{"id":250604,"date":"2023-05-23T06:02:20","date_gmt":"2023-05-22T22:02:20","guid":{"rendered":"\/\/m.iemloyee.com\/?p=250604"},"modified":"2023-05-22T17:02:36","modified_gmt":"2023-05-22T09:02:36","slug":"chem-%e6%b0%a2%e9%94%ae%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e4%b8%ad%e7%9a%84%e5%b1%80%e5%9f%9f%e5%8a%a8%e5%8a%9b%e5%ad%a6%ef%bc%8c%e7%94%a8%e4%ba%8e%e5%8f%af%e7%bc%96%e7%a8%8b%e5%8f%91%e5%85%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=250604","title":{"rendered":"Chem. :\u6c22\u952e\u6709\u673a\u6846\u67b6\u4e2d\u7684\u5c40\u57df\u52a8\u529b\u5b66\uff0c\u7528\u4e8e\u53ef\u7f16\u7a0b\u53d1\u5149\u7684\u81ea\u9002\u5e94\u5ba2\u4f53\u5bb9\u7eb3"},"content":{"rendered":"<p style=\"text-align: center;\"><strong>Chem. :\u6c22\u952e\u6709\u673a\u6846\u67b6\u4e2d\u7684\u5c40\u57df\u52a8\u529b\u5b66\uff0c\u7528\u4e8e\u53ef\u7f16\u7a0b\u53d1\u5149\u7684\u81ea\u9002\u5e94\u5ba2\u4f53\u5bb9\u7eb3<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>charfreen<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u4f5c\u4e3a\u4e00\u7c7b\u65b0\u5174\u7684\u529f\u80fd\u591a\u5b54\u6750\u6599\uff0c\u6c22\u952e\u6709\u673a\u9aa8\u67b6\uff08HOFs\uff09\u5728\u5404\u79cd\u5e94\u7528\u4e2d\u8868\u73b0\u51fa\u5de8\u5927\u7684\u6f5c\u529b\u3002\u4e3a\u4e86\u907f\u514d\u76f8\u5bf9\u8106\u5f31\u7684\u6c22\u952e\u53ef\u80fd\u5bfc\u81f4\u7684\u8f83\u5dee\u9aa8\u67b6\u7a33\u5b9a\u6027\uff0c\u4ee5\u5f80\u7684\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u5728\u6784\u5efa\u575a\u56fa\u7684HOFs\uff0c\u4f7f\u5176\u5728\u4e0d\u53d7\u5916\u754c\u523a\u6fc0\u7684\u60c5\u51b5\u4e0b\u4fdd\u6301\u539f\u6709\u7684\u591a\u5b54\u7ed3\u6784\u3002\u4e0e\u575a\u56fa\u7684HOFs\u76f8\u6bd4\uff0c\u67d4\u6027HOFs\uff08FHOFs\uff09\u66f4\u96be\u5b9e\u73b0\uff0c\u4f46\u5177\u6709\u72ec\u7279\u7684\u52a8\u529b\u5b66\u884c\u4e3a\uff08\u968f\u5ba2\u4f53\u3001\u6e29\u5ea6\u548c\u673a\u68b0\u538b\u529b\u53d8\u5316\u800c\u53d1\u751f\u5b54\u5f84\u548c\u5f62\u72b6\u53d8\u5316\u7684\u53ef\u9006\u7ed3\u6784\u8f6c\u53d8\uff09\u548c\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u800c\u5907\u53d7\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5148\u524d\u62a5\u9053\u7684FHOFs\u7684\u7ed3\u6784\u52a8\u529b\u5b66\u4e3b\u8981\u6d89\u53ca\u4f53\u79ef\u53d8\u5316\uff0c\u6574\u4e2a\u591a\u5b54\u9aa8\u67b6\u7684\u626d\u66f2\uff0c\u751a\u81f3\u6784\u5efa\u5355\u5143\u7684\u91cd\u6392\uff0c\u53ef\u5f52\u4e3a\u5168\u5c40\u52a8\u529b\uff1b\u800c\u4e14\u4f1a\u5bfc\u81f4\u7ed3\u6784-\u6027\u8d28\u5173\u7cfb\u7684\u4e0d\u786e\u5b9a\u6027\u3