{"id":250775,"date":"2023-05-14T06:16:23","date_gmt":"2023-05-13T22:16:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=250775"},"modified":"2023-05-11T15:24:52","modified_gmt":"2023-05-11T07:24:52","slug":"%e4%b8%93%e9%a2%98-co2rr%e6%9c%80%e6%96%b0%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=250775","title":{"rendered":"\u4e13\u9898: \u00a0CO2RR\u6700\u65b0\u8fdb\u5c55"},"content":{"rendered":"

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\u00a0<\/strong>2020\u5e749\u6708\u4e2d\u56fd\u660e\u786e\u63d0\u51fa2030\u5e74\u201c\u78b3\u8fbe\u5cf0\u201d\u4e0e2060\u5e74\u201c\u78b3\u4e2d\u548c\u201d\u76ee\u6807\uff0c\u7b80\u79f0\u4e3a\u201c\u53cc\u78b3\u201d\u3002\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94\uff08CO2<\/sub>RR\uff09\u5177\u6709\u4fc3\u8fdb\u78b3\u4e2d\u548c\u7684\u5de8\u5927\u6f5c\u529b\u3002CO2<\/sub>RR\u53ef\u4ee5\u5c06\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e3a\u9ad8\u9644\u52a0\u503c\u7684\u5316\u5b66\u54c1\u548c\u71c3\u6599\uff0c\u4f8b\u5982\u5229\u7528CO2<\/sub>\u7684\u8fd8\u539f\u751f\u4ea7\u4e00\u6c27\u5316\u78b3\uff08CO\uff09\uff0c\u7532\u70f7\uff08CH4<\/sub>\uff09\uff0c\u4e59\u70ef\uff08C2<\/sub>H4<\/sub>\uff09\uff0c\u7532\u9178\u76d0\uff08HCOO\u2013<\/sup>\uff09\uff0c\u4e59\u9187\uff08C2<\/sub>H5<\/sub>OH\uff09\u548c\u4e19\u9187\uff08C3<\/sub>H7<\/sub>OH\uff09\u7b49\u7b49\uff0c\u56e0\u6b64\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u30022\u67088\u65e5\uff0cNature\u62a5\u9053\u4e86\u52a8\u6001\u73b0\u573a\u539f\u4f4d\u63ed\u793a\u94dc\u7eb3\u7c73\u9897\u7c92\u7684CO2<\/sub>RR\u8fc7\u7a0b\uff0c\u56e0\u6b64\u672c\u4e13\u9898\u6c47\u96c6\u4e86CO2<\/sub>RR\u57282023\u5e74\u7684\u4e00\u4e9b\u6700\u65b0\u7814\u7a76\u6210\u679c\u3002<\/p>\n

 <\/p>\n

1.\u00a0<\/b>\u590d\u65e6\u5927\u5b66\u5f90\u6615Nat. Commun.\uff1a\u7cbe\u786e\u8ba1\u7b97\u5438\u9644\u5206\u5b50-\u91d1\u5c5e\u8868\u9762\u7684\u76f8\u4e92\u4f5c\u7528\u53ca\u5176\u5728\u94dc\u8868\u9762CO2RR\u4e2d\u7684\u5e94\u7528<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

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\u539f\u6587\u8be6\u60c5\uff1a\u590d\u65e6\u5927\u5b66\u5f90\u6615Nat. Commun.\uff1a\u7cbe\u786e\u8ba1\u7b97\u5438\u9644\u5206\u5b50-\u91d1\u5c5e\u8868\u9762\u7684\u76f8\u4e92\u4f5c\u7528\u53ca\u5176\u5728\u94dc\u8868\u9762CO2RR\u4e2d\u7684\u5e94\u7528<\/a><\/p>\n

