{"id":255289,"date":"2023-10-24T06:24:23","date_gmt":"2023-10-23T22:24:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=255289"},"modified":"2023-10-23T21:24:39","modified_gmt":"2023-10-23T13:24:39","slug":"pnas%ef%bc%9a%e6%9e%81%e7%ab%af%e6%9d%a1%e4%bb%b6%e4%b8%8blmb%e6%ba%b6%e5%89%82%e5%8c%96%e5%8f%8d%e5%ba%94%e7%9a%84%e5%ae%9a%e9%87%8f%e7%95%8c%e9%9d%a2%e5%88%86%e6%9e%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=255289","title":{"rendered":"PNAS\uff1a\u6781\u7aef\u6761\u4ef6\u4e0bLMB\u6eb6\u5242\u5316\u53cd\u5e94\u7684\u5b9a\u91cf\u754c\u9762\u5206\u6790"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u662f\u73b0\u4ee3\u4fbf\u643a\u5f0f\u7535\u5b50\u4ea7\u54c1\u548c\u7535\u52a8\u6c7d\u8f66\u7684\u57fa\u7840\u6280\u672f\u3002\u5728\u4f17\u591a\u5019\u9009\u8005\u4e2d\uff0c\u9502\u91d1\u5c5e\u7535\u6c60\uff08LMB\uff09\u4ee5\u9502\u91d1\u5c5e\uff083860 mAh g<sup>-1<\/sup>\uff09\u53d6\u4ee3\u77f3\u58a8\u8d1f\u6781\uff08372 mAh g<sup>-1<\/sup>\uff09\uff0c\u662f\u6700\u6709\u524d\u9014\u7684\u3002\u9664\u4e86\u65e8\u5728\u51cf\u8f7b\u5bc4\u751f\u53cd\u5e94\u548c\u4f53\u79ef\u53d8\u5316\u7684\u8bbe\u8ba1\u6311\u6218\u5916\uff0cLMB\u8fd8\u5fc5\u987b\u9075\u5b88\u4e0e\u65b0\u4e00\u4ee3\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u540c\u6216\u76f8\u4f3c\u7684\u4f7f\u7528\u6761\u4ef6\u3002\u4e5f\u5c31\u662f\u8bf4\uff0c\u5fc5\u987b\u5728\u5feb\u901f\u5145\u7535\u548c\u4f4e\u6e29\u64cd\u4f5c\u7b49\u52a8\u6001\u5e94\u53d8\u64cd\u4f5c\u6761\u4ef6\u4e0b\u786e\u4fddLMB\u7684\u80fd\u91cf\u8f93\u51fa\u3001\u5e93\u4ed1\u6548\u7387\uff08CE\uff09\u5b9a\u4e49\u7684\u5faa\u73af\u6027\u548c\u5b89\u5168\u6027\u3002\u8fd1\u671f\u7814\u7a76\u8868\u660e\uff0cLi<sup>+<\/sup>\u7684\u53bb\u6eb6\u5242\u52a8\u529b\u5b66\u5728\u5b9e\u73b0\u8fd9\u79cd\u6761\u4ef6\u4e0b\u7684\u8fd0\u884c\u4e2d\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u7136\u800c\uff0c\u5bf9\u8fd9\u4e00\u8fc7\u7a0b\u7684\u8c03\u8282\u901a\u5e38\u662f\u901a\u8fc7\u5728\u7cfb\u7edf\u4e2d\u8bf1\u5bfc\u5b9a\u6027\u7a0b\u5ea6\u7684\u79bb\u5b50\u914d\u5bf9\u6765\u5b9e\u73b0\u7684\u3002<\/p>\n<p><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u52a0\u5dde\u5927\u5b66\u5723\u8fed\u6208\u5206\u6821\u9648\u653f\u6559\u6388\u8054\u5408<\/strong><strong>Liu Ping<\/strong><strong>\u3001<\/strong><strong>John Holoubek<\/strong><strong>\u7b49\u4eba<\/strong>\u7814\u7a76\u53d1\u73b0\uff0c\u5bf9\u79bb\u5b50\u914d\u5bf9\u8fdb\u884c\u5b9a\u91cf\u7684\u63a7\u5236\u5bf9\u4e8e\u6700\u5927\u9650\u5ea6\u5730\u51cf\u5c11\u5e26\u7535\u754c\u9762\u5904\u7684\u53bb\u6eb6\u5242\u5316\u635f\u5931\uff0c\u4ece\u800c\u6700\u5927\u9650\u5ea6\u5730\u964d\u4f4e\u9502\u91d1\u5c5e\u8d1f\u6781\u5728\u52a8\u6001\u5e94\u53d8\u4e0b\u7684\u53ef\u9006\u6027\u81f3\u5173\u91cd\u8981\u3002\u8fd9\u79cd\u6548