002\u7531\u4e8e\u7f3a\u4e4f\u5bf9\u5206\u5b50\u7ed3\u6784\u3001\u9aa8\u67b6\u67d4\u6027\u548c\u6027\u8d28\u4e4b\u95f4\u5173\u7cfb\u7684\u6df1\u5165\u7814\u7a76\uff0c\u8fd9\u79cd\u5168\u5c40\u52a8\u529b\u5b66\u5927\u5927\u589e\u52a0\u4e86FHOFs\u529f\u80fd\u5316\u7684\u8bbe\u8ba1\u96be\u5ea6\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u5177\u6709\u826f\u597d\u53ef\u9884\u6d4b\u6027\u548c\u53ef\u63a7\u6027\u7684\u5176\u4ed6\u7c7b\u578b\u7684FHOFs\u662f\u975e\u5e38\u5fc5\u8981\u7684\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u8fd1\u65e5\uff0c\u4e2d\u5c71\u5927\u5b66\u6c60\u632f\u56fd\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u9996\u4f8b\u7531\u8f6f\u70f7\u57fa\u916f\u94fe\u8bf1\u5bfc\u7684\u5177\u6709\u5c40\u57df\u52a8\u529b\u5b66\u7684FHOF\uff088PZ\uff09\u3002\u4e0e\u4e4b\u524d\u62a5\u9053\u7684FHOFs\u4e0d\u540c\uff0c\u5728\u54cd\u5e94\u4e0d\u540c\u7684\u5916\u754c\u523a\u6fc0\u5982\u4e0d\u540c\u7684\u5ba2\u4f53\u548c\u6e29\u5ea6\u65f6\uff0c\u901a\u8fc7\u8f6f\u7684\u4e59\u57fa\u916f\u94fe\u7684\u5c40\u90e8\u8fd0\u52a8\u6765\u89c2\u5bdf\u5c40\u90e8\u52a8\u529b\u5b66\u884c\u4e3a\uff0c\u800c\u4e0d\u4f1a\u5f15\u8d77\u6676\u80de\u4f53\u79ef\u548c\u5206\u5b50\u7ec4\u88c5\u5f62\u5f0f\u7684\u5de8\u5927\u53d8\u5316\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5c40\u57df\u52a8\u529b\u5b66\uff0c8PZ\u53ef\u4ee5\u9002\u5e94\u4e00\u7cfb\u5217\u5177\u6709\u5927\u8303\u56f4\u70f7\u57fa\u94fe\u957f\u53d8\u5316\u76843-\u70f7\u57fa\u567b\u5429\uff0c\u5e76\u751f\u621010\u79cd\u5177\u6709\u5927\u8303\u56f4\u6e29\u5ea6\u4f9d\u8d56\u53d1\u5149\u54cd\u5e94\u7684\u4e3b\u5ba2\u4f53\u5171\u6676\u3002\u8fd8\u901a\u8fc7\u903b\u8f91\u7f16\u7a0b\u5c55\u793a\u4e86\u8fd9\u4e9b\u5171\u6676\u5728\u5fae\u5c3a\u5ea6\u53d1\u5149\u70ed\u62a5\u8b66\u5668\u548c\u591a\u91cd\u4fe1\u606f\u52a0\u5bc6\u4e2d\u7684\u5e94\u7528\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Local dynamics in a hydrogen-bonded organic framework for adaptive guest accommodation with programmable luminescence<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728<strong><em>Chem<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250611\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u6807\u9898.png\" alt=\"\" width=\"1027\" height=\"362\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u6807\u9898.png 1027w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u6807\u9898-300x106.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u6807\u9898-768x271.