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2.\u00a0<\/b>\u54c8\u5de5\u5927\u8054\u5408\u9ed1\u9f99\u6c5f\u5927\u5b66\uff1aPd3Au\u50ac\u5316\u5242\u4e0aCO2\u8fd8\u539f\u751f\u6210\u7532\u9178\u7684\u663e\u5f0f\u6eb6\u5242\u6a21\u578b\u7406\u8bba\u7814\u7a76<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u5468\u6b23\u8bfe\u9898\u7ec4\u548c\u9ed1\u9f99\u6c5f\u5927\u5b66\u674e\u660e\u971e\u8bfe\u9898\u7ec4\u91c7\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7814\u7a76\u4e86Pd3<\/sub>Au\u5408\u91d1\u4e0d\u540c\u8868\u9762\u4e0aCO2<\/sub>\u8fd8\u539f\u4e3a\u7532\u9178\u7684\u673a\u5236\uff0c\u5e76\u63ed\u793a\u4e86\u50ac\u5316\u5242\u529f\u51fd\u6570\u548cd-\u5e26\u4e2d\u5fc3\u5dee\u5f02\u4e0e\u8fc7\u7535\u4f4d\u4e4b\u95f4\u7684\u6f5c\u5728\u5173\u7cfb\u3002\u7535\u5b50\u7ed3\u6784\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u50ac\u5316\u5242\u7684\u8868\u9762\u7c97\u7cd9\u5ea6\u548c\u7535\u5b50\u7ed3\u6784\u5171\u540c\u51b3\u5b9a\u4e86CO2<\/sub>\u8fd8\u539f\u4e3a\u7532\u9178\u7684\u50ac\u5316\u6d3b\u6027\u3002\u540c\u65f6\uff0c\u53d1\u73b0\u50ac\u5316\u5242\u8868\u9762\u51c0\u7535\u8377\u4e0eHER\u6d3b\u6027\u4e4b\u95f4\u5b58\u5728\u826f\u597d\u7684\u7ebf\u6027\u5173\u7cfb\u3002\u5177\u6709\u8f83\u4f4e\u8868\u9762\u51c0\u7535\u8377\u7684Pd3<\/sub>Au\uff08110\uff09\u8868\u9762\u53ef\u4ee5\u6709\u6548\u6291\u5236HER\u3002\u6c34\u6eb6\u6db2\u4e2d\u52a8\u6001\u6c22\u952e\u7f51\u7edc\u662f\u51b3\u5b9a\u53cd\u5e94\u673a\u5236\u7684\u5173\u952e\uff0c\u53cd\u6620\u4e86\u6c34\u5206\u5b50\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u4f5c\u7528\uff0c\u8868\u660e\u5728\u8ba1\u7b97\u53cd\u5e94\u673a\u5236\u65f6\u4f7f\u7528\u663e\u5f0f\u6eb6\u5242\u6a21\u578b\u6a21\u62df\u6eb6\u5242\u5316\u6548\u5e94\u7684\u91cd\u8981\u6027\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cTheoretical study on the reduction mechanism of CO2<\/sub>\u00a0to HCOOH on Pd3Au: an explicit solvent model is essential\u201d\u53d1\u8868\u5728Journal of Materials Chemistry A<\/i><\/em>\u4e0a\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a\u54c8\u5de5\u5927\u8054\u5408\u9ed1\u9f99\u6c5f\u5927\u5b66\uff1aPd3Au\u50ac\u5316\u5242\u4e0aCO2\u8fd8\u539f\u751f\u6210\u7532\u9178\u7684\u663e\u5f0f\u6eb6\u5242\u6a21\u578b\u7406\u8bba\u7814\u7a76<\/a><\/p>\n

 <\/p>\n

3.\u00a0<\/b>\u798f\u5efa\u7269\u6784\u6240\u66f9\u8363\u56e2\u961fNano Research\uff1a\u4f4eAu\u542b\u91cf\u63ba\u91d1\u94dc\u7eb3\u7c73\u7ebf\u5bf9\u7535\u50ac\u5316CO2\u8fd8\u539f\u4e3a\u591a\u78b3\u4ea7\u7269\u7684\u534f\u540c\u6548\u5e94<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

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\u539f\u6587\u8be6\u60c5\uff1a\u798f\u5efa\u7269\u6784\u6240\u66f9\u8363\u56e2\u961fNano Research\uff1a\u4f4eAu\u542b\u91cf\u63ba\u91d1\u94dc\u7eb3\u7c73\u7ebf\u5bf9\u7535\u50ac\u5316CO2\u8fd8\u539f\u4e3a\u591a\u78b3\u4ea7\u7269\u7684\u534f\u540c\u6548\u5e94<\/a><\/b><\/strong><\/h1>\n

