{"id":254458,"date":"2023-09-19T06:26:56","date_gmt":"2023-09-18T22:26:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=254458"},"modified":"2023-09-18T21:27:10","modified_gmt":"2023-09-18T13:27:10","slug":"%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6%e5%9b%a2%e9%98%9f%e9%a2%86%e8%a1%94nature-energy%ef%bc%9a%e7%94%b5%e8%a7%a3%e8%b4%a8%e5%b7%a5%e7%a8%8b%e7%ad%96%e7%95%a5%e5%8a%a9%e5%8a%9b%e6%9e%81%e7%ab%af","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=254458","title":{"rendered":"\u6e05\u534e\u5927\u5b66\u56e2\u961f\u9886\u8854Nature Energy\uff1a\u7535\u89e3\u8d28\u5de5\u7a0b\u7b56\u7565\u52a9\u529b\u6781\u7aef\u5de5\u4f5c\u6761\u4ef6\u4e0b\u8fd0\u884c\u7684\u9ad8\u538b\u9502\u7535"},"content":{"rendered":"

\u4e00\u3001<\/strong> \u3010\u5bfc\u8bfb\u3011<\/strong>\u00a0 <\/strong><\/p>\n

\u57fa\u4e8e\u919a\u7684\u7535\u89e3\u8d28\u56e0\u5176\u4e0e\u9502\u91d1\u5c5e\u7684\u76f8\u5bf9\u4f4e\u53cd\u5e94\u6027\u5728\u9502\u91d1\u5c5e\u7535\u6c60\u4e2d\u5f97\u5230\u5e7f\u6cdb\u5e94\u7528\u3002\u919a\u7c7b\u7535\u89e3\u8d28\u6eb6\u6db2\u5177\u6709\u4f4e\u7c98\u5ea6\u548c\u9ad8\u79bb\u5b50\u5bfc\u7535\u6027\uff0c\u4fc3\u8fdb\u4e86\u5feb\u901f\u7684\u9502\u79bb\u5b50\u4f20\u5bfc\u548c\u5feb\u901f\u7684\u754c\u9762\u7535\u8377\u4ea4\u6362\u3002\u919a\u6eb6\u5242\u7684\u4f4e\u51b0\u70b9\u4f7f\u5f97\u7535\u6c60\u5728\u96f6\u4e0b\u6e29\u5ea6\u4e0b\u80fd\u591f\u8868\u73b0\u51fa\u5353\u8d8a\u7684\u6027\u80fd\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u57fa\u4e8e\u919a\u7684\u7535\u89e3\u8d28\u5bf9\u9502\u91d1\u5c5e\u8d1f\u6781\u5177\u6709\u8f83\u9ad8\u7684\u517c\u5bb9\u6027\uff0c\u53ef\u4ee5\u6291\u5236\u5145\u7535\u65f6\u7684\u679d\u6676\u751f\u957f\u3002<\/p>\n

