{"id":250922,"date":"2023-05-16T06:00:08","date_gmt":"2023-05-15T22:00:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=250922"},"modified":"2023-05-15T09:50:31","modified_gmt":"2023-05-15T01:50:31","slug":"%e5%bc%a0%e6%bc%a9%e7%a0%94%e7%a9%b6%e5%91%98%ef%bc%8c%e5%a7%9c%e9%93%b6%e7%8f%a0%e6%95%99%e6%8e%88-am%ef%bc%9a%e5%88%86%e7%ba%a7%e7%a6%bb%e5%ad%90%e4%bc%a0%e8%be%93%e8%b7%af%e5%be%84%e6%bf%80","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=250922","title":{"rendered":"\u5f20\u6f29\u7814\u7a76\u5458\uff0c\u59dc\u94f6\u73e0\u6559\u6388 AM\uff1a\u5206\u7ea7\u79bb\u5b50\u4f20\u8f93\u8def\u5f84\u6fc0\u53d1MOF\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387"},"content":{"rendered":"
<\/p>\n
\u5168\u6587\u901f\u89c8\uff1a<\/strong><\/p>\n \u8d1f\u8f7d\u7535\u89e3\u6db2\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599(LE-laden MOFs)\u662f\u7528\u4e8e\u91d1\u5c5e\u8d1f\u6781\u7535\u6c60\u7684\u6781\u5177\u524d\u666f\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u3002\u76ee\u524d\u7814\u7a76\u8005\u4eec\u666e\u904d\u8ba4\u4e3a\u8bbe\u8ba1\u8fde\u7eed\u4e14\u81f4\u5bc6\u7684\u8d1f\u8f7d\u7535\u89e3\u6db2\u7684MOF\u5c42\u662f\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u4e3b\u8981\u9014\u5f84\u3002\u7136\u800c\uff0c\u672c\u6587\u5728\u4e00\u79cd\u5bcc\u542b\u95f4\u9699\u5b54\u548c\u88c2\u7eb9\u7684MOF\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u89c2\u5bdf\u5230\u9ad8\u8fbe1.02 mS\u00b7cm-1<\/sup>\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u672c\u6587\u901a\u8fc7\u8c03\u63a7\u5f62\u8c8c\u548c\u51b7\u538b\u5de5\u827a\u5728HKUST-1\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u5236\u5907\u4e86\u542b\u4e0d\u540c\u5b8f\u89c2\u5b54\u548c\u4ecb\u89c2\u5b54\u7684\u5206\u7ea7\u591a\u5b54\u7ed3\u6784\u3002\u5176\u4e2d\uff0c\u5f62\u8c8c\u4e3a\u7acb\u65b9\u516b\u9762\u4f53\u3001\u51b7\u538b\u538b\u529b\u4e3a150MPa\u7684HKUST-1\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28(Li-Cuboct-H)\u8868\u73b0\u51fa\u6700\u9ad8\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387(1.02 mS\u00b7cm-1<\/sup>)\u3002\u6211\u4eec\u53d1\u73b0\u7535\u89e3\u8d28\u4e2d\u7684\u95f4\u9699\u548c\u88c2\u7f1d\u4e0e\u56fa\u6709\u7684MOF\u901a\u9053\u4e00\u8d77\u6784\u5efa\u4e86\u4e00\u7ec4\u4e92\u8fde\u7684\u7535\u89e3\u6db2\u7f51\u7edc\uff0c\u4fc3\u8fdb\u4e86\u9502\u79bb\u5b50\u5728\u590d\u5408\u4f20\u8f93\u8def\u5f84\u4e2d\u7684\u8f6c\u79fb\u3002\u57fa\u4e8eLi-Cuboct-H\u7684Li\/LiFePO4\u7535\u6c60\u57281 C\u4e0b\u7ecf\u8fc7210\u6b21\u5faa\u73af\u540e\u4ecd\u4fdd\u630193%\u7684\u51fa\u8272\u5bb9\u91cf\u3002\u6b64\u5916\uff0c\u8fd0\u7528\u8be5\u8bbe\u8ba1\u539f\u5219\u4e0d\u540c\u7684\u79bb\u5b50\u5bfc\u4f53\u4f53\u7cfb(Na\u3001Mg\u548cAl)\u5747\u53ef\u5b9e\u73b0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387(\u5747\u9ad8\u4e8e10-4<\/sup> S