{"id":254422,"date":"2023-09-18T06:35:36","date_gmt":"2023-09-17T22:35:36","guid":{"rendered":"\/\/m.iemloyee.com\/?p=254422"},"modified":"2023-09-17T22:59:59","modified_gmt":"2023-09-17T14:59:59","slug":"jacs-%e5%a4%9a%e7%ba%a7%e5%ad%94%e5%85%b1%e4%bb%b7%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e9%a2%97%e7%b2%92%e7%9a%84%e7%bb%84%e5%90%88%e5%90%88%e6%88%90%e5%8f%8a%e5%85%b6%e5%82%ac%e5%8c%96%e5%ba%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=254422","title":{"rendered":"JACS.: \u591a\u7ea7\u5b54\u5171\u4ef7\u6709\u673a\u6846\u67b6\u9897\u7c92\u7684\u7ec4\u5408\u5408\u6210\u53ca\u5176\u50ac\u5316\u5e94\u7528"},"content":{"rendered":"<p style=\"text-align: center;\">\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/p>\n<p>\u50ac\u5316\u3001\u6c14\u4f53\u5b58\u50a8\u548c\u5206\u79bb\u7b49\u5404\u79cd\u5e94\u7528\u9886\u57df\u5bf9\u5177\u6709\u5206\u5c42\u7ed3\u6784\u548c\u9ad8\u6bd4\u8868\u9762\u79ef\u7684\u591a\u5b54\u6750\u6599\u7684\u9700\u6c42\u65e5\u76ca\u589e\u957f\u3002\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u56e0\u5176\u53ef\u8c03\u6574\u7684\u7ed3\u6784\u3001\u9ad8\u7a33\u5b9a\u6027\u548c\u529f\u80fd\u5316\u6f5c\u529b\uff0c\u5df2\u6210\u4e3a\u4e00\u7c7b\u524d\u666f\u5e7f\u9614\u7684\u591a\u5b54\u6750\u6599\u3002\u540c\u65f6\uff0cCOFs\u4e5f\u5177\u6709\u9ad8\u5206\u5b50\u6750\u6599\u7684\u5171\u540c\u7279\u70b9\uff1a\u4ece\u5206\u5b50\u6c34\u5e73\u5230\u7eb3\u7c73\u3001\u4ecb\u89c2\u548c\u5b8f\u89c2\u6c34\u5e73\u7684\u7ed3\u6784\u590d\u6742\u6027\u6216\u5c42\u6b21\u6027\u3002\u76ee\u524d\uff0c\u5728\u6846\u67b6\u8bbe\u8ba1\u548c\u5fae\u5b54\u5408\u6210\u65b9\u9762\u53d6\u5f97\u4e86\u91cd\u5927\u8fdb\u5c55\u3002\u4eba\u4eec\u8fd8\u901a\u8fc7\u81ea\u7ec4\u88c5\u6216\u7269\u7406\u52a0\u5de5\u6765\u5236\u9020\u9ad8\u9636\u7ed3\u6784\uff0c\u5305\u62ec\u7eb3\u7c73\u7403\u3001\u4e2d\u7a7a\u7ea4\u7ef4\u3001\u8584\u819c\u3001\u6ce1\u6cab\u7b49\u3002\u7136\u800c\uff0c\u5408\u6210\u5177\u6709\u5206\u5c42\u5b54\u9699\u7684COFs\u4ecd\u7136\u662f\u4e00\u9879\u6311\u6218\uff0c\u5927\u591a\u6570\u62a5\u9053\u7684\u65b9\u6cd5\u90fd\u6d89\u53ca\u5408\u6210\u540e\u4fee\u9970\u6216\u6a21\u677f\u8f85\u52a9\u5408\u6210\uff0c\u800c\u8fd9\u4e9b\u65b9\u6cd5\u5f80\u5f80\u590d\u6742\u800c\u8017\u65f6\u3002\u540c\u65f6\uff0c\u7531\u4e8eCOFs\u7684\u4e0d\u6eb6\u6027\u548c\u4e0d\u7194\u5316\u6027\u8d28\u9650\u5236\u5176\u518d\u52a0\u5de5\uff0c\u4ee5\u53ca\u5728\u5176\u4ed6\u5fae\u5b54\u6750\u6599\uff08\u5982\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff09\u4e2d\u5f15\u5165\u4ecb\u89c2\u7ed3\u6784\u53ef\u4ee5\u663e\u7740\u63d0\u9ad8\u5176\u50ac\u5316\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u63a7\u5236\u591a\u7ea7\u7ed3\u6784\u4ee5\u5b9a\u5236\u5206\u7ea7\u5b54COFs\u7684\u7b80\u4fbf\u5408\u6210\u7b56\u7565\u5bf9\u4e8eCOFs\u7684\u6027\u80fd\u548c\u5e94\u81f3\u5173\u91cd\u8981\u3002<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/p>\n<p>\u8fd1\u65e5\uff0c\u6d59\u6c5f\u5927\u5b66\u5316\u5b66\u5de5\u7a0b\u4e0e\u751f\u7269\u5de5\u7a0b\u5b66\u9662\u5218\u5e73\u4f1f\u526f\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8e\u52a8\u6001\u5171\u4ef7\u5316\u5b66\u7684\u65b0\u7b56\u7565\uff0c\u53ef\u5b9e\u73b0\