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4.\u00a0<\/b>Nano Today\uff1a \u4e59\u4e8c\u80fa\u884d\u751f\u7269\u4ecb\u5bfc\u9ad8\u6d53\u5ea6C\u3001N\u3001O\u5171\u63ba\u6742Zn\u3001S\u5171\u7f3a\u9677ZnS\u9897\u7c92\u7684\u8bbe\u8ba1\u548c\u9009\u62e9\u6027\u5149\u50ac\u5316\u6d3b\u6027<\/b><\/strong><\/h1>\n

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\u539f\u6587\u8be6\u60c5\uff1aNano Today\uff1a \u4e59\u4e8c\u80fa\u884d\u751f\u7269\u4ecb\u5bfc\u9ad8\u6d53\u5ea6C\u3001N\u3001O\u5171\u63ba\u6742Zn\u3001S\u5171\u7f3a\u9677ZnS\u9897\u7c92\u7684\u8bbe\u8ba1\u548c\u9009\u62e9\u6027\u5149\u50ac\u5316\u6d3b\u6027<\/a><\/p>\n

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5.\u00a0<\/b>\u97e9\u5e03\u5174\u9662\u58eb&\u6731\u5e86\u5bab\u7814\u7a76\u5458JACS\uff1ap\u533a\u91d1\u5c5e\u63ba\u6742Cu\u8bf1\u5bfcp-d\u6742\u5316\u4fc3\u8fdbCO2\u7535\u8fd8\u539f\u5236\u5907\u591a\u78b3\u4ea7\u7269<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u4e2d\u79d1\u9662\u5316\u5b66\u7814\u7a76\u6240\u97e9\u5e03\u5174\u9662\u58eb\u548c\u6731\u5e86\u5bab\u7814\u7a76\u5458\u56e2\u961f<\/strong>\u901a\u8fc7\u7b80\u5355\u7684\u4e24\u6b65\u6cd5\u6784\u5efa\u4e86\u5177\u6709p-d\u8f68\u9053\u6742\u5316\u7279\u5f81\u7684p\u533a\u91d1\u5c5eGa\u63ba\u6742Cu\uff08CuGa\uff09\u50ac\u5316\u5242\uff0c\u8be5\u50ac\u5316\u5242\u53ef\u4ee5\u5728\u5b89\u57f9\u7ea7\u7535\u6d41\u5bc6\u5ea6\u4e0b\u4fc3\u8fdbCO2<\/sub>\u9ad8\u6548\u7535\u50ac\u5316\u751f\u6210C2+<\/sub>\u4ea7\u7269\u3002\u5728-1.07 V\u7684\u7535\u4f4d\u4e0b\uff0c\u7535\u6d41\u5bc6\u5ea6\u53ef\u8fbe\u52300.9 A\/cm2<\/sup>\uff0c\u5e76\u4e14C2+<\/sub>\u6cd5\u62c9\u7b2c\u6548\u7387\uff08FE\uff09\u9ad8\u8fbe81.5%\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u7814\u7a76\u8868\u660e\uff0cCuGa\u7684\u4f18\u5f02\u6027\u80fd\u6e90\u81eaCu\u548cGa\u7684p-d\u6742\u5316\u76f8\u4e92\u4f5c\u7528\uff0c\u4e0d\u4ec5\u4e30\u5bcc\u4e86\u53cd\u5e94\u4f4d\u70b9\uff0c\u8fd8\u589e\u5f3a\u4e86*CO\u4e2d\u95f4\u4f53\u7684\u7ed3\u5408\u5f3a\u5ea6\uff0c\u4fc3\u8fdb\u4e86C-C\u5076\u8054\u3002\u8fd9\u79cdp-d\u6742\u5316\u7b56\u7565\u53ef\u4ee5\u6269\u5c55\u5230\u5176\u4ed6p\u533a\u91d1\u5c5e\u63ba\u6742\u7684Cu\u50ac\u5316\u5242\uff0c\u5982CuAl\u548cCuGe\uff0c\u4fc3\u8fdbCO2<\/sub>\u7535\u8fd8\u539f\u4ee5\u4ea7\u751fC2+<\/sub>\u3002\u57280.9 A\/cm2<\/sup>\u4e0bFE\u5206\u522b\u4e3a77.3%\u548c75.5%\u3002\u672c\u5de5\u4f5c\u9996\u6b21\u4f7f\u7528p\u533a\u91d1\u5c5e\u63ba\u6742Cu\u50ac\u5316\u5242\uff0c\u901a\u8fc7p-d\u8f68\u9053\u6742\u5316\u76f8\u4e92\u4f5c\u7528\u4fc3\u8fdb\u7535\u5316\u5b66CO2<\/sub>\u8fd8\u539f\u53cd\u5e94\u751f\u6210C2+<\/sub>\u4ea7\u7269\uff0c\u4e0d\u4ec5\u6df1\u5165\u63ed\u793a\u4e86p-d\u6742\u5316\u5bf9CO2<\/sub>RR\u4e2dC2+<\/sub>\u4ea7\u7269\u751f\u6210\u7684\u5f71\u54cd\uff0c\u800c\u4e14\u4e3a\u5728\u5b9e\u9645\u8bbe\u5907\u4e2d\u8bbe\u8ba1\u66f4\u5177\u521b\u65b0\u6027\u548c\u6548\u7387\u7684\u7528\u4e8e\u5b89\u57f9\u7ea7CO2<\/sub>\u7535\u89e3\u7684\u7535\u50ac\u5316\u5242\u5f00\u8f9f\u4e86\u9053\u8def\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cp\u2013d Orbital Hybridization Induced by p-Block Metal-Doped Cu Promotes the Formation of C<\/strong>2+<\/sub><\/strong>\u00a0Products in Ampere-Level CO<\/strong>2<\/sub><\/strong>\u00a0Electroreduction<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aJ. Am. Chem. Soc.<\/i><\/em><\/strong>\u4e0a\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a\u97e9\u5e03\u5174\u9662\u58eb&\u6731\u5e86\u5bab\u7814\u7a76\u5458JACS\uff1ap\u533a\u91d1\u5c5e\u63ba\u6742Cu\u8bf1\u5bfcp-d\u6742\u5316\u4fc3\u8fdbCO2\u7535\u8fd8\u539f\u5236\u5907\u591a\u78b3\u4ea7\u7269<\/a><\/b><\/strong><\/h1>\n