\u7136\u800c\uff0c\u4f7f\u7528\u6613\u71c3\u7684\u919a\u6eb6\u5242\u5b58\u5728\u5b89\u5168\u9690\u60a3\u3002\u919a\u7c7b\u7684\u4f4e\u6cb8\u70b9\uff08\u4f8b\u5982\uff0c1,2-\u4e8c\u7532\u6c27\u57fa\u4e59\u70f7\uff08DME\uff09\u4e3a84\u00b0C\uff0c\u4e59\u919a\u4e3a34.6\u00b0C\uff09\u53ef\u80fd\u5f15\u53d1\u706b\u707e\u3001\u7206\u70b8\u548c\u6db2\u4f53\u6cc4\u6f0f\u7b49\u5b89\u5168\u98ce\u9669\u3002\u6b64\u5916\uff0c\u57fa\u4e8e\u919a\u7684\u7535\u89e3\u8d28\u7684\u6c27\u5316\u7a33\u5b9a\u6027\u4e0d\u8db3\uff0c\u53ef\u80fd\u5bfc\u81f4\u5728\u9ad8\u7535\u538b\uff08>4V vs Li\/Li+<\/sup>\uff09\u4e0b\u65e0\u6cd5\u63a7\u5236\u7684\u6eb6\u5242\u5206\u89e3\uff0c\u4e25\u91cd\u6076\u5316\u9ad8\u538b\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u4f7f\u7528\u6d53\u5ea6\u8f83\u9ad8\u7684\u919a\u6eb6\u6db2\u4f1a\u5bfc\u81f4\u9502\u79bb\u5b50\u6eb6\u5242\u7ed3\u6784\u4e2d\u53ef\u81ea\u7531\u6eb6\u5242\u5206\u5b50\u53d7\u9650\uff0c\u4ece\u800c\u7f29\u77ed\u4e86\u81ea\u7184\u706d\u65f6\u95f4\uff08SET\uff09\uff0c\u8fdb\u800c\u5b9e\u73b0\u9ad8\u6c27\u5316\u7a33\u5b9a\u6027\u3002\u7136\u800c\uff0c\u6b64\u7c7b\u6d53\u7f29\u6eb6\u6db2\u7684\u9ad8\u76d0\u6210\u672c\u4ee5\u53ca\u9ad8\u7c98\u5ea6\u548c\u7535\u6781\u6da6\u6e7f\u6027\u5dee\u663e\u8457\u9650\u5236\u4e86\u5b83\u4eec\u7684\u5e7f\u6cdb\u5e94\u7528\u3002\u4e3a\u4e86\u964d\u4f4e\u9ad8\u6d53\u5ea6\u7535\u89e3\u8d28\u6eb6\u6db2\u7684\u7c98\u5ea6\u548c\u76d0\u7528\u91cf\uff0c\u5df2\u7ecf\u5f00\u53d1\u4e86\u5f31\u6eb6\u5242\u5355\u6eb6\u5242\u7535\u89e3\u8d28\u6eb6\u6db2\u6216\u5c40\u90e8\u9ad8\u6d53\u5ea6\u53cc\u6eb6\u5242\u7535\u89e3\u8d28\u6eb6\u6db2\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u4f18\u5316\u7684\u57fa\u4e8e\u919a\u7684\u7535\u89e3\u8d28\u6eb6\u6db2\u4e0e\u9ad8\u538b\u6b63\u6781\u6750\u6599\u4e4b\u95f4\u7684\u517c\u5bb9\u6027\u4ecd\u9700\u8fdb\u4e00\u6b65\u63d0\u9ad8\uff0c\u56e0\u4e3a\u5b83\u4eec\u4ecd\u5b58\u5728\u5b89\u5168\u98ce\u9669\uff08\u4f8b\u5982\u706b\u707e\u548c\u6cc4\u6f0f\uff09\u3002\u867d\u7136\u53ef\u4ee5\u901a\u8fc7\u5728\u7535\u89e3\u8d28\u6eb6\u6db2\u4e2d\u6eb6\u89e3\u5927\u91cf\uff08>10\uff05\uff09\u7684\u963b\u71c3\u5242\uff08\u5982\u6709\u673a\u78f7\u9178\u76d0\uff09\u6765\u5b9e\u73b0\u975e\u6613\u71c3\u6027\uff0c\u4f46\u8fd9\u7c7b\u6dfb\u52a0\u5242\u901a\u5e38\u4f1a\u5728\u6d3b\u6027\u8d1f\u6781\u8868\u9762\u4e0a\u4e0d\u53ef\u9006\u5730\u5206\u89e3\uff0c\u5bfc\u81f4\u8d1f\u6781\u8868\u9762\u819c\u7684\u6301\u7eed\u589e\u539a\uff0c\u5e76\u4e14\u9502\u8d1f\u6781\u548c\u7535\u89e3\u8d28\u6eb6\u6db2\u4e4b\u95f4\u7684\u9502\u79bb\u5b50\u4f20\u8f93\u80fd\u529b\u6025\u5267\u6076\u5316\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u5b89\u5168\