{"id":251556,"date":"2023-06-11T06:20:30","date_gmt":"2023-06-10T22:20:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=251556"},"modified":"2023-06-10T22:20:43","modified_gmt":"2023-06-10T14:20:43","slug":"aem%ef%bc%9a%e5%a4%9a%e8%81%9a%e9%85%9e%e8%8f%81%e5%8c%85%e8%a6%86%e7%a2%b3%e7%ba%b3%e7%b1%b3%e7%ae%a1%e4%bd%9c%e4%b8%ba%e9%94%82%e7%a1%ab%e7%94%b5%e6%b1%a0%e7%9a%84%e9%ab%98%e6%95%88%e6%b0%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=251556","title":{"rendered":"AEM\uff1a\u591a\u805a\u915e\u83c1\u5305\u8986\u78b3\u7eb3\u7c73\u7ba1\u4f5c\u4e3a\u9502\u786b\u7535\u6c60\u7684\u9ad8\u6548\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong>\u00a0 <\/strong><\/p>\n

\u7531\u4e8e\u4e25\u91cd\u7684\u5168\u7403\u80fd\u6e90\u5371\u673a\u548c\u5bf9\u53ef\u518d\u751f\u80fd\u6e90\u7684\u9700\u6c42\u8fc5\u901f\u589e\u957f\uff0c\u9502\u786b\u7535\u6c60\u56e0\u5176\u6bd4\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u66f4\u5177\u6210\u672c\u6548\u76ca\u548c\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff082600 W h kg-1)\u800c\u5f15\u8d77\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u5174\u8da3\u3002\u7136\u800c\uff0c\u76ee\u524d\u53ef\u7528\u7684\u9502\u786b\u7535\u6c60\u56fa\u6709\u7684\u5c40\u9650\u6027–\u5373\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u81a8\u80c0\u3001\u591a\u786b\u5316\u9502\u7684\u7a7f\u68ad\u6548\u5e94\u548c\u786b\u7684\u4f4e\u672c\u5f81\u7535\u5bfc\u7387–\u963b\u788d\u4e86\u5b83\u4eec\u7684\u5546\u4e1a\u5316\u3002\u9700\u8981\u5e7f\u6cdb\u7684\u7814\u7a76\u6765\u5f00\u53d1\u80fd\u591f\u89e3\u51b3\u4e0a\u8ff0\u5c40\u9650\u6027\u7684\u8d1f\u62c5\u5f97\u8d77\u7684\u786b\u4e3b\u4f53\u6750\u6599\uff0c\u8fd9\u5c06\u6709\u52a9\u4e8e\u5f00\u53d1\u51fa\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u4f18\u826f\u5faa\u73af\u7a33\u5b9a\u6027\u7684\u5b9e\u7528\u9502\u786b\u7535\u6c60\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u91d1\u5c5e\u915e\u83c1(Pc)\u914d\u5408\u7269\u5177\u6709\u53ef\u8c03\u8c10\u7684\u6027\u8d28\u548c\u72ec\u7279\u7684\u03c0-\u7535\u5b50\u7ed3\u6784\uff0c\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u529f\u80fd\u6709\u673a\u6750\u6599\u3002\u5c3d\u7ba1\u6709\u8fd9\u4e9b\u4f18\u70b9\uff0c\u4f46\u805a\u5408\u7269\u91d1\u5c5ePc\u5728\u9502-\u786b(Li-S)\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u8fd8\u6709\u5f85\u63a2\u7d22\u3002\u57fa\u4e8e\u6b64\uff0c\u9999\u6e2f\u7406\u5de5\u5927\u5b66Jeongyeon Lee\u548c\u6210\u5747\u9986\u5927\u5b66Ho Seok Park\u505a\u4e86\u4e09\u4e59\u4e8c\u9187\u8fde\u63a5\u5242(TCP)\u7684\u591a\u529f\u80fd\u805a\u5408\u94b4Pc\u7684\u5206\u5b50\u8bbe\u8ba1\uff0c\u5176\u53ef\u4ee5\u4e3aPc\u4e2d\u5fc3\u7684Co\u79bb\u5b50\u63d0\u4f9b\u6c27\u5316\u8fd8\u539f\u4e2d\u4ecb\u80fd\u529b\uff0cN\u539f\u5b50\u4e0eLi\u7684\u5f3a\u6781\u6027\u76f8\u4e92\u4f5c\u7528\uff0c\u4ee5\u53ca\u7528\u4e8e\u9ad8\u6548\u9502- s\u7535\u6c60\u7684\u4eff\u51a0\u919a\u4eb2\u77f3\u4f4d\u70b9\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cMultifunctional Polymeric Phthalocyanine-Coated Carbon Nanotubes for Efficient Redox Mediators of Lithium\u2013Sulfur Batteries<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aAdvanced Energy Materials<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