\u5e94\u5728\u57fa\u4e8e\u5f3a\/\u5f31\u7ed3\u5408\u7684\u919a\u6eb6\u5242\u7684\u5c40\u90e8\u7535\u89e3\u8d28\u4e2d\u5f97\u5230\u4e86\u8bc1\u660e\uff0c\u5176\u5141\u8bb8\u6eb6\u5242\u5316\u5316\u5b66\u548c\u7ed3\u6784\u7684\u53cd\u5377\u79ef\u3002\u51fa\u4e4e\u610f\u6599\u7684\u662f\uff0c\u4f5c\u8005\u53d1\u73b0\u79bb\u5b50\u914d\u5bf9\u7684\u6700\u5927\u7a0b\u5ea6\u5bf9\u4e8e\u8d85\u4f4e\u6e29\u548c\u9ad8\u500d\u7387\u8fd0\u884c\u6765\u8bf4\u5e76\u4e0d\u7406\u60f3\uff0c\u5e76\u4e14\u901a\u8fc7\u8fdc\u79bb\u9971\u548c\u70b9\u7684\u8f7b\u5fae\u5c40\u90e8\u7a00\u91ca\uff0c\u53ef\u9006\u6027\u5f97\u5230\u4e86\u663e\u8457\u6539\u5584\u3002\u6b64\u5916\uff0c\u5728\u6bcf\u4e2a\u7cfb\u7edf\u7684\u6700\u4f73\u79bb\u5b50\u914d\u5bf9\u7a0b\u5ea6\u4e0b\uff0c\u5f31\u7ed3\u5408\u6eb6\u5242\u4ecd\u7136\u4f1a\u4ea7\u751f\u4f18\u5f02\u7684\u6027\u80fd\u3002\u901a\u8fc7\u5b9e\u9a8c\u548c\u8ba1\u7b97\u5206\u6790\uff0c\u660e\u786e\u5730\u89e3\u51b3\u4e86\u8fd9\u4e9b\u7ed3\u6784\u548c\u5316\u5b66\u6548\u5e94\u5bf9\u7535\u8377\u8f6c\u79fb\u7684\u5f71\u54cd\u3002\u6700\u540e\u8bc1\u660e\u4e86\u7ecf\u8fc7\u5c40\u90e8\u4f18\u5316\u7684\u57fa\u4e8e\u4e8c\u4e59\u919a\u7684\u5c40\u90e8\u9ad8\u6d53\u5ea6\u7535\u89e3\u8d28\u652f\u6301\u52a8\u529b\u5b66\u5e94\u53d8\u64cd\u4f5c\u6761\u4ef6\uff0c\u5305\u62ec\u4f4e\u81f3-60\u2103\u7684\u5faa\u73af\u548cLMB\u5168\u7535\u6c60\u4e2d20\u5206\u949f\u7684\u5feb\u901f\u5145\u7535\u3002\u8fd9\u9879\u5de5\u4f5c\u8868\u660e\uff0c\u8981\u5f00\u53d1\u51fa\u80fd\u591f\u5728\u4f4e\u6e29\u548c\u9ad8\u901f\u6761\u4ef6\u4e0b\u5de5\u4f5c\u7684LMB\u7535\u89e3\u8d28\uff0c\u5c31\u5fc5\u987b\u5bf9Li<sup>+<\/sup>\u6eb6\u89e3\u72b6\u6001\u8fdb\u884c\u660e\u786e\u7684\u5b9a\u91cf\u4f18\u5316\u8fd9\u4e9b\u53d1\u73b0\u63d0\u51fa\u4e86\u6eb6\u5242\u5316\u548c\u52a8\u529b\u5b66\u4e4b\u95f4\u66f4\u5b9a\u91cf\u7684\u5173\u7cfb\uff0c\u5e76\u4e3a\u4f4e\u6e29\u5feb\u901f\u5145\u7535\u7684\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u53ef\u64cd\u4f5c\u7684\u6307\u5bfc\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>Toward a quantitative interfacial description of solvation for Li metal battery operation under extreme conditions<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520a<strong><em>PNAS<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255290\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/0-3.png\" alt=\"\" width=\"600\" height=\"152\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/0-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/0-3-300x76.