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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255674\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/\u56fe\u7247-5-1.png\" alt=\"\" width=\"700\" height=\"696\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/\u56fe\u7247-5-1.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/\u56fe\u7247-5-1-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/\u56fe\u7247-5-1-300x298.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe5. PMDA-NiPc-G\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u7684CV\u66f2\u7ebf\u4ee5\u53ca\u5cf0\u503c\u7535\u6d41\u4e0e\u626b\u63cf\u901f\u7387\u6216\u626b\u63cf\u901f\u7387\u5e73\u65b9\u6839\u7684\u5bf9\u5e94\u7ebf\u6027\u62df\u5408\u3002<\/p>\n<p><strong><b>\u8981\u70b9\u56db\uff1a<\/b><\/strong><strong><b>PMDA-NiPc\u7684\u50a8\u9502\u673a\u5236\u53ca\u5404\u7ec4\u5206\u5bb9\u91cf\u8d21\u732e\u5360\u6bd4<\/b><\/strong><\/p>\n<p>\u5229\u7528XPS\u5149\u8c31\u7814\u7a76\u4e86C\u3001N\u3001O\u5143\u7d20\u5728\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0b\u7684\u4ef7\u6001\u53d8\u5316\uff0c\u8bc1\u5b9e\u4e86\u4e2d\u82ef\u73af\u7684C=C\u3001C=O\u3001N=C\u53c2\u4e0e\u4e86\u8131\u5d4c\u9502\u53cd\u5e94\u5e76\u4e14\u5177\u6709\u826f\u597d\u7684\u53ef\u9006\u6027\u3002\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\uff0c\u4ece\u7406\u8bba\u4e0a\u63a2\u8ba8\u4e86\u9502\u5316-\u53bb\u9502\u673a\u7406\u3002\u57fa\u4e8e\u6bcf\u4e2aPMDA-NiPc\u5355\u4f53\u76847\u6b65\u9502\u5316-\u8131\u9502\u8fc7\u7a0b\uff0c\u5171\u670952\u4e2a\u7684\u9502\u5b58\u50a8\u4f4d\u70b9\u300252\u4e2a\u9502\u79bb\u5b50\u5b58\u50a8\u53ef\u4ee5\u5927\u81f4\u5206\u4e3a7\u4e2a\u6b65\u9aa4\uff0c\u4ece\u8fd9\u4e9b\u5b9e\u9a8c\u6570\u636e\u53ef\u4ee5\u8ba1\u7b97\u51fa\u6bcf\u4e2a\u9502\u79bb\u5b50\u7684\u5b9e\u9a8c\u653e\u7535\u5bb9\u91cf\u4e3a47 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alt=\"\" width=\"700\" height=\"626\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/\u56fe\u7247-8.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/\u56fe\u7247-8-300x268.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe6 a) PMDA-NiPc\u5355\u4f53\u9502\u5316\u5404\u9636\u6bb5\u7684HOMO-LUMO\u95f4\u9699\u3002b) PMDA-NiPc\u5355\u4f53\u9502\u5316\u5404\u9636\u6bb5\u7684\u53cd\u5e94\u81ea\u7531\u80fd(\u0394G)\u3002c) PMDA-NiPc\u5728\u653e\u7535\u548c\u5145\u7535\u5faa\u73af\u4e2d\u9010\u6e10\u9502\u5316\u548c\u8870\u51cf\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255676\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/\u56fe\u7247-7.png\" alt=\"\" width=\"700\" height=\"537\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/\u56fe\u7247-7.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/\u56fe\u7247-7-300x230.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe7 PMDA-NiPc-G\u4e2dPMDA-NiPc\u5bb9\u91cf\u8d21\u732e\u7684\u653e\u7535\u66f2\u7ebf\uff1a(a)\u7b2c600\u5708\uff0c(b)\u7b2c274\u5708\uff0c(c)\u7b2c177\u5708\uff0c(d)\u7b2c20\u5708\u5faa\u73af\u3002<\/p>\n<p><strong><b>\u3010\u6587\u7ae0\u94fe\u63a5\u3011<\/b><\/strong><\/p>\n<p>Two Birds One Stone: Graphene Assisted Reaction Kinetics\u00a0and Ionic Conductivity in Phthalocyanine-Based Covalent\u00a0Organic Framework Anodes for Lithium-ion Batteries<\/p>\n<p><a