cm-1<\/sup>)\u3002\u8fd9\u9879\u5de5\u4f5c\u5237\u65b0\u4e86\u5bf9MOF\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u79bb\u5b50\u8f93\u8fd0\u673a\u5236\u7684\u7406\u89e3\uff0c\u4e3a\u7a81\u7834MOF\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684\u74f6\u9888\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n \u80cc\u666f\u4ecb\u7ecd\uff1a<\/strong><\/p>\n MOF\u56e0\u5176\u591a\u6837\u7684\u5316\u5b66\u7ec4\u6210\u3001\u6709\u5e8f\u7684\u5b54\u9053\u7ed3\u6784\u548c\u53ef\u8c03\u8282\u7684\u5b54\u9699\u7387\u6210\u4e3a\u65b0\u5174\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\uff08QSE\uff09\u6750\u6599\u3002MOF\u9897\u7c92\u5185\u90e8\u7684\u5b54\u9053\u80fd\u5bb9\u7eb3\u7535\u89e3\u6db2\u6216\u79bb\u5b50\u6db2\u4f53\uff0c\u76f8\u5e94\u7684MOF\u590d\u5408\u6750\u6599\u4e5f\u83b7\u5f97\u4e86\u4f20\u5bfc\u91d1\u5c5e\u79bb\u5b50\u7684\u80fd\u529b\u3002\u76ee\u524d\u7684\u4e3b\u6d41\u89c2\u70b9\u8ba4\u4e3a\u5728MOF\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u4e2dMOF\u5185\u90e8\u7684\u5fae\u5b54\u662f\u79bb\u5b50\u4f20\u8f93\u7684\u4e3b\u8981\u573a\u6240\uff0cMOF\u5b54\u9053\u4e0e\u8d1f\u8f7d\u7684\u7535\u89e3\u6db2\u4e4b\u95f4\u7684\u5c40\u90e8\u7269\u7406\u5316\u5b66\u4f5c\u7528\u4e5f\u4e00\u76f4\u662f\u8fd1\u5e74\u7684\u7814\u7a76\u70ed\u70b9\u3002\u5927\u591a\u6570\u6587\u732e\u8ba4\u4e3aMOF\u9897\u7c92\u4e4b\u95f4\u7684\u95f4\u9699\u548c\u9897\u7c92\u5185\u90e8\u7684\u88c2\u7eb9\u5bf9MOF\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684\u6027\u80fd\u53d1\u6325\u4e0d\u5229\uff0c\u4e5f\u6709\u90e8\u5206\u5b66\u8005\u8ba4\u4e3a\u7535\u89e3\u8d28\u5236\u5907\u7684\u51b7\u538b\u8fc7\u7a0b\u4e2d\u7535\u89e3\u6db2\u4f1a\u6d41\u5165MOF\u9897\u7c92\u4e4b\u95f4\uff0c\u4f46\u8fd9\u90e8\u5206\u7535\u89e3\u6db2\u5bf9\u79bb\u5b50\u7535\u5bfc\u8d21\u732e\u4e0d\u5927\u3002\u7136\u800c\uff0c\u4ece\u53e6\u4e00\u7c7b\u5178\u578b\u7684\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u6750\u6599\u2014\u2014\u51dd\u80f6\u6001\u7535\u89e3\u8d28\u53ef\u4ee5\u53d1\u73b0\uff0c\u8d2f\u7a7f\u6574\u4e2a\u7535\u89e3\u8d28\u7684\u4e09\u7ef4\u5b54\u9053\u7f51\u7edc\u53ef\u663e\u8457\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u5e76\u4e14\uff0c\u5df2\u6709\u7684\u62a5\u9053\u8bc1\u660eMOF\u9897\u7c92\u5185\u90e8\u7684\u5206\u7ea7\u5b54\u9053\u7ed3\u6784\u80fd\u6709\u6548\u4fc3\u8fdb\u4f20\u8d28\u3002\u57fa\u4e8e\u4ee5\u4e0a\u4fe1\u606f\uff0c\u672c\u6587\u8ba4\u4e3aMOF\u57fa\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u7684\u95f4\u9699\u548c\u88c2\u7eb9\u53ef\u80fd\u5bf9\u79bb\u5b50\u4f20\u5bfc\u6709\u5173\u952e\u4f5c\u7528\u3002<\/p>\n \u672c\u6587\u4eae\u70b9\uff1a<\/strong><\/p>\n \u56fe\u6587\u89e3\u6790\uff1a<\/strong><\/p>\n \u56fe1. \u516b\u9762\u4f53(Oct)\u3001\u7acb\u65b9\u516b\u9762\u4f53(Cuboct)\u548c\u7acb\u65b9\u4f53\u5f62\u8c8c(Cube)\u7684HKUST-1\u7c89\u672b\u7684\uff08a\uff09XRD\u56fe\u50cf\u548c(b)SEM\u56fe\u7247\u3002(c)\u4e0d\u540c\u81f4\u5bc6\u5ea6\u7684\u7acb\u65b9\u9762\u4f53\u5f62\u8c8c\u7684\u539f\u59cbHKUST-1\u538b\u576f\u3002<\/p>\n \u5982\u56fe1(a)\u548c(b)\u6240\u793a\uff0c\u672c\u6587\u901a\u8fc7\u5f15\u5165\u6708\u6842\u9178\u4f5c\u4e3a\u8c03\u8282\u5242\u3001\u7528\u6eb6\u5242\u70ed\u6cd5\u5236\u5907\u4e86\u516b\u9762\u4f53(Oct)\u3001\u7acb\u65b9\u516b\u9762\u4f53(Cuboct)\u548c\u7acb\u65b9\u4f53(Cube)\u5f62\u8c8c\u7684HKUST-1\u7c89\u672b\u3002\u518d\u901a\u8fc7\u7814\u78e8\u5c06\u4e0d\u540c\u5f62\u8c8c\u7684HKUST-1\u7c89\u672b\u4e0e\u7535\u89e3\u6db2Li-LE\uff081M LiClO4<\/sub> in PC\uff09\u8fdb\u884c\u590d\u5408\u3002\u4e4b\u540e\uff0c\u91c7\u752837.5 MPa\u3001150 MPa\u6216300MPa\u7684\u51b7\u538b\u538b\u529b\u5236\u5907\u51fa\u677e\u6563\u72b6\u6001\uff08L\uff09\u3001\u5206\u7ea7\u591a\u5b54\u72b6\u6001\uff08H\uff09\u548c\u81f4\u5bc6\u72b6\u6001\uff08D\uff09\u7684\u590d\u5408\u7535\u89e3\u8d28\u7247\u3002\u56fe1(c\uff09\u53ef\u770b\u51fa\u539f\u59cbHKUST-1\u538b\u576f\u968f\u7740\u81f4\u5bc6\u5ea6\u589e\u52a0\uff0c\u95f4\u9699\u6570\u91cf\u51cf\u5c11\u3001\u88c2\u7eb9\u6570\u91cf\u589e\u52a0\u3002<\/p>\n <\/p>\n \u56fe2. (a) Cube-H, (b) Cuboct-H, (c) Oct-H, (d) Li-Cube-H, (e)Li-Cuboct-H\u548c(f) Li-Oct-H\u538b\u576f\u7684\u5b54\u9053\u7ed3\u6784\u5206\u5e03\u3002\u4e0d\u540c\u5f62\u8c8c\u3001\u81f4\u5bc6\u72b6\u6001\u7684(g)\u539f\u59cbHKUST-1\u538b\u576f\u548c(h)\u590d\u5408HKUST-1\u7247\u7684\u5b54\u5bb9\uff1a\u5176\u4e2d\u84dd\u8272\u6761\u5f62\u4ee3\u8868\u95f4\u9699\u5b54\u5bb9\uff0c\u7eff\u8272\u6761\u5f62\u4ee3\u8868\u88c2\u7eb9\u5b54\u5bb9\u3002<\/p>\n \u5229\u7528\u538b\u6c5e\u6cd5\u5206\u6790\u4e86\u4e0d\u540c\u5f62\u8c8c\u548c\u81f4\u5bc6\u72b6\u6001\u7684\u539f\u59cbHKUST-1\u538b\u576f\u3001\u590d\u5408HKUST-1\u538b\u576f\u7684\u5b54\u9053\u7ed3\u6784\u3002\u4ece\u56fe2(a)-(c)\u53ef\u770b\u51fa\uff0c\u539f\u59cbHKUST-1\u538b\u576f\u5b58\u5728\u4e24\u79cd\u7279\u5f81\u5b54\uff1a\u5927\u5b54\uff081 \u03bcm-100 nm\uff09\u548c\u4ecb\u5b54\uff0850 nm-5 nm\uff09\u3002\u7ed3\u5408SEM\u7167\u7247\uff0c\u53ef\u5f97\u77e5\u5927\u5b54\u5f52\u5c5e\u4e8e\u95f4\u9699\uff0c\u4ecb\u5b54\u5f52\u5c5e\u4e8e\u88c2\u7eb9\u3002\u56fe2(g)\u8868\u660e\uff0c\u968f\u7740\u81f4\u5bc6\u5ea6\u589e\u52a0\uff0c\u4e09\u79cd\u5f62\u8c8c\u7684\u539f\u59cbHKUST-1\u538b\u576f\u7684\u6574\u4f53\u5b54\u5bb9\uff08\u95f4\u9699+\u88c2\u7eb9\uff09\u4e0b\u964d\uff0c\u4f46\u662f\u88c2\u7eb9\u7684\u5360\u6bd4\u660e\u663e\u589e\