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\u4e00\u3001<\/strong> \u3010\u5bfc\u8bfb\u3011<\/strong>\u00a0 <\/strong><\/p>\n

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\"\"<\/p>\n

\u00a0<\/strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

\u8fd9\u9879\u7814\u7a76\u9996\u6b21\u5b9e\u73b0\u4e86\u901a\u8fc7\u72ec\u7279\u7684\u6784\u5efa\u5355\u5143\u5728\u4e0d\u540c\u6eb6\u5242\u6761\u4ef6\u4e0b\u53ef\u63a7\u5408\u6210\u4e09\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7684\u62d3\u6251\u540c\u5206\u5f02\u6784\u4f53\uff0c\u4e3aCOF\u6750\u6599\u7684\u7ed3\u6784\u591a\u6837\u6027\u548c\u5e94\u7528\u62d3\u5c55\u63d0\u4f9b\u4e86\u521b\u65b0\u6027\u7684\u65b9\u6cd5\u3002<\/p>\n

\u00a0<\/strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1<\/strong> JUC-620\u548cJUC-621\u7684\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09\u548c\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\uff08PXRD\uff09\u7814\u7a76\u3002JUC-620\uff08a\uff09\u548cJUC-621\uff08b\uff09\u7684TEM\u56fe\u50cf\u3002JUC-620\uff08c\uff09\u548cJUC-621\uff08d\uff09\u7684\u5b9e\u9a8c\u548c\u62df\u5408PXRD\u56fe\u8c31\u3002\u00a9 2023 American Chemical Society<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2<\/strong> \u4f7f\u7528EM\u5bf9JUC-621\u8fdb\u884c\u7684\u7ed3\u6784\u5206\u6790\u3002 (a\u548cb) \u6cbf[100]\u548c[001]\u65b9\u5411\u83b7\u53d6\u7684TEM\u56fe\u50cf\uff0c\u663e\u793a\u4e25\u683c\u548c\u5df1\u9187\u6392\u5217\u7684\u901a\u9053\uff0c\u4ee5\u53ca\u76f8\u5e94\u7684\u9009\u533a\u7535\u5b50\u884d\u5c04\uff08SAED\uff09\u56fe\u6848\uff08i\uff09\u548c\u52a8\u529b\u5b66\u6a21\u62df\u7ed3\u679c\uff08ii\uff09\uff1b (c) \u6cbf[100]\u9009\u533a\u8f74\u83b7\u5f97\u7684JUC-621\u7684\u9ad8\u5206\u8fa8\u7387iDPC-STEM\u56fe\u50cf\uff1b (d) p1\u5bf9\u79f0\u4e0b\u7684\u683c\u70b9\u5e73\u5747\u56fe\u50cf\uff08i\uff09\uff0cp2mm<\/em>\u5bf9\u79f0\u7ea6\u675f\u4e0b\u7684\u56fe\u50cf\uff08ii\uff09\uff0c\u6a21\u62df\u7684iDPC-STEM\u56fe\u50cf\uff08iii\uff09\u548c\u76f8\u5e94\u7684\u7ed3\u6784\u6295\u5f71\uff08iv\uff09\uff1b (e\u548cf) \u6cbf[110]\u548c[001]\u9009\u533a\u8f74\u91cd\u65b0\u6784\u5efa\u7684\u4e09\u7ef4\u9759\u7535\u52bf\u56fe\uff0c\u4e0e\u7ed3\u6784\u6a21\u578b\u53e0\u52a0\u663e\u793a\u3002 (d) \u548c(f) \u4e2d\u7684\u65b9\u6846\u8868\u793a\u4e00\u4e2a\u6676\u80de\u3002\u00a9 2023 American Chemical Society<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3<\/strong> N2<\/sub>\u5438\u9644-\u8131\u9644\u548c\u7d2b\u5916\/\u53ef\u89c1\u5149\u8c31\u3002 (a) JUC-620\u572877K\u4e0b\u7684N2<\/sub>\u5438\u9644-\u8131\u9644\u7b49\u6e29\u7ebf\u3002\u63d2\u56fe\uff1aJUC-620\u7684\u5b54\u5f84\u5206\u5e03\u3002 (b) JUC-621\u572877K\u4e0b\u7684N2<\/sub>\u5438\u9644-\u8131\u9644\u7b49\u6e29\u7ebf\u3002(c) JUC-620\u5bf9\u7532\u57fa\u6a59\u7684\u5feb\u901f\u5438\u9644\u7684\u7d2b\u5916\/\u53ef\u89c1\u5149\u8c31\uff0c\u6301\u7eed\u65f6\u95f4\u4e3a120\u5206\u949f\u3002 (d) JUC-621\u5bf9\u7532\u57fa\u6a59\u7684\u5feb\u901f\u5438\u9644\u7684\u7d2b\u5916\/\u53ef\u89c1\u5149\u8c31\uff0c\u6301\u7eed\u65f6\u95f4\u4e3a120\u5206\u949f\u3002\u00a9 2023 American Chemical Society<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4<\/strong> \u7898\u5438\u9644\u7814\u7a76\u3002JUC-620\uff08a\uff09\u548cJUC-621\uff08b\uff09\u572875\u2103\u548c\u5e38\u538b\u4e0b\u968f\u66b4\u9732\u65f6\u95f4\u7684I2<\/sub>\u5438\u6536\u91cf\u3002JUC-620\uff08c\uff09\u548cJUC-621\uff08d\uff09\u5728I2<\/sub>\u5438\u6536\u540e\u7684XPS\u8c31\u56fe\u3002JUC-620\uff08e\uff09\u548cJUC-621\uff08f\uff09\u5728I2<\/sub>\u5438\u6536\u524d\uff08\u7ea2\u8272\u66f2\u7ebf\uff09\u548c\u5438\u6536\u540e\uff08\u9ed1\u8272\u66f2\u7ebf\uff09\u7684\u62c9\u66fc\u5149\u8c31\u3002\u00a9 2023 American Chemical Society<\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u603b\u800c\u8a00\u4e4b\uff0c\u672c\u7814\u7a76\u9996\u6b21\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4e24\u79cd\u5177\u6709\u62d3\u6251\u540c\u5206\u5f02\u6784\u7684\u4e09\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff0c\u5206\u522b\u4e3aJUC-620\uff08\u5177\u6709dia\u7f51\u7edc\uff09\u548cJUC-621\uff08\u5177\u6709qtz\u7f51\u7edc\uff09\u3002\u8fd9\u4e9b\u540c\u5206\u5f02\u6784\u4f53\u5728\u591a\u5b54\u6027\u80fd\u4e0a\u8868\u73b0\u51fa\u660e\u663e\u5dee\u5f02\uff0c\u7279\u522b\u662fJUC-621\u5177\u6709\u8f83\u5927\u7684\u4ecb\u5b54\u548c\u8868\u9762\u79ef\uff0c\u5e76\u5c55\u73b0\u51fa\u66f4\u9ad8\u7684\u67d3\u6599\u5438\u9644\u548c\u7898\u5438\u9644\u80fd\u529b\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u89c2\u5bdf\u5230\u4e86\u4e09\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7684\u62d3\u6251\u540c\u5206\u5f02\u6784\u73b0\u8c61\uff0c\u8fd8\u4e3aCOF\u6750\u6599\u7684\u7ed3\u6784-\u6027\u80fd\u5173\u7cfb\u7814\u7a76\u63d0\u4f9b\u4e86\u63a8\u52a8\u3002<\/p>\n

 <\/p>\n

\u539f\u6587\u8be6\u60c5\uff1aLiu, Y.;\u00a0 Li, J.;\u00a0 Lv, J.;\u00a0 Wang, Z.;\u00a0 Suo, J.;\u00a0 Ren, J.;\u00a0 Liu, J.;\u00a0 Liu, D.;\u00a0 Wang, Y.;\u00a0 Valtchev, V.;\u00a0 Qiu, S.;\u00a0 Zhang, D.; Fang, Q., Topological Isomerism in Three-Dimensional Covalent Organic Frameworks. Journal of the American Chemical Society 2023, 145 (17), 9679-9685.<\/p>\n

https:\/\/doi.org\/ 10.1021\/jacs.3c01070<\/p>\n

\u672c\u6587\u7531jiojio\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"

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