{"id":255796,"date":"2023-11-13T10:29:38","date_gmt":"2023-11-13T02:29:38","guid":{"rendered":"\/\/m.iemloyee.com\/?p=255796"},"modified":"2023-11-13T10:29:49","modified_gmt":"2023-11-13T02:29:49","slug":"%e6%ad%a6%e6%b1%89%e5%a4%a7%e5%ad%a6energy-environmental-science%ef%bc%9a%e5%ae%bd%e5%b8%a6%e9%9a%99%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0%ef%bc%9a%e5%9f%8b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=255796","title":{"rendered":"\u6b66\u6c49\u5927\u5b66Energy & Environmental Science\uff1a\u5bbd\u5e26\u9699\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff1a\u57cb\u5e95\u754c\u9762\u5de5\u7a0b\u5b9e\u73b0\u8d85\u4f4e\u5f00\u538b\u635f\u5931"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u5168\u9499\u949b\u77ff\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60(TSC)\u5177\u6709\u5f88\u597d\u7684\u5e94\u7528\u524d\u666f\uff0c\u6709\u671b\u7a81\u7834\u5355\u7ed3\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u6781\u9650\u3002\u7136\u800c\uff0c\u4f5c\u4e3a\u5168\u9499\u949b\u77ff\u4e32\u8054\u7535\u6c60\u7684\u91cd\u8981\u7ec4\u6210\u90e8\u5206\uff0c\u5bbd\u5e26\u9699\u9499\u949b\u77ff\u5b50\u7535\u6c60\u4f9d\u7136\u9762\u4e34\u4e25\u91cd\u7684\u975e\u8f90\u5c04\u7535\u8377\u590d\u5408\uff0c\u6210\u4e3a\u5f00\u53d1\u9ad8\u6548\u7387\u5168\u9499\u949b\u77ff\u4e32\u8054\u7535\u6c60\u7684\u5173\u952e\u74f6\u9888\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6b66\u6c49\u5927\u5b66\u65b9\u56fd\u5bb6\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u578b\u57cb\u5730\u754c\u9762\u5de5\u7a0b\u65b9\u6cd5\uff0c\u5373\u4f7f\u7528Me-4PACz\u5bf92PACz\u7a7a\u7a74\u9009\u62e9\u5c42\u8fdb\u884c\u6539\u6027\u3002\u8868\u5f81\u7ed3\u679c\u8868\u660e\uff0cMe-4PACz\u7684\u754c\u9762\u5de5\u7a0b\u4e0d\u4ec5\u6539\u53d8\u4e862PACz\u5728ITO\u7684\u8868\u9762\u7535\u52bf\u5206\u5e03\uff0c\u800c\u4e14\u5f71\u54cd\u4e86\u968f\u540e\u9499\u949b\u77ff\u5c42\u7684\u7ed3\u6676\u3002\u8fd9\u5bfc\u81f4\u5728\u63a9\u57cb\u754c\u9762\u5904\u5f62\u6210\u66f4\u81f4\u5bc6\u7684\u9499\u949b\u77ff\u819c\uff0c\u4ece\u800c\u6539\u5584\u4e86\u9499\u949b\u77ff\u5c42\u548c\u7a7a\u7a74\u9009\u62e9\u5c42\u4e4b\u95f4\u7684\u80fd\u7ea7\u6392\u5217\uff0c\u5e76\u6291\u5236\u4e86\u975e\u8f90\u5c04\u590d\u5408\u3002\u4f18\u5316\u7684WBG\u7535\u6c60\u8868\u73b0\u51fa1.36 V\u7684\u663e\u8457VOC<\/sub>\u3001\u4ee5\u53ca\u521b\u7eaa\u5f55\u7684\u4f4eVOC<\/sub>\u635f\u5931\u20140.42V\u3002\u6b64\u5916\uff0c\u5b9e\u73b0\u4e86PCE\u5206\u522b\u9ad8\u8fbe27.34%\u300128.05%\u7684\u4e24\u7aef\u548c\u56db\u7aefTSC\u3002\u8be5\u5de5\u4f5c\u4e3aWBG\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u548c\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cLead halide coordination competition at buried interfaces for low VOC<\/sub>-deficits in wide-bandgap perovskite solar cells\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aEnergy Environ. Sci.\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

\u63d0\u51fa\u4e86\u4e00\u79cd\u7b80\u5355\u660e\u4e86\u7684\u754c\u9762\u5de5\u7a0b\u7b56\u7565\uff0c\u5373\u987a\u5e8f\u6c89\u79ef2PACz\u548cMe-4PACz\u4f5c\u4e3a\u7a7a\u7a74\u9009\u62e9\u5c42\uff0c\u901a\u8fc7\u63a7\u5236\u9499\u949b\u77ff\u7684\u7ed3\u6676\u8fc7\u7a0b\u548c\u57cb\u5e95\u754c\u9762\u7684\u7535\u8377\u8f7d\u6d41\u5b50\u4f20\u8f93\uff0c\u6291\u5236\u975e\u8f90\u5c04\u7535\u8377\u590d\u5408\u3002<\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1 <\/strong>\u9499\u949b\u77ff\u819c\u5904\u7406\u8fc7\u7a0b\u53ca\u8868\u5f81 \u00a9 The Royal Society of Chemistry 2023<\/strong><\/p>\n