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u901a\u8fc7\u5b9e\u9a8c\u548c\u8ba1\u7b97\u7814\u7a76\u4e86\u4e00\u7cfb\u5217\u987a\u5e8f\u8c03\u5236\u7684\u7535\u89e3\u8d28\uff0c\u8fd9\u4e9b\u7535\u89e3\u8d28\u5728\u6210\u5206\u7565\u5fae\u7a00\u91ca\u3001\u8fdc\u79bb\u6700\u5927\u79bb\u5b50\u914d\u5bf9\u72b6\u6001\u65f6\u8868\u73b0\u51fa\u5353\u8d8a\u7684\u52a8\u529b\u5b66\u6027\u80fd\u3002\u8fd9\u4e9b\u53d1\u73b0\u63a8\u8fdb\u4e86\u6eb6\u89e3\u4e0e\u52a8\u529b\u5b66\u4e4b\u95f4\u7684\u5b9a\u91cf\u5173\u7cfb\uff0c\u4e3a\u4f4e\u6e29\u5feb\u901f\u5145\u7535LMB\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002<\/p>\n<p><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255291\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/1-9.png\" alt=\"\" width=\"600\" height=\"283\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/1-9.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/1-9-300x142.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1\u00a0 <\/strong><strong>\u672c\u7814\u7a76\u603b\u89c8<\/strong><strong> \u00a9 2023 National Academy of Science<\/strong><\/p>\n<p>\uff08A\uff09\u5c40\u90e8\u548c\uff08B\uff09\u957f\u7a0bLi<sup>+<\/sup>\u6eb6\u5242\u5316\u6001\u7684\u4ea4\u7ec7\u6548\u5e94\u53ca\u5176\u5bf9\uff08C\uff09\u754c\u9762\u5904\u7684\u53bb\u6eb6\u5242\u5316\u52a8\u529b\u5b66\u548c\uff08D\uff09\u52a8\u529b\u5b66\u5e94\u53d8\u4e0b\u7684Li\u91d1\u5c5e\u5faa\u73af\u884c\u4e3a\u7684\u5f71\u54cd\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255292\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/2-8.png\" alt=\"\" width=\"600\" height=\"596\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/2-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/2-8-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/2-8-300x298.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2\u00a0 LHCE<\/strong><strong>\u7a00\u91ca\u5bf9\u9502\u91d1\u5c5e\u8d1f\u6781\u6027\u80fd\u7684\u5f71\u54cd<\/strong><strong> \u00a9 2023 National Academy of Science<\/strong><\/p>\n<p>\uff08A\uff09\u7531DEE\uff08LDEE\uff09\u548cDME\uff08LDME\uff09\u7ec4\u6210\u7684LHCE\u7cfb\u7edf\u7684\u6574\u4f53\u548c\u5c40\u90e8\u7a00\u91ca\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08B-C\uff09LDME\u548cLDEE\u4f53\u7cfb\u5728\u9971\u548c\u76d0\/\u6eb6\u5242\u5316\u6eb6\u5242\u6bd4\u4e0eBTFE\u91cf\u7684\u5173\u7cfb\u3002<\/p>\n<p>\uff08D-E\uff0923\u00b0C\u548c\u221240\u00b0C\u6761\u4ef6\u4e0b\uff0cLDME\u548cLDEE\u4f53\u7cfb\u57280.5 mA cm<sup>-2<\/sup>\u65f6\u7684Li||Cu CE\u6d4b\u91cf\u7ed3\u679c\uff0c\u4f5c\u4e3a\u6574\u4f53\u7a00\u91ca\u7684\u51fd\u6570\u3002<\/p>\n<p>\uff08F\uff09LDME\u548cLDEE\u7cfb\u7edf\u5728\u6700\u4f73BTFE\u91cf\u4e0b\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4f5c\u4e3a\u5c40\u90e8\u7a00\u91ca\u7684\u51fd\u6570\u3002<\/p>\n<p>\uff08G\uff09\u603b\u7ed3\u6d4b\u91cf\u4e86LDME\u548cLDEE\u7cfb\u7edf\u5728-60\u2103\u548c0.25 mA cm<sup>-2<\/sup>\u4e0b\u7684Li CE\u4f5c\u4e3aDME\u548cDEE\u542b\u91cf\u7684\u51fd\u6570\u3002<\/p>\n<p>\uff08H-I\uff09LDME\u548cLDEE\u7cfb\u7edf\u57280.25 