{"id":251452,"date":"2023-05-30T06:30:29","date_gmt":"2023-05-29T22:30:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=251452"},"modified":"2023-05-29T10:40:44","modified_gmt":"2023-05-29T02:40:44","slug":"small-%e5%9f%ba%e4%ba%8en-%e6%b7%b7%e6%9d%82%e7%9a%84%e9%87%91%e5%b1%9e%e5%8d%9f%e5%95%89%e5%9f%ba%e5%85%b1%e4%bb%b7%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e6%9d%90%e6%96%99%e9%ab%98%e6%95%88%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=251452","title":{"rendered":"Small: \u57fa\u4e8eN-\u6df7\u6742\u7684\u91d1\u5c5e\u535f\u5549\u57fa\u5171\u4ef7\u6709\u673a\u6846\u67b6\u6750\u6599\u9ad8\u6548\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94"},"content":{"rendered":"

Small<\/em><\/strong>: <\/strong>\u57fa\u4e8e<\/strong>N-<\/strong>\u6df7\u6742\u7684\u91d1\u5c5e\u535f\u5549\u57fa\u5171\u4ef7\u6709\u673a\u6846\u67b6\u6750\u6599\u9ad8\u6548\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94<\/strong><\/p>\n

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

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\u00a0 \u00a0 \u00a0 \u00a0\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cDesigning N-Confused Metalloporphyrin-Based Covalent Organic Frameworks for Enhanced Electrocatalytic Carbon Dioxide Reduction<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Small<\/em><\/strong>\u4e0a\u3002<\/p>\n

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\u56fe<\/strong>2.<\/strong> a\uff09Por-COFs\u8868\u9762\u53ef\u80fd\u7684CO2<\/sub>RR\u9014\u5f84\u548c\u4ea7\u7269\uff1bb\uff09\u5404\u53cd\u5e94\u4ea7\u7269\u5bf9\u5e94\u7684\u53cd\u5e94\u5f0f\u53ca\u5176\u6807\u51c6\u6c27\u5316\u8fd8\u539f\u7535\u4f4d<\/p>\n

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\u56fe<\/strong>3 <\/strong>\u8ba1\u7b97\u5f97\u5230\u7684MN4<\/sub>-Por-COFs\u7684\u7ed3\u5408\u80fd\uff08x\u8f74\uff09\u3001\u7ed3\u5408\u80fd\u4e0e\u56e2\u805a\u80fd\u4e4b\u5dee\uff08y\u8f74\uff09\u548c\u6eb6\u89e3\u7535\u52bf\uff08z\u8f74\uff09\uff0c\u5176\u4e2dM\u4e3aSc\/Ti\/V\/Cr\/Mn\/Fe\/Co\/Ni\/Cu\/Zn\uff1bb\uff09MN4<\/sub>-Por-COFs\u8868\u9762\u751f\u6210*COOH\/*OCHO\u4e2d\u95f4\u4f53\u4e0e\u751f\u6210*H\u4e2d\u95f4\u4f53\u81ea\u7531\u80fd\u53d8\u5316\u7684\u6bd4\u8f83\u3002C\uff09MN4<\/sub>-Por-COFs\u8868\u9762CO2<\/sub>RR\u751f\u6210CO\u548cd\uff09HCOOH\u7684\u81ea\u7531\u80fd\u66f2\u7ebf<\/p>\n

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\u56fe<\/strong>4 <\/strong>a\uff09CoN4<\/sub>-Por-COF\u3001b\uff09CoN3<\/sub>C1<\/sub>-Por-COF\u548cc\uff09CoN2<\/sub>C2<\/sub>-Por-COF\u8868\u9762\u7684CO2<\/sub>RR\u81ea\u7531\u80fd\u66f2\u7ebf<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5 <\/strong>a\uff09\u4e09\u79cdCo-Por-COFs\u7684\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u56fe\u548cb\uff09CoN4<\/sub>-\u3001CoN3<\/sub>C1<\/sub>-\u548cCoN2<\/sub>C2<\/sub>-\u6838\u5fc3\u7684\u6295\u5f71\u7535\u5b50\u6001\u5bc6\u5ea6(PDOS)\u3002\u9752\u8272\/\u9ec4\u8272\u8868\u793a\u7535\u5b50\u635f\u5931\/\u805a\u96c6\u533a\u57df\u3002\u7535\u8377\u5bc6\u5ea6\u7b49\u503c\u9762\u8bbe\u7f6e\u4e3a0.003 e \u00c5\u22123<\/sup>\u3002C\uff09\u5438\u9644\u7269\u76842p<\/em>\u8f68\u9053\u4e0eCo\u539f\u5b50\u76843d<\/em>\u8f68\u9053\u4e4b\u95f4\u7684\u8f68\u9053\u6742\u5316\u793a\u610f\u56fe\uff1b d\uff09*COOH\u548ce\uff09*CHOH\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u6784\u578b\u53ca\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u56fe\u3002\u4e0d\u540c\u5c0f\u7403\u4ee3\u8868\u7684\u539f\u5b50\u79cd\u7c7b\uff1a\u7d2b\u8272\uff0cCo\uff1b\u7070\u8272\uff0cC\uff1b\u84dd\u8272\uff0cN\uff1b\u7ea2\u8272\uff0cO\uff1b\u767d\u8272\uff0cH<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>6 <\/strong>a\uff09\u4e09\u79cdCo-Por-COFs\u8868\u9762\u7684CO2<\/sub>RR\u81ea\u7531\u80fd\u66f2\u7ebf\uff1bb\uff09CrN4<\/sub>-\u3001CrN3<\/sub>C1<\/sub>-\u3001CrN2<\/sub>C2<\/sub>-Por-COFs\u7684\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u56fe\u3002\u9752\u8272\/\u9ec4\u8272\u8868\u793a\u7535\u5b50\u635f\u5931\/\u805a\u96c6\u533a\u57df\u3002\u7535\u8377\u5bc6\u5ea6\u7b49\u503c\u9762\u8bbe\u7f6e\u4e3a0.003 e \u00c5\u22123<\/sup>\u3002C\uff09*OCHO\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u6784\u578b\u53ca\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u56fe\u3002\u4e0d\u540c\u5c0f\u7403\u4ee3\u8868\u7684\u539f\u5b50\u79cd\u7c7b\uff1a\u7eff\u8272\uff0cCr\uff1b\u7070\u8272\uff0cC\uff1b\u84dd\u8272\uff0cN\uff1b\u7ea2\u8272\uff0cO\uff1b\u767d\u8272\uff0cH<\/p>\n

