{"id":253415,"date":"2023-08-10T07:02:56","date_gmt":"2023-08-09T23:02:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=253415"},"modified":"2023-08-09T23:08:44","modified_gmt":"2023-08-09T15:08:44","slug":"%e6%b8%a9%e9%b8%a3%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9f%e9%80%9a%e8%bf%87%e5%8f%8c%e8%b4%b1%e9%87%91%e5%b1%9e%e7%83%af%e7%9a%84%e7%a1%ab%e7%a3%b7%e5%8c%96%e5%ae%9e%e7%8e%b0cofeps%e4%bf%83%e8%bf%9b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=253415","title":{"rendered":"\u6e29\u9e23\u6559\u6388\u56e2\u961f\u901a\u8fc7\u53cc\u8d31\u91d1\u5c5e\u70ef\u7684\u786b\u78f7\u5316\u5b9e\u73b0CoFePS\u4fc3\u8fdb\u9ad8\u6548\u6790\u6c27\u53cd\u5e94"},"content":{"rendered":"<p>\u7535\u50ac\u5316\u6c34\u89e3\u4ea7\u6c22\u662f\u83b7\u5f97\u53ef\u6301\u7eed\u9ad8\u7eaf\u5ea6\u6e05\u6d01\u80fd\u6e90\u6c22\u6c14\u7684\u6709\u6548\u9014\u5f84\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u6c34\u89e3\u8fc7\u7a0b\u4e2d\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u56e0\u8f83\u9ad8\u7684\u53cd\u5e94\u80fd\u5792\u548c\u590d\u6742\u7684\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u5f80\u5f80\u8868\u73b0\u51fa\u7f13\u6162\u7684\u52a8\u529b\u5b66\uff0c\u540c\u65f6OER\u6d3b\u6027\u8f83\u9ad8\u7684\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u4f7f\u5f97\u5546\u4e1a\u7535\u89e3\u6c34\u6210\u672c\u5c45\u9ad8\u4e0d\u4e0b\u3002\u8fd1\u5e74\u6765\uff0c\u5177\u6709\u9ad8\u6d3b\u6027\u4f4e\u6210\u672c\u7684\u8fc7\u6e21\u91d1\u5c5eOER\u7535\u50ac\u5316\u5242\u6210\u4e3a\u80fd\u6e90\u9886\u57df\u548c\u7535\u5316\u5b66\u7814\u7a76\u7684\u524d\u6cbf\u548c\u70ed\u70b9\u3002\u4e8c\u7ef4\u4e9a\u7eb3\u7c73\u8d85\u8584\u7ed3\u6784\u80fd\u5728\u6709\u6548\u589e\u52a0\u7535\u89e3\u8d28\u4e0e\u50ac\u5316\u5242\u63a5\u89e6\u8868\u9762\u79ef\u7684\u540c\u65f6\u83b7\u5f97\u6d3b\u6027\u4f4d\u70b9\u7684\u5145\u5206\u66b4\u9732\u3002\u540c\u6d4e\u5927\u5b66\u6e29\u9e23\u6559\u6388\u8bfe\u9898\u7ec4\u901a\u8fc7\u5bf9\u53cc\u8d31\u91d1\u5c5e\u70ef\u7684\u540c\u6b65\u786b\u78f7\u5316\uff0c\u83b7\u5f97\u4e86\u4e9a\u7eb3\u7c73\u539a\u5ea6\u8d85\u8584\u7ed3\u6784\u7684CoFePS\u56db\u5143\u5408\u91d1\u3002\u7531\u4e8eP\u548cS\u80fd\u534f\u540c\u8c03\u8282\u76f8\u90bb\u91d1\u5c5e\u539f\u5b50\u7684\u8d39\u7c73\u80fd\u7ea7\uff0c\u964d\u4f4e\u53cd\u5e94\u80fd\u5792\uff0c\u540c\u65f6\u63d0\u5347\u5bfc\u7535\u6027\uff0c\u5728OER\u8fc7\u7a0b\u4e2d\uff0c1.8 V\u7684\u7535\u538b\u4e0b\u83b7\u5f97\u4e861053\u00a0mA\u00b7cm<sup>\u22122<\/sup>\u7684\u5927\u7535\u6d41\u5bc6\u5ea6\uff0c\u80fd\u5b8c\u5168\u6ee1\u8db3\u5546\u4e1a\u7535\u89e3\u6c34\u5bf9\u50ac\u5316\u5242\u7684\u8981\u6c42\u3002\u7814\u7a76\u4e3a\u9ad8\u6548\u8d85\u8584\u7ed3\u6784\u591a\u5143\u5408\u91d1OER\u7535\u50ac\u5316\u5242\u7684\u53d1\u5c55\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cCoFePS Quaternary Alloy Sub-nanometric-sheets by Synchronously Phospho-sulfurizing CoFe-bimetallene for Boosting Oxygen Evolution Reaction\u201d \u4e3a\u9898\u8fd1\u65e5\u5728\u7ebf\u53d1\u8868\u4e8e\u6750\u6599\u79d1\u5b66\u9886\u57df\u56fd\u9645\u8457\u540d\u5b66\u672f\u671f\u520a\u300a\u5148\u8fdb\u529f\u80fd\u6750\u6599\u300b(Advanced Functional Materials, 2023, <a href=\"https:\/\/doi.org\/10.1002\/adfm.202308422\">doi.org\/10.1002\/adfm.202308422<\/a>)\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-253416\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72471-6.png\" alt=\"\" width=\"660\" height=\"308\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72471-6.png 660w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72471-6-300x140.png 300w\" sizes=\"(max-width: 660px) 100vw, 660px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-253417\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72472-4.png\" alt=\"\" width=\"476\" height=\"434\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72472-4.png 476w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72472-4-300x274.png 300w\" sizes=\"(max-width: 476px) 100vw, 476px\" \/>\u00a0\u00a0\u00a0\u00a0 <\/b><\/strong><\/p>\n<p>\u9ad8\u6548\u7535\u50ac\u5316\u6750\u6599\u7684\u8bbe\u8ba1\u53ef\u4ee5\u4ece\u4ee5\u4e0b\u65b9\u9762\u8003\u8651\u3002\u4e0e\u5177\u6709\u76f8\u540c\u51e0\u4f55\u7ed3\u6784\u7684\u5355\u91d1\u5c5e\u786b\/\u78f7\u5316\u7269\uff08\u5df2\u88ab\u8bc1\u5b9e\u4e3a\u5177\u6709\u4f18\u5f02\u6d3b\u6027\u7684OER\u7535\u50ac\u5316\u5242\uff09\u76f8\u6bd4\uff0c\u5408\u91d1\u5316\u540e\u7684\u53cc\u91d1\u5c5e\u7cfb\u7edf\u4e2d\uff0c\u91d1\u5c5e\u7684d-\u7535\u5b50\u6784\u578b\u901a\u8fc7\u66f4\u7cbe\u7ec6\u7684\u8c03\u6574\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u964d\u4f4e\u9650\u901f\u6b65\u9aa4\u7684\u53cd\u5e94\u80fd\u5792\uff1b\u800c\u4e14\uff0c\u5229\u7528\u7535\u8d1f\u6027\u4e0d\u540c\u7684\u78f7\uff08P\uff09\u548c\u786b\uff08S\uff09\u8fdb\u884c\u540c\u6b65\u6742\u539f\u5b50\u5316\uff0c\u53ef\u4ee5\u5728\u7535\u50ac\u5316\u6750\u6599\u4e2d\u5f62\u6210\u65b0\u7684M-P-S\u952e\u5e76\u5f15\u53d1\u6676\u683c\u7578\u53d8\uff0c\u4ece\u800c\u589e\u5f3a\u5176\u672c\u5f81\u6d3b\u6027\u4ee5\u53ca\u5316\u5b66\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u7136\u800c\uff0c\u5982\u4f55\u6700\u5927\u9650\u5ea6\u5730\u5c06\u6d3b\u6027\u4f4d\u70b9\u66b4\u9732\u4e8e\u8868\u9762\u5e76\u4fdd\u6301\u9ad8\u7684\u50ac\u5316\u7a33\u5b9a\u6027\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\uff0c\u8fd9\u53ef\u4ee5\u901a\u8fc7\u51e0\u4f55\u7ed3\u6784\u7684\u8bbe\u8ba1\u8fdb\u884c\u89e3\u51b3\u3002\u4e8c\u7ef4\u4e9a\u7eb3\u7c73\u8d85\u8584\u7ed3\u6784\u4fdd\u8bc1\u4e86\u6d3b\u6027\u4f4d\u70b9\u7684\u5145\u5206\u66b4\u9732\uff0c\u53ef\u6709\u6548\u589e\u52a0\u7535\u89e3\u8d28\u548c\u50ac\u5316\u5242\u8868\u9762\u6d3b\u6027\u4f4d\u70b9\u4e4b\u95f4\u7684\u63a5\u89e6\u9762\u79ef\u3002\u4f46\u56e0\u8f83\u9ad8\u7684\u8868\u9762\u80fd\u4f7f\u5176\u8d8b\u5411\u81ea\u805a\u96c6\uff0c\u82e5\u91c7\u7528\u4f20\u7edf\u591a\u6b65\u6cd5\u5408\u6210\u591a\u5143\u5408\u91d1\u4e9a\u7eb3\u7c73\u7247\uff0c\u8fd9\u79cd\u81ea\u805a\u96c6\u73b0\u8c61\u4f1a\u66f4\u4e25\u91cd\u3002\u672c\u7814\u7a76\u53d1\u5c55\u4e86\u4e00\u79cd\u58f0\u