u52a0\uff0c\u4e0eSEM\u7684\u7ed3\u679c\u4e00\u81f4\u3002\u7ed3\u5408\u56fe2\uff08h\uff09\u53ef\u77e5\uff0c\u5206\u7ea7\u5b54\u9053\u7ed3\u6784\u72b6\u6001\u4e0b\u590d\u5408HKUST-1\u538b\u576f\u7684\u5b54\u5bb9\u76f8\u6bd4\u4e8e\u539f\u59cbHKUST-1\u538b\u576f\u660e\u663e\u4e0b\u964d\uff0c\u8bf4\u660e\u7535\u89e3\u6db2\u7684\u786e\u53ef\u4ee5\u586b\u5145\u81f3\u590d\u5408MOF\u9897\u7c92\u7684\u95f4\u9699\u548c\u88c2\u7eb9\u4e2d\u3002\u5176\u4e2d\uff0cLi-Cuboct-H\u7684\u5b54\u5bb9\u4e0b\u964d\u6700\u660e\u663e\uff0c\u8bf4\u660e\u7535\u89e3\u6db2\u5728\u8be5\u538b\u576f\u4e2d\u5927\u5b54\uff08\u95f4\u9699\uff09\u548c\u4ecb\u5b54\uff08\u88c2\u7eb9\uff09\u4e2d\u7684\u586b\u5145\u6700\u5145\u5206\u3002<\/p>\n \u56fe3. (a) Li-Cuboct-H \u7684Raman\u5149\u8c31\uff1b\uff08b\uff09\u8d1f\u8f7dLi-LE\u7684HKUST-1\u548cLi-LE(1M LiClO4 in PC)\u5728293 K\u76847<\/sup>Li MAS NMR\u8c31\uff1b(c)\u8d1f\u8f7dLi-LE\u7684HKUST-1\u7c89\u672b\u4e0d\u540c\u6e29\u5ea6\u4e0b\u76847Li\u534a\u9ad8\u5bbd\uff1b(d)\u8d1f\u8f7dLi-LE\u7684HKUST-1\u548cLi-LE\u7684\u9502\u81ea\u6269\u6563\u7cfb\u6570\u7684Arrhenius\u56fe\u3002<\/p>\n \u5229\u7528\u62c9\u66fc\u5149\u8c31\u548c\u56fa\u60017<\/sup>Li MAS NMR\u7814\u7a76\u4e86\u7535\u89e3\u6db2\u5728HKUST-1\u901a\u9053\u5185\u7684\u5316\u5b66\u73af\u5883\u4ee5\u53caLi\u79bb\u5b50\u5728HKUST-1\u5fae\u5b54\u4e2d\u7684\u4f20\u8f93\u52a8\u529b\u5b66\u3002\u62c9\u66fc\u5149\u8c31\u663e\u793aLi-Cuboct-H\u4e2d\u5b58\u5728\u5f88\u5f3a\u7684PC-Li+<\/sup>\u76f8\u4e92\u4f5c\u7528\u548c\u5927\u91cf\u7684Li+<\/sup>-PC-ClO4<\/sub>–<\/sup>\u7ed3\u6784\uff0c\u4e0e\u9ad8\u6d53\u7535\u89e3\u6db2(3M LiClO4<\/sub> in PC)\u76f8\u4f3c\uff0c\u8bf4\u660eMOF\u5fae\u5b54\u7684\u9650\u57df\u4f5c\u7528\u4f7fLi-LE\u5448\u73b0\u51fa\u66f4\u9ad8\u6d53\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u30027<\/sup>Li MAS NMR\u7ed3\u679c\u8868\u660eHKUST-1\u5fae\u5b54\u4e2d\u7684Li-LE\u76f8\u5bf9\u4f53\u76f8\u6709\u660e\u663e\u7684\u5316\u5b66\u4f4d\u79fb\uff0c\u4e5f\u8bc1\u660e\u4e86HKUST-1\u5fae\u5b54\u7684\u9650\u57df\u4f5c\u7528\u3002\u8d1f\u8f7dLi-LE\u7684HKUST-1\u968f\u6e29\u5ea6\u5347\u9ad8\u76847<\/sup>Li\u7ebf\u5bbd\u53d8\u5316\u66f4\u5c0f\u8bf4\u660eHKUST-1\u5fae\u5b54\u7684\u9650\u5236\u4f7f\u9502\u79bb\u5b50\u7684\u6269\u6563\u5448\u5404\u5411\u5f02\u6027\u3002\u540c\u65f6\uff0c\u4e8c\u8005\u7684\u9502\u6269\u6563\u6d3b\u5316\u80fd\u63a5\u8fd1\u8bf4\u660e\u5728HKUST-1\u5fae\u5b54\u4e2d\u548cLi-LE\u4f53\u76f8\u4e2d\u9502\u79bb\u5b50\u7684\u6269\u6563\u673a\u5236\u76f8\u4f3c\u3002<\/p>\n <\/p>\n \u56fe4. (a)-(d) \u4e0d\u540c\u81f4\u5bc6\u72b6\u6001\u3001\u4e0d\u540c\u6676\u7c92\u5f62\u8c8c\u7684HKUST-1\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387. (e)-(f) M-Cuboct-H (M=Li, Na, Mg, Al)\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002(g) \u4e0d\u540c\u81f4\u5bc6\u72b6\u6001\u4e0bHKUST-1\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u4f20\u8f93\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n \u7531\u56fe4\u53ef\u77e5\uff0cCube\uff0cCuboct\u548cOct\u5f62\u8c8c\u7684HKUST-1\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u968f\u7740\u81f4\u5bc6\u5ea6\u7684\u63d0\u5347\uff0c\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u5747\u5448\u73b0\u51fa\u5148\u5347\u540e\u964d\u7684\u8d8b\u52bf\u3002\u677e\u6563\u72b6\u6001\u4e0bLi-LE\u65e0\u6cd5\u586b\u6ee1\u7684\u95f4\u9699\uff0c\u800c\u81f4\u5bc6\u72b6\u6001\u4e0bLi-LE\u53ef\u586b\u5145\u7684\u95f4\u9699\u5b54\u548c\u88c2\u7eb9\u6570\u91cf\u51cf\u5c11\uff0c\u90fd\u4f1a\u5bfc\u81f4\u6574\u4e2a\u7535\u89e3\u8d28\u4e2dLi-LE\u7f51\u7edc\u4e0d\u8fde\u7eed\u4ece\u800c\u963b\u788dLi+<\/sup>\u4f20\u8f93\u3002\u800c\u5728\u5206\u7ea7\u591a\u5b54\u72b6\u6001\u4e0b\uff0c\u95f4\u9699\u3001\u88c2\u7f1d\u548c\u56fa\u6709MOF\u901a\u9053\u4e2d\u5f62\u6210\u4e86\u4e00\u7ec4\u76f8\u4e92\u8fde\u901a\u7684Li-LE\u7f51\u7edc\uff0c\u4fc3\u8fdbLi+<\/sup>\u4ee5\u5206\u7ea7\u8def\u5f84\u8fc1\u79fb\u3002\u5176\u4e2d\uff0cLi-Cuboct-H\u5448\u73b0\u51faLi-LE\u586b\u5145\u6700\u5145\u5206\u7684\u5206\u7ea7\u5b54\u9699\uff0c\u8868\u73b0\u51fa\u6700\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff081.02 mS cm-1<\/sup>\uff09\u3002\u5206\u7ea7\u79bb\u5b50\u4f20\u8f93\u8def\u5f84\u5728\u5176\u4ed6\u79bb\u5b50\u5bfc\u4f53\u4f53\u7cfb\u4e5f\u6210\u529f\u5e94\u7528\uff0cM-Cuboct-H (M=Li, Na, Mg, Al)\u5747\u8868\u73b0\u51fa\u9ad8\u4e8e10-4<\/sup> Scm-1<\/sup>\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002<\/p>\n \u56fe5. Li-Cuboct-H\u5728\u9502\u91d1\u5c5e\u7535\u6c60\u4e2d\u7684(a)\u7535\u5316\u5b66\u7a97\u53e3\uff1b(b)\u79bb\u5b50\u8fc1\u79fb\u6570\uff1b(c)\u5bf9\u79f0\u7535\u6c60\u500d\u7387\u6027\u80fd\uff1b (d) \u5bf9\u79f0\u7535\u6c60\u5faa\u73af\u6027\u80fd\uff1b(e) Li\/LFP\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u548c(f) Li\/LFP\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n \u5bf9Li-Cuboct-H\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u8fdb\u884c\u4e86\u4e00\u7cfb\u5217\u7535\u5316\u5b66\u6d4b\u8bd5\u3002\u5176\u7535\u538b\u7a97\u53e3\u9ad8\u8fbe5 V (vs. Li\/Li+<\/sup>)\uff1b\u79bb\u5b50\u8fc1\u79fb\u6570\u4e3a0.56 (Li-LE\u4e3a0.22)\uff1b\u6240\u7ec4\u88c5\u7684\u9502\u91d1\u5c5e\u7535\u6c60\u57280.1\u52300.4 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8868\u73b0\u51fa78 mV, 89 mV, 187 mV\u548c230 mV\u7684\u8fc7\u7535\u4f4d\uff0c\u57280.2 mA cm-2<\/sup>\uff0c0.2 mA h cm-2<\/sup>\u7684\u6761\u4ef6\u4e0b\u53ef\u7a33\u5b9a\u5faa\u73af800h\u4ee5\u4e0a\u3002\u4ee5LiFePO4 <\/sub>(LFP)\u4e3a\u6b63\u6781\u6750\u6599\u7ec4\u88c5Li\/LFP\u534a\u7535\u6c60\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u51fa\u8272\u7684\u5faa\u73af\u6027\u80fd\uff1a2C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u4ecd\u670997 mA h g-1<\/sup>\uff0c\u57281C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af210\u5708\u4ecd\u670993%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002<\/p>\n \u603b\u7ed3\u4e0e\u5c55\u671b\uff1a<\/strong><\/p>\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u63a2\u8ba8\u4e86\u8d1f\u8f7dLi-LE\u7684HKUST-1\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u5728\u4e0d\u540c\u5b8f\u89c2\u548c\u4ecb\u89c2\u5b54\u9699\u7ed3\u6784\u4e0b\u7684\u9502\u79bb\u5b50\u4f20\u8f93\u884c\u4e3a\u3002\u6211\u4eec\u89c2\u5bdf\u5230\u4e00\u4e2a\u5947\u7279\u73b0\u8c61\uff1a\u95f4\u9699\u548c\u88c2\u7f1d\u5bf9MOF\u57fa\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u4e2dLi+<\/sup>\u7684\u4f20\u8f93\u8d77\u7740\u91cd\u8981\u4f5c\u7528\uff0c\u5b83\u4eec\u53ef\u4f5c\u4e3a\u7535\u89e3\u6db2\u50a8\u5e93\uff0c\u4e0eMOF\u5185\u90e8\u901a\u9053\u4e00\u8d77\u63d0\u4f9b\u5206\u7ea7\u79bb\u5b50\u8f93\u8fd0\u8def\u5f84\u3002\u5177\u5907\u6700\u4f73\u5206\u7ea7\u5b54\u9699\u7ed3\u6784\u7684Li-Cuboct-H\u7535\u89e3\u8d28\u53ef\u4ee5\u5f62\u6210\u9ad8\u5ea6\u8fde\u901a\u7684Li-LE\u5b58\u50a8\u7f51\u7edc\uff0c\u5b9e\u73b0\u4e861.02 mS cm-1\u7684\u4f18\u5f02\u79bb\u5b50\u7535\u5bfc\u7387\u30010.55\u7684\u9ad8\u8fc1\u79fb\u6570\u548c\u5bbd\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3(5 V vs. Li\/Li+<\/sup>)\u3002\u91c7\u7528Li-Cuboct-H\u51c6\u56fa\u6001\u7535\u89e3\u8d28\u7ec4\u88c5\u7684\u9502\u5bf9\u79f0\u7535\u6c60\u5177\u6709\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027(\u57280.2 mA cm-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7a33\u5b9a\u5faa\u73af800\u5c0f\u65f6\u4ee5\u4e0a)\u3002\u57fa\u4e8eLi-Cuboct-H\u7684Li\/LFP\u7535\u6c60\u57281C\u5faa\u73af210\u6b21\u540e\u8868\u73b0\u51fa93%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u6b64\u5916\uff0c\u5728\u62d3\u7684\u5c55\u79bb\u5b50\u5bfc\u4f53\u4f53\u7cfb\u4e2d\uff0cM-Cuboct-H (M=Na, Mg\u548cAl)\u4e5f\u90fd\u5448\u73b0\u51fa>10-4<\/sup> S cm-1<\/sup>\u7684\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3002<\/p>\n \u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n Extraordinary Ionic Conductivity Excited by Hierarchical Ion Transport Pathways in MOF-based Quasi-solid Electrolytes. Advanced Materials, 2023.