{"id":254064,"date":"2023-09-04T06:15:31","date_gmt":"2023-09-03T22:15:31","guid":{"rendered":"\/\/m.iemloyee.com\/?p=254064"},"modified":"2023-09-03T11:23:04","modified_gmt":"2023-09-03T03:23:04","slug":"angew-chem-int-ed%ef%bc%9a%e9%94%97%e5%9f%ba%e6%89%8b%e6%80%a7%e9%92%99%e9%92%9b%e7%9f%bf-%e6%96%b0%e5%9e%8b%e6%89%8b%e6%80%a7%e9%9d%9e%e7%ba%bf%e6%80%a7%e5%85%89%e5%ad%a6%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=254064","title":{"rendered":"Angew. Chem. Int. Ed\uff1a\u9517\u57fa\u624b\u6027\u9499\u949b\u77ff \u65b0\u578b\u624b\u6027\u975e\u7ebf\u6027\u5149\u5b66\u6750\u6599"},"content":{"rendered":"<p>\u624b\u6027\u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u5177\u6709\u5f88\u591a\u72ec\u7279\u7684\u6027\u8d28\uff0c\u5982\uff1a\u5706\u4e8c\u8272\u6027\u3001\u5706\u504f\u632f\u53d1\u5149\u3001\u624b\u6027\u8bf1\u5bfc\u81ea\u65cb\u9009\u62e9\u6548\u5e94\u3001\u624b\u6027\u4f9d\u8d56\u5706\u504f\u632f\u5149\u4f0f\u6548\u5e94\u3001\u81ea\u65cb\u585e\u8d1d\u514b\u6548\u5e94\u548c\u624b\u6027\u975e\u7ebf\u6027\u5149\u5b66\u6548\u5e94\u7b49\uff0c\u5728\u8fd1\u5e74\u6765\u53d7\u5230\u79d1\u5b66\u5bb6\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u624b\u6027\u9499\u949b\u77ff\u540c\u65f6\u5177\u6709\u5149\u5b66\u6d3b\u6027\u548c\u975e\u4e2d\u5fc3\u5bf9\u79f0\u7ed3\u6784\uff0c\u4e0d\u4ec5\u662f\u5b9e\u73b0\u500d\u9891\u6548\u5e94\u7684\u53ef\u9760\u6750\u6599\uff0c\u8fd8\u53ef\u4ee5\u5b9e\u73b0\u624b\u6027\u4f9d\u8d56\u7684\u500d\u9891\u6548\u5e94(second-harmonic generation circular dichroism\uff0cSHG-CD)\u3002<\/p>\n<p>\u5173\u4e8e\u624b\u6027\u9499\u949b\u77ff\u7684SHG-CD\u6548\u5e94\u7814\u7a76\u6700\u65e9\u662f\u57fa\u4e8e\u94c5\u57fa\u624b\u6027\u9499\u949b\u77ff\u3002\u8003\u8651\u5230\u94c5\u7684\u6bd2\u6027\u548c\u5bf9\u73af\u5883\u4ea7\u751f\u7684\u5371\u5bb3\uff0c\u79d1\u5b66\u5bb6\u4eec\u5f00\u59cb\u53d1\u5c55\u975e\u94c5\u624b\u6027\u9499\u949b\u77ff\u3002\u94dc\u57fa\u548c\u94cb\u57fa\u624b\u6027\u9499\u949b\u77ff\u7684SHG-CD\u6548\u5e94\u5148\u540e\u88ab\u62a5\u9053\uff0c\u4f46\u5176\u624b\u6027\u500d\u9891\u6548\u5e94\u7684\u4e0d\u5bf9\u79f0\u56e0\u5b50\uff08<em>g<\/em><sub>SHG-CD<\/sub>\uff09\u8fd8\u6709\u5f85\u63d0\u9ad8\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5177\u6709\u5f3a\u624b\u6027\u975e\u7ebf\u6027\u5149\u5b66\u6548\u5e94\u4e14\u73af\u5883\u53cb\u597d\u7684\u624b\u6027\u9499\u949b\u77ff\u5177\u6709\u91cd\u8981\u7684\u79d1\u7814\u548c\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n<p>\u57fa\u4e8e\u6b64\uff0c\u5357\u5f00\u5927\u5b66\u9f99\u5b98\u594e\u8bfe\u9898\u7ec4\u548c\u6df1\u5733\u5927\u5b66\u8d3a\u5ef7\u8d85\u8bfe\u9898\u7ec4\u5408\u4f5c\u5f00\u53d1\u4e86\u9996\u4e2a\u9517\u57fa\u9499\u949b\u77ff\uff1a<em>R<\/em>\/<em>S<\/em>-NGI\u3002\u8be5\u7c7b\u9517\u57fa\u624b\u6027\u9499\u949b\u77ff\u5728800-960 nm\u7684\u6fc0\u5149\u5149\u7167\u5c04\u4e0b\uff0c\u8868\u73b0\u51fa\u660e\u663e\u7684SHG\u4fe1\u53f7\uff0c\u5176\u6fc0\u5149\u635f\u4f24\u9608\u503c\u53ef\u4ee5\u9ad8\u8fbe38.46 GW\/cm<sup>2<\/sup>\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8be5\u9517\u57fa\u624b\u6027\u9499\u949b\u77ff\u8868\u73b0\u51fa\u975e\u5e38\u5f3a\u7684\u624b\u6027\u975e\u7ebf\u6027\u5149\u5b66\u6548\u5e94\uff1a\u5728880 