mA cm<sup>-2<\/sup>\u4e0b\u7684\u6d4b\u91cf\u7535\u538b\u66f2\u7ebf\uff0c\u4f5c\u4e3a\u5c40\u90e8\u7a00\u91ca\u7684\u51fd\u6570\u3002<\/p>\n<p>\uff08J-K\uff09\u5728LDME 1.8\u548cLDEE 2.6\u4e2d\u8fdb\u884c\u51b7\u51bbFIB\u7814\u78e8\u540e\uff0c\u5728-60\u00b0C\u548c0.25 mA cm<sup>-2<\/sup>\u4e0b\u9540\u8986\u76840.25 mAh cm<sup>-2<\/sup> Li\u91d1\u5c5e\u7684SEM\u663e\u5fae\u955c\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255293\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/3-9.png\" alt=\"\" width=\"600\" height=\"308\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/3-9.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/3-9-300x154.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3\u00a0 LHCE<\/strong><strong>\u7cfb\u7edf\u4e2d<\/strong><strong>Li||Cu<\/strong><strong>\u7535\u6c60\u7684\u9ad8\u901f\u7387\u6027\u80fd<\/strong><strong> \u00a9 2023 National Academy of Science<\/strong><\/p>\n<p>\uff08A\uff09\u91c7\u7528LHCE\u7cfb\u7edf\u7684Li||Cu\u7535\u6c60\u7684\u53ef\u53d8\u901f\u7387CE\u3002<\/p>\n<p>\uff08B\uff09\u572810 mA cm<sup>-2<\/sup>\u548c3 mAh cm<sup>-2<\/sup>\u4e0b\u8fd0\u884c\u7684\u91c7\u7528LDME\u7535\u89e3\u8d28\u7684Li||Cu\u7535\u6c60\u7684\u7535\u538b\u5206\u5e03\u3002<\/p>\n<p>\uff08C\uff09\u572810 mA cm<sup>-2<\/sup>\u548c3 mAh cm<sup>-2<\/sup>\u4e0b\uff0c\u91c7\u7528LDEE\u7535\u89e3\u8d28\u7684Li||Cu\u7535\u6c60\u7684CE\u3002<\/p>\n<p>\uff08D\uff09\u572810 mA cm<sup>-2<\/sup>\u548c5 mAh cm<sup>-2<\/sup>\u4e0b\uff0c\u4f7f\u7528LDEE\u7535\u89e3\u8d28\u7684Li||Cu\u7535\u6c60\u7684CE\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255294\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/4-7.png\" alt=\"\" width=\"600\" height=\"410\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/4-7.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/4-7-300x205.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4\u00a0 <\/strong><strong>\u7535\u89e3\u8d28\u4e2d\u9502\u91d1\u5c5e\u7684\u963b\u6297\u5206\u6790<\/strong><strong> \u00a9 2023 National Academy of Science<\/strong><\/p>\n<p>\uff08A\uff09\u7535\u6c60\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08B\uff0923\u00b0C\u548c-60\u00b0C\u4e4b\u95f4EIS\u6d4b\u91cf\u7684\u5f1b\u8c6b\u65f6\u95f4\u5206\u5e03\uff08DRT\uff09\u66f2\u7ebf\u3002<\/p>\n<p>\uff08C-D\uff09LDME 1.8\u548cLDEE 2.6\u7535\u89e3\u8d28\u6d4b\u8bd5\u57fa\u8d28\u4e2dSEI\u548c\u7535\u8377\u8f6c\u79fb\u5cf0\u7684\u5cf0\u503c\u6700\u5927\u503c\u4e0e\u6e29\u5ea6\u7684\u51fd\u6570\u5173\u7cfb\u6c47\u603b\u3002<\/p>\n<p>\uff08E\uff09LDEE\u548cLDME\u7a00\u91ca\u6d4b\u8bd5\u57fa\u8d28\u4e2d\u7535\u8377\u8f6c\u79fb\u5cf0\u6700\u5927\u503c\u4e0e\u6e29\u5ea6\u7684\u51fd\u6570\u5173\u7cfb\u6c47\u603b\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255295\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/5-7.png\" alt=\"\" width=\"600\" height=\"661\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/5-7.