<\/p>\n DOI: 10.1002\/adma.202300888<\/p>\n <\/p>\n \u4f5c\u8005\u4ecb\u7ecd\uff1a<\/strong><\/p>\n \u5218\u6167\u73b2\uff0c<\/strong>\u6d59\u6c5f\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\uff0c2019\u7ea7\u76f4\u535a\u751f\u3002\u7814\u7a76\u65b9\u5411\u4e3aMOF \u57fa\u51c6\u56fa\u6001\/\u56fa\u6001\u7535\u89e3\u8d28\u7684\u5236\u5907\u53ca\u5176\u5728\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n \u59dc\u94f6\u73e0<\/strong>\uff0c\u6d59\u6c5f\u5927\u5b66\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c1998\u5e74\u83b7\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6750\u6599\u5316\u5b66\u4e0e\u8ba1\u7b97\u673a\u5e94\u7528\u53cc\u5b66\u58eb\u5b66\u4f4d\uff0c2007\u5e74\u83b7\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u535a\u58eb\u5b66\u4f4d\uff0c2007\u5e74\u5728\u4e9a\u7533\u79d1\u6280\u7814\u53d1\u4e2d\u5fc3\uff08\u4e0a\u6d77\uff09\u6709\u9650\u516c\u53f8\u4efb\u804c\u9879\u76ee\u7ecf\u7406\u30012007-2008\u5e74\u5728\u82f1\u56fdHeriot-Watt\u5927\u5b66\u4efb\u804c\u535a\u58eb\u540e\u30012008-2010\u5e74\u83b7\u5fb7\u56fd\u6d2a\u5821\u5b66\u8005\u57fa\u91d1\u4f1a\u8d44\u52a9\u5728\u5fb7\u56fdBielefeld\u5927\u5b66\u4ece\u4e8b\u7814\u7a76\u5de5\u4f5c\u30022010\u5e74\u8d77\u52a0\u5165\u6d59\u6c5f\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u4efb\u804c\u526f\u6559\u6388\uff0c2017\u5e74\u664b\u5347\u6559\u6388\u3002\u957f\u671f\u4ece\u4e8b\u7535\u5316\u5b66\u50a8\u80fd\u6750\u6599\u4e0e\u5668\u4ef6\u9886\u57df\u7684\u7814\u53d1\u5de5\u4f5c\uff0c\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u5305\u62ec\u5148\u8fdb\u9502\u79bb\u5b50\u7535\u6c60\u3001\u94a0\u79bb\u5b50\u7535\u6c60\u3001\u56fa\u6001\u7535\u6c60\u3001\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u3001\u7535\u6c60\u68c0\u6d4b\u4e0e\u5931\u6548\u5206\u6790\u7b49\u3002\u4f5c\u4e3a\u9879\u76ee\u8d1f\u8d23\u4eba\u627f\u62c5\u4e86\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u653f\u5e9c\u95f4\u5408\u4f5c\u9879\u76ee\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u4f18\u79c0\u9752\u5e74\u9879\u76ee\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\/\u9752\u5e74\u9879\u76ee\u3001\u6d59\u6c5f\u7701\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u6770\u51fa\u9752\u5e74\u9879\u76ee\u7b49\u7eb5\u5411\u9879\u76ee10\u4f59\u9879\u4ee5\u53ca\u56fd\u5bb6\u7535\u7f51\u5168\u7403\u80fd\u6e90\u4e92\u8054\u7f51\u7814\u7a76\u9662\u3001\u6d59\u6c5f\u534e\u4e91\u4fe1\u606f\u79d1\u6280\u6709\u9650\u516c\u53f8\u7b49\u6a2a\u5411\u59d4\u6258\u5f00\u53d1\u9879\u76ee\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u5728Adv. Mater.\u3001Energy Environ. Sci.\u3001Adv. Funct. Mater.\u3001Nano Energy\u3001Sci. Bull.