(a) Me-4PACz\u754c\u9762\u5de5\u7a0b\u8fc7\u7a0b\u793a\u610f\u56fe \uff1b<\/p>\n

(b) \u6c89\u79ef\u5728\u4e0d\u540c\u886c\u5e95\u4e0a\u7684\u9499\u949b\u77ff\u819c\u7684PLQY\u503c\u4ee5\u53ca\u6839\u636ePLQY\u8ba1\u7b97\u7684\u76f8\u5e94VOC<\/sub>\u975e\u8f90\u5c04\u590d\u5408\u635f\u5931\uff1b<\/p>\n

(c,d) \u9499\u949b\u77ff\u63a9\u57cb\u754c\u9762\u5904\uff0c\u5bf9\u7167\u9499\u949b\u77ff\u819c\u548c\u76ee\u6807\u9499\u949b\u77ff\u819c\u7684\u4fef\u89c6SEM\u56fe\u50cf\uff1b<\/p>\n

(e,f) \u5bf9\u7167\u9499\u949b\u77ff\u819c\u548c\u76ee\u6807\u9499\u949b\u77ff\u819c\u7684PL\u6620\u5c04\u56fe\u6848\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2 <\/strong>\u9499\u949b\u77ff\u819c\u6750\u6599\u6027\u80fd\u3001\u63a9\u57cb\u754c\u9762\u7684\u76f8\u4e92\u4f5c\u7528\u673a\u5236\u53ca\u5668\u4ef6\u80fd\u7ea7\u6392\u5217<\/strong><\/p>\n

\u00a0\u00a9 The Royal Society of Chemistry 2023<\/strong><\/p>\n

(a) \u9499\u949b\u77ff\u8584\u819c\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

(b,c) \u4e0d\u540c\u63a0\u5165\u5c04\u89d2\u4e0b\uff0c\u5bf9\u7167\u9499\u949b\u77ff\u819c\u548c\u76ee\u6807\u9499\u949b\u77ff\u819c\u7684GIXRD\u5149\u8c31\uff1b<\/p>\n

(d-f) \u91c7\u7528\/\u4e0d\u91c7\u7528Me-4PACz\u754c\u9762\u5de5\u7a0b\u7684\u9499\u949b\u77ff\u819c\u4e2dI 3d\u3001Pb 4f\u548cO 1s\u7684XPS\u5149\u8c31\uff1b<\/p>\n

(e) \u5bf9\u7167\u7ec4\u5408PDA\u5904\u7406\u819c\u57280.15\u00b0\u5165\u5c04\u89d2\u7684GIWAXS\u56fe\uff1b<\/p>\n

(g) DMSO\u5206\u5b50\u548cMe-4PACz\u5206\u5b50\u4e0ePbI2<\/sub>\u5206\u5b50\u7684\u7ed3\u5408\u80fd\uff1b<\/p>\n

(h) \u5bf9\u7167\u88c5\u7f6e\u548c\u76ee\u6807\u88c5\u7f6e\u7684\u80fd\u7ea7\u56fe\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 Me-4PACz<\/strong>\u754c\u9762\u5de5\u7a0b\u673a\u5236\u793a\u610f\u56fe \u00a9 The Royal Society of Chemistry 2023<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe4 <\/strong>\u5355\u7ed3WBG PSC<\/strong>\u7684\u5149\u4f0f\u6027\u80fd \u00a9 The Royal Society of Chemistry 2023<\/strong><\/p>\n

(a) \u5bf9\u7167\u7ec4\u548c\u76ee\u6807\u7ec4\u6700\u4f73\u8bbe\u5907\u7684J\u2013V\u66f2\u7ebf\uff08\u56fe\u793a\u4e3a\u8bbe\u5907\u7ed3\u6784\u793a\u610f\u56fe\uff09\uff1b<\/p>\n

(b) \u5bf9\u7167\u7ec4\u548c\u76ee\u6807\u7ec4\u7684\u8bbe\u5907\u6027\u80fd\u53c2\u6570\uff08VOC<\/sub>\u3001FF\u548cPCE\uff09\u65b9\u6846\u56fe\uff1b<\/p>\n

(c) \u5bf9\u7167\u7ec4\u548c\u76ee\u6807\u7ec4\u51a0\u519b\u5668\u68b0\u7684EQE\u66f2\u7ebf\uff1b<\/p>\n

(d) WBG PSC\u7684VOC<\/sub>\u4e0e\u5e26\u9699\u503c\u7684\u5173\u7cfb\uff08\u7ea2\u661f\u2014\u2014Me-4PACz\u754c\u9762\u5de5\u7a0b\uff09\uff1b<\/p>\n

