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(A)\uff08R\uff0cR\uff09-TEG\u53ef\u4ee5\u805a\u5408\u6210\u9ad8\u5ea6\u5168\u540c\u7acb\u6784\u7684\u7ed3\u6676\u805a\u786b\u916f\u5e76\u5316\u5b66\u518d\u5faa\u73af\u6210\u624b\u6027\u5355\u4f53\u3002(B)\u8d77\u59cb\u7684\uff08R\uff0cR\uff09-TEG\uff08\u9876\u90e8\uff09\u3001\u6765\u81ea\u901a\u8fc7DMAP\u89e3\u805a\u7684D-PTEG\u7684\u518d\u5faa\u73af\u7684\u5916\u6d88\u65cb-TEG\uff08\u4e2d\u4e0a\u90e8\uff09\u3001\u6765\u81ea\u901a\u8fc72c\u89e3\u805a\u7684D-PTEG\u7684\u518d\u5faa\u73af\u7684\uff08R\uff0cR\uff09-TEG\uff08\u4e2d\u4e0b\u90e8\uff09\u548cD-PTEG\uff08\u5e95\u90e8\uff09\u5728CDCl 3\u4e2d\u76841H NMR\u5149\u8c31\u7684\u53e0\u52a0\u3002(C)\u901a\u8fc7DMAP\u89e3\u805a\u6765\u81eaD-PTEG\u7684\u518d\u5faa\u73af\u7684\u5916\u6d88\u65cb-TEG\uff08\u9876\u90e8\uff09\u3001\u901a\u8fc72c\u89e3\u805a\u6765\u81eaD-PTEG\u7684\u518d\u5faa\u73af\u7684\uff08R\uff0cR\uff09-TEG\uff08\u4e2d\u95f4\uff09\u548c\u901a\u8fc72c\u89e3\u805a\u6765\u81eaL-PTEG\u7684\u518d\u5faa\u73af\u7684\uff08S\uff0cS\uff09-TEG\uff08\u5e95\u90e8\uff09\u7684HPLC\u8272\u8c31\u56fe\u7684\u91cd\u53e0\u56fe\u3002\u00a92023 Angew<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-251204\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/7-4.png\" alt=\"\" width=\"811\" height=\"567\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/7-4.png 811w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/7-4-300x210.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/7-4-768x537.png 768w\" sizes=\"(max-width: 811px) 100vw, 811px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe7. TEG\u9009\u62e9\u6027ROP\u7684\u91cf\u5b50\u5316\u5b66\u6a21\u62df\u3002\u00a92023 Angew<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-251205\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/8-1.png\" alt=\"\" width=\"819\" height=\"571\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/8-1.png 819w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/8-1-300x209.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/8-1-768x535.png 768w\" sizes=\"(max-width: 819px) 100vw, 819px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe8. (A)\uff08a\uff09\u65e0\u89c4\u7acb\u6784PTEG\uff08Mn=19.9 kg mol<sup>-1<\/sup>\uff09\uff0c\uff08b\uff09D-PTEG\uff08Mn=18.9 kg mol<sup>-1<\/sup>\uff09\uff0c\uff08c\uff09L-PTEG\uff08Mn=17.6 kg mol<sup>-1<\/sup>\uff09\u548c\uff08d\uff09\u4e24\u79cd\u805a\u5408\u7269\u7684\u7acb\u4f53\u7edc\u5408\u6df7\u5408\u7269\u7684DSC\u70ed\u5206\u6790\u56fe\u3002(B)D-PTEG\u3001L-PTEG\u548csc-PTEG\u7684\u7c89\u672bXRD\u56fe\u8c31\u3002(C)\u4f5c\u4e3a\u54d1\u94c3\u5f62\u8bd5\u6837\u7684\u5168\u540c\u7acb\u6784PTEG\u7684\u7167\u7247\u548c\u5168\u540c\u7acb\u6784PTEG\u3002\u00a92023 Angew<\/p>\n<p><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u5728\u672c\u6587\u4e2d\uff0c\u516c\u5f00\u4e86\u4e00\u79cd\u6709\u6548\u7684\u91d1\u5c5e\u50ac\u5316\u4e8c\u786b\u4ee3\u5185\u916f\u7684\u7acb\u4f53\u4fdd\u7559 