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u6807\u9898-1024x361.png 1024w\" sizes=\"(max-width: 1027px) 100vw, 1027px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p><strong>\u221a<\/strong> <strong>\u4f5c\u8005\u62a5\u9053\u4e86\u9996\u4f8b\u5177\u6709\u5c40\u90e8\u52a8\u529b\u5b66\u7684\u67d4\u6027<\/strong><strong>HOF<\/strong><strong>\uff08<\/strong><strong>8PZ<\/strong><strong>\uff09\uff0c\u901a\u8fc7\u5f15\u5165\u8f6f\u7684\u4e59\u916f\u94fe\u6765\u5b9e\u73b0\u81ea\u9002\u5e94\u5ba2\u4f53\u5bb9\u7eb3\u3002\u5355\u6676<\/strong><strong>X<\/strong><strong>\u5c04\u7ebf\u884d\u5c04\uff08<\/strong><strong>SXRD<\/strong><strong>\uff09\u5206\u6790\u8868\u660e\uff0c\u5728\u54cd\u5e94\u5404\u79cd\u5916\u90e8\u523a\u6fc0\u65f6\uff0c\u4e59\u916f\u94fe\u5c40\u90e8\u8fd0\u52a8\u800c<\/strong><strong>8PZ<\/strong><strong>\u7684\u5206\u5b50\u7ec4\u88c5\u5f62\u5f0f\u4e0d\u53d8\uff0c\u8fd9\u53ef\u4ee5\u6709\u6548\u5730\u8c03\u8282\u5b54\u5f84\uff0c\u540c\u65f6\u5141\u8bb8\u7a33\u5b9a\u7684\u53d1\u5149\u6027\u80fd\u3002<\/strong><\/p>\n<p><strong>\u221a <\/strong><strong>8PZ<\/strong><strong>\u53ef\u4ee5\u901a\u8fc7\u5176\u5c40\u90e8\u52a8\u529b\u5b66\u9002\u5e94\u4e00\u7cfb\u5217\u70f7\u57fa\u94fe\u957f\u53d8\u5316\u8f83\u5927\u7684<\/strong><strong>3-<\/strong><strong>\u70f7\u57fa\u567b\u5429\uff0c\u5f62\u6210\u4e86\u9002\u7528\u4e8e<\/strong><strong>SXRD<\/strong><strong>\u5206\u6790\u7684\u4e3b\u5ba2\u4f53\u5171\u6676\uff0c\u5b83\u4eec\u5177\u6709\u53ef\u7f16\u7a0b\u7684\u6e29\u5ea6\u4f9d\u8d56\u7684\u53d1\u5149\u884c\u4e3a\uff0c\u5e76\u663e\u793a\u51fa\u5728\u5404\u79cd\u5173\u952e\u5e94\u7528\u4e2d\u7684\u6f5c\u529b\u3002<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-250605 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/1-2.png\" alt=\"\" width=\"832\" height=\"388\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/1-2.png 832w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/1-2-300x140.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/1-2-768x358.png 768w\" sizes=\"(max-width: 832px) 100vw, 832px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1.<\/strong> FHOFs\u4e2d\u4e0d\u540c\u7c7b\u578b\u7684\u7ed3\u6784\u52a8\u529b\u5b66\u793a\u610f\u56fe\u3002<strong>(A)<\/strong> HOFs\u4e2d\u7684\u5168\u5c40\u52a8\u529b\u5b66\u793a\u610f\u56fe\uff0c\u5728\u5916\u90e8\u523a\u6fc0\u4e0b\u8868\u73b0\u51fa\u4e3b\u8981\u7684\u4f53\u79ef\u53d8\u5316\u3001\u6574\u4e2a\u591a\u5b54\u9aa8\u67b6\u7684\u626d\u66f2\uff0c\u751a\u81f3\u662f\u6784\u7b51\u5355\u5143\u7684\u91cd\u6392\u3002<strong>(B)<\/strong> HOFs\u5c40\u90e8\u52a8\u529b\u5b66\u793a\u610f\u56fe\uff0c\u5728\u4fdd\u6301\u539f\u6709\u6574\u4f53\u6846\u67b6\u7ed3\u6784\u7684\u540c\u65f6\uff0c\u4ec5\u5c55\u793a\u5c40\u90e8\u5728\u5916\u754c\u523a\u6fc0\u4e0b\u7684\u8fd0\u52a8\u3002\u00a9 2023 Elsevier Inc.