u4e00\u6b65\u6cd5\u5408\u6210\u5177\u6709\u5206\u5c42\u5b54\u9699\u7684\u7a7a\u5fc3COF\u9897\u7c92\u3002\u6240\u5f97\u9897\u7c92\u4ea7\u54c1\u5177\u6709\u9ad8\u7ed3\u6676\u5ea6\u548c\u5206\u7ea7\u5b54\u9699\uff0c\u4e14\u5728\u4f5c\u4e3a\u7eb3\u7c73\u8f7d\u4f53\u539f\u4f4d\u8d1f\u8f7d\u50ac\u5316\u5242\u7684\u5e94\u7528\u4e2d\u8868\u73b0\u51fa\u72ec\u7279\u7684\u4f18\u52bf\uff0c\u4e3a\u8bbe\u8ba1\u5177\u6709\u5206\u5c42\u5b54\u7ed3\u6784\u7684COF\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u201c<em>Combinatorial Synthesis of Covalent Organic Framework Particles with Hierarchical Pores and Their Catalytic Application<\/em>\u201d\u4e3a\u9898\u53d1\u8868\u5728<em>Journal Of The American Chemical Society<\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254423\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/0-3.png\" alt=\"\" width=\"1595\" height=\"509\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/0-3.png 1595w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/0-3-300x96.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/0-3-768x245.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/0-3-1024x327.png 1024w\" sizes=\"(max-width: 1595px) 100vw, 1595px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n<p>\u4f5c\u8005\u5c55\u793a\u4e86\u4e00\u79cd\u65b0\u7684\u4e00\u6b65\u6cd5\u5408\u6210COF\u9897\u7c92\uff0c\u5e76\u5c06\u5176\u7528\u4f5c\u9ad8\u6548\u7684\u7eb3\u7c73\u8f7d\u4f53\u3002\u8be5\u65b9\u6cd5\u57fa\u4e8e\u52a8\u6001\u5171\u4ef7\u5316\u5b66\uff0c\u901a\u8fc7\u4e00\u6b65\u53cd\u5e94\u6784\u5efa\u4e9a\u7532\u57fa\u5316\u9170\u80fa\u57fa\u56e2\u7684\u7a7a\u5fc3COF\u9897\u7c92\uff0c\u4ece\u800c\u5b9e\u73b0\u9ad8\u7ed3\u6676\u5ea6\u548c\u5206\u7ea7\u5b54\u9699\u3002\u8be5\u65b9\u6cd5\u5177\u6709\u7b80\u5355\u3001\u9ad8\u6548\u3001\u53ef\u6269\u5c55\u6027\u5f3a\u7b49\u4f18\u70b9\u3002<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254424\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/1-10.png\" alt=\"\" width=\"438\" height=\"500\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/1-10.png 438w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/1-10-263x300.png 263w\" sizes=\"(max-width: 438px) 100vw, 438px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe1 \u00a0COF\u9897\u7c92\u7684\u5408\u6210\u548c\u5fae\u89c2\u8868\u5f81\u3002 \u00a0\u00a92023 <strong>American Chemical Society<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254425\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/2-7.png\" alt=\"\" width=\"500\" height=\"423\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/2-7.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/2-7-300x254.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe2\u00a0 COF\u4ea7\u54c1\u7684\u8868\u5f81\u3002\u00a0 \u00a92023 <strong>American Chemical Society<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254426\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/3-7.png\" alt=\"\" width=\"500\" height=\"396\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/3-7.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/3-7-300x238.