6781\u5927\u90e8\u5206\u4e2dLi<sup>+<\/sup>\u7684\u6269\u6563\u3002\u5176\u4e2d\uff0c\u8868\u9762\u9650\u5236\u6269\u6563\u7684\u7ed3\u679c\u53ef\u4ee5\u660e\u663e\u5730\u4ece\u7535\u5316\u5b66\u5bb9\u91cf\u66f2\u7ebf\u4e2d\u5d4c\u9502\u8fc7\u7a0b\u7684\u53d8\u5316\u4e2d\u770b\u5230\u3002<strong>\u00a0<\/strong><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b02882\" target=\"_blank\">Solid Electrolyte Interphase Growth and Capacity Loss in Silicon Electrodes<\/a> \uff08Journal of the American Chemical Society\uff0c2016\uff0c DOI: 10.1021\/jacs.6b02882\uff09<\/p>\n<p><strong style=\"line-height: 1.5;\">7\u3001<\/strong><strong style=\"line-height: 1.5;\">\u5bf9\u7528\u4e8e\u7535\u50ac\u5316\u5236\u6c22\u7684\u77ac\u6001\u94b4\u6c22\u5316\u7269\u4e2d\u95f4\u4f53\u7684<\/strong><strong style=\"line-height: 1.5;\">\u7535\u5316\u5b66\u68c0\u6d4b\u7814\u7a76<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-25619 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/07-01.jpg\" alt=\"07-01\" width=\"500\" height=\"174\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/07-01.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/07-01-300x104.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>7 \u00a0\u4e24\u79cd\u4e2d\u95f4\u4f53\u7684\u7ed3\u6784\u56fe<\/strong><\/p>\n<p>\u5404\u79cd\u5404\u6837\u7684\u94b4\u914d\u5408\u7269\u5206\u5b50\u88ab\u7528\u4e8e\u7535\u50ac\u5316\u5236\u6c22\uff0c\u4f46\u662f\u5176\u4e2d\u5173\u952e\u7684\u94b4\u6c22\u5316\u7269\u4e2d\u95f4\u4f53\u7531\u4e8e\u5177\u6709\u975e\u5e38\u9ad8\u7684\u53cd\u5e94\u6d3b\u6027\u800c\u5e38\u5e38\u96be\u4ee5\u88ab\u68c0\u6d4b\u548c\u8868\u5f81\u3002<\/p>\n<p>\u592a\u5e73\u6d0b\u897f\u5317\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u5206\u5b50\u7535\u50ac\u5316\u4e2d\u5fc3\u7684Eric S. Wiedner\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u5229\u7528\u53ef\u53d8\u7684\u7ec4\u5408\u626b\u63cf\u901f\u7387\u5faa\u73af\u4f0f\u5b89\u6cd5\u548c\u6ce2\u8c37\u5206\u6790\u6cd5\uff08FOWA\uff09\u53ef\u4ee5\u7528\u4e8e\u68c0\u6d4b\u5229\u7528[Co<sup>II<\/sup>(PtBu<sub>2<\/sub>NPh<sub>2<\/sub>)(CH<sub>3<\/sub>CN)<sub>3<\/sub>]<sup>2+<\/sup> \u548c