u8010\u7528\u7684\u9ad8\u538b\/\u9ad8\u80fd\u91cf\u9502\u91d1\u5c5e\u7535\u6c60\u9ad8\u5ea6\u517c\u5bb9\u7684\u7535\u89e3\u8d28\u7cfb\u7edf\u4ecd\u7136\u9762\u4e34\u5de8\u5927\u6311\u6218\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u6df1\u5733\u56fd\u9645\u7814\u7a76\u751f\u9662\u5468\u680b\u6559\u6388\u3001\u674e\u5b9d\u534e\u6559\u6388\u8054\u5408\u897f\u73ed\u7259\u5df4\u65af\u514b\u7814\u7a76\u5b66\u4f1a<\/strong>Michel Armand<\/strong>\u6559\u6388\uff0c\u6089\u5c3c\u79d1\u6280\u5927\u5b66\u6c6a\u56fd\u79c0\u6559\u6388\u4ee5\u53ca\u4ee5\u8272\u5217\u5df4\u4f0a\u5170\u5927\u5b66<\/strong>Doron Aurbach<\/strong>\u6559\u6388\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u4f18\u5316\u919a\u57fa\u7535\u89e3\u8d28\u7684\u901a\u7528\u7b56\u7565\uff0c\u6d88\u9664\u5176\u5b89\u5168\u95ee\u9898\uff0c\u540c\u65f6\u63d0\u9ad8\u7535\u6781\u7684\u517c\u5bb9\u6027\u3002\u8be5\u7b56\u7565\u5c55\u793a\u4e86\u6c1f\u5316\u53cd\u6eb6\u5242\u548c\u4e01\u6c27\u57fa\u73af\u4e09\u78f7\u8148\uff08BCPN\uff09\u5355\u4f53\u7684\u51dd\u80f6\u5904\u7406\u4e4b\u95f4\u7684\u534f\u540c\u4f5c\u7528\u3002\u6dfb\u52a0\u6c1f\u5316\u53cd\u6eb6\u5242\u4e0d\u4ec5\u964d\u4f4e\u4e86\u7535\u89e3\u8d28\u6eb6\u6db2\u7684\u6613\u71c3\u6027\uff0c\u8fd8\u8c03\u6574\u4e86Li+<\/sup>\u7684\u6eb6\u5242\u9798\uff0c\u63d0\u9ad8\u4e86\u7535\u89e3\u8d28\u6eb6\u6db2\u7684\u6c27\u5316\u7a33\u5b9a\u6027\u3002\u4e0e\u73b0\u6709\u7684\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\u76f8\u6bd4\uff0c\u5177\u6709\u9ad8\u4ea4\u8054\u5ea6\u7684BCPN\u57fa\u805a\u5408\u7269\u57fa\u8d28\u4e0d\u4ec5\u907f\u514d\u5bf9\u79bb\u5b50\u5bfc\u7535\u4ea7\u751f\u663e\u8457\u963b\u788d\uff0c\u800c\u4e14\u6d88\u9664\u4e86\u706b\u707e\u548c\u7535\u89e3\u8d28\u6eb6\u6db2\u6cc4\u6f0f\u7684\u5b89\u5168\u98ce\u9669\u3002\u6b64\u5916\uff0c\u5728\u805a\u5408\u53cd\u5e94\u540e\u6b8b\u7559\u7684\u5c11\u91cfBCPN\u5355\u4f53\u4f5c\u4e3a\u9ad8\u6548\u7684\u9634\u6781\u7535\u89e3\u8d28\u754c\u9762\uff08CEI\uff09\u5f62\u6210\u6dfb\u52a0\u5242\uff0c\u8fdb\u4e00\u6b65\u6291\u5236\u4e86\u6b63\u6781\u4e0a\u7535\u89e3\u8d28\u7684\u6c27\u5316\u5206\u89e3\uff0c\u5e76\u9632\u6b62\u4e86\u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u9634\u6781\u5728\u9502\u91d1\u5c5e\u7535\u6c60\u4e2d\u7684\u7ed3\u6784\u6076\u5316\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6587\u7ae0\u4ee5\u201cDesigning phosphazene-derivative electrolyte matrices to enable high-voltage lithium metal batteries for extreme working conditions<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Energy<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u00a0<\/strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

