{"id":255725,"date":"2023-11-09T08:17:00","date_gmt":"2023-11-09T00:17:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=255725"},"modified":"2023-11-09T08:17:00","modified_gmt":"2023-11-09T00:17:00","slug":"%e6%ad%a6%e6%b1%89%e5%a4%a7%e5%ad%a6%ef%bc%8c%e4%bb%8a%e6%97%a5nature%ef%bc%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=255725","title":{"rendered":"\u6b66\u6c49\u5927\u5b66\uff0c\u4eca\u65e5Nature\uff01"},"content":{"rendered":"

\u4e00\u3001<\/b><\/strong>\u3010\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u8fc7\u53bb\u5341\u5e74\u4e2d\uff0c\u6709\u673a\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\u6750\u6599\uff08ABX3<\/sub>\uff09\u5df2\u6210\u4e3a\u5149\u4f0f\u6280\u672f\u4e2d\u5438\u5149\u6750\u6599\u6709\u524d\u9014\u7684\u9009\u62e9\u3002\u4e3a\u4e86\u5b9e\u73b0\u5355\u7ed3\u592a\u9633\u80fd\u7535\u6c60\u7684\u7a84\u5e26\u9699\uff08NBG\uff09\uff0c\u4ee5\u53ca\u5168\u9499\u949b\u77ff\u4e32\u8054\u7684\u5b50\u7535\u6c60\uff0c\u5728 1.1~1.4 eV\u7684\u8303\u56f4\u5185\uff0c\u94c5\uff08Pb\uff09\u548c\u9521\uff08Sn\uff09\u53ef\u4ee5\u5728B\u4f4d\u91d1\u5c5e\u79bb\u5b50\u4e2d\u5408\u91d1\u5316\u3002\u7136\u800c\uff0c\u7531\u4e8eSn\u7684\u6613\u6c27\u5316\u6027\uff0c\u5236\u5907\u9ad8\u6548\u7a33\u5b9a\u7684NBG\u9521\u94c5\uff08Sn-Pb\uff09\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSCs\uff09\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\uff0c\u5bfc\u81f4p\u578b\u81ea\u63ba\u6742\u3001\u8f7d\u6d41\u5b50\u5bff\u547d\u77ed\u548c\u5668\u4ef6\u6027\u80fd\u4e0b\u964d\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u7814\u7a76\u8005\u5df2\u7ecf\u63d0\u51fa\u4e86\u5404\u79cd\u7b56\u7565\uff0c\u5305\u62ec\u5728\u5668\u4ef6\u5236\u9020\u8fc7\u7a0b\u4e2d\u4f7f\u7528\u591a\u79cd\u6dfb\u52a0\u5242\uff0c\u4ee5\u63d0\u9ad8\u6df7\u5408Sn-Pb PSC\u7684\u6027\u80fd\uff0c\u901a\u8fc7\u4f18\u5316NBG\u6df7\u5408Sn-Pb\u4e9a\u7535\u6c60\u548c\u5bbd\u5e26\u9699\uff08WBG\uff09\u5b50\u7535\u6c60\uff0c\u5b9e\u73b0\u4e86\u5168\u9499\u949b\u77ff\u4e32\u8054\u7535\u6c60\u7684\u521b\u7eaa\u5f55\u6027\u80fd\u3002\u7136\u800c\uff0c\u5355\u7ed3Sn-Pb PSC\u7684\u6027\u80fd\u4ecd\u6709\u5f88\u5927\u63d0\u9ad8\u7684\u7a7a\u95f4\uff0c\u8fd9\u6700\u7ec8\u51b3\u5b9a\u4e86\u5168\u9499\u949b\u77ff\u4e32\u8054\u7684\u4e0a\u9650\u3002<\/p>\n

\u4e8c\u3001<\/b><\/strong>\u3010\u6210\u679c\u63a0\u5f71\u3011<\/b><\/strong><\/p>\n