Co<sup>II<\/sup>(dmgBF<sub>2<\/sub>)<sub>2<\/sub>(CH<sub>3<\/sub>CN)<sub>2<\/sub>\u7535\u50ac\u5316\u5236\u6c22\u8fc7\u7a0b\u4e2d\u7684\u77ac\u6001Co<sup>\u2162<\/sup>H\u548cCo<sup>\u2161<\/sup>H\u4e2d\u95f4\u4f53\u3002\u4e24\u79cd\u60c5\u51b5\u4e0b\uff0c\u77ac\u6001\u50ac\u5316\u5242\u4e2d\u95f4\u4f53\u80fd\u591f\u88ab\u968f\u673a\u5730\u8fd8\u539f\u6210Co<sup>\u2161<\/sup>\u548cCo<sup>\u2160<\/sup>\uff0c\u6bcf\u4e00\u8fd8\u539f\u8fc7\u7a0b\u90fd\u8868\u73b0\u51fa\u51c6\u53ef\u9006\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\uff0c\u8fd9\u4e0eCo<sup>\u2162<\/sup>H\u5230Co<sup>\u2161<\/sup>H\u8fc7\u7a0b\u540c\u65f6\u53d1\u751f\uff0c\u800c\u5176\u4e2dCo<sup>\u2161<\/sup>H\u6700\u7ec8\u4e0e\u9178\u53cd\u5e94\u4ea7\u751fH<sub>2\u3002<\/sub>1000psi\u7684H<sub>2<\/sub>\u4f0f\u5b89\u56fe\u8bb0\u5f55\u4e2d\u53d1\u73b0Co<sup>I<\/sup>\u4e2d\u95f4\u4f53\u662f\u88abCo<sup>II<\/sup>(dmgBF<sub>2<\/sub>)<sub>2<\/sub>(CH<sub>3<\/sub>CN)<sub>2<\/sub>\u50ac\u5316\u5242\u6392\u9664\u5728\u5916\u7684\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u88ab\u7528\u4e8e\u8ba1\u7b97Co<sup>\u2162<\/sup>-H\u548cCo<sup>\u2161<\/sup>-H\u952e\u5f3a\uff0c\u5c3d\u7ba1\u5b83\u4eec\u5177\u6709\u4e0d\u540c\u7684\u914d\u4f53\uff0c\u4f46\u94b4\u6c22\u5316\u7269\u50ac\u5316\u5242\u5177\u6709\u76f8\u4f3c\u7684Co-H\u952e\u5f3a\u4ee5\u53ca\u5747\u88c2\u548c\u5f02\u88c2\u7279\u6027\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b04779\" target=\"_blank\">Electrochemical Detection of Transient Cobalt Hydride Intermediates of Electrocatalytic Hydrogen Production<\/a> \uff08Journal of the American Chemical Society\uff0c 2016\uff0c DOI: 10.1021\/jacs.6b04779\uff09<\/p>\n<p><strong style=\"line-height: 1.5;\">8\u3001\u00a0<\/strong><strong style=\"line-height: 1.5;\">\u77f3\u58a8\u70ef\u5355\u6676\u7684\u81ea\u7ec4\u88c5\u2014\u2014<\/strong><strong style=\"line-height: 1.5;\">\u7b2c\u4e00\u4e2a\u4e8c\u7ef4\u8d85\u6709\u5e8f\u7ed3\u6784<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-25620 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/08.jpg\" alt=\"08\" width=\"500\" height=\"280\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/08.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/08-300x168.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>8 2DSOS\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n<p>\u9762\u5bf9\u9ad8\u901f\u53d1\u5c55\u7684\u96c6\u6210\u7535\u5b50\uff0c\u5149\u7535\u5b50\u548c\u5fae\u673a\u7535\u7cfb\u7edf\uff0c\u8feb\u5207\u9700\u8981\u9ad8\u6548\u88c5\u914d\u6280\u672f\u6765\u751f\u4ea7\u5177\u6709\u6709\u5e8f\u7ed3\u6784\u548c\u6f5c\u5728\u5e94\u7528\u6027\u80fd\u7684\u4f7f\u7528\u7ec4\u4ef6\u3002<\/p>\n<p>\u6b66\u6c49\u5927\u5b66\u4ed8\u78ca\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u6b66\u6c49\u7269\u7406\u4e0e\u6570\u5b66\u7814\u7a76\u6240\u79e6\u5fd7\u8f89\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