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\n \u5357\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66\u7684Pravas Deria\u6559\u6388\u56e2\u961f\u5c55\u793a\u4e86\u4e00\u79cd\u9884\u8bbe\u8ba1\u7684\u53d1\u8272\u56e2\u8fde\u63a5\u4f53\uff0c\u4f7f\u7528\u7279\u6b8a\u8bbe\u8ba1\u7684ISC\u6548\u7387\u6781\u4f4e\u7684\u53d1\u8272\u8fde\u63a5\u4f53\u4ecd\u7136\u53ef\u4ee5\u5bfc\u81f4MOF\u4e2d\u4e09\u7ebf\u6001\u7684\u5f62\u6210\u3002\u8fd9\u4e0e\u4f7f\u7528\u5177\u6709\u66f4\u9ad8ISC\u6548\u7387\u7684\u8fde\u63a5\u4f53\u6784\u5efa\u7684MOF\u5f62\u6210\u5bf9\u6bd4\u3002\u8fd9\u4e00\u66ff\u4ee3\u9014\u5f84\u7684\u53d1\u73b0\u4e3aMOF\u5316\u5b66\u9886\u57df\u5728\u80fd\u91cf\u8f6c\u6362\u65b9\u6848\u4e2d\u7684\u5149\u7269\u7406\u548c\u5149\u5316\u5b66\u5e94\u7528\u5f00\u8f9f\u4e86\u65b0\u7684\u53ef\u80fd\u6027\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cTriplet Generation Through Singlet Fission in Metal-Organic Framework: An Alternative Route to Inefficient Singlet-Triplet Intersystem Crossing\u201d\u53d1\u8868\u5728Angew. Chem. Int. Ed.\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/strong>
\n \u7279\u6b8a\u8bbe\u8ba1\u7684ISC\u6548\u7387\u6781\u4f4e\u7684\u53d1\u8272\u8fde\u63a5\u4f53\u4ecd\u7136\u53ef\u4ee5\u5bfc\u81f4MOF\u4e2d\u4e09\u7ebf\u6001\u7684\u5f62\u6210<\/p>\n

\u56db\u3001\u6570\u636e\u6982\u89c8<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1 MOF\u4e2d\u53d1\u8272\u56e2\u7ec4\u88c5\u4f53\u4e2d\u5355\u7ebf\u6001\u5230\u4e09\u7ebf\u6001\u8f6c\u6362\u7684\u80fd\u91cf\u56fe\u3002@2023 The Wiley<\/p>\n

\"\"<\/p>\n

\u56fe2 (a)TBAPy\u3001(b)PEPF\u548c(c)PEA\u8fde\u63a5\u4f53\u53ca\u5176(d)Zr6<\/sub>IV<\/sup>-oxo MOF\u7684\u7ed3\u6784,(e) NU-1000\u3001(f) SIU-100\u548c(g)SIU-175\u3002(h\u2013j)\u76f8\u5e94\u7684\u5149\u5b66\u663e\u5fae\u56fe\u50cf\u3002@2023 The Wiley<\/p>\n

\"\"<\/p>\n

\u56fe3 (a-c)\u672a\u7ec4\u88c5\u7684Et4<\/sub>TBAPy\u8fde\u63a5\u4f53\u5728\u7eb3\u79d2\u65f6\u95f4\u5c3a\u5ea6\u4e0b\u7684TA\u5149\u8c31, (a)\u5728\u8131\u6c14\u7684MeTHF\u6eb6\u5242\u4e2d\u663e\u793a\u51fa\u5f31\u4f46\u957f\u5bff\u547d\u7684T1<\/sub>-Tn<\/sub>\u5438\u6536\uff0c\u5728(b)\u5bf9\u5e94\u7684\u901a\u6c14\u6eb6\u5242\u4e2d\u731d\u706d\uff1b(c)\u76f8\u5e94\u7684\u52a8\u529b\u5b66\u66f2\u7ebf\u3002(d-f)NU-1000\u7684\u6c27\u4e0d\u654f\u611fns-TA\u5149\u8c31\u7279\u5f81\u663e\u793a\u65e9\u671fS1<\/sub>\u2192Sn<\/sub>\u5438\u6536\u548c\u5bbd\u51c6\u5206\u5b50\uff0c\u5bfc\u81f4\u5bbd\u3001\u957f\u5bff\u547d\u3001\u65e0\u7279\u5f81\u7684\u8d1f\u4fe1\u53f7\uff0c\u8be5\u4fe1\u53f7\u6e90\u4e8e\u5404\u79cd\u5355\u7ebf\u6001\u590d\u5408\u7269\u3002@2023 The Wiley<\/p>\n