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/5-7-272x300.png 272w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5\u00a0 <\/strong><strong>\u672c\u4f53\u548c\u7535\u5316\u5b66\u754c\u9762\u7535\u89e3\u8d28\u7ed3\u6784\u5fae\u89c2\u5206\u6790\u548c\u70ed\u529b\u5b66\u5206\u6790<\/strong><strong> \u00a9 2023 National Academy of Science<\/strong><\/p>\n<p>\uff08A\uff09\u672c\u4f53\u7535\u89e3\u8d28\u7684\u4ee3\u8868\u6027MD\u5feb\u7167\u3002<\/p>\n<p>\uff08B\uff09LDME 1.2\u548c1.8\u76f8\u5bf9\u4e8eDME O\u914d\u4f4d\u7684\u4e00\u7ef4\u81ea\u7531\u80fd\u5206\u5e03\u3002<\/p>\n<p>\uff08C\uff09LDEE 1.7\u548c2.6\u76f8\u5bf9\u4e8eDME O\u914d\u4f4d\u7684\u4e00\u7ef4\u81ea\u7531\u80fd\u5206\u5e03\u3002<\/p>\n<p>\uff08D\uff09\u76f8\u5bf9\u4e8eD<sub>2<\/sub>O\u4e2d1 M LiCl\u7684LHCE\u7cfb\u7edf\u7684<sup>7<\/sup>Li\uff08194 MHz\uff09NMR\u5149\u8c31\u3002<\/p>\n<p>\uff08E\uff09\u4f7f\u7528\u7684\u504f\u7f6e\uff0811.6\u81f311.7\u03bcC cm<sup>-2<\/sup>\uff09\u754c\u9762\u6a21\u62df\u7684\u4ee3\u8868\u6027MD\u5feb\u7167\u3002<\/p>\n<p>\uff08F-G\uff09LDME 1-1.2-4\u548cLDME 1-1.8-4\u5728\u7535\u5316\u5b66\u754c\u9762\u5904\u76f8\u5bf9\u4e8eLi<sup>+<\/sup>\/\u7535\u6781\u8ddd\u79bb\u548cLi<sup>+<\/sup> DME O\u914d\u4f4d\u7684\u4e8c\u7ef4\u81ea\u7531\u80fd\u8c31\u3002<\/p>\n<p>\uff08H-I\uff09\u4eceLDME 1.2\u548cLDME 1.8\u7684\u4e8c\u7ef4\u5149\u8c31\u4e2d\u83b7\u5f97\u7684\u4e00\u7ef4\u81ea\u7531\u80fd\u8def\u5f84\u3002<\/p>\n<p>\uff08J-K\uff09LDEE 1-1.7-2\u548cLDEE 1-2.6-2\u5728\u7535\u5316\u5b66\u754c\u9762\u5904\u76f8\u5bf9\u4e8eLi<sup>+<\/sup>\/\u7535\u6781\u8ddd\u79bb\u548cLi<sup>+<\/sup> DME O\u914d\u4f4d\u7684\u4e8c\u7ef4\u81ea\u7531\u80fd\u8c31\u3002<\/p>\n<p>\uff08L-M\uff09\u4eceLDEE 1.7\u548cLDEE 2.6\u7684\u4e8c\u7ef4\u5149\u8c31\u4e2d\u83b7\u5f97\u7684\u4e00\u7ef4\u81ea\u7531\u80fd\u9014\u5f84\u3002<\/p>\n<p>\uff08N\uff09\u754c\u9762\u5904\u6eb6\u5242\u914d\u4f4d\u6570\uff08CN\uff09\u4f9d\u8d56\u6027Li<sup>+<\/sup>\u8fc1\u79fb\u9014\u5f84\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-255296\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/6-4.png\" alt=\"\" width=\"600\" height=\"379\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/6-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/10\/6-4-300x190.