5229\u7528\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u7684\u5355\u4f4d\u5206\u5b50\u6709\u5e8f\u7ed3\u6784\u7684\u81ea\u53d1\u7ec4\u7ec7\uff0c\u6210\u529f\u5408\u6210\u51fa\u4e86\u7b2c\u4e00\u4e2a\u4e8c\u7ef4\u8d85\u6709\u5e8f\u7ed3\u6784\u6750\u6599\uff082DSOS\uff09\u3002\u5728\u8be5\u9879\u7814\u7a76\u4e2d\uff0c\u4ed6\u4eec\u5de7\u5999\u5730\u91c7\u7528\u9884\u64ad\u79cd\u548c\u6c14\u6d41\u6270\u52a8\u7b56\u7565\uff0c\u5b9e\u73b0\u4e86\u77f3\u58a8\u70ef\u5355\u6676\u5728\u6db2\u6001\u57fa\u5e95\u8868\u9762\u7684\u8d85\u6709\u5e8f\u81ea\u7ec4\u88c5\u3002\u6574\u4e2a\u77f3\u58a8\u70ef\u8d85\u6709\u5e8f\u7ed3\u6784\u8868\u73b0\u51fa\u975e\u5e38\u4f18\u5f02\u7684\u5468\u671f\u6027\uff0c\u6bcf\u4e2a\u77f3\u58a8\u70ef\u7ed3\u6784\u5355\u5143\u5c3a\u5bf8\u548c\u95f4\u8ddd\u5747\u4e00\u3002\u66f4\u6709\u8da3\u7684\u662f\uff0c\u901a\u8fc7\u6539\u53d8\u6270\u52a8\u6c14\u6d41\u7684\u5927\u5c0f\uff0c\u77f3\u58a8\u70ef\u8d85\u6709\u5e8f\u7ed3\u6784\u7684\u5468\u671f\u6027\u53ef\u4ee5\u88ab\u7cbe\u786e\u8c03\u63a7\uff0c\u901a\u8fc7\u56fa\u6001\u78b3\u6e90\u7684\u8bbe\u8ba1\uff0c\u77f3\u58a8\u70ef\u5355\u5143\u7684\u5316\u5b66\u6027\u8d28\u53ef\u4ee5\u88ab\u5e7f\u6cdb\u8c03\u8282\uff0c\u4ece\u800c\u6ee1\u8db3\u672a\u6765\u4e0d\u540c\u7684\u5e94\u7528\u9700\u6c42\u3002\u4ece\u5355\u4e2a\u9ad8\u8d28\u91cf\u7684\u4e8c\u7ef4\u539f\u5b50\u6676\u4f53\u5355\u6676\uff0c\u5230\u4e8c\u7ef4\u5e73\u9762\u4e0a\u7684\u8d85\u6709\u5e8f\u7ed3\u6784\uff0c\u8fd9\u79cd\u65b9\u6cd5\u6253\u5f00\u4e86\u9ad8\u8d28\u91cf\u4e8c\u7ef4\u539f\u5b50\u6676\u4f53\u6750\u5728\u4e8c\u7ef4\u5c3a\u5ea6\u4e0a\u81ea\u7ec4\u88c5\u7684\u5927\u95e8\uff0c\u8fd9\u5bf9\u4e8c\u7ef4\u6750\u6599\u5728\u672a\u6765\u96c6\u6210\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u5c06\u5e26\u6765\u6781\u5927\u7684\u7a81\u7834\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b03208\" target=\"_blank\">Self-Assembly of Graphene Single Crystals with Uniform Size and Orientation: the First 2D Super-Ordered Structure<\/a> \uff08Journal of the American Chemical Society\uff0c2016\uff0cDOI: 10.1021\/jacs.6b03208\uff09<\/p>\n<p><strong>9\u3001\u5bf9\u57fa\u4e8e<\/strong><strong>TiO<sub>2<\/sub><\/strong><strong>\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u5feb\u7535\u5b50\u4f20\u8f93\u7684\u539f\u7406\u63ed\u793a<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-25622 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/09.jpg\" alt=\"09\" width=\"500\" height=\"408\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/09.