5316\u5b66\u6cd5\u5408\u6210\u53cc\u91d1\u5c5e\u70ef\u7ed3\u5408\u540c\u6b65\u786b\u78f7\u5316\u6784\u7b51\u56db\u5143\u5408\u91d1\u4e8c\u7ef4\u4e9a\u7eb3\u7c73\u8d85\u8584\u7ed3\u6784\u7684\u7b56\u7565\uff0c\u5b9e\u73b0\u4e86\u9ad8\u6548\u7a33\u5b9a\u4fc3\u8fdb\u7535\u50ac\u5316OER\u7684\u76ee\u7684\u3002<\/p>\n<p>\u56fe1\u7684TEM\u548cAFM\u7167\u7247\u8868\u660e\uff0cCoFePS\u56db\u5143\u5408\u91d1\u8868\u73b0\u4e3a\u4e8c\u7ef4\u7247\u72b6\u7ed3\u6784\uff0c\u5176\u539a\u5ea6\u4ec5\u4e3a0.85 nm\u5de6\u53f3\u3002\u901a\u8fc7\u5bf9\u6bd4\u4e0d\u540c\u91d1\u5c5e\u6bd4\u4f8b\u7684XRD\u884d\u5c04\u56fe\u8c31\uff0c\u53ef\u4ee5\u53d1\u73b0CoFePS\u7684\u6676\u683c\u95f4\u8ddd\u53ca\u6676\u9762\u4fe1\u606f\u660e\u663e\u6709\u522b\u4e8eCoPS\u6216FePS\uff0c\u4e14Co\u3001Fe\u3001P\u548cS\u5143\u7d20\u4ee51:\u00a01: 1: 1\u7684\u539f\u5b50\u6bd4\u5747\u5300\u5206\u6563\u5728\u4e9a\u7eb3\u7c73\u7247\u7684\u6574\u4e2a\u7ed3\u6784\u4e2d\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-253418\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72473-4.png\" alt=\"\" width=\"1473\" height=\"763\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72473-4.png 1473w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72473-4-300x155.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72473-4-768x398.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72473-4-1024x530.png 1024w\" sizes=\"(max-width: 1473px) 100vw, 1473px\" \/><\/b><\/strong><\/p>\n<p>\u56fe1\uff1aCoFePS\u56db\u5143\u5408\u91d1\u7684\u5f62\u8c8c\u4e0e\u7ed3\u6784\u8868\u5f81<\/p>\n<p>\u901a\u8fc7\u4e0d\u540c\u5bf9\u6bd4\u6750\u6599\u7684OER\u6027\u80fd\u6d4b\u8bd5\u53ef\u4ee5\u770b\u51fa\uff0cCoFePS\u5728\u4ec5211 mV\u7684\u8fc7\u7535\u4f4d\u4e0b\u5c31\u83b7\u5f97\u4e8610 mA\u00b7cm<sup>\u22122<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u4e14\u57281.8 V\u7684\u7535\u538b\u4e0b\uff0c\u5176\u6700\u5927\u7535\u6d41\u5bc6\u5ea6\u53ef\u8fbe1053\u00a0mA\u00b7cm<sup>\u22122<\/sup>\uff0cTafel\u659c\u7387\u4ec5\u4e3a14 mV\u00b7dec<sup>\u22121<\/sup>\uff1b\u540c\u65f6\uff0c\u5176\u6cd5\u62c9\u7b2c\u6548\u7387\u8fbe\u5230\u4e8697%\u3002\u6b64\u5916\uff0cCoFePS\u7ef4\u6301\u8f83\u9ad8\u6027\u80fd\u7684\u540c\u65f6\u4e5f\u5177\u6709\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\uff0c\u57281.45 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V\u7684\u7535\u538b\u4e0b\u83b7\u5f97200 ~ 400mA\u00b7cm<sup>\u22122<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff09\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-253419\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72474-4.png\" alt=\"\" width=\"1301\" height=\"659\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72474-4.png 1301w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72474-4-300x152.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72474-4-768x389.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/08\/\u56fe\u72474-4-1024x519.png 1024w\" sizes=\"(max-width: 1301px) 100vw, 1301px\" 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