\"\"<\/p>\n

\u56fe4 \u5728NU-1000\u4e2d\uff0c\u5bf9\u4e8e\u4e09\u89d2\u5f62\u7684H4<\/sub>TBAPy\u7ec4\u88c5\u4f53\uff0c\u8ba1\u7b97\u5f97\u5230\u4e86\uff08\u9876\u90e8\uff09S1<\/sub>\u80fd\u5e26\u4e2d\u4e09\u4e2a\u6fc0\u5b50\u6001\u7684TDMs\u8f6e\u5ed3\u56fe\uff08\u4e24\u4e2a\u6697\u8272\uff0c\u4e00\u4e2a\u4eae\u8272\uff09\u3002\u4e0b\u65b9\u8868\u793a\u4e86T1<\/sub>\u80fd\u5e26\u4e2d\u5bf9\u5e94\u7684\u4e09\u4e2a\u6700\u4f4e\u80fd\u91cf\u4e09\u91cd\u6fc0\u5b50\u6001\uff0c\u7a81\u51fa\u663e\u793a\u4e86\u5c40\u90e8\u7cfb\u7edf\u3002@2023 The Wiley<\/p>\n

\"\"<\/p>\n

\u56fe5\u4e3aDMF\u6d78\u6ce1\u7684SIU-175\u6536\u96c6\u7684PSRD\u6a21\u5f0f;\u4eceRietveld\u5efa\u6a21\u4e2d\u83b7\u5f97\u7684\u6a21\u62df\u6a21\u5f0f\u4e0e\u5b9e\u9a8c\u6a21\u5f0f\u5177\u6709\u826f\u597d\u7684\u4e00\u81f4\u6027\u3002@2023 The Wiley<\/p>\n

\"\"<\/p>\n

\u56fe6 (a)SIU-175\uff08\u7d2b\u8272\uff09\u4e0eH4<\/sub>PEA\u8fde\u63a5\u4f53\uff08\u865a\u7ebf\uff0c\u84dd\u8272\uff09\u7684\u5438\u6536\u7535\u5b50\u8dc3\u8fc1\u3002(b)Et4<\/sub>PEA(\u22480.4 \u03bcM)\u548c(c)\u5728\u8131\u6c14MeTHF\u6eb6\u5242\u4e2d\u6536\u96c6\u7684SIU-175\u7684\u6fc0\u53d1\u53d1\u5c04\u56fe\u8c31(EEMS)\uff08RT\uff1b\u6df1\u84dd\u8272\u533a\u57df\u4ee3\u8868\u6700\u5f3a\u4fe1\u53f7\uff09\u3002@2023 The Wiley<\/p>\n

\"\"<\/p>\n

\u56fe7 \u5728MeTHF\u6eb6\u5242\u4e2dSIU-175\u7684TRES\u56fe\u3002@2023 The Wiley<\/p>\n

\"\"<\/p>\n

\u56fe8 \uff08a\uff09\u901a\u8fc7\u6eb6\u5242\u8f85\u52a9\u8fde\u63a5\u4f53\u63ba\u5165(SALI)\u4e3a\u4ecb\u5b54\u6750\u6599SIU-175\u7684Zr6<\/sub>-oxo\u8282\u70b9\u5904\u5b89\u88c5atRA\uff1b\uff08b\uff09SIU-175\u4e2d\u5ef6\u8fdf\u7684\u8367\u5149\u731d\u706d\u7531\u5206\u5b50\u6c27\uff08\u7c89\u8272\uff09\u548c\u5728RA@SIU-175\u8282\u70b9\u4e2d\u5b89\u88c5\u7684atRA\uff08\u7d2b\u8272\uff09\u5f15\u8d77\u7684\uff1b\uff08c\uff09\u5728550 nm\u5904\u63a2\u6d4b\u7684ns\u77ac\u6001\u52a8\u529b\u5b66\u66f2\u7ebf\uff0c\u7a81\u51fa\u663e\u793a\u4e86atRA@SIU-175\u4e2d\u4e09\u91cd\u6001\u7fa4\u4f53\u7684\u731d\u706d\u3002@2023 The Wiley<\/p>\n

\"\"<\/p>\n

\u56fe9 \u6807\u8bb0\u5ef6\u8fdf\u65f6\u95f4\u4e0bSIU-175\u60ac\u6d6e\u6db2\u5728MeTHF\u6eb6\u5242\u4e2d\u7684\u4ee3\u8868\u6027fs-TA\u5149\u8c31\u3002@2023 The Wiley<\/p>\n

\"\"<\/p>\n

\u56fe10 \uff08a\uff09\u7531SIU-175\u5728MeTHF\u6eb6\u5242\u4e2d\u7684fs-TA\u6570\u636e\u7684GTA\u6a21\u578b\u62df\u5408\u751f\u6210\u7684SAS\u56fe\uff1b\uff08b\uff09\u4e0b\u9762\u663e\u793a\u4e86\u76f8\u5e94\u7684\u6210\u5206\u52a8\u6001\u3002@2023 The Wiley<\/p>\n

\"\"<\/p>\n

\u56fe11 \u63cf\u8ff0\u4e0eSF\u8fc7\u7a0b\u76f8\u5173\u7684\u6fc0\u53d1\u6001\u7269\u8d28\u7684\u52a8\u529b\u5b66\u7684\u80fd\u91cf\u56fe\u3002@2023 The Wiley<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aTriplet Generation Through Singlet Fission in Metal-Organic Framework: An Alternative Route to Inefficient Singlet-Triplet Intersystem Crossing. Angew. Chem. Int. Ed. (2023).
\n https:\/\/doi.org\/10.1002\/anie.202305323
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