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/09-300x245.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>9 \u67d3\u6599\u5206\u5b50\u5411TiO<sub>2<\/sub>\u548cZnO\u8f6c\u79fb\u7535\u5b50\u7684\u793a\u610f\u56fe<\/strong><\/p>\n<p>\u5728\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u7535\u5b50\u4ece\u5149\u6fc0\u53d1\u7684\u67d3\u6599\u5206\u5b50\u8f6c\u79fb\u5230\u534a\u5bfc\u4f53\u57fa\u5e95\u7684\u8fc7\u7a0b\u4ecd\u7136\u662f\u5236\u7ea6\u8be5\u9886\u57df\u8fdb\u4e00\u6b65\u53d1\u5c55\u7684\u4e00\u5927\u74f6\u9888\u3002\u7531\u4e8eZnO\u5177\u6709\u66f4\u5927\u7684\u7535\u5b50\u6d41\u52a8\u6027\uff0c\u6240\u4ee5\u7528ZnO\u4ee3\u66ffTiO<sub>2<\/sub>\u7684\u65b9\u6cd5\u88ab\u8ba4\u4e3a\u53ef\u4ee5\u589e\u52a0\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\uff08DSCs\uff09\u7684\u6548\u7387\uff0c\u4f46\u662f\uff0c\u5b83\u4eec\u5374\u5177\u6709\u76f8\u4f3c\u7684\u80fd\u5e26\u7ed3\u6784\u3002\u7136\u800c\uff0c\u5b9e\u9a8c\u8868\u660e\uff0c\u57fa\u4e8eZnO\u7684DSCs\u7684\u8f6c\u5316\u6548\u7387\u53ea\u67097%\uff0c\u8fdc\u4f4e\u4e8e\u57fa\u4e8eTiO<sub>2<\/sub>\u7684DSCs\u768413%\u7684\u8f6c\u5316\u6548\u7387\uff0c\u8fd9\u4f7f\u5f97\u4eba\u4eec\u5bf9\u4e8e\u5176\u4e2d\u7684\u539f\u7406\u5b58\u5728\u957f\u65f6\u95f4\u7684\u56f0\u60d1\u3002<\/p>\n<p>\u4e2d\u56fd\u79d1\u5b66\u9662\u534a\u5bfc\u4f53\u7814\u7a76\u6240\u9a86\u519b\u59d4\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u7f8e\u56fd\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4Lin-Wang Wang\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u9996\u6b21\u5229\u7528Marcus\u7406\u8bba\u5206\u522b\u5bf9\u4e86\u7535\u5b50\u4ece\u67d3\u6599\u5206\u5b50\u5230ZnO\u548c\u5230TiO<sub>2<\/sub>\u4e24\u8fc7\u7a0b\u8fdb\u884c\u4e86\u539f\u7406\u6027\u8ba1\u7b97\u3002\u901a\u8fc7\u7406\u8bba\u9884\u6d4b\uff0c\u57fa\u4e8eTiO<sub>2<\/sub>\u7684DSCs\u7684\u7535\u5b50\u8f6c\u79fb\u901f\u7387\u4e3a1.15\u00d7109 s<sup>\u22121<\/sup>\uff0c\u662f\u57fa\u4e8eZnO\u7684DSCs\u7684\u7535\u5b50\u8f6c\u79fb\u901f\u7387\u768415\u500d\uff0c\u8fd9\u4e0e\u5b9e\u9a8c\u6570\u636e\u5b8c\u5168\u4e00\u81f4\u3002\u4ed6\u4eec\u53d1\u73b0\uff0c\u4e0eZnO\u76f8\u6bd4\uff0c\u5bfc\u5e26\u8fb9\u7f18\u66f4\u5927\u5bc6\u5ea6\u72b6\u6001\u7684TiO<sub>2<\/sub>\u662f\u9020\u6210\u57fa\u4e8eTiO<sub>2<\/sub>\u7684DSCs\u7684\u7535\u5b50\u8f6c\u79fb\u901f\u7387\u66f4\u5feb\u7684\u4e3b\u8981\u5f71\u54cd\u56e0\u7d20\u3002\u8fd9\u4e9b\u5bc6\u96c6\u72b6\u6001\u63d0\u4f9b\u4e86\u989d\u5916\u7684\u9ad8\u6548\u7684\u7535\u5b50\u8f6c\