\u5408\u6210\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u542bTEG\u7684\u805a\u5408\u7269\u94b4Pc\uff0c\u5e76\u5c06\u5176\u5305\u8986\u5728MCs\u4e0a\uff0c\u901a\u8fc7\u5f3a\u03c0-\u03c0\u4f5c\u7528\u5f62\u6210TCP\/MCs\u3002\u7ed3\u679c\u8868\u660e\uff0cTCP\/MCs\u4e2d\u7684TCP\u7531\u4e8e\u5177\u6709\u6c27\u5316\u8fd8\u539f\u4ecb\u5bfc\u80fd\u529b\uff0c\u4fc3\u8fdb\u4e86LiPS\u7684\u5438\u6536\u548c\u8f6c\u5316\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u800cTCP\/MCs\u7684TEG\u8fde\u63a5\u7269\u4e2d\u542b\u6709\u4eb2\u77f3\u4f4d\u70b9\uff0c\u53ef\u7ed3\u5408Li\u79bb\u5b50\u3002\u6b64\u5916\uff0cTCP\/MCs\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u663e\u8457\u589e\u5f3a\u4e86Li2S\u7684\u6790\u51fa\u5f62\u8c8c\uff0c\u540c\u65f6\u6291\u5236\u4e86\u5145\u7535\u8fc7\u7a0b\u4e2d\u542b\u7edd\u7f18\u6027S\u590d\u5408\u6750\u6599\u7c07\u7c07\u7684\u6301\u7eed\u5f62\u6210\u3002\u56e0\u6b64\uff0cS@TCP\/MC\u7535\u6781\u57280.1\u548c5.0 C(\u5206\u522b\u4e3a1392.8\u548c667.9 mA h g\u22121)\u65f6\u5177\u6709\u51fa\u8272\u7684\u901f\u7387\u6027\u80fd\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u521d\u59cb\u5bb9\u91cf\u3002S@TCP\/MC\u7535\u6781\u5faa\u73af\u6027\u80fd\u7a33\u5b9a\uff0c\u5faa\u73af200\u6b21\u540e\u5bb9\u91cf\u8870\u51cf\u7387\u4e3a0.092%\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a81.5%\u3002\u6b64\u5916\uff0c\u5373\u4f7f\u5728\u9ad8S\u8d1f\u8f7d(6.6 mg cm\u22122)\u4e0b\uff0cS@TCP\/MC\u7535\u6781\u57280.2\u2103\u65f6\u7684\u521d\u59cb\u5bb9\u91cf\u4e3a1032 mA h g\u22121\uff0c\u5bf9\u5e94\u7684\u9762\u79ef\u5bb9\u91cf\u4e3a6.83 mA h cm\u22122<\/sup>\u3002<\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1\u00a0 \u5728MC\u6a21\u677f\u7684\u8868\u9762\u4e0a\u6d82\u8986\u5747\u5300\u7684\u805a\u5408TCP\u5c42\u00a9 2023 Wiley<\/p>\n

(a) S@TCP\/MCs\u7535\u6781\u7684\u5408\u6210\u793a\u610f\u56fe\uff1b(b) TCP\/ mc\u7684STEM\u56fe\u50cf\uff1b(c) TCP\/MC\u7684\u8fb9\u754c\u56fe\u50cf\u53d6\u81ea(b)\u4e2d\u7ea2\u8272\u865a\u7ebf\u77e9\u5f62\u6807\u8bb0\u7684\u533a\u57df\uff1b(d)\u539f\u59cbMC\u7684\u8fb9\u754c\u56fe\u50cf\uff1b(e) TCP\/MC\u7684STEM\u56fe\u50cf\u5bf9\u5e94\u7684\u5143\u7d20\u6620\u5c04\u56fe\u50cf<\/p>\n

