{"id":255598,"date":"2023-11-04T06:47:52","date_gmt":"2023-11-03T22:47:52","guid":{"rendered":"\/\/m.iemloyee.com\/?p=255598"},"modified":"2023-11-03T22:48:04","modified_gmt":"2023-11-03T14:48:04","slug":"%e9%b2%8d%e7%ab%8b%e9%a3%98%e5%8d%a2%e5%85%b4adv-mater-%ef%bc%9a%e8%b6%85%e9%ab%98%e5%ae%b9%e9%87%8f%e9%93%9d%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=255598","title":{"rendered":"\u9c8d\u7acb\u98d8&amp;\u5362\u5174Adv. Mater.\uff1a\u8d85\u9ad8\u5bb9\u91cf\u94dd\u79bb\u5b50\u7535\u6c60"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u7531\u4e8e\u94dd\u91d1\u5c5e\u5177\u6709\u9ad8\u5b89\u5168\u6027\u3001\u9ad8\u4e30\u5ea6\u3001\u4f4e\u6210\u672c\u548c\u8d85\u9ad8\u7406\u8bba\u5bb9\u91cf\uff082980 mAh g<sup>-1<\/sup>\uff09\u7684\u4f18\u70b9\uff0c\u53ef\u5145\u7535\u94dd\u79bb\u5b50\u7535\u6c60\uff08RABs\uff09\u5df2\u6210\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u4e00\u79cd\u6781\u5177\u524d\u666f\u7684\u66ff\u4ee3\u54c1\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5df2\u62a5\u9053\u7684\u5ba4\u6e29\u975e\u6c34\u7cfb\u94dd\u79bb\u5b50\u7535\u6c60\u7684\u6700\u9ad8\u653e\u7535\u6bd4\u5bb9\u91cf\u7ea6\u4e3a315 mAh g<sup>-1<\/sup>\uff0c\u8003\u8651\u5230\u91d1\u5c5e\u94dd\u7684\u8d85\u9ad8\u7406\u8bba\u5bb9\u91cf\uff0c\u8fd9\u7ed3\u679c\u4ecd\u7136\u4e0d\u5c3d\u5982\u4eba\u610f\u3002\u5728\u6b64\u60c5\u51b5\u4e0b\uff0c\u5f00\u53d1\u65b0\u578b\u7535\u6781\u6750\u6599\uff0c\u4ee5\u63d0\u4f9b\u66f4\u6709\u6548\u7684\u80fd\u91cf\u5b58\u50a8\u673a\u5236\u662f\u5f53\u524d\u7684\u5173\u952e\u95ee\u9898\u548c\u6311\u6218\u3002<\/p>\n<p><strong>\u00a0<\/strong><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u9c8d\u7acb\u98d8\u6559\u6388\u3001\u5362\u5174\u6559\u6388\u7b49\u4eba<\/strong>\u7814\u62a5\u544a\u4e86\u4e00\u79cd\u5229\u7528\u96f6\u7ef4\u5bcc\u52d2\u70efC<sub>70<\/sub>\u4f5c\u4e3a\u6b63\u6781\u5728RABs\u4e2d\u50a8\u5b58\u80fd\u91cf\u7684\u65b0\u578b\u7edc\u5408\u673a\u5236\u3002\u8be5\u673a\u5236\u4f7f\u5f97RABs\u8868\u73b0\u51fa\u521b\u7eaa\u5f55\u7684\u8d85\u9ad8\u53ef\u9006\u6bd4\u5bb9\u91cf\uff08\u5728200 mA g<sup>-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8fbe\u5230750 mAh g<sup>-1<\/sup>\uff09\u548c\u8f83\u9ad8\u7684\u653e\u7535\u7535\u538b\uff08\u7ea61.65 V\uff09\u3002\u901a\u8fc7\u539f\u4f4d\u62c9\u66fc\u3001\u8d28\u8c31\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\uff0c\u53d1\u73b0\u8fd9\u79cd\u8d85\u9ad8\u7684\u5bb9\u91cf\u5f52\u56e0\u4e8e\u4e00\u4e2aC<sub>70<\/sub>\u5206\u5b50\u4e0e23.5\u4e2a\uff08\u8d85\uff09\u5364\u7d20\u57fa\u56e2\uff08\u8d85\u5364\u7d20AlCl<sub>4<\/sub>\u548c\/\u6216\u5364\u7d20Cl\uff09\u76f4\u63a5\u5f62\u6210\u8d85\u5364\u4ee3C<sub>70<\/sub>[AlCl<sub>4<\/sub>]<sub>m<\/sub>Cl<sub>n-m<\/sub>\u914d\u5408\u7269\u3002\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cC<sub>70<\/sub>[AlCl<sub>4<\/sub>]<sub>m<\/sub>Cl<sub>n-m<\/sub>\u89e3\u7edc\u5408\u91ca\u653e\u51faAlCl<sub>4<\/sub><sup>\u2212<\/sup>\/Cl<sup>\u2212<\/sup>\u79bb\u5b50\uff0c\u540c\u65f6\u4fdd\u6301\u5b8c\u6574\u7684\u5bcc\u52d2\u70ef\u7b3c\u7ed3\u6784\u3002\u8be5\u5de5\u4f5c\u63d0\u51fa\u7684\u7edc\u5408\u673a\u7406\u4e3a\u5b9e\u73b0\u9ad8\u5bb9\u91cf\u548c\u957f\u5bff\u547dRABs\u5f00\u8f9f\u4e86\u65b0\u9014\u5f84\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>Ultrahigh Capacity from Complexation-Enabled Aluminum-Ion Batteries with C<sub>70<\/sub> as the Cathode<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520a<strong><em>Adv. Mater.