u79fb\u6e20\u9053\u3002\u57fa\u4e8e\u8be5\u7814\u7a76\u6210\u679c\uff0c\u4ed6\u4eec\u56e2\u961f\u540c\u65f6\u8fd8\u8bbe\u8ba1\u901a\u8fc7\u9ad8\u8fc1\u79fb\u7387\u7684\u9633\u6781\u534a\u5bfc\u4f53\u8868\u9762\u5de5\u7a0b\u8fc7\u7a0b\u6765\u63d0\u9ad8DSCs\u8f6c\u5316\u6548\u7387\u7684\u65b9\u6848\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b03524\" target=\"_blank\">Revealing the origin of fast electron transfer in TiO2-based dye-sensitized solar cells<\/a> \uff08Journal of the American Chemical Society\uff0c2016\uff0c DOI: 10.1021\/jacs.6b03524\uff09<\/p>\n<p><strong>10\u3001\u00a0<\/strong><strong>\u57fa\u4e8e\u7eb3\u7c73\u626b\u63cf\u7535\u5316\u5b66\u663e\u5fae\u955c\u7684\u5355\u94c2\u7eb3\u7c73\u7c92\u5b50\u7535\u50ac\u5316\u6d3b\u6027\u7814\u7a76<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-25623 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/10-8.jpg\" alt=\"10\" width=\"500\" height=\"128\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/10-8.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/07\/10-8-300x77.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>10 \u4e2a\u4f53Pt\u7eb3\u7c73\u7c92\u5b50\u5c16\u7aef\u7684SECM\u89c2\u6d4b\u53ca\u5176\u7406\u8bba\u6a21\u578b\u5206\u6790\u56fe\u793a<\/strong><\/p>\n<p>\u5728\u7535\u5316\u5b66\u50ac\u5316\u5668\u4ef6\u4e2d\u61c2\u5f97\u7eb3\u7c73\u91d1\u5c5e\u50ac\u5316\u5242\u7c92\u5b50\u7ed3\u6784\u4e0e\u53cd\u5e94\u6d3b\u6027\u7684\u5173\u7cfb\u662f\u5f97\u5230\u66f4\u9ad8\u6548\u7387\u7684\u5173\u952e\u3002\u5176\u4e2d\u5b58\u5728\u7684\u91cd\u5927\u6311\u6218\u5728\u4e8e\u7814\u7a76\u5404\u4e2a\u7c92\u5b50\u95f4\u7684\u76f8\u4e92\u5173\u7cfb\u3002<\/p>\n<p>\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u5316\u5b66\u7cfb\u7684Allen J. Bard\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u53d1\u5c55\u4e86\u4e00\u79cd\u5229\u7528\u7eb3\u7c73\u7ea7\u626b\u63cf\u7535\u5316\u5b66\u663e\u5fae\u955c\uff08SECM\uff09\u7684\u65b9\u6cd5\u7528\u4e8e\u5bf9Pt\u7684\u7eb3\u7c73\u7c92\u5b50\u7684\u51e0\u4f55\u5f62\u72b6\u548c\u5728\u6c22\u6c27\u5316\u53cd\u5e94\uff08HOR\uff09\u4e2d\u7684\u50ac\u5316\u6d3b\u6027\u8fdb\u884c\u4e86\u7814\u7a76\u3002\u6240\u7528\u7684\u5c3a\u5bf8\u5728\u51e0\u5341\u5230\u4e00\u767e\u7eb3\u7c73\u7684Pt\u7eb3\u7c73\u7c92\u5b50\u901a\u8fc7\u9884\u64ad\u79cd\u548c\u6676\u6838\u751f\u957f\u7684\u65b9\u6cd5\u76f4\u63a5\u7535\u6c89\u79ef\u5728\u9ad8\u5b9a\u5411\u70ed\u89e3\u77f3\u58a8\uff08HOPG\uff09\u8868\u9762\u3002\u4e00\u4e2a\u5f88\u597d\u5b9a\u4e49\u7684\u7eb3\u7c73\u5c