ROP\uff0c\u4ece\u800c\u4ea7\u751f\u4e86\u6027\u80fd\u4f18\u8d8a\u7684\u7b49\u89c4\u805a\u786b\u916f\u3002\u4e3a\u4e86\u5efa\u7acb\u8fd9\u79cd\u65b9\u6cd5\uff0c\u63d0\u51fa\u4e86\u4e24\u4e2a\u5047\u8bbe\u3002\u53d1\u73b0\u4e86\u6709\u673a\u91d1\u5c5e\u94dd\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u4e8c\u786b\u4ee3\u5185\u916f\u7684\u5316\u5b66\u9009\u62e9\u6027\u805a\u5408\uff0c\u5176\u7279\u5f81\u662f\u6700\u5c0f\u7684\u5dee\u5411\u5f02\u6784\u5316\u3002\u901a\u8fc7\u9002\u5f53\u7684\u914d\u4f53\u8bbe\u8ba1\u548c\u4fee\u9970\uff0c \u94dd\u50ac\u5316\u5242\u80fd\u591f\u751f\u4ea7\u51fa\u9ad8\u5ea6\u7b49\u89c4\u7684\u7acb\u4f53\u7edc\u5408\u805a\u786b\u916f\uff0c\u5e76\u83b7\u5f97\u4e86\u9ad8\u5206\u5b50\u91cf\u805a\u5408\u7269\u3002\u5b9e\u9a8c\u548c\u8ba1\u7b97\u7814\u7a76\u8868\u660e\uff0c\u94dd\u914d\u5408\u7269\u4e0e\u786b\u5316\u7269\u5408\u6210\u7269\u79cd\u5177\u6709\u9002\u5f53\u7684\u7ed3\u5408\u4eb2\u548c\u529b\uff0c\u907f\u514d\u4e86\u50ac\u5316\u5242\u4e2d\u6bd2\u5e76\u6700\u5927\u9650\u5ea6\u5730\u51cf\u5c11\u4e86\u5dee\u5411\u5f02\u6784\u5316\u53cd\u5e94\uff0c\u8fd9\u662f\u4f7f\u7528\u5176\u4ed6\u91d1\u5c5e\u50ac\u5316\u5242\u65e0\u6cd5\u5b9e\u73b0\u7684\u3002\u6240\u83b7\u5f97\u7684\u4e8c\u786b\u4ee3\u5185\u916f\u57fa\u5851\u6599\u662f\u4e00\u79cd\u575a\u97e7\u7684\u534a\u7ed3\u6676\u6750\u6599\uff0c\u5e76\u8868\u73b0\u51fa\u5b8c\u5168\u7684\u53ef\u56de\u6536\u6027\uff0c\u4f7f\u5851\u6599\u53ef\u4ee5\u56de\u6536\u5e76\u518d\u6b21\u4f7f\u7528\u3002\u8fd9\u79cd\u9ad8\u6548\u7684\u94dd\u50ac\u5316\u6280\u672f\u548c\u6700\u7ec8\u4ea7\u54c1\u4f53\u73b0\u4e86\u4ece\u6447\u7bee\u5230\u6447\u7bee\u7684\u5faa\u73af\uff0c\u4e3a\u751f\u4ea7\u6027\u80fd\u4f18\u8d8a\u7684\u53ef\u56de\u6536\u5851\u6599\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u4f1a\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5\uff1a<\/strong>https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/ange.202302898<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u5851\u6599\uff0c\u662f\u65e0\u5904\u4e0d\u5728\u7684\u8010\u7528\u6750\u6599\u3002\u7136\u800c\uff0c\u5851\u6599\u4ea7\u751f\u7684\u5e9f\u7269\u7f3a\u4e4f\u540e\u7eed\u7684\u7ba1\u7406\uff0c\u52a0\u4e4b\u5176\u751f\u4ea7\u901f\u5ea6\u8fc7\u5feb\uff0c\u7531\u6b64\u4ea7\u751f\u7684\u4e0d\u53ef\u964d\u89e3\u7684\u5851\u6599\u5e9f\u7269\u5feb\u901f\u7d2f\u79ef\uff0c\u5bf9\u73af\u5883\u4ea7\u751f\u4e86\u4e25\u91cd\u7684\u8d1f\u9762\u5f71&#8230;<\/p>\n","protected":false},"author":35611,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-251196","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/251196"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/35611"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=251196"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/251196\/revisions"}],"predecessor-version":[{"id":251961,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/251196\/revisions\/251961"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=251196"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=251196"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=251196"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}