<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255599\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/0.png\" alt=\"\" width=\"600\" height=\"215\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/0.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/0-300x108.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u5229\u7528\u96f6\u7ef4\u5bcc\u52d2\u70efC<sub>70<\/sub>\u4f5c\u4e3a\u6b63\u6781\u5f00\u53d1\u4e86\u65b0\u578b\u7684\u975e\u6c34\u7cfbRABs\uff0c\u8be5RABs\u5177\u6709\u521b\u7eaa\u5f55\u7684\u6bd4\u5bb9\u91cf\uff0c\u968f\u540e\u901a\u8fc7\u539f\u4f4d\u62c9\u66fc\u3001\u8d28\u8c31\u548cDFT\u5bf9\u5176\u8fdb\u884c\u4e86\u673a\u5236\u7814\u7a76\uff0c\u63d0\u51fa\u7684\u7edc\u5408\u673a\u7406\u4e3a\u5b9e\u73b0\u9ad8\u5bb9\u91cf\u548c\u957f\u5bff\u547dRABs\u5f00\u8f9f\u4e86\u65b0\u9014\u5f84\u3002<\/p>\n<p><strong>\u00a0<\/strong><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255600\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/1.png\" alt=\"\" width=\"600\" height=\"249\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/1-300x125.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1\u00a0 <\/strong><strong>\u4ee3\u8868\u6027\u7684\u5ba4\u6e29<\/strong><strong>RABs<\/strong><strong>\u653e\u7535\u5bb9\u91cf\u5bf9\u6bd4<\/strong><strong> \u00a9 2023 Wiely<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255601\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/2.png\" alt=\"\" width=\"600\" height=\"213\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/2.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/2-300x107.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2\u00a0 Al-C<sub>70<\/sub><\/strong><strong>\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><strong> \u00a9 2023 Wiely<\/strong><\/p>\n<p>\uff08a\uff09C<sub>70<\/sub>\u6b63\u6781\u57281 mV s<sup>-1<\/sup>\u626b\u63cf\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\uff08CV\uff09\u66f2\u7ebf\u3002<\/p>\n<p>\uff08b\uff09C<sub>70<\/sub>\u6b63\u6781\u5728200 mA g<sup>-1<\/sup>\u4e0b\u7684\u7535\u538b-\u5bb9\u91cf\u66f2\u7ebf\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255602\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/3.png\" alt=\"\" width=\"600\" height=\"329\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/3-300x165.