3a\u5bf8\u7684\u5c16\u7aef\u53ef\u4ee5\u4e0e\u7eb3\u7c73\u9897\u7c92\u7684\u7ef4\u5ea6\u76f8\u5ab2\u7f8e\uff0c\u800c\u4e14\u5c16\u7aef\u4e0e\u7eb3\u7c73\u9897\u7c92\u95f4\u7a33\u5b9a\u7684\u7eb3\u7c73\u95f4\u8ddd\u53ef\u4ee5\u4f7f\u5f97\u7814\u7a76\u4eba\u5458\u5bf9\u7535\u5b50\u5feb\u901f\u4f20\u8f93\u8fc7\u7a0b\u7684\u52a8\u529b\u5b66\u5b9e\u73b0\u6a2a\u5411\u548c\u7eb5\u5411\u7684\u53cc\u91cd\u7a7a\u95f4\u5206\u8fa8\u7387\u3002\u5c24\u5176\u662f\uff0c\u6c27\u5316\u8fd8\u539f\u4e2d\u95f4\u4f53\u5177\u6709\u4e24\u79cd\u4e0d\u540c\u4e2d\u5e94\u7528\u65f6\uff1a1\uff09\u5916\u7403\u5f62\u4e2d\u95f4\u4f53\u548c2\uff09\u5185\u7403\u5f62\u4e2d\u95f4\u4f53\u3002\u8fd9\u79cd\u4e0d\u540c\uff0c\u4f1a\u4f7f\u5f97Pt\u7eb3\u7c73\u7c92\u5b50\u5177\u6709\u4e0d\u540c\u7684\u5fae\u89c2\u5f62\u8c8c\u548c\u50ac\u5316\u6d3b\u6027\uff0c\u540c\u65f6\u610f\u5473\u7740\u5728\u6c22\u6c27\u5316\u53cd\u5e94\u4e0a\u5177\u6709\u9ad8\u7684\u6548\u7387\uff0c\u5176\u4e2d\uff0c\u6bcf\u4e2aPt \u7eb3\u7c73\u9897\u7c92\u7684\u7535\u5316\u5b66\u901f\u7387\u5e38\u6570\u4e0d\u5c0f\u4e8e2 cm\/s\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u7ed3\u5408\u7406\u8bba\u6a21\u578b\u4e0e\u5206\u6790\uff0cSECM\u4e2a\u4f53\u6c34\u5e73\u4e0a\u7684\u68c0\u6d4b\u53ef\u4ee5\u786e\u5b9aPt\u7eb3\u7c73\u7c92\u5b50\u7684\u5c3a\u5bf8\u3001\u5f62\u8c8c\u3001\u65b9\u5411\u6027\u548c\u50ac\u5316\u6d3b\u6027\u7684\u7b49\u4fe1\u606f\u3002\u8fd9\u79cd\u65b9\u6cd5\u53ef\u4ee5\u88ab\u5f88\u5bb9\u6613\u5730\u6269\u5c55\u8fd0\u7528\u5230\u8868\u9762\u6027\u80fd\u7684\u5b9a\u91cf\u68c0\u6d4b\uff0c\u4f8b\u5982\uff0c\u4e0d\u540c\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u50ac\u5316\u5242\u8868\u9762\u5b98\u80fd\u56e2\u5bf9\u5176\u50ac\u5316\u6d3b\u6027\u7684\u5f71\u54cd\u7684\u7814\u7a76\u7b49\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b03980\" target=\"_blank\">Electrocatalytic Activity of Individual Pt Nanoparticles Studied by Nanoscale Scanning<\/a>\u00a0<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b03980\">Electrochemical Microscopy<\/a> \uff08Journal of the American Chemical Society\uff0c2016\uff0c DOI: 10.1021\/jacs.6b03980\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4Carbon\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\uff0c\u4e00\u8d77\u8fdb\u884c\u6750\u6599\u9876\u520a\u5b66\u672f\u52a8\u6001\u7684\u8ddf\u8e2a\u548c\u62a5\u9053\u4ee5\u53caSCI\u76f8\u5173\u77e5\u8bc6\u79d1\u666e\u7b49\u3002\u52a0\u5165\u65b9\u5f0f\uff1a\uff081\uff09<a 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