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\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

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\u00a0<\/strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u9ad8\u6566\u5cf0\u7814\u7a76\u5458<\/strong>\u56e2\u961f\u62a5\u544a\u4e00\u79cd\u901a\u8fc7\u6784\u5efa\u91d1\u5c5e\u6709\u673a\u754c\u9762\u4eceCO\u7535\u89e3\u4e2d\u9ad8\u9009\u62e9\u6027\u751f\u4ea7\u4e59\u9178\u76d0\u7684\u7b56\u7565\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u5728\u78b1\u6027\u819c\u7535\u6781\u7ec4\u88c5\u7535\u89e3\u69fd\u4e2d\uff0c\u901a\u8fc7\u539f\u4f4d\u91cd\u6784Cu\u590d\u5408\u7269\u6784\u5efa\u7684Cu\u6709\u673a\u754c\u9762\u663e\u793a\u51fa\u975e\u5e38\u663e\u8457\u7684\u4e59\u9178\u76d0\u9009\u62e9\u6027\uff0c\u5176\u4e59\u9178\u76d0\u751f\u4ea7\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u9ad8\u8fbe84.2%\uff0c\u78b3\u9009\u62e9\u6027\u9ad8\u8fbe92.1%\u3002\u4e59\u9178\u5206\u7535\u6d41\u5bc6\u5ea6\u548c\u4e59\u9178\u4ea7\u7387\u5206\u522b\u9ad8\u8fbe605 mA cm-2<\/sup>\u548c63.4%\uff0c\u5bf9\u5e94\u4e59\u9178\u751f\u6210\u901f\u7387\u4e3a0.38 mmol\/min\u3002\u4e00\u7cfb\u5217\u8868\u5f81\u548c\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u5747\u8868\u660e\uff0c\u94dc\u2014\u6709\u673a\u754c\u9762\u521b\u9020\u4e86\u4e00\u4e2a\u6709\u5229\u7684\u53cd\u5e94\u5fae\u73af\u5883\uff0c\u53ef\u589e\u5f3a*CO\u5438\u9644\uff0c\u964d\u4f4eC-C\u5076\u8054\u7684\u80fd\u91cf\u969c\u788d\uff0c\u4fc3\u8fdbCH3<\/sub>COOH\u7684\u5f62\u6210\u800c\u975e\u5176\u4ed6\u591a\u78b3\u4ea7\u7269\uff0c\u4ece\u800c\u5408\u7406\u5730\u5b9e\u73b0\u4e86\u9009\u62e9\u6027\u4e59\u9178\u76d0\u751f\u4ea7\u3002\u6df1\u5165\u7814\u7a76\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u3001\u6709\u673a\u914d\u4f53\u548c\u53cd\u5e94\u4e2d\u95f4\u7269\u79cd\u4e4b\u95f4\u7684\u590d\u6742\u76f8\u4e92\u4f5c\u7528\uff0c\u6709\u671b\u8fdb\u4e00\u6b65\u5b9e\u73b0\u9ad8\u6d3b\u6027\u3001\u9ad8\u9009\u62e9\u6027CO2<\/sub>\/CO\u7535\u89e3\u5236\u5176\u5b83\u5355\u4e00C2+<\/sub>\u4ea7\u7269\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cDirecting the Selectivity of CO Electrolysis to Acetate by Constructing Metal-Organic Interfaces<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aAngew. Chem. Int. Ed.<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

\u901a\u8fc7\u6784\u5efa\u91d1\u5c5e\u2014\u6709\u673a\u754c\u9762\u8c03\u63a7\u53cd\u5e94\u5fae\u73af\u5883\uff0c\u6784\u5efa\u51fa\u94dc\u2014\u6709\u673a\u754c\u9762\uff0c\u8bf1\u5bfc\u5f62\u6210\u6709\u5229\u4e8e\u4e59\u9178\u8def\u5f84\u7684\u53cd\u5e94\u5fae\u73af\u5883\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u4e59\u9178\u9009\u62e9\u6027\uff1a\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a500mA cm-2<\/sup>\u65f6\uff0c\u4e59\u9178\u6cd5\u62c9\u7b2c\u6548\u7387\u548c\u78b3\u9009\u62e9\u6027\u5206\u522b\u8fbe\u523084.2%\u548c92.1%\uff0c\u4e59\u9178\u5206\u7535\u6d41\u5bc6\u5ea6\u548c\u4e59\u9178\u4ea7\u7387\u5206\u522b\u9ad8\u8fbe605 mA cm-2<\/sup>\u548c63.4%\u3002<\/p>\n

\u00a0<\/strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>1\u00a0 CuPc<\/strong>\u7535\u6781\u7684<\/strong>CO<\/strong>\u7535\u89e3\u6027\u80fd<\/strong> \u00a9 2023 Wiely<\/strong><\/p>\n

\uff08a-b\uff09\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b\u6d4b\u91cf\u7684FE\u548c\u7535\u6c60\u7535\u538b\u4e0e\u5916\u52a0\u7535\u6d41\u5bc6\u5ea6\u7684\u51fd\u6570\u5173\u7cfb\uff1a0.1 M KOH\u30010.1 MPa\u8fdb\u6599\uff1b1 M KOH\u30011 MPa\u8fdb\u6599\u3002<\/p>\n