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3\u00a0 <\/strong><strong>\u53ef\u5145\u7535<\/strong><strong>Al-C<sub>70<\/sub><\/strong><strong>\u7535\u6c60\u7684\u673a\u5236\u7814\u7a76<\/strong><strong> \u00a9 2023 Wiely<\/strong><\/p>\n<p>\uff08a\uff09\u5145\u653e\u7535\u8fc7\u7a0b\u4e2dAl-C<sub>70<\/sub>\u7535\u6c60\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08b\uff09C<sub>70<\/sub>\u6b63\u6781\u7684\u7535\u5316\u5b66\u6c27\u5316\u8fd8\u539f\u673a\u5236\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08c\uff09C<sub>70<\/sub>\u5728\u9996\u4e2a\u5faa\u73af\u671f\u95f4\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255603\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/4.png\" alt=\"\" width=\"600\" height=\"659\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/4-273x300.png 273w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4\u00a0 C<sub>70<\/sub><\/strong><strong>\u7535\u6781\u5728\u4e0d\u540c\u5145\u653e\u7535\u9636\u6bb5\u7684\u8868\u5f81\u53ca\u9884\u6d4b\u7ed3\u6784<\/strong><strong> \u00a9 2023 Wiely<\/strong><\/p>\n<p>\uff08a\uff09\u4e0d\u540c\u5145\u653e\u7535\u9636\u6bb5\u7684\u8d28\u8c31\u7ed3\u679c\u3002<\/p>\n<p>\uff08b\uff09C<sub>70<\/sub>Al<sub>5<\/sub>Cl<sub>36<\/sub>\u3001C<sub>70<\/sub>Al<sub>5<\/sub>Cl<sub>36<\/sub>O\u548cC<sub>70<\/sub>Al<sub>5<\/sub>Cl<sub>36<\/sub>O<sub>2<\/sub>\u7684\u9884\u6d4b\u7ed3\u6784\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255604\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/5.png\" alt=\"\" width=\"600\" height=\"504\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/11\/5-300x252.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5\u00a0 <\/strong><strong>\u4e0d\u540c\u5145\u7535\u5faa\u73af\u6b21\u6570\u4e0b\u7684\u5145\u653e\u7535\u56fe\u548c\u8868\u5f81<\/strong><strong> \u00a9 2023 Wiely<\/strong><\/p>\n<p>\uff08a\uff09\u5b8c\u5168\u5145\u7535\u72b6\u6001\u4e0b\u524d30\u4e2a\u5faa\u73af\u4e2d\u7535\u6781\u6750\u6599\u53d8\u5316\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08b-c\uff09\u4e0d\u540c\u5faa\u73af\u540e\uff08\u5145\u81f32.4 V\uff09C<sub>70<\/sub>\u6b63\u6781\u7684SEM\u56fe\u50cf\u548cXRD\u56fe\u3002<\/p>\n<p>\uff08d\uff09C<sub>70<\/sub>\u6b63\u6781\u5728200 mA g<sup>-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p>\uff08e\uff09\u4ee5200 mA g<sup>-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u8fdb\u884c\u5145\u653e\u7535\u6d4b\u8bd5\u65f6\uff0cC<sub>70<\/sub>\u6b63\u6781\u7684\u5728\u4e0d\u540c\u5faa\u73af\u6b21\u6570\u4e0b\u7684\u7535\u538b-\u5bb9\u91cf\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u8be5\u7814\u7a76\u901a\u8fc7\u91c7\u7528\u96f6\u7ef4C<sub>70<\/sub>\u4f5c\u4e3a\u6b63\u6781\u6750\u6599\uff0c\u5728\u63d0\u5347\u53ef\u9006\u94dd\u79bb\u5b50\u7535\u6c60\u6027\u80fd\u65b9\u9762\u53d6\u5f97\u4e86\u663e\u8457\u8fdb\u5c55\u3002C<sub>70<\/sub>\u6b63\u6781\u5c55\u73b0\u4e86\u521b\u7eaa\u5f55\u7684\u6bd4\u5bb9\u91cf\uff08\u5728200 mA g<sup>-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u653e\u7535\u6bd4\u5bb9\u91cf\u4e3a750 mAh g<sup>-1<\/sup>\uff09\u548c\u663e\u8457\u7684\u653e\u7535\u7535\u538b\u5e73\u53f0\uff08\u7ea6\u4e3a1.65 V\uff09\u3002\u901a\u8fc7\u76f4\u63a5\u7edc\u5408\u673a\u5236\u7684Al-C<sub>70<\/sub>\u7535\u6c60\uff0c\u53ef\u63d0\u4f9b\u521b\u7eaa\u5f55\u7684\u6bcf\u5355\u4f4d\u6d3b\u6027\u7269\u8d28\u8d28\u91cf\u4e0b\uff0c1237.5 