    \n
  1. \u672c\u6587\u6240\u5f00\u53d1\u7684\u51dd\u80f6\u7535\u89e3\u8d28\u4f53\u7cfb\u4e2d\u7684\u6c1f\u5316\u53cd\u6eb6\u5242\u3001\u805a\u5408\u7269\u57fa\u8d28\u548c\u6b8b\u7559\u7684BCPN\u5355\u4f53\u6709\u52a9\u4e8e\u5728\u9502\u91d1\u5c5e\u548cNCM811\u7535\u6781\u4e0a\u5f62\u6210\u9ad8\u5ea6\u7a33\u5b9a\u7684\u4fdd\u62a4\u548c\u949d\u5316\u8868\u9762\u819c\uff0c\u4ece\u800c\u8d4b\u4e88\u7a33\u5b9a\u7684\u957f\u671f\u5faa\u73af\uff08\u8d85\u8fc7300\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a88%\uff09\u3002<\/li>\n
  2. \u57fa\u4e8e\u672c\u6587\u5f00\u53d1\u7684\u65b0\u578b\u590d\u5408\u7535\u89e3\u8d28\u57fa\u8d28\u7684\u9ad8\u80fd\u91cf\u9502\u7535\u6c60\u5177\u6709\u8d85\u51fa\u73b0\u6709\u6280\u672f\u6c34\u5e73\u7684\u6027\u80fd\uff0c\u5e76\u4e14\u7279\u522b\u9002\u7528\u4e8e\u6781\u7aef\u73af\u5883\u4e2d\u7684\u5e94\u7528\uff08\u4f8b\u5982\u822a\u7a7a\u822a\u5929\u3001\u6f5c\u6c34\u8247\u548c\u6781\u5730\u8bbe\u5907\uff09\u3002<\/li>\n<\/ol>\n