\u5728\u6b64\uff0c\u6b66\u6c49\u5927\u5b66\u65b9\u56fd\u5bb6\u6559\u6388\u548c\u67ef\u7ef4\u4fca\u6559\u6388\u7b49\u4eba<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u805a\u7126\u7a84\u7981\u5e26\u4e9a\u7535\u6c60\uff0c\u5e76\u4e3a\u5b83\u4eec\u5f00\u53d1\u4e86\u4e00\u79cd\u591a\u5408\u4e00\u7684\u63ba\u6742\u7b56\u7565\u3002\u5177\u4f53\u6765\u8bf4\uff0c\u4f5c\u8005\u5c06\u5929\u51ac\u6c28\u9178\uff08AspCl\uff09\u5f15\u5165\u5e95\u90e8\u805a\uff083,4-\u4e59\u70ef\u4e8c\u6c27\u567b\u5429\uff09-\u805a\uff08\u82ef\u4e59\u70ef\u78fa\u9178\u916f\uff09\u548c\u5757\u72b6\u9499\u949b\u77ff\u5c42\uff0c\u7136\u540e\u8fdb\u884cAspCl\u540e\u5904\u7406\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5355\u4e00\u7684AspCl\u6dfb\u52a0\u5242\u53ef\u4ee5\u6709\u6548\u5730\u949d\u5316\u7f3a\u9677\uff0c\u964d\u4f4eSn4+<\/sup>\u6742\u8d28\u548c\u8d39\u7c73\u80fd\u7ea7\u7684\u504f\u79fb\u3002\u6b64\u5916\uff0cAspCl-Sn\/Pb\u7898\u5316\u7269\u548cAspCl-AspCl\u7684\u5f3a\u5206\u5b50\u952e\u53ef\u4ee5\u589e\u5f3aSn-Pb\u9499\u949b\u77ff\u7684\u7ed3\u6784\uff0c\u4ece\u800c\u63d0\u9ad8\u5176\u7a33\u5b9a\u6027\u3002\u6700\u7ec8\uff0c\u5728Sn-Pb\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2dAspCl\u63ba\u6742\u540e\uff0c\u5355\u7ed3\u7535\u6c60\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\u4e3a22.46%\uff0c\u4e32\u8054\u7535\u6c60\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\u4e3a27.84%\uff0827.62%\u7a33\u5b9a\uff0c27.34%\u8ba4\u8bc1\uff09\uff0c\u5728\u88c5\u6ee1\u6c2e\u6c14\u624b\u5957\u7bb1\u50a8\u5b582000\u5c0f\u65f6\u540e\u4fdd\u6301\u7387\u4e3a95%\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u591a\u5408\u4e00AspCl\u63ba\u6742\u662f\u63d0\u9ad8\u5355\u7ed3Sn-Pb\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u53ca\u5176\u4e32\u8054\u5668\u4ef6\u6548\u7387\u548c\u7a33\u5b9a\u6027\u7684\u6709\u5229\u7b56\u7565\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cAspartate all-in-one doping strategy enables efficient all-perovskite tandems<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728N<\/i><\/em><\/strong>ature<\/i><\/em><\/strong>\u4e0a\u3002\"\"<\/p>\n

\u4e09\u3001<\/b><\/strong>\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/b><\/strong><\/p>\n

1.\u5355\u4e00\u7684AspCl\u6dfb\u52a0\u5242\u53ef\u4ee5\u6709\u6548\u5730\u949d\u5316\u7f3a\u9677\uff0c\u964d\u4f4eSn4+<\/sup>\u6742\u8d28\u548c\u8d39\u7c73\u80fd\u7ea7\u7684\u504f\u79fb\u3002\u540c\u65f6\uff0cAspCl-Sn\/Pb\u7898\u5316\u7269\u548cAspCl-AspCl\u7684\u5f3a\u5206\u5b50\u952e\u53ef\u4ee5\u589e\u5f3aSn-Pb\u9499\u949b\u77ff\u7684\u7ed3\u6784\uff0c\u4ece\u800c\u63d0\u9ad8\u5176\u7a33\u5b9a\u6027\u3002<\/p>\n

2.\u5728Sn-Pb\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2dAspCl\u63ba\u6742\u540e\uff0c\u5355\u7ed3\u7535\u6c60\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\u4e3a22.46%\uff0c\u4e32\u8054\u7535\u6c60\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\u4e3a27.84%\uff0827.62%\u7a33\u5b9a\uff0c27.34%\u8ba4\u8bc1\uff09\uff0c\u5728\u88c5\u6ee1\u6c2e\u6c14\u624b\u5957\u7bb1\u50a8\u5b582000\u5c0f\u65f6\u540e\u4fdd\u6301\u7387\u4e3a95%\u3002<\/p>\n