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>6\u00a0 <\/strong><strong>\u9502\u91d1\u5c5e\u5168\u7535\u6c60\u5728\u964d\u4f4e\u6e29\u5ea6\u548c\u63d0\u9ad8\u5145\u7535\u901f\u7387\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/strong><strong> \u00a9 2023 National Academy of Science<\/strong><\/p>\n<p>\uff08A\uff0920\u03bcm Li||10 mg cm<sup>-2<\/sup>NCA\u786c\u5e01\u578b\u5168\u7535\u6c60\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08B-E\uff09\u7535\u6c60\u5206\u522b\u5728\u4ee5\u4e0b\u6761\u4ef6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1a\uff08B\uff0923 \u2103\uff0cC\/3\u5145\u7535||C\/3\u653e\u7535\u548c4.3 V\u622a\u6b62\u7535\u538b\uff1b\uff08C\uff0923\u2103\uff0c20\u5206\u949f\u5145\u7535||C\/3\u653e\u7535\u548c4.3 V\u622a\u6b62\u7535\u538b\uff1b\uff08D\uff09-40\u2103\uff0c0.1C||0.2C\u548c4.4 V\u622a\u6b62\u7535\u538b\uff1b\uff08E\uff09-60\u2103\uff0c0.1C||0.2C\u548c4.5 V\u622a\u6b62\u7535\u538b\u3002<\/p>\n<p>\uff08F\uff09\u4f7f\u75283 g Ah<sup>-1<\/sup> LDEE 2.6\u7535\u89e3\u8d28\u7684\u5355\u5c4220 \u03bcm Li||10 mg cm<sup>-2<\/sup> NCA\u888b\u5f0f\u5168\u7535\u6c60\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08G\uff09TPDBD\u901a\u9053\u8fb9\u7f18\u548c\u4e2d\u5fc3\u7684Na<sup>+<\/sup>\u4f20\u8f93\u901f\u5ea6\u3002<\/p>\n<p>\uff08H\uff09\u4f5c\u4e3a\u6b63\u6781\u8d1f\u8f7d\u548c\u5de5\u4f5c\u6e29\u5ea6\u7684\u51fd\u6570\u7684\u7535\u6c60\u7ea7\u80fd\u91cf\u5bc6\u5ea6\u9884\u6d4b\u3002<\/p>\n<p><strong>\u00a0<\/strong><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u901a\u8fc7\u5bf9\u7531\u4e8c\u7532\u919a\u548c\u4e8c\u4e59\u919a\u7ec4\u6210\u7684 LHCE \u7cfb\u7edf\u4e2d\u7684\u5168\u5c40\u7a00\u91ca\u3001\u5c40\u90e8\u7a00\u91ca\u548c\u6eb6\u5242\u5316\u5b66\u6027\u8d28\u7684\u72ec\u7acb\u8c03\u5236\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0\u6eb6\u5242\u7ed3\u5408\u548c\u79bb\u5b50\u914d\u5bf9\u7a0b\u5ea6\u5728Li<sup>+<\/sup>\u53bb\u6eb6\u5242\u5316\u52a8\u529b\u5b66\u4e2d\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u6700\u91cd\u8981\u7684\u662f\uff0c\u5f53\u79bb\u5b50\u914d\u5bf9\u7a0b\u5ea6\u5c0f\u4e8e\u6bcf\u4e2a\u4f53\u7cfb\u7684\u76d0\u9971\u548c\u6781\u9650\u65f6\uff0c\u6eb6\u89e3\u72b6\u6001\u5c31\u4f1a\u51fa\u73b0\u6700\u4f73\u5206\u5e03\u3002\u8fd9\u4e9b\u6548\u5e94\u5728\u6539\u5584\u9502\u91d1\u5c5e\u8d1f\u6781\u5728\u52a8\u529b\u5b66\u5e94\u53d8\u6761\u4ef6\u4e0b\u7684\u6027\u80fd\u65b9\u9762\u53d1\u6325\u4e86\u663e\u8457\u4f5c\u7528\uff0c\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0cLDEE\u548cLDME\u7cfb\u7edf-60\u2103\u65f6\u7684CE\u5206\u522b\u4e3a98.9%\u548c98.0%\u3002\u6b64\u5916\u8fd8\u53d1\u73b0DEE\u548c\u5c40\u90e8\u7a00\u91ca\u6709\u5229\u4e8e\u9502\u91d1\u5c5e\u8d1f\u6781\u572810 mA\u30015 mAh