\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u63ed\u793a\u4e86\u6539\u53d8\u6d3b\u6027\u91d1\u5c5e\u7684\u914d\u4f4d\u6a21\u5f0f\u662f\u76f4\u63a5\u8c03\u63a7CO2<\/sub>\u8fd8\u539f\u7535\u50ac\u5316\u5242\u6027\u80fd\u7684\u6709\u6548\u7b56\u7565\uff0c\u4e3a\u540e\u7eed\u5b9e\u9a8c\u5408\u6210\u5177\u6709\u4f18\u5f02\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\u7684\u65b0\u578b\u535f\u5549\u57faCOFs\u7c7b\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u9884\u6d4b\u6307\u5bfc\u3002<\/p>\n

\u7b2c\u4e00\u4f5c\u8005\uff1a\u4efb\u5fd7\u946b<\/p>\n

\u901a\u8baf\u4f5c\u8005\uff1a\u8c22\u9759<\/p>\n

\u901a\u8baf\u5355\u4f4d\uff1a\u5317\u4eac\u7406\u5de5\u5927\u5b66<\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a<\/strong>https:\/\/doi.org\/10.1002\/smll.202301818<\/p>\n

\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u00a0 \u00a0 \u00a0 \u00a0 \u8c22\u9759<\/strong>\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u7814\u7a76\u65b9\u5411\u4e3a\u7406\u8bba\u4e0e\u8ba1\u7b97\u5316\u5b66\uff0c\u7814\u7a76\u9886\u57df\u6709\u5206\u5b50\u53cd\u5e94\u52a8\u529b\u5b66\u3001\u5fae\u6db2\u6ef4\u5316\u5b66\u3001\u50ac\u5316\u5316\u5b66\u3002\u76ee\u524d\u8bfe\u9898\u7ec4\u4e3b\u8981\u5f00\u5c55\u4e24\u65b9\u9762\u5de5\u4f5c\uff1a 1\uff09\u5fae\u6db2\u6ef4\u53cd\u5e94\u52a8\u529b\u5b66\u6a21\u62df\u4e0e\u7406\u8bba\u7814\u7a76\uff0c\u5305\u542b\u6c14\u76f8\u3001\u5fae\u6eb6\u5242\u76f8\u3001\u6c14\u6db2\u754c\u9762\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\u6a21\u62df\uff0c\u63a2\u7d22\u6709\u673a\u53cd\u5e94\u3001\u81ea\u7531\u57fa\u53cd\u5e94\u3001\u5927\u6c14\u53cd\u5e94\u673a\u7406\u7b49\uff1b 2\uff09\u529f\u80fd\u6750\u6599\u8bbe\u8ba1\uff0c\u5305\u542bMOF\/COF\u5206\u79bb\u4e0e\u50ac\u5316\u6750\u6599\u8ba1\u7b97\uff0c\u9502\u786b\u7535\u6c60\u6b63\u6781\u6750\u6599\u8bbe\u8ba1\uff0c\u4ee5\u53ca\u91d1\u5c5e\u56e2\u7c07\u6d3b\u5316\u5c0f\u5206\u5b50\u7b49\u3002\u5165\u9009\u5317\u4eac\u7406\u5de5\u5927\u5b66\u201c\u7279\u7acb\u9752\u5e74\u5b66\u8005\u201d\u4eba\u624d\u8ba1\u5212\uff0c\u201c\u5317\u4eac\u5e02\u79d1\u534f\u9752\u5e74\u6258\u4e3e\u5de5\u7a0b\u201d\uff0c\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\/\u9752\u5e74\u9879\u76ee\u3001\u5317\u4eac\u5e02\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\u3001\u79d1\u6280\u90e8\u5916\u4e13\u9879\u76ee\u7b49\u3002\u8fc4\u4eca\u53d1\u8868SCI\u8bba\u658750\u4f59\u7bc7\uff0c\u5305\u62ecScience<\/em>\uff0cNature<\/em>\uff0cNat. Chem.<\/em>\uff0cJ. Am. Chem. Soc.<\/em>\uff0cAngew. Chem. Int. Ed.<\/em>\uff0cNat. Commun.<\/em>\uff0cAcc. Chem. Res.<\/em>\uff0cChem. Sci.<\/em>\uff0cJ. Phys. Chem. Lett.<\/em>\uff0cInorg. Chem.<\/em>\uff0cChem. Eur. J.<\/em>\uff0cPhys. Chem. Chem. Phys.<\/em>\u7b49\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a<\/strong>https:\/\/doi.org\/10.1002\/smll.202301818<\/p>\n

\u672c\u6587\u7531<\/strong>charfreen, Zhixin Ren<\/strong>\u64b0\u7a3f<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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