    \u00a0<\/strong><\/p>\n

    \u00a0<\/strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

    \u00a0\"\"<\/strong><\/p>\n

    \u56fe<\/strong>1<\/strong> NGPE<\/strong>\u7684\u8bbe\u8ba1\u53ca\u6eb6\u5242\u5316\u7ed3\u6784\u7684\u7814\u7a76\u3002<\/strong>a, <\/strong>\u919a\u57fa\u7535\u89e3\u8d28\u7684\u91cd\u65b0\u8bbe\u8ba1\u539f\u5219\uff0c\u7528\u4e8e\u9ad8\u538b\u548c\u9ad8\u5b89\u5168\u6027\u9502\u91d1\u5c5e\u7535\u6c60\u3002<\/strong> b, <\/strong>\u4ece<\/strong>MD<\/strong>\u6a21\u62df\u4e2d\u83b7\u5f97\u7684<\/strong>NGPE<\/strong>\u7684<\/strong>Li+<\/sup><\/strong>\u5f84\u5411\u5206\u5e03\u51fd\u6570<\/strong>g(r)<\/strong>\u3002<\/strong>c, <\/strong>\u6d4b\u91cf\u5f97\u5230\u7684<\/strong>1 M LiTFSI-DEE<\/strong>\u3001<\/strong>1 M LiTFSI-DEE:SFE<\/strong>\u7535\u89e3\u8d28\u548c<\/strong>NGPE<\/strong>\u7684\u7535\u6c60\u7535\u4f4d\u548c\u6eb6\u5242\u5316\u80fd\u3002\u6d4b\u8bd5\u7535\u6c60\u7684\u793a\u610f\u56fe\u5982\u63d2\u56fe\u6240\u793a\u3002<\/strong>\u00a9 2023 Springer Nature<\/strong><\/p>\n

    \u00a0\"\"<\/strong><\/p>\n

    \u56fe<\/strong>2<\/strong> NGPE<\/strong>\u7684\u5b89\u5168\u6027\u3002<\/strong>a, <\/strong>\u4e09\u79cd\u919a\u7c7b\u3001\u919a\u7c7b\u4e0e<\/strong>SFE<\/strong>\u7684\u6df7\u5408\u7269\u4ee5\u53ca\u76f8\u5e94\u7684<\/strong>NGPE<\/strong>\u7684\u71c3\u70e7\u6d4b\u8bd5\u3002<\/strong> b, NGPE<\/strong>\u7684\u53ef\u80fd\u963b\u71c3\u673a\u5236\u3002<\/strong>c, <\/strong>\u5bf9<\/strong>1M LiTFSI-DEE:SFE<\/strong>\u6db2\u6001\u7535\u89e3\u8d28\u548c<\/strong>NGPE<\/strong>\u8fdb\u884c\u6cc4\u6f0f\u6d4b\u8bd5\u3002<\/strong>d, <\/strong>\u5728<\/strong>5mV\/s<\/strong>\u7684\u626b\u63cf\u901f\u7387\u4e0b\uff0c\u4f7f\u7528\u94c2\u7b94\u4f5c\u4e3a\u5de5\u4f5c\u7535\u6781\uff0c\u9502\u7b94\u4f5c\u4e3a\u5bf9\u6bd4\u548c\u53c2\u8003\u7535\u6781\uff0c\u6d4b\u5f97<\/strong>1M LiTFSI-DEE<\/strong>\u3001<\/strong>1M LiTFSI-DEE:SFE<\/strong>\u7535\u89e3\u8d28\u548c<\/strong>NGPE<\/strong>\u7684<\/strong>LSV<\/strong>\u66f2\u7ebf\u3002<\/strong>\u00a9 2023 Springer Nature<\/strong><\/p>\n