\"\"<\/p>\n

\u56fe2\u00a0 \u5229\u7528\u5149\u8c31\u6280\u672f\u5bf9TCP\u548cTCP\/MC\u7684\u7535\u5b50\u548c\u5316\u5b66\u7ed3\u6784\u8fdb\u884c\u8868\u5f81\u00a0 <\/strong>\u00a9<\/strong> 2023 Wiley<\/p>\n

(a) TCP\u548cTCP\/MC\u7684\u7d2b\u5916-\u53ef\u89c1\u5149\u8c31\uff1b(b) \u62c9\u66fc\u5149\u8c31\uff1b(c) TCP\/MC\u3001TCP\u548cMC\u7684FTIR\u5149\u8c31\uff0c\u9ad8\u5206\u8fa8\u7387 XPS \u914d\u7f6e\u6587\u4ef6\uff1b(d) \u9ad8\u5206\u8fa8\u7387Co 2p\u5149\u8c31\uff1b(e) N1 s\u5149\u8c31\uff1b<\/p>\n

(f) O1 s\u5149\u8c31\uff1b(g) C1 s \u7684 TCP\/MC \u5cf0<\/p>\n

\"\"<\/p>\n

\u56fe3\u00a0 \u5c06TCP\/MCs\u548cMCs\u6837\u54c1\u6d78\u51655 mm Li\u6eb6\u6db2\u4e2d\u8fdb\u884c\u4e86\u5438\u9644\u8bd5\u9a8c\u00a0 \u00a9<\/strong> 2023 Wiley<\/p>\n

(a)\u5438\u9644\u524d\u540eLi2S6\u6eb6\u6db2\u7684\u7d2b\u5916-\u53ef\u89c1\u5149\u8c31(\u9644\u56fe\u4e3a\u4e0a\u8ff0\u6eb6\u6db2\u7684\u5149\u5b66\u56fe\u50cf)\uff1b(b)\u542b\u6709TCP\/MC\u7684\u5bf9\u79f0\u7535\u6c60\u4e0e\u542b\u6709MC\u7684\u5bf9\u79f0\u7535\u6c60\u7684CV\u66f2\u7ebf\uff1b(c)-(d) Li2S8\u6eb6\u6db2\u5728TCP\/MC\u548cMC\u7535\u6781\u4e0a\u7684\u6052\u7535\u4f4d\u6210\u6838\u5256\u9762(\u63d2\u56fe:Li2S\u6210\u6838\u540eTCP\/MC\u548cMC\u7684SEM\u56fe\u50cf)<\/p>\n

\"\"<\/p>\n

\u56fe4\u00a0 \u7535\u5316\u5b66\u6027\u80fd\u5bf9\u6bd4\u00a0 \u00a9<\/strong> 2023 Wiley<\/p>\n

(a) \u626b\u63cf\u901f\u7387\u4e3a0.1mVs-1<\/sup>\u65f6\u7684CV\u66f2\u7ebf\uff1b(b) S@TCP\/MC \u7535\u6781\u5728 0.1 C \u65f6\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u4e0e S@mTCP\/MC \u548c S@MC \u7535\u6781\u7684\u6bd4\u8f83\uff1b(c) S@TCP\/MC\u3001S@mTCP\/MC \u548cS@MC\u7535\u6781\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u901f\u7387\u6027\u80fd\uff1b(d) \u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684QL\/QH\u6bd4\u65f6\u7684\u5faa\u73af\u6027\u80fd\uff1b(e) 0.2c\uff1b(f) 1.0c\uff1b(g) 0.2C\uff0c\u9ad8S\u8d1f\u8377<\/p>\n

\"\"<\/p>\n

\u56fe5\u00a0 \u6784\u5efaTafel\u56fe\u4ee5\u786e\u5b9a\u5145\u653e\u7535\u8fc7\u7a0b\u7684\u901f\u7387\u00a0 \u00a9<\/strong> 2023 Wiley<\/p>\n