\uff08c\uff09\u6700\u5927\u4e59\u9178\u76d0FE\u548c\u76f8\u5e94\u7684\u4e59\u9178\u76d0EE\u3002<\/p>\n

\uff08d\uff09CO\u7535\u89e3\u751f\u6210\u4e59\u9178\u76d0\u7684\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n

\uff08e\uff091 M KOH\u30010.5 MPa\u8fdb\u6599\u65f6\u5728300 mA cm-2<\/sup>\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2\u00a0 CuPc<\/strong>\u7535\u6781\u7ed3\u6784\u8868\u5f81<\/strong> \u00a9 2023 Wiely<\/strong><\/p>\n

\uff08a\uff09\u5236\u5907\u7684CuPc\u7535\u6781\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\uff08b\uff09CuPc\u7535\u6781\u5728500mA cm-2<\/sup>\u4e0bCO\u7535\u89e3\u540e\u7684SEM\u56fe\u50cf\u548c\u5143\u7d20\u56fe\u8c31\u3002<\/p>\n

\uff08c-d\uff09CuPc\u7535\u6781\u5728500mA cm-2<\/sup>\u4e0bCO\u7535\u89e3\u540e\u7684TEM\u548cHRTEM\u56fe\u50cf\u3002<\/p>\n

\uff08e-f\uff09CuPc\u7535\u6781\u5728500mA cm-2<\/sup>\u4e0bCO\u7535\u89e3\u540e\u7684XRD\u56fe\u8c31\u548c\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3\u00a0 CuPc<\/strong>\u7535\u6781\u6210\u5206\u5206\u6790<\/strong> \u00a9 2023 Wiely<\/strong><\/p>\n

\uff08a-b\uff09CuPc\u7535\u6781\u7684Cu K\u8fb9XANES\u548cEXAFS\u5149\u8c31\u3002<\/p>\n

\uff08c-e\uff09\u5728500 mA cm-2<\/sup>\u4e0bCO\u7535\u89e3\u524d\u540eCuPc\u7535\u6781\u7684Cu2p\u3001Cu LMM\u548cN1s\u7684\u51c6\u539f\u4f4dXPS\u5149\u8c31\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4\u00a0 CuPc<\/strong>\u7535\u6781\u7535\u89e3<\/strong>CO<\/strong>\u5236\u4e59\u9178\u6027\u80fd\u8868\u5f81<\/strong> \u00a9 2023 Wiely<\/strong><\/p>\n

\uff08a\uff09\u53cd\u5e94\u540e\u7684CuPc\u7535\u6781\u548cCO\u7535\u89e3\u540e\u7528\u6d17\u6da4\u8fc7\u7684CuPc\u50ac\u5316\u5242\u5236\u5907\u7684\u5bf9\u7167\u7535\u6781\u7684N1s XPS\u5149\u8c31\u3002<\/p>\n

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\uff08c-d\uff09CuTPP\u548cCuDMP\u7535\u6781\u7684Cu K\u8fb9 XANES\u548cEXAFS\u5149\u8c31\u3002<\/p>\n

\uff08e\uff09LDEE\u548cLDME\u7a00\u91ca\u6d4b\u8bd5\u57fa\u8d28\u4e2d\u7535\u8377\u8f6c\u79fb\u5cf0\u6700\u5927\u503c\u4e0e\u6e29\u5ea6\u7684\u51fd\u6570\u5173\u7cfb\u6c47\u603b\u3002<\/p>\n

\uff08f\uff09CuPc\u3001CuTPP\u548cCuDMP\u7535\u6781\u4e0a\u4e59\u9178\u548cC2+<\/sub>\u90e8\u5206\u7535\u6d41\u5bc6\u5ea6\u4e0e\u7535\u6c60\u7535\u538b\u7684\u51fd\u6570\u5173\u7cfb\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5\u00a0 <\/strong>\u5de5\u51b5\u62c9\u66fc\u5149\u8c31\u8868\u5f81\u548c\u7406\u8bba\u8ba1\u7b97<\/strong> \u00a9 2023 Wiely<\/strong><\/p>\n

\uff08a\uff09\u57280.1 M KOH\u6eb6\u6db2\u4e2d\u4ee550 mA cm-2<\/sup>\u7684\u7535\u6d41\u6d4b\u91cf\u7684CuPc\u548cCuPc\u6c34\u6d17\u540e\u7535\u6781\u7684\u5de5\u51b5\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n

\uff08b-c\uff09\u6709\/\u65e0H2Pc-H2<\/sub>O\u5206\u5b50\u5b58\u5728\u65f6\uff0cCO\u5728Cu(111)\u8868\u9762\u7535\u89e3\u4e3aCH3COOH\u7684CO\u5438\u9644\u80fd\u548c\u53cd\u5e94\u81ea\u7531\u80fd\u66f2\u7ebf\u3002<\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

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\u539f\u6587\u8be6\u60c5<\/strong>\uff1aDirecting the Selectivity of CO Electrolysis to Acetate by Constructing Metal-Organic Interfaces<\/a> (Angew. Chem. Int. Ed.<\/em> 2023<\/strong>, e202309893.)<\/p>\n

 <\/p>\n

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