    \u00a0\"\"<\/strong><\/p>\n

    \u56fe<\/strong>3 NGPE<\/strong>\u4e0e\u7535\u6781\u7684\u754c\u9762\u76f8\u5bb9\u6027\u3002<\/strong>a, Li<\/strong>\u79bb\u5b50\u7535\u9540<\/strong>–<\/strong>\u5265\u79bb\u7684<\/strong>CE<\/strong>\u3002<\/strong>b,<\/strong>\u4e0d\u540c\u500d\u7387\u4e0b<\/strong>Li | | Li<\/strong>\u5bf9\u79f0\u7535\u6c60\u7684\u7535\u538b\u66f2\u7ebf\u3002<\/strong>c,<\/strong>\u5728<\/strong>0.5C<\/strong>\u4e0b\u7ecf\u8fc7\u5341\u4e2a\u5faa\u73af\u540e\u4ece<\/strong>Li | NGPE | NCM811<\/strong>\u7535\u6c60\u4e2d\u83b7\u5f97\u7684<\/strong>NCM811<\/strong>\u6b63\u6781\u7684<\/strong>TEM<\/strong>\u56fe\u50cf\u3002<\/strong>d, 1M LiPF6<\/sub>-EC:DMC<\/strong>\uff0c<\/strong>1M LiTFSI-DEE<\/strong>\u548c<\/strong>NGPE<\/strong>\u4e2d<\/strong>NCM811<\/strong>\u6b63\u6781<\/strong> | <\/strong>\u7535\u89e3\u8d28\u754c\u9762\u548c\u94dd\u96c6\u6d41\u4f53\u7684\u8150\u8680\u884c\u4e3a\u7684\u793a\u610f\u56fe\u3002<\/strong>e,<\/strong>\u5728\u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\uff0c\u5c06<\/strong>Al | | Li<\/strong>\u7ebd\u6263\u7535\u6c60\u5728<\/strong>4.4V<\/strong>\u4e0b\u4fdd\u6301<\/strong>10<\/strong>\u5c0f\u65f6\u7684\u6052\u5b9a\u5b89\u57f9\u6cd5\u56fe\u3002\u56fe\u4e2d\u663e\u793a\u4e86<\/strong>1M LiTFSI-DEE<\/strong>\u548c<\/strong>NGPE<\/strong>\u4e2d\u7ecf\u8fc7\u6052\u5b9a\u5b89\u57f9\u6cd5\u6d4b\u8bd5\u540e\u7684<\/strong>Al<\/strong>\u7b94\u7684<\/strong>FE-SEM<\/strong>\u56fe\u50cf\u3002<\/strong>f,<\/strong>\u901a\u8fc7<\/strong>DSC<\/strong>\u6d4b\u91cf\uff0c\u4e0d\u540c\u7535\u89e3\u6db2\u4e0b\u5b8c\u5168\u5145\u7535\u7684<\/strong>NCM811<\/strong>\u6b63\u6781\u7684\u70ed\u91cf\u4ea7\u751f\u60c5\u51b5\u3002<\/strong>\u00a9 2023 Springer Nature<\/strong><\/p>\n