(a) \u6db2\u56fa\u8fd8\u539f\u8fc7\u7a0b\u7684Tafel\u56fe\uff08\u7b2c\u4e8c\u4e2a\u9634\u6781\u5cf0\uff09\uff1b(b) S@TCP\/MC\u3001S@mTCP\/MC \u548cS@MC\u9634\u6781\u7684\u5948\u594e\u65af\u7279\u56fe\uff1b(c) \u5728\u4f4e\u9891\u533a\uff0c\u5b9e\u7535\u963b(Z\u2032)\u4e0e\u89d2\u901f\u5ea6(\u03c9-1\/2)\u7684\u5e73\u65b9\u6839\u7684\u5173\u7cfb\uff1b(d)-(e) CV\u66f2\u7ebf\u4e2d\u7b2c\u4e8c\u4e2a\u9634\u6781\u5cf0\u548ce\uff09\u7b2c\u4e00\u4e2a\u9633\u6781\u5cf0\u7684\u7535\u6d41\u503c\u4e0e\u901f\u7387\u5e73\u65b9\u6839\u7684\u5173\u7cfb\u56fe\uff1b(f) S@Tcp\/MC\u3001S@Mtcp\/MC\u548cS@MC\u9634\u6781\u7684\u9502\u79bb\u5b50\u6269\u6563\u7cfb\u6570<\/p>\n

\"\"<\/p>\n

\u56fe6\u00a0 \u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\uff0c\u9610\u660eTCP\u7684\u4f5c\u7528\u00a0 \u00a9<\/strong> 2023 Wiley<\/p>\n

(a) TCP\u5438\u9644Li2S6\u5206\u5b50\u7ed3\u6784\u7684\u5bc6\u5ea6\u6cdb\u51fd\u8ba1\u7b97\uff1b(b) \u4e0e\u78b3\u952e\u8fde\u63a5\u7684COPC\u76841-4\u4f4d\u7684\u9502\u79bb\u5b50\u7ed3\u5408\u80fd\u76f8\u6bd4\uff0cTCP\u76841-4\u4f4d\u7684\u9502\u79bb\u5b50\u7ed3\u5408\u80fd\uff1b(c) Co 2p\u7684XPS\u914d\u7f6e\u6587\u4ef6\uff1b(d) N1 s\u7684XPS\u914d\u7f6e\u6587\u4ef6\uff1b(e) \u5438\u9644Li2S6\u524d\u540eTCP\/MC\u7684O1S\u5cf0\uff1b(f)-(g) S@TCP\/MC\u7535\u6781\u5faa\u73af\u524d\u548c100\u6b21\u653e\u7535-\u5145\u7535\u5faa\u73af\u540e\u7684SEM\u56fe\u50cf\uff1b(h) MCS\u5faa\u73af\u524d\u548c100\u6b21\u653e\u7535-\u5145\u7535\u5faa\u73af\u540e\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf<\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u5728MC\u6a21\u677f\u8868\u9762\u6d82\u8986\u5747\u5300\u7684\u805a\u5408TCP\uff0c\u4f7f\u5176\u5177\u6709\u8f83\u9ad8\u7684\u5bfc\u7535\u6027\uff0c\u4ece\u800c\u53ef\u4ee5\u4f7f\u5b83\u4eec\u5728Li-S\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u5927\u653e\u5f02\u5f69\u3002\u672c\u6587\u4f5c\u8005\u901a\u8fc7\u5b9e\u9a8c\u8bc1\u5b9e\u4e86S@TCP\/MC\u4f18\u4e8e\u5176\u4ed6\u53d8\u4f53\uff0c\u9610\u8ff0\u4e86MC\u4f5c\u4e3a\u78b3\u6a21\u677f\u7684\u9002\u7528\u6027\uff0c\u5177\u6709\u5bb9\u6613\u7684\u6d82\u5c42\u80fd\u529b\u3001\u51fa\u8272\u7684\u5bfc\u7535\u6027\u548c\u7ed3\u6784\u8010\u4e45\u6027\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u6709\u673a\u5316\u5408\u7269\u6d82\u6577\u5728\u78b3\u8d28\u6a21\u677f\u4e0a\uff0c\u53ef\u4ee5\u5728Li-S\u7535\u6c60\u4e2d\u5f62\u6210\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u548cs -\u5bbf\u4e3b\u7684\u7ed3\u6784\uff0c\u8fd9\u7a81\u51fa\u4e86\u8fd9\u79cdLi-S\u7535\u6c60\u4f5c\u4e3a\u5148\u8fdb\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u50a8\u80fd\u7cfb\u7edf\u7684\u6f5c\u529b\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1a<\/p>\n

Multifunctional Polymeric Phthalocyanine-Coated Carbon Nanotubes for Efficient Redox Mediators of Lithium\u2013Sulfur Batteries (Advanced Energy Materials 2023, DOI: 10.1002\/aenm.202204353)<\/em><\/p>\n

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