nm\u98de\u79d2\u6fc0\u5149\u6fc0\u53d1\u4e0b\uff0c<em>R<\/em>-NGI\u548c<em>S<\/em>-NGI\u7684<em>g<\/em><sub>SHG-CD<\/sub> \u5206\u522b\u53ef\u4ee5\u8fbe\u52300.48\u548c0.45\uff0c\u662f\u76ee\u524d\u5df2\u62a5\u9053\u7684\u975e\u94c5\u624b\u6027\u9499\u949b\u77ff\u4e2d\u7684\u6700\u9ad8\u503c\u3002\u8fd9\u4e2a\u5de5\u4f5c\u9996\u6b21\u62a5\u9053\u4e86\u9517\u57fa\u624b\u6027\u9499\u949b\u77ff\uff0c\u62d3\u5c55\u4e86\u624b\u6027\u9499\u949b\u77ff\u7684\u79cd\u7c7b\uff0c\u4e3a\u672a\u6765\u5f00\u53d1\u65b0\u7684\u624b\u6027\u975e\u7ebf\u6027\u5149\u5b66\u6750\u6599\u63d0\u4f9b\u4e86\u601d\u8def\u3002\u7814\u7a76\u6210\u679c\u4ee5Chiral Hybrid Germanium(II) Halide with Strong Nonlinear Chiroptical Properties\u4e3a\u9898\u53d1\u8868\u4e8eAngew. Chem. Int. Ed\u3002\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5357\u5f00\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u7684\u738b\u8d3a\u5f6c\u548c\u6df1\u5733\u5927\u5b66\u7269\u7406\u4e0e\u5149\u7535\u5de5\u7a0b\u5b66\u9662\u7684\u674e\u73fa\u5b50\u535a\u58eb\u540e\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u5357\u5f00\u5927\u5b66\u7684\u9f99\u5b98\u594e\u7814\u7a76\u5458\u548c\u6df1\u5733\u5927\u5b66\u7684\u8d3a\u5ef7\u8d85\u6559\u6388\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254073\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u5fae\u4fe1\u622a\u56fe_20230903112158.png\" alt=\"\" width=\"700\" height=\"315\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u5fae\u4fe1\u622a\u56fe_20230903112158.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u5fae\u4fe1\u622a\u56fe_20230903112158-300x135.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254069\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72471.jpg\" alt=\"\" width=\"721\" height=\"600\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72471.jpg 721w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72471-300x250.jpg 300w\" sizes=\"(max-width: 721px) 100vw, 721px\" \/><\/p>\n<p>\u56fe1. \u9517\u57fa\u624b\u6027\u9499\u949b\u77ff\u7528\u4e8e\u5706\u504f\u632f\u4e8c\u6b21\u8c10\u6ce2\u4ea7\u751f\uff0c\u5176\u4e0d\u5bf9\u79f0\u56e0\u5b50\uff08<em>g<\/em><sub>SHG-CD<\/sub>\uff09\u53ef\u4ee5\u8fbe\u52300.48\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254070\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72472-2.png\" alt=\"\" width=\"865\" height=\"538\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72472-2.png 865w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72472-2-300x187.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72472-2-768x478.png 768w\" sizes=\"(max-width: 865px) 100vw, 865px\" \/><\/p>\n<p>\u56fe2. \uff08a\uff09\u624b\u6027\u9517\u57fa\u9499\u949b\u77ff\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b\uff08b\uff09<em>R<\/em>\/<em>S<\/em>-NEA\u7684\u5316\u5b66\u7ed3\u6784\uff1b\uff08c\uff09\u624b\u6027\u9517\u57fa\u9499\u949b\u77ff\u5355\u6676\u7684\u7167\u7247\uff1b\uff08d\uff09\u624b\u6027\u9517\u57fa\u9499\u949b\u77ff\u7684\u6676\u4f53\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254071\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72473-1.png\" alt=\"\" width=\"800\" height=\"424\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72473-1.png 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72473-1-300x159.