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe3\u00a0 \u8f6c\u53d8\u8fc7\u7a0b\u7684\u7814\u7a76\u3002\u00a0 \u00a92023 <strong>American Chemical Society<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254427\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/4-7.png\" alt=\"\" width=\"463\" height=\"500\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/4-7.png 463w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/4-7-278x300.png 278w\" sizes=\"(max-width: 463px) 100vw, 463px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe4 \u8f6c\u53d8\u673a\u5236\u7684\u7814\u7a76\u3002\u00a0 \u00a92023 <strong>American Chemical Society<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254428\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/5-6.png\" alt=\"\" width=\"500\" height=\"376\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/5-6.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/5-6-300x226.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe5 \u7531\u56db\u79cd\u5355\u4f53\u7ec4\u6210\u7684DCL\u7684\u7814\u7a76\u3002\u00a0 \u00a92023 <strong>American Chemical Society<\/strong><\/p>\n<p style=\"text-align: center;\"><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254429\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/6-2.png\" alt=\"\" width=\"397\" height=\"500\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/6-2.png 397w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/6-2-238x300.png 238w\" sizes=\"(max-width: 397px) 100vw, 397px\" \/><\/strong><\/p>\n<p style=\"text-align: center;\">\u56fe6 \u4f7f\u7528COF\u7eb3\u7c73\u8f7d\u4f53\u5408\u6210\u548c\u8868\u5f81\u805a\u916e\uff08POK\uff09\u3002\u00a0 \u00a92023 <strong>American Chemical Society<\/strong><\/p>\n<p style=\"text-align: center;\">\u00a0<\/p>\n<p style=\"text-align: center;\">\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u4ecb\u7ecd\u4e86\u4e00\u79cd\u5408\u6210\u5206\u7ea7\u5b54\u9699COF\u7684\u65b0\u7b56\u7565\uff0c\u8be5\u65b9\u6cd5\u6d89\u53ca\u4e8c\u80fa\u548c\u919b\u7684\u53cd\u5e94\uff0c\u4ece\u800c\u5f62\u6210\u4e9a\u80fa\u952e\u548cCOF\u9897\u7c92\u7684\u81ea\u7ec4\u88c5\u3002\u4f7f\u7528\u5177\u6709\u5927\u53d6\u4ee3\u57fa\u548c\u957f\u70f7\u57fa\u94fe\u7684\u4e8c\u80fa\u53ef\u4fc3\u8fdb\u4e2d\u5b54\u7684\u5f62\u6210\uff0c\u800c\u4f7f\u7528\u5c0f\u919b\u548c\u4f4e\u6d53\u5ea6\u50ac\u5316\u5242\u5219\u6709\u5229\u4e8e\u5927\u5b54\u7684\u5f62\u6210\u3002\u5206\u5c42\u5b54\u9699\u7ed3\u6784\u63d0\u4f9b\u4e86\u8f83\u5927\u7684\u8868\u9762\u79ef\uff0c\u6709\u5229\u4e8e\u53cd\u5e94\u7269\u548c\u4ea7\u7269\u7684\u6269\u6563\uff0c\u4f7f\u9897\u7c92\u6210\u4e3a\u539f\u4f4d\u8d1f\u8f7d\u94af\u50ac\u5316\u5242\u7684\u9ad8\u6548\u7eb3\u7c73\u8f7d\u4f53\u3002\u94af\u8d1f\u8f7d\u7684COF\u9897\u7c92\u5728 Suzukii-Miyaura \u5076\u8054\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u8be5\u7814\u7a76\u4e3a\u8bbe\u8ba1\u548c\u5408\u6210\u5177\u6709\u5c42\u6b21\u7ed3\u6784\u7684\u591a\u5b54\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u7684\u89c1\u89e3\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n<p>https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.3c04995<\/p>\n<p>\u672c\u6587\u7531WYH\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 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