 <\/p>\n

 <\/p>\n

6.\u00a0<\/b>\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u90b5\u654f\u534e\u56e2\u961fEcoMat\uff1a\u5fae\u6ce2\u8f85\u52a9\u7b56\u7565\u5b9e\u73b0CO2RR\u6c27\u5316\u7269\u884d\u751f\u94dc\u7eb3\u7c73\u7247\u50ac\u5316\u5242\u7684\u7b80\u6613\u5408\u6210<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u90b5\u654f\u534e\u6559\u6388\u548c\u845b\u5a67\u6377\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u5f00\u53d1\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u5fae\u6ce2\u8f85\u52a9\u65b9\u6cd5\u6765\u5408\u6210\u6c27\u5316\u7269\u884d\u751f\u7684Cu\u7eb3\u7c73\u7247\uff08OD-Cu NS\uff09\uff0c\u5e76\u63ed\u793a\u4e86Cu\u7684\u6c27\u5316\u6001\u80fd\u591f\u901a\u8fc7\u6539\u53d8Cu\u524d\u9a71\u4f53\u91cf\u6765\u63a7\u5236\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u7eb3\u7c73\u7ea7Cu\u7ed3\u6784\u7684\u5f62\u6210\u4f1a\u5f71\u54cdOD-Cu NS\u7684\u8868\u9762\u7c97\u7cd9\u5ea6\u3002\u7ed3\u679c\u663e\u793a\uff0c\u5728\u4e2d\u6027KHCO3<\/sub>\u6eb6\u6db2\u4e2d\uff0c\u90e8\u5206\u6c27\u5316\u7684Cu\u8868\u9762\u5bf9C2+<\/sub>\u4ea7\u7269\u8868\u73b0\u51fa\u9ad8\u8fbe72%\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff08FE\uff09\uff0c\u5176\u90e8\u5206\u7535\u6d41\u5bc6\u5ea6\u4e3a55 mA cm-2<\/sup>\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u7531\u6b64\u5f97\u5230\u7684OD-Cu NS\uff0c\u901a\u8fc7\u5f3a\u7ed3\u5408\u80fd\u4fc3\u8fdb\u4e86CO2<\/sub>\u5206\u5b50\u89e3\u79bb\uff0c\u4ee5\u53ca\u901a\u8fc7\u589e\u5927\u7684\u7535\u5316\u5b66\u8868\u9762\u79ef\u4fc3\u8fdb\u4e86C2+<\/sub>\u5316\u5408\u7269\u5236\u5907\uff0c\u663e\u793a\u51fa\u534f\u540c\u4f5c\u7528\u3002\u672c\u6587\u4e5f\u4e3a\u8bbe\u8ba1\u9ad8\u6548\u7684CO2RR OD-Cu\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cFacile design of oxide-derived Cu nanosheet electrocatalyst\u00a0for CO<\/i><\/em><\/strong>2<\/i><\/em><\/strong>\u00a0reduction reaction<\/i><\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728EcoMat<\/i><\/em><\/strong>\u4e0a\u3002<\/p>\n