    \u00a0\"\"<\/strong><\/p>\n

    \u56fe<\/strong>4 Li| NGPE | NCM811<\/strong>\u7ebd\u6263\u7535\u6c60\u5728\u6781\u7aef\u5de5\u4f5c\u73af\u5883\u4e0b\u7684\u6027\u80fd\u3002<\/strong>a, b<\/strong>\uff0c<\/strong>1M LiPF6<\/sub>-EC:DMC<\/strong>\u7535\u89e3\u6db2\u548c<\/strong>NGPE<\/strong>\u7684\u5145\u653e\u7535\u7535\u538b\u66f2\u7ebf\uff08<\/strong>a<\/strong>\uff09\uff0c\u4ee5\u53ca<\/strong>0.5 C<\/strong>\u4e0b<\/strong>Li\u2009|\u2009|\u2009NCM811<\/strong>\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff08<\/strong>b<\/strong>\uff09\u3002<\/strong>c, d<\/strong>\uff0c\u5728<\/strong>25\u00b0C (c)<\/strong>\u548c<\/strong>-20\u00b0C (d)<\/strong>\u4e0b\uff0c\u5177\u6709\u9ad8\u8d1f\u8f7d<\/strong> (~20 mg cm\u22122<\/sup>) NCM811<\/strong>\u6b63\u6781\uff08\u7535\u89e3\u8d28<\/strong>\/<\/strong>\u5bb9\u91cf\u6bd4\uff1a<\/strong>~6.5 g Ah\u22121<\/sup><\/strong>\uff09\u548c<\/strong>50 \u03bcm<\/strong>\u9502\u8d1f\u6781\u7684<\/strong>Li\u2009|\u2009NGPE\u2009|\u2009NCM811<\/strong>\u7535\u6c60\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\u3002\u63d2\u56fe\u663e\u793a\u4e86\u5728<\/strong>-20\u00b0C<\/strong>\u4e0b\u4e0d\u540c\u7535\u89e3\u6db2\u7684\u89c6\u89c9\u89c2\u5bdf\u7ed3\u679c\u3002<\/strong>e,<\/strong>\u76d1\u6d4b\u5728<\/strong>Li\u2009|\u2009NGPE\u2009|\u2009NCM811<\/strong>\u7535\u6c60\u5faa\u73af\u8fc7\u7a0b\u4e2d\u65bd\u52a0\u7684\u5806\u53e0\u538b\u529b\u7684\u652f\u67b6\u7684\u793a\u610f\u56fe\u3002<\/strong>f,<\/strong>\u5806\u53e0\u538b\u529b\u5bf9<\/strong>Li\u2009|\u2009|\u2009NCM811<\/strong>\u7535\u6c60\uff08\u8d1f\u8f7d\uff1a<\/strong>3 mg cm\u22122<\/sup><\/strong>\uff0c\u9502\u7b94\uff1a<\/strong>50 \u03bcm<\/strong>\uff0c\u7535\u89e3\u8d28\u542b\u91cf\uff1a<\/strong>60 \u03bcl<\/strong>\uff09\u5faa\u73af\u7a33\u5b9a\u6027\u7684\u5f71\u54cd\u3002<\/strong>\u00a9 2023 Springer Nature<\/strong><\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>5 Li| NGPE | NCM811<\/strong>\u8f6f\u5305\u7535\u6c60\u5728\u6ee5\u7528\u6761\u4ef6\u4e0b\u7684\u6027\u80fd\u3002<\/strong>a,<\/strong>\u4f7f\u7528<\/strong>1M LiPF6<\/sub>-EC:DMC<\/strong>\u6eb6\u6db2\u548c<\/strong>NGPE<\/strong>\uff0c\u5728<\/strong>0.5C<\/strong>\u4e0b\u5bf9<\/strong>50<\/strong>\u5fae\u7c73\u539a\u7684\u9502\u7b94<\/strong>| | NCM811<\/strong>\u5355\u5c42\u8f6f\u5305\u7535\u6c60\u8fdb\u884c\u5faa\u73af\u6027\u80fd\u6d4b\u8bd5\u3002<\/strong>b, c,<\/strong>\u5149\u7535\u4e8c\u6781\u7ba1\u7531<\/strong>Li | 1M LiPF6<\/sub>-EC:DMC | NCM811<\/strong>\uff08<\/strong>b<\/strong>\uff09\u548c<\/strong>Li | NGPE | NCM811<\/strong>\uff08<\/strong>c<\/strong>\uff09\u8f6f\u5305\u7535\u6c60\u4f9b\u7535\u7684\u5149\u5b66\u56fe\u50cf\u3002<\/strong>d,<\/strong>\u5728\u4ece\u5f00\u8def\u7535\u538b\u5230<\/strong>10V<\/strong>\u7684\u626b\u63cf\u901f\u7387\u4e3a<\/strong>20mV\/s<\/strong>\u7684\u6761\u4ef6\u4e0b\uff0c\u663e\u793a\u4e86<\/strong>Li | 1M LiPF6<\/sub>-EC:DMC | NCM811<\/strong>\u548c<\/strong>Li | NGPE | NCM811<\/strong>\u8f6f\u5305\u7535\u6c60\u7684<\/strong>LSV<\/strong>\u66f2\u7ebf\u53ca\u5176\u76f8\u5e94\u7684\u7ea2\u5916\u70ed\u6210\u50cf\u7167\u7247\u3002<\/strong>\u00a9 2023 Springer Nature<\/strong><\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>6<\/strong>\u6ee5\u7528\u6761\u4ef6\u4e0b\u7684<\/strong>500 mAh<\/strong>\u8f6f\u5305\u7535\u6c60\u6027\u80fd\u3002<\/strong>a, b,<\/strong>\u5b8c\u5168\u5145\u7535\u7684<\/strong>Li\u2009|\u2009|\u2009NCM811<\/strong>\u7535\u6c60\u5728<\/strong>ARC<\/strong>\u6d4b\u8bd5\u4e2d\u4f7f\u7528<\/strong>1\u2009M LiPF6<\/sub>-EC:DMC<\/strong>\u6216<\/strong>NGPE<\/strong>\u65f6\u7684\u70ed\u5931\u63a7\u6e29\u5ea6\u66f2\u7ebf\uff08<\/strong>a<\/strong>\uff09\u548c\u6e29\u5347\u7387\u56fe\uff08<\/strong>b<\/strong>\uff09\u3002<\/strong>c,<\/strong>\u5145\u6ee1\u7535\u7684<\/strong>Li\u2009|\u20091\u2009M LiPF6<\/sub>-EC:DMC\u2009|\u2009NCM811<\/strong>\u548c<\/strong>Li\u2009|\u2009NGPE\u2009|\u2009NCM811<\/strong>\u8f6f\u5305\u7535\u6c60\u5728\u9489\u523a\u6d4b\u8bd5\u671f\u95f4\u7684\u7535\u538b\u53d8\u5316\u53ca\u5176\u76f8\u5e94\u7684\u7ea2\u5916\u70ed\u6210\u50cf\u7167\u7247\u3002<\/strong>d,<\/strong>\u6839\u636e\u516d\u4e2a\u64cd\u4f5c\u53c2\u6570\uff0c\u5bf9\u6bd4\u4e86\u6240\u7814\u7a76\u7684\u4e0d\u540c\u7535\u89e3\u8d28\u4f53\u7cfb\u7535\u6c60\u7684\u6027\u80fd\u3002<\/strong>\u00a9 2023 Springer Nature<\/strong><\/p>\n