\u56db\u3001<\/b><\/strong>\u3010\u6570\u636e\u6982\u89c8\u3011<\/b><\/strong>\"\"<\/p>\n

\u56fe<\/b><\/strong>1 NBG Sn-Pb\u9499\u949b\u77ff\u4e2dAspCl\u7684\u5236\u5907\u53ca\u673a\u7406\u00a9 2023 Springer Nature<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>2 NBG Sn-Pb\u9499\u949b\u77ff\u8584\u819c\u7684\u8868\u5f81\u00a9 2023 Springer Nature<\/b><\/strong>\"\"<\/p>\n

\u56fe<\/b><\/strong>3 \u5355\u7ed3NBG Sn-Pb PSC\u7684\u6027\u80fd\u00a9 2023 Springer Nature<\/b><\/strong>\"\"<\/p>\n

\u56fe<\/b><\/strong>4 2T\u5168\u9499\u949b\u77ff\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\u00a9 2023 Springer Nature<\/b><\/strong><\/p>\n

\u4e94\u3001<\/b><\/strong>\u3010\u6210\u679c\u542f\u793a\u3011<\/b><\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cdSn-Pb PSCs\u7684\u591a\u5408\u4e00\u63ba\u6742\u65b9\u6cd5\uff0c\u5c06\u624b\u6027\u5929\u51ac\u6c28\u9178\uff08AspCl\uff09\u5206\u5b50\u63ba\u5165\u5e95\u90e8\u805a\uff083,4-\u4e59\u70ef\u4e8c\u6c27\u567b\u5429\uff09-\u805a\uff08\u82ef\u4e59\u70ef\u78fa\u9178\u916f\uff09PEDOT\uff1aPSS\uff08PEDOT\uff09\u3001\u4e2d\u95f4\u9499\u949b\u77ff\u5438\u5149\u5c42\uff08Bulk\uff09\u548c\u9876\u90e8\u5c01\u76d6\u5c42\uff08POST\uff09\u4e2d\u3002Cl–<\/sup>\u9634\u79bb\u5b50\u6291\u5236\u7898\u7a7a\u4f4d\u7684\u5f62\u6210\uff0c\u6c28\u57fa\u4e0eI–<\/sup>\u914d\u4f4d\u51cf\u5c11\u9677\u9631\u72b6\u6001\u5e76\u6291\u5236\u7898\u79bb\u5b50\u8fc1\u79fb\uff0c\u7fa7\u57fa\u4e0ePb\u3001Sn\u79bb\u5b50\u914d\u4f4d\uff0c\u6291\u5236\u9499\u949b\u77ff\u5206\u89e3\u3002\u6b64\u5916\uff0c\u5728\u9499\u949b\u77ff\u8584\u819c\u548c\u9499\u949b\u77ff\/\u5e95\u5b54\u4f20\u8f93\u5c42\uff08HTL\uff09\u548c\u9499\u949b\u77ff\/\u9876\u76d6\u5c42\u7684\u754c\u9762\u4e2d\uff0c\u4e24\u4e2aAspCl\u5206\u5b50\u4e2d\u7684\u6c28\u57fa\u548c\u7fa7\u57fa\u53ef\u4ee5\u901a\u8fc7\u5206\u5b50\u95f4\u6c22\u952e\u76f8\u4e92\u7ed3\u5408\u3002\u56e0\u6b64\uff0c\u8fd9\u79cdAspCl\u63ba\u6742\u7b56\u7565\u4e3a\u9499\u949b\u77ff\u521b\u9020\u4e86\u4e00\u4e2a\u5185\u90e8\u5206\u5b50\u9501\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u949d\u5316\u8868\u9762\u7f3a\u9677\uff0c\u63d0\u9ad8\u5668\u4ef6\u7a33\u5b9a\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/strong>Aspartate all-in-one doping strategy enables efficient all-perovskite tandems<\/u><\/strong><\/a>\u201d<\/strong>\uff08<\/strong>N<\/i><\/em><\/strong>ature<\/i><\/em><\/strong>\uff0c<\/b><\/strong>202<\/strong>3<\/strong>\uff0c<\/strong>10.1038\/s41586-023-06707-z<\/strong>\uff09<\/strong><\/p>\n

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