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7.\u00a0<\/b>ACS Catalysis\uff1a\u7a33\u5b9a\u6c27\u5316\u6001SnO2\u5728\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5b9e\u73b0\u9ad8\u9009\u62e9\u6027CO2\u7535\u8fd8\u539f\u6210\u7532\u9178\u76d0<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u8fd1\u65e5\uff0c\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u4e54\u4e16\u748b\u6559\u6388\u548c\u90d1\u5c27\u526f\u6559\u6388\u7b49\u4eba\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u4e0d\u540c\u91d1\u5c5e\u5355\u539f\u5b50(Cu\u3001Bi\u548cPt)\u63ba\u6742\u7684SnO2<\/sub>\uff0c\u4ee5\u63a2\u7a76CO2<\/sub>RR\u8fc7\u7a0b\u4e2d\u539f\u5b50\u63ba\u6742\u7f3a\u9677\u5bf9SnO2<\/sub>\u4fdd\u62a4\u7684\u5f71\u54cd\u3002Cu\u63ba\u6742\u7684SnO2<\/sub>\u5728\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8868\u73b0\u51fa\u6700\u4f73\u7684CO2<\/sub>RR\u6d3b\u6027\uff0c\u7279\u522b\u662f\u5728500 mA cm-2<\/sup>\u4e0b\u4e5f\u80fd\u4fdd\u630181%\u7684FEformate<\/sub>\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\u4ee5\u201cStabilizing Oxidation State of SnO<\/strong>2<\/sub><\/strong>\u00a0for Highly Selective CO<\/strong>2<\/sub><\/strong>\u00a0Electroreduction to Formate at Large Current Densities<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aACS Catalysis<\/i><\/em>\u4e0a\u3002<\/p>\n

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8.\u00a0<\/b>\u4e2d\u79d1\u9662\u7269\u7406\u7814\u7a76\u6240\u8054\u5408\u5c71\u4e1c\u5927\u5b66\uff1a\u76f8\u754c\u8bf1\u5bfcSnO2\/Cu6Sn5\/CuO\u50ac\u5316\u5242\u4e2d\u591a\u6d3b\u6027\u4e2d\u5fc3\u5bf9CO2\u4e32\u8054\u7535\u8fd8\u539f\u5236\u7532\u9178<\/b><\/strong><\/h1>\n