(e) \u5bf9\u7167\u548c\u76ee\u6807\u5668\u4ef6\u7684\u5149\u5f3a\u76f8\u5173J\u2013V\u66f2\u7ebf\uff1b<\/p>\n

(f) \u5948\u594e\u65af\u7279\u56fe\uff1b<\/p>\n

(g) \u7535\u5bb9\u2013\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n

(h) \u5bf9\u7167\u5668\u4ef6\u548c\u76ee\u6807\u5668\u4ef6\u5ba4\u6e29\u4e0b\u7684\u9677\u9631\u6001\u5bc6\u5ea6\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5 <\/strong>\u9499\u949b\u77ff\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u4f0f\u6027\u80fd\u00a9 The Royal Society of Chemistry 2023<\/strong><\/p>\n

(a) \u9499\u949b\u77ff\/\u9499\u949b\u77ff2-T\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u7684\u5668\u4ef6\u7ed3\u6784\uff1b<\/p>\n

(b) \u6700\u4f732-T\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u57289 V\u504f\u7f6e\u7535\u538b\u4e0b\u6d4b\u91cf\u7684J\u2013V\u66f2\u7ebf\u548c\u7a33\u6001\u529f\u7387\u8f93\u51fa\uff1b<\/p>\n

(c) \u6700\u4f73\u6027\u80fd\u76842-T\u4e32\u8054\u7535\u6c60\u7684EQE\u66f2\u7ebf\uff1b<\/p>\n

(d) \u9499\u949b\u77ff\/\u9499\u949b\u77ff4-T\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u7684\u5668\u4ef6\u7ed3\u6784\uff1b<\/p>\n

(e) \u4e09\u79cd\u4e0d\u540c\u5668\u4ef6\u7684J\u2013V\u66f2\u7ebf\uff1a\u5355\u7ed3NBG PSC\u3001\u5355\u7ed3\u534a\u900f\u660eWBG\uff08STWGB\uff09PSC\u548c\u6ee4\u6ce2NBG PSC\uff1b<\/p>\n

(f) \u5355\u7ed3\u534a\u900f\u660eWBG PSC\u548c\u6ee4\u6ce2NBG PSC\u7684EQE\u66f2\u7ebf\uff1b<\/p>\n

(g) 4-T\u5168\u9499\u949b\u77ff\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u7684PCE\u6f14\u53d8\uff1b<\/p>\n

(h) \u534a\u900f\u660eWBG PSC\u548c\u6ee4\u6ce2NBG PSC\u5206\u522b\u57281.14V\u548c0.74V\u504f\u7f6e\u7535\u538b\u4e0b\u7684\u7a33\u6001\u529f\u7387\u8f93\u51fa\u3002<\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u901a\u8fc7Me-4PACz\u754c\u9762\u5de5\u7a0b\u663e\u8457\u63d0\u9ad8\u4e86WBG\u9499\u949b\u77ff\u5355\u7ed3\u548c\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\uff0c\u5305\u62ecVOC<\/sub>\u3001FF\u548cPCE\u5728\u5185\u7684\u5404\u79cd\u5173\u952e\u53c2\u6570\u65b9\u9762\u53d6\u5f97\u4e86\u663e\u8457\u6539\u5584\u3002\u4e0d\u900f\u660e\u548c\u534a\u900f\u660e\u76841.78eV\u5e26\u9699\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5206\u522b\u8868\u73b0\u51fa19.83%\u548c18.25%\u7684\u4ee4\u4eba\u5370\u8c61\u6df1\u523b\u7684\u6700\u4f73PCE\u3002\u5229\u7528\u8fd9\u4e00\u7b56\u7565\uff0c\u80fd\u591f\u5236\u9020\u51fa\u9ad8\u6548\u7684\u5168\u9499\u949b\u77ff\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u3002\u5176\u5f00\u53d1\u76842-T\u548c4-T\u4e32\u8054\u7535\u6c60\u5206\u522b\u83b7\u5f97\u4e8627.34%\u548c28.05%\u7684\u4f18\u5f02\u6548\u7387\uff0c\u5c55\u793a\u4e86\u5728\u9ad8\u6548\u591a\u7ed3\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u5e94\u7528\u4e2d\u7684\u6f5c\u529b\u3002\u8be5\u7814\u7a76\u5bf9\u9499\u949b\u77ff\u5c42\u5e95\u90e8\u754c\u9762\u7684\u7814\u7a76\u548c\u8c03\u63a7\u3001\u9499\u949b\u77ff\u5149\u4f0f\u9886\u57df\u7684\u8fdb\u4e00\u6b65\u6539\u8fdb\u548c\u4f18\u5316\u63d0\u4f9b\u4e86\u6709\u4ef7\u503c\u7684\u89c1\u89e3\u3002<\/p>\n

 <\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a <\/strong>10.1039\/D3EE02818F<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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