\u7b49\u56fd\u9645\u77e5\u540d\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u6587100\u4f59\u7bc7\uff0c\u4ed6\u5f154000\u4f59\u6b21\uff1b\u6388\u6743\u56fd\u5bb6\u53d1\u660e\u4e13\u522920\u4f59\u9879\uff0c\u7533\u8bf7PCT\u56fd\u9645\u4e13\u52291\u9879\uff1b\u83b72014\u5e74\u6d59\u6c5f\u7701\u6280\u672f\u53d1\u660e\u4e00\u7b49\u5956\uff08R3\uff09\u3002<\/p>\n \u5f20\u6f29<\/strong>\u4e8e\u8377\u8bed\u9c81\u6c76\u5927\u5b66(KU Leuven)\u6750\u6599\u5de5\u7a0b\u7cfb\u83b7\u5f97\u535a\u58eb\u5b66\u4f4d\u3002\u73b0\u5728\u6d59\u6c5f\u5927\u5b66\u676d\u5dde\u56fd\u9645\u79d1\u521b\u4e2d\u5fc3\u4efb\u804c\u7814\u7a76\u5458\uff0c\u517c\u8058\u4e8e\u6d59\u6c5f\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u3002\u8fd1\u5e74\u6765\u5f20\u6f29\u7814\u7a76\u5458\u957f\u671f\u575a\u6301\u81f4\u529b\u4e8e\u4ece\u4e8b\u7535\u6c89\u79ef\u76f8\u5173\u7814\u7a76\uff0c\u5e76\u4ee5\u6b64\u4e3a\u57fa\u7840\u6d89\u53ca\u7535\u50ac\u5316\u3001\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u3001\u7eb3\u6ee4\u819c\u3001\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u5316\u5408\u7269\uff08MOFs\uff09\u8584\u819c\u548c\u7eb3\u7c73\u6750\u6599\u5408\u6210\u7b49\u65b9\u9762\u7684\u7814\u7a76\u5de5\u4f5c\u3002\u76ee\u524d\u4e3a\u6b62\uff0c\u4ee5\u7b2c\u4e00\u4f5c\u8005\u6216\u901a\u8baf\u4f5c\u8005\u8eab\u4efd\u5728Matter, Adv. Mater., Angew. Chem. Int. Ed, Adv. Funct. Mater., Adv. Sci.\uff0cNano energy \u548c Energy Storage Mater.\u7b49\u8457\u540d\u56fd\u9645\u671f\u520a\u53d1\u8868\u8bba\u658725\u7bc7\uff0c\u591a\u7bc7\u5f53\u9009\u4e3a\u201cESI\u9ad8\u88ab\u5f15\u8bba\u6587\u201d\u3002\u603b\u5171\u53d1\u8868\u5171\u540c\u4f5c\u8005SCI\u8bba\u658750\u4f59\u7bc7\u3002\u4e3b\u6301\u76f8\u5173\u9879\u76ee5\u9879\u3002<\/p>\n \u8bfe\u9898\u7ec4\u5b66\u672f\u6c1b\u56f4\u6d53\u539a,\u5e08\u751f\u5173\u7cfb\u878d\u6d3d,\u8bfe\u9898\u7ec4\u7ecf\u8d39\u5145\u8db3\u3001\u4eea\u5668\u8bbe\u5907\u9f50\u5168, \u5b9e\u9a8c\u5ba4\u73af\u5883\u4f18\u826f\uff0c\u73b0\u6709\u535a\u58eb\u540e\uff0c\u79d1\u7814\u52a9\u7406\uff0c\u52a9\u7406\u7814\u7a76\u5458\u7b49\u591a\u4e2a\u5c97\u4f4d\u7a7a\u7f3a<\/strong>\uff0c\u6b22\u8fce\u611f\u5174\u8da3\u7684\u540c\u5b66\u52a0\u5165\uff08\u91cd\u70b9\u62db\u6536\u65b9\u5411\uff1a<\/strong>MOFs, <\/strong>\u7535\u6c89\u79ef<\/strong>, <\/strong>\u7535\u5316\u5b66\u5408\u6210\u548c\u7535\u6c60\u9694\u819c\u7b49\u76f8\u5173\u65b9\u5411<\/strong>\uff09\u3002\u90ae\u7bb1\uff1axuanzhangzju@zju.edu.cn<\/a>\u3002<\/p>\n <\/p>\n \u8bba\u6587\u76f8\u5173\u4fe1\u606f<\/strong>\uff1a<\/p>\n \u7b2c\u4e00\u4f5c\u8005\uff1a\u5218\u6167\u73b2 \u535a\u58eb<\/p>\n \u901a\u8baf\u4f5c\u8005\uff1a\u5f20\u6f29 \u7814\u7a76\u5458\uff0c \u59dc\u94f6\u73e0 \u6559\u6388\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/p>\n \u901a\u8baf\u5355\u4f4d\uff1a\u6d59\u6c5f\u5927\u5b66\uff0c\u6d59\u6c5f\u5927\u5b66\u676d\u5dde\u56fd\u9645\u79d1\u521b\u4e2d\u5fc3<\/p>\n \u8bba\u6587DOI\uff1a10.1002\/adma.202300888<\/p>\n<\/p>\n
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