\"\"<\/p>\n

\u76ee\u524d\uff0c\u94dc\u9521\u5408\u91d1\u50ac\u5316\u5242\u5df2\u663e\u793a\u51fa\u5c06CO2<\/sub>\u8fd8\u539f\u4e3a\u7532\u9178\u6216\u7532\u9178\u76d0\u7684\u80fd\u529b\u3002CO2<\/sub>\u8fd8\u539f\u6d89\u53ca\u5438\u9644\u3001\u6d3b\u5316\u3001\u52a0\u6c22\u7b49\u591a\u4e2a\u6b65\u9aa4\uff0c\u7136\u800c\uff0c\u5b83\u4eec\u5bf9CO2<\/sub>\u5206\u5b50\u7684\u5438\u9644\u548c\u6d3b\u5316\u80fd\u529b\u8f83\u5dee\uff0c\u4ee5\u53caH\u4f9b\u5e94\u52a8\u529b\u5b66\u7f13\u6162\uff0c\u9650\u5236\u4e86\u7535\u50ac\u5316CO2<\/sub>RR\u751f\u6210\u7532\u9178\u7684\u8d28\u5b50\u8026\u5408\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u3002\u4e3a\u4e86\u89e3\u51b3\u4e0a\u8ff0\u95ee\u9898\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u8c37\u6797\uff0c\u8054\u5408\u5c71\u4e1c\u5927\u5b66\u6676\u4f53\u6750\u6599\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u53ca\u6d4e\u5357\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5de5\u5b66\u9662\u9ad8\u7b49\u4ea4\u53c9\u5b66\u79d1\u7814\u7a76\u9662\u5218\u5b8f\u6559\u6388\u7b49\u4eba\uff0c\u91c7\u7528\u6fc0\u5149\u6e85\u5c04\u6cd5\u5236\u5907\u4e86\u5177\u6709\u8d85\u6807\u91cf\u76f8\u754c\u7684\u8d85\u5c0fSnO2<\/sub>\/Cu6<\/sub>Sn5<\/sub>\/CuO\u7eb3\u7c73\u50ac\u5316\u5242\u3002SnO2<\/sub>\u7684\u5f15\u5165\u589e\u5f3a\u4e86CO2<\/sub>\u7684\u5438\u9644\u548c\u6d3b\u5316\uff0c\u800cCuO\u4fc3\u8fdb\u4e86H2<\/sub>O\u7684\u5206\u89e3\u5e76\u63d0\u4f9b\u4e86\u4e30\u5bcc\u7684 *H\u4e2d\u95f4\u4f53\uff0c\u4ece\u800c\u5728\u590d\u5408\u50ac\u5316\u5242\u4e0a\u5f62\u6210\u4e86\u4e32\u8054\u7684\u50ac\u5316\u4e2d\u5fc3\uff0c\u56e0\u6b64\u5177\u6709\u4f18\u5f02\u7684CO2<\/sub>RR\u6d3b\u6027\u548c\u9ad8\u7684\u7532\u9178\u9009\u62e9\u6027\u3002SnO2<\/sub>\/ Cu6<\/sub>Sn5<\/sub>\/CuO\u7535\u6781\u4e0a\u7532\u9178\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff08FEHCOOH<\/sub>\uff09\u8fbe\u523090.13%\uff0c\u5728-0.95 V\u53ef\u9006\u6c22\u7535\u6781\u7535\u538b\u6761\u4ef6\u4e0b\uff0c\u7535\u6d41\u5bc6\u5ea6\u9ad8\u8fbe25.2 mA cm\u22122<\/sup>\u3002\u901a\u8fc7\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u548c\u52a8\u529b\u5b66\u540c\u4f4d\u7d20\u6548\u5e94\u5b9e\u9a8c\u8bc1\u5b9e\u4e86\u901a\u8fc7\u5f15\u5165\u6c27\u5316\u7269\u800c\u6784\u9020\u7684\u591a\u76f8\u8fb9\u754c\u7684\u4f5c\u7528\u3002\u8fd9\u9879\u5de5\u4f5c\u4ee5\u6807\u9898\u4e3a\uff1a\u201cSuperscalar Phase Boundaries Derived Multiple Active Sites in SnO2<\/sub>\/ Cu6<\/sub>Sn5<\/sub>\/CuO for Tandem Electroreduction of CO2<\/sub>\u00a0to Formic Acid\u201d\u53d1\u8868\u5728Advanced Energy Materials\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a\u4e2d\u79d1\u9662\u7269\u7406\u7814\u7a76\u6240\u8054\u5408\u5c71\u4e1c\u5927\u5b66\uff1a\u76f8\u754c\u8bf1\u5bfcSnO2\/Cu6Sn5\/CuO\u50ac\u5316\u5242\u4e2d\u591a\u6d3b\u6027\u4e2d\u5fc3\u5bf9CO2\u4e32\u8054\u7535\u8fd8\u539f\u5236\u7532\u9178<\/a><\/b><\/strong><\/h1>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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