href=\"https:\/\/doi.org\/10.1002\/smll.202303353\"><u>https:\/\/doi.org\/10.1002\/smll.202303353<\/u><\/a><\/p>\n<p><strong><b>\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p>\u9648\u519b\u6559\u6388\u7b80\u4ecb\uff1a2009\u5e74\u6bd5\u4e1a\u4e8e\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\uff0c\u6709\u673a\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\u30022014\u5e74\u52a0\u5165\u6c5f\u897f\u7406\u5de5\u5927\u5b66\uff0c\u73b0\u4e3a\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u6559\u6388\uff0c\u6c5f\u897f\u7406\u5de5\u5927\u5b66\u201c\u6e05\u6c5f\u201d\u62d4\u5c16\u4eba\u624d\uff0c\u6c5f\u897f\u7701\u8d63\u9131\u4fca\u624d\u652f\u6301\u8ba1\u5212-\u4e3b\u8981\u5b66\u79d1\u5b66\u672f\u5e26\u5934\u4eba\u9886\u519b\u4eba\u624d\u57f9\u517b\u5bf9\u8c61\u3002\u957f\u671f\u4ece\u4e8b\u9502\u79bb\u5b50\u7535\u6c60\u6709\u673a\u7535\u6781\u6750\u6599\u7814\u7a76\u5de5\u4f5c\u3002\u4ee5\u7b2c\u4e00\u6216\u901a\u8baf\u4f5c\u8005\u8eab\u4efd\u5728Small, Chemical Engineering Journal, Journal of Power Sources,\u00a0Science China Materials, ChemSusChem, Journal of Colloid and Interface Science, Nanoscale, Journal of Materials Chemistry C\u7b49\u5b66\u672f\u520a\u7269\u4e0a\u53d1\u8868\u8bba\u658760\u4f59\u7bc7\uff0c\u88ab\u5f15\u75281,100 \u4f59\u6b21\uff0cH\u56e0\u5b5022\u3002<\/p>\n<p>\u674e\u7389\u6d9b\u7814\u7a76\u5458\u7b80\u4ecb\uff1a2013\u5e74\u535a\u58eb\u6bd5\u4e1a\u4e8e\u6e05\u534e\u5927\u5b66\u6750\u6599\u5b66\u9662\uff0c2013\u5e74-2022\u5e74\uff0c\u5728\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u4ece\u4e8b\u535a\u58eb\u540e\u548c\u52a9\u7406\u7814\u7a76\u5458\u5de5\u4f5c\uff0c\u5e08\u4ece\u201d\u9502\u7535\u4e4b\u7236\u201cJohn\u00a0B.\u00a0Goodenough\u6559\u6388\uff0c2022\u5e74\u5e95\u52a0\u5165\u4e2d\u79d1\u9662\u7269\u7406\u6240\uff0c\u4efb\u7279\u8058\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u4e3b\u6301\/\u53c2\u4e0e\u591a\u9879\u5168\u56fa\u6001\u7535\u6c60\u7814\u53d1\u9879\u76ee\u3002\u4e3b\u8981\u7814\u7a76\u5185\u5bb9\u5305\u62ec\u65b0\u578b\u56fa\u6001\u7535\u89e3\u8d28\u6750\u6599\u8bbe\u8ba1\u3001\u5bfc\u7535\u673a\u5236\u5206\u6790\u3001\u754c\u9762\u4f18\u5316\u548c\u5168\u56fa\u6001\u7535\u6c60\u5e94\u7528\u3002\u76f8\u5173\u5de5\u4f5c\u4ee5\u7b2c\u4e00\u548c\u901a\u8baf\u4f5c\u8005\u5728J. Am. Chem. Soc.\u3001PNAS\u3001Angew. Chem. Int. Ed.\u3001Sci. Adv.\u7b49\u671f\u520a\u53d1\u8868\uff0cESI\u9ad8\u88ab\u5f15\u8bba\u658725\u7bc7\uff0c\u603b\u5f15\u752815200\u591a\u6b21\uff0c\u83b72021-2022\u5e74\u5168\u7403\u4ea4\u53c9\u5b66\u79d1\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u3002<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u7b2c\u4e00<\/b><\/strong><strong><b>\u4f5c\u8005\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n<p>\u8d75\u5efa\u519b\uff0c\u7855\u58eb\u6bd5\u4e1a\u4e8e\u6c5f\u897f\u7406\u5de5\u5927\u5b66\uff0c\u73b0\u4e3a\u5317\u4eac\u5316\u5de5\u5927\u5b66\u535a\u58eb\u7814\u7a76\u751f\uff1b<\/p>\n<p>\u5468\u82d7\u82d7\uff0c\u7855\u58eb\u6bd5\u4e1a\u4e8e\u6c5f\u897f\u7406\u5de5\u5927\u5b66\uff0c\u73b0\u4e3a\u4e2d\u56fd\u77ff\u4e1a\u5927\u5b66\u5927\u5b66\uff08\u5317\u4eac\uff09\u535a\u58eb\u7814\u7a76\u751f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6587\u7ae0\u4fe1\u606f\u3011 \u4e00\u77f3\u4e8c\u9e1f\uff1a\u77f3\u58a8\u70ef\u5265\u79bb\u915e\u83c1\u57faCOF\u5b9e\u73b0\u9502\u79bb\u5b50\u7535\u6c60\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u5feb\u901f\u53cd\u5e94\u52a8\u529b\u5b66 \u7b2c\u4e00\u4f5c\u8005\uff1a\u8d75\u5efa\u519b\uff0c\u5468\u82d7\u82d7 \u901a\u8baf\u4f5c\u8005\uff1a\u9648\u519b*\uff0c\u674e\u7389\u6d9b* \u5355\u4f4d\uff1a\u6c5f\u897f\u7406\u5de5\u5927&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-255667","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/255667"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=255667"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/255667\/revisions"}],"predecessor-version":[{"id":255677,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/255667\/revisions\/255677"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=255667"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=255667"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=255667"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}