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72473-1-768x407.png 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><\/p>\n<p>\u56fe3. \uff08a\uff09SHG\u6d4b\u8bd5\u8bbe\u5907\u793a\u610f\u56fe\uff1b\uff08b\uff09<em>S<\/em>-NGI\u5728800-960 nm\u6fc0\u5149\u6fc0\u53d1\u4e0b\u7684SHG\u4fe1\u53f7\uff1b\uff08c\uff09\u76f8\u540c\u6761\u4ef6\u4e0b\uff0cY-cut\u77f3\u82f1\u3001<em>S<\/em>-NGI\u3001<em>rac<\/em>-NGI\u7684SHG\u4fe1\u53f7\uff0c\u6fc0\u53d1\u6e90\u4e3a880 nm\u98de\u79d2\u6fc0\u5149\uff1b\uff08d\uff09<em>S<\/em>-NGI\u7684SHG\u5f3a\u5ea6\u968f\u6fc0\u5149\u7ebf\u504f\u632f\u89d2\u5ea6\u53d8\u5316\u7684\u54cd\u5e94\u56fe\uff1b\uff08e-f\uff09<em>S<\/em>-NGI\u7684SHG\u5f3a\u5ea6\u968f\u6fc0\u5149\u5706\u504f\u632f\u89d2\u5ea6\u53d8\u5316\u7684\u54cd\u5e94\u56fe\u548c\u6781\u5750\u6807\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-254072\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72474-1.png\" alt=\"\" width=\"800\" height=\"413\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72474-1.png 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72474-1-300x155.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/09\/\u56fe\u72474-1-768x396.png 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><\/p>\n<p>\u56fe4. \uff08a\uff09\u4e0d\u540c\u529f\u7387\u6fc0\u5149\u6fc0\u53d1\u4e0b\u7684SHG\u5149\u8c31\uff1b\uff08b\uff09<em>S<\/em>-NGI\u7684SHG\u4fe1\u53f7\u5f3a\u5ea6\u968f\u6fc0\u53d1\u5149\u529f\u7387\u7684\u53d8\u5316\uff0c\u84dd\u8272\u70b9\u4e3a\u5b9e\u9a8c\u6570\u636e\uff0c\u7ea2\u8272\u7ebf\u4e3a\u62df\u5408\u6570\u636e\u3002\uff08c\uff09\u4e0d\u540c\u529f\u7387\u4e0b<em>S<\/em>-NGI\u7684SHG\u4fe1\u53f7\u5f3a\u5ea6\u968f\u6fc0\u53d1\u5149\u529f\u7387\u7684\u53d8\u5316\uff1b\uff08d\uff09\u4e0d\u540c\u529f\u7387\u4e0b<em>S<\/em>-NGI\u7684SHG\u4fe1\u53f7\u5f3a\u5ea6\u968f\u6fc0\u53d1\u5149\u529f\u7387\u7684\u53d8\u5316\uff08\u6781\u5750\u6807\uff09\uff1b\uff08e\uff09SHG\u5f3a\u5ea6\u548c<em>g<\/em><sub>SHG-CD<\/sub>\u968f\u5165\u5c04\u5149\u529f\u7684\u53d8\u5316\uff1b\uff08f\uff09\u6bd4\u8f83\u624b\u6027\u9517\u57fa\u9499\u949b\u77ff\u4e0e\u5df2\u62a5\u9053\u624b\u6027\u975e\u94c5\u9499\u949b\u77ff\u7684<em>g<\/em><sub>SHG-CD<\/sub>\u3002<\/p>\n<p><strong>\u8bba\u6587\u5730\u5740<\/strong>\uff1a<\/p>\n<p>&nbsp;<\/p>\n<p>https:\/\/doi.org\/10.1002\/anie.202309600<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u624b\u6027\u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u5177\u6709\u5f88\u591a\u72ec\u7279\u7684\u6027\u8d28\uff0c\u5982\uff1a\u5706\u4e8c\u8272\u6027\u3001\u5706\u504f\u632f\u53d1\u5149\u3001\u624b\u6027\u8bf1\u5bfc\u81ea\u65cb\u9009\u62e9\u6548\u5e94\u3001\u624b\u6027\u4f9d\u8d56\u5706\u504f\u632f\u5149\u4f0f\u6548\u5e94\u3001\u81ea\u65cb\u585e\u8d1d\u514b\u6548\u5e94\u548c\u624b\u6027\u975e\u7ebf\u6027\u5149\u5b66\u6548\u5e94\u7b49\uff0c\u5728\u8fd1\u5e74&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-254064","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/254064"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=254064"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/254064\/revisions"}],"predecessor-version":[{"id":254074,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/254064\/revisions\/254074"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=254064"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=254064"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=254064"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}