     <\/p>\n

    \u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

    \u672c\u6587\u5f00\u53d1\u4e86\u9002\u7528\u4e8e\u9ad8\u6027\u80fd\u9502\u91d1\u5c5e\u7535\u6c60\u5728\u6781\u7aef\u6761\u4ef6\u4e0b\u5de5\u4f5c\u7684\u7535\u89e3\u8d28\u57fa\u8d28\u3002\u8fd9\u4e9b\u7535\u89e3\u8d28\u5177\u6709\u9ad8\u7535\u6781\u76f8\u5bb9\u6027\u548c\u51fa\u8272\u7684\u5b89\u5168\u7279\u6027\u3002\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u590d\u5408\u7535\u89e3\u8d28\u7cfb\u7edf\u4e2d\u4e3b\u8981\u4f7f\u7528\u4ee5\u919a\u4e3a\u57fa\u7840\u7684\u6eb6\u6db2\uff0c\u56e0\u4e3a\u4e0e\u78b3\u9178\u916f\u57fa\u7535\u89e3\u8d28\u76f8\u6bd4\uff0c\u5b83\u4eec\u5bf9\u9502\u9633\u6781\u8868\u9762\u7684\u53cd\u5e94\u6027\u8f83\u4f4e\u3002\u901a\u8fc7\u4e0e\u5408\u6210\u7684BCPN\u5355\u4f53\u8fdb\u884c\u51dd\u80f6\u5904\u7406\uff0c\u5e76\u4e0e\u542b\u6c1f\u53cd\u6eb6\u5242\u534f\u540c\u5229\u7528\uff0c\u786e\u5b9a\u5e76\u7406\u8bba\u4e0a\u8ba4\u5b9a\u8fd9\u662f\u9488\u5bf9\u919a\u57fa\u6eb6\u6db2\u7684\u9ad8\u8d1f\u6781\u7a33\u5b9a\u6027\u548c\u51fa\u8272\u5b89\u5168\u6027\u7684\u6700\u4f73\u9009\u62e9\u3002\u6839\u636e\u8fd9\u79cd\u8bbe\u8ba1\u7406\u5ff5\uff0c\u57fa\u4e8e\u6613\u71c3\u919a\u7c7b\u6eb6\u5242\u7684\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\u7cfb\u7edf\u5c55\u73b0\u51fa\u8db3\u591f\u7684\u79bb\u5b50\u5bfc\u7535\u6027\uff08\u7ea61.12 mS cm\u22121<\/sup>\uff09\u3001\u9ad8\u6297\u6c27\u5316\u7a33\u5b9a\u6027\uff08\u9ad8\u8fbe\u7ea65.25 V vs Li\/Li+<\/sup>\uff09\u3001\u826f\u597d\u7684\u9502\u91d1\u5c5e\u8d1f\u6781SEI\u5f62\u6210\u80fd\u529b\uff08\u5e73\u5747\u9502\u6c89\u79ef\/\u5265\u79bb\u5e93\u4ed1\u6548\u7387\u4e3a99.6%\uff09\u548c\u5353\u8d8a\u7684\u5b89\u5168\u7279\u6027\uff08\u5373\u65e0\u53ef\u71c3\u6027\u548c\u65e0\u6e17\u6f0f\u6027\uff09\u3002\u6240\u5f00\u53d1\u7684\u51dd\u80f6\u7535\u89e3\u8d28\u7cfb\u7edf\u4e2d\u7684\u542b\u6c1f\u53cd\u6eb6\u5242\u3001\u805a\u5408\u7269\u57fa\u8d28\u548c\u6b8b\u7559\u7684BCPN\u5355\u4f53\u6709\u52a9\u4e8e\u5f62\u6210\u9ad8\u5ea6\u7a33\u5b9a\u7684\u4fdd\u62a4\u548c\u949d\u5316\u8868\u9762\u819c\uff0c\u4ece\u800c\u8d4b\u4e88\u51c6\u56fa\u6001Li\u2009|\u2009|\u2009NCM811\u7535\u6c60\u7a33\u5b9a\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\uff08300\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u8d85\u8fc788%\uff09\u3001\u51fa\u8272\u7684\u4f4e\u6e29\u548c\u8010\u538b\u6027\u80fd\u4ee5\u53ca\u6297\u6ee5\u7528\u7279\u6027\uff08\u5373\u5728\u53d8\u5f62\u548c\u8fc7\u5145\u6761\u4ef6\u4e0b\u7a33\u5b9a\u7684\u4f9b\u7535\uff09\u3002\u672c\u7814\u7a76\u7684\u6838\u5fc3\u53d1\u73b0\u5bf9\u4e8e\u5728\u6076\u52a3\u64cd\u4f5c\u6761\u4ef6\u4e0b\u9ad8\u80fd\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u6709\u6548\u8fd0\u884c\u8fc8\u51fa\u4e86\u91cd\u8981\u4e00\u6b65\u3002<\/p>\n

     <\/p>\n

    \u539f\u6587\u8be6\u60c5<\/strong>\uff1aMeng, Y., Zhou, D., Liu, R. et al. Designing phosphazene-derivative electrolyte matrices to enable high-voltage lithium metal batteries for extreme working conditions. Nat Energy (2023). https:\/\/doi.org\/10.1038\/s41560-023-01339-z<\/p>\n

     <\/p>\n

    \u672c\u6587\u7531\u666f\u884c\u64b0\u7a3f<\/strong><\/p>\n

     <\/p>\n","protected":false},"excerpt":{"rendered":"

    \u4e00\u3001 \u3010\u5bfc\u8bfb\u3011\u00a0 \u57fa\u4e8e\u919a\u7684\u7535\u89e3\u8d28\u56e0\u5176\u4e0e\u9502\u91d1\u5c5e\u7684\u76f8\u5bf9\u4f4e\u53cd\u5e94\u6027\u5728\u9502\u91d1\u5c5e\u7535\u6c60\u4e2d\u5f97\u5230\u5e7f\u6cdb\u5e94\u7528\u3002\u919a\u7c7b\u7535\u89e3\u8d28\u6eb6\u6db2\u5177\u6709\u4f4e\u7c98\u5ea6\u548c\u9ad8\u79bb\u5b50\u5bfc\u7535\u6027\uff0c\u4fc3\u8fdb\u4e86\u5feb\u901f\u7684\u9502\u79bb\u5b50\u4f20\u5bfc\u548c\u5feb\u901f\u7684\u754c\u9762…<\/p>\n","protected":false},"author":36004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[67],"tags":[],"class_list":["post-254458","post","type-post","status-publish","format-standard","hentry","category-zhoubao"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/254458"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/36004"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=254458"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/254458\/revisions"}],"predecessor-version":[{"id":254466,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/254458\/revisions\/254466"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=254458"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=254458"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=254458"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}