cm<sup>-2<\/sup>\u5faa\u73af\u6761\u4ef6\u4e0b\u7684\u8fd0\u884c\uff0c\u800cLDME\u7535\u6c60\u5728\u8fd9\u79cd\u6761\u4ef6\u4e0b\u7684\u8fd0\u884c\u65f6\u95f4\u8f83\u77ed\u3002\u8fd9\u4e9b\u5c40\u90e8\u7a00\u91ca\u548c\u6eb6\u5242\u5316\u5b66\u6548\u5e94\u51b3\u5b9a\u4e86\u4f4e\u6e29\u6027\u80fd\uff0c\u5e76\u6781\u5927\u5730\u5f71\u54cd\u4e86\u9ad8\u500d\u7387\u4e0b\u7684\u5ba4\u6e29\u53ef\u9006\u6027\uff0c\u5b83\u4eec\u662f\u589e\u5f3a\u578b\u8131\u6eb6\u52a8\u529b\u5b66\u7684\u57fa\u672c\u7ed3\u679c\uff0c\u901a\u8fc7\u57fa\u4e8eDRT\u7684\u591a\u7cfb\u7edf\u5206\u6790\u5bf9\u5176\u8fdb\u884c\u4e86\u89e3\u6784\u3002\u901a\u8fc7\u8ba1\u7b97\u7814\u7a76\uff0c\u7814\u7a76\u4eba\u5458\u9884\u6d4b\u4e0d\u540c\u7684\u6eb6\u5242\u5316\u5fae\u89c2\u72b6\u6001\u5728\u754c\u9762\u5904\u4ea7\u751f\u76f8\u5e94\u7684\u4e0d\u540c\u7684\u53bb\u6eb6\u5242\u5316\u52bf\u5792\uff0c\u5176\u4e2d\u5177\u6709\u4f4e\u3001\u975e\u96f6\u914d\u4f4d\u6eb6\u5242\u91cf\u7684\u7ed3\u6784\u663e\u793a\u51fa\u4f18\u8d8a\u7684\u52a8\u529b\u5b66\u3002\u57fa\u4e8eNCA\u7684LMB\u5168\u7535\u6c60\u5229\u7528\u4e86\u8fd9\u4e9b\u6548\u5e94\uff0c\u5728\u4f4e\u81f3-60\u2103\u548c\u5ba4\u6e2920\u5206\u949f\u5feb\u901f\u5145\u7535\u6761\u4ef6\u4e0b\u663e\u793a\u51fa\u5353\u8d8a\u7684\u53ef\u9006\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u65e8\u5728\u5c55\u793a\u9502\u7535\u89e3\u8d28\u4e2d\u6eb6\u89e3\u7ed3\u6784\u8bbe\u8ba1\u7684\u4e00\u79cd\u66f4\u7ec6\u81f4\u7684\u65b9\u6cd5\uff0c\u901a\u8fc7\u63a7\u5236\u754c\u9762\u4e0a\u5404\u4e2a\u5fae\u89c2\u72b6\u6001\u7684\u5206\u5e03\uff0c\u53ef\u5728\u52a8\u529b\u5b66\u5e94\u53d8\u64cd\u4f5c\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e0b\u4e00\u4ee3\u9ad8\u6027\u80fdLMB\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1a<a href=\"https:\/\/www.pnas.org\/doi\/10.1073\/pnas.2310714120\" target=\"_blank\" rel=\"noopener\">Toward a quantitative interfacial description of solvation for Li metal battery operation under extreme conditions<\/a> (<em>PNAS <\/em><strong>2023<\/strong>, <em>120<\/em>, e2310714120)<\/p>\n<p>\u672c\u6587\u7531\u8d5b\u6069\u65af\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u662f\u73b0\u4ee3\u4fbf\u643a\u5f0f\u7535\u5b50\u4ea7\u54c1\u548c\u7535\u52a8\u6c7d\u8f66\u7684\u57fa\u7840\u6280\u672f\u3002\u5728\u4f17\u591a\u5019\u9009\u8005\u4e2d\uff0c\u9502\u91d1\u5c5e\u7535\u6c60\uff08LMB\uff09\u4ee5\u9502\u91d1\u5c5e\uff083860 mAh g-1\uff09\u53d6\u4ee3\u77f3\u58a8\u8d1f&#8230;<\/p>\n","protected":false},"author":36791,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-255289","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/255289"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/36791"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=255289"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/255289\/revisions"}],"predecessor-version":[{"id":255297,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/255289\/revisions\/255297"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=255289"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=255289"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=255289"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}