Wh Kg<sup>-1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u901a\u8fc7\u5bf9\u5176\u8fdb\u884c\u4e86\u7cfb\u7edf\u8868\u5f81\uff0c\u53d1\u73b0\u5353\u8d8a\u7684\u7535\u5316\u5b66\u6027\u80fd\u5f52\u56e0\u4e8e\u4e24\u4e2a\u4e3b\u8981\u56e0\u7d20\uff1a\u5bcc\u52d2\u70ef\u7684\u9ad8\u5316\u5b66\u6d3b\u6027\u4f7f\u5f97\u6bcf\u4e2a\u78b3\u7b3c\u4e0a\u53ef\u4ee5\u6dfb\u52a0\u6570\u5341\u4e2a\uff08\u8d85\u7ea7\uff09\u5364\u7d20AlCl<sub>4<\/sub>\/Cl\uff0c\u8fd9\u662f\u5176\u8d85\u9ad8\u5bb9\u91cf\u7684\u57fa\u7840\uff1b\u800c\u5bcc\u52d2\u70ef\u72ec\u7279\u7684\u96f6\u7ef4\u7ed3\u6784\u5177\u6709\u9ad8\u7a33\u5b9a\u6027\uff0c\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u5176\u56fa\u6709\u7ed3\u6784\u4e0d\u4f1a\u88ab\u7834\u574f\uff0c\u786e\u4fdd\u4e86\u51fa\u8272\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u5bcc\u52d2\u70ef\u63d0\u4f9b\u4e86\u4e00\u4e2a\u7c7b\u4f3c\u4e8e\u77f3\u58a8\u6750\u6599\u5171\u8f6d\u7ed3\u6784\u7684\u9ad8\u653e\u538b\u5e73\u53f0\uff0c\u786e\u4fdd\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3002\u8be5\u7814\u7a76\u4e0d\u4ec5\u4e3a\u53ef\u5145\u7535\u94dd\u79bb\u5b50\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u7cfb\u5217\u6709\u6781\u5927\u6f5c\u529b\u7684\u5bcc\u52d2\u70ef\u6b63\u6781\u6750\u6599\uff0c\u540c\u65f6\u4e5f\u4e3a\u65b0\u578b\u7535\u6c60\u7684\u5408\u7406\u8bbe\u8ba1\u548c\u7075\u6d3b\u6269\u5c55\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u7684\u50a8\u80fd\u673a\u5236\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.202306244\" target=\"_blank\" rel=\"noopener\">Ultrahigh Capacity from Complexation-Enabled Aluminum-Ion Batteries with C<sub>70<\/sub> as the Cathode<\/a> (<em>Adv. Mater.<\/em> <strong>2023<\/strong>, 2306244.)<\/p>\n<p>\u672c\u6587\u7531\u8d5b\u6069\u65af\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u7531\u4e8e\u94dd\u91d1\u5c5e\u5177\u6709\u9ad8\u5b89\u5168\u6027\u3001\u9ad8\u4e30\u5ea6\u3001\u4f4e\u6210\u672c\u548c\u8d85\u9ad8\u7406\u8bba\u5bb9\u91cf\uff082980 mAh g-1\uff09\u7684\u4f18\u70b9\uff0c\u53ef\u5145\u7535\u94dd\u79bb\u5b50\u7535\u6c60\uff08RABs\uff09\u5df2\u6210\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u4e00\u79cd\u6781\u5177\u524d\u666f&#8230;<\/p>\n","protected":false},"author":36791,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[5095],"class_list":["post-255598","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-5095"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/255598"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/36791"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=255598"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/255598\/revisions"}],"predecessor-version":[{"id":255608,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/255598\/revisions\/255608"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=255598"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=255598"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=255598"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}