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-250606 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/2-1.png\" alt=\"\" width=\"567\" height=\"517\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/2-1.png 567w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/2-1-300x274.png 300w\" sizes=\"(max-width: 567px) 100vw, 567px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2.<\/strong> 8PZ\u7684\u5355\u6676\u7ed3\u6784\u7814\u7a76\u3002<strong>(A)<\/strong> TPE-4PZ\u7684\u5206\u5b50\u7ed3\u6784\u53ca\u793a\u610f\u56fe\u3002<strong>(B)<\/strong> DCM@8PZ\u5355\u6676\u7ed3\u6784\u4e2d\u6cbf\u7740a\u8f74150 K\u7684\u6c22\u952e\u3002<strong>(C)<\/strong> DCM@8PZ\u5728150 K\u4e0b\u6cbfa\u8f74\u65b9\u5411\u7684\u5806\u79ef\u56fe\u3002\u4e3a\u6e05\u6670\u8d77\u89c1\uff0c\u7701\u7565\u4e86\u6eb6\u5242\u3002<strong>(D)<\/strong> \u88c5\u9970\u6709\u4e59\u916f\u94fe\u95e8\u7684\u5b54\u7684\u63d2\u56fe\u3002<strong>(E)<\/strong> DCM@8PZ\u4e2dTPE-4PZ\u7684ESP\u56fe\uff0c\u52bf\u80fd\u8303\u56f4\u4e3a40.0 ~ 20.0 kcal \/ mol\u3002<strong>(F)<\/strong> \u75281.2 \u00c5\u7684\u63a2\u5934\u5728150 K\u4e0b\u751f\u6210DCM@8PZ\u7684S\u578b\u5b54\u9053\u8868\u9762\u7684\u53ef\u89c6\u5316\u3002\u00a9 2023 Elsevier Inc.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-250607 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/3-2.png\" alt=\"\" width=\"1272\" height=\"512\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/3-2.png 1272w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/3-2-300x121.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/3-2-768x309.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/3-2-1024x412.png 1024w\" sizes=\"(max-width: 1272px) 100vw, 1272px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3. <\/strong>8PZ\u7684\u5c40\u90e8\u52a8\u529b\u5b66\u5bf9\u6eb6\u5242\u548c\u6e29\u5ea6\u7684\u54cd\u5e94\u3002<strong>(A)<\/strong> 150 K\u4e0bDCM@8PZ\u5355\u6676\u7ed3\u6784\u4e2d\u4e59\u916f\u94fe\u7684\u5b54\u5f84\u3001\u9762\u5185\u548c\u9762\u5916\u8fd0\u52a8\u7684\u8868\u5f81\u3002C\u539f\u5b50\u5206\u522b\u5448\u84dd\u7eff\u8272\u3001\u9ec4\u8272\u548c\u7070\u8272\u3002O\u539f\u5b50\u5206\u522b\u5448\u73ab\u7470\u8272\u548c\u7070\u8272\u3002\u4e3a\u4e86\u6e05\u6670\u8d77\u89c1\uff0c\u7701\u7565\u4e86\u90e8\u5206TPE-4PZ\u5206\u5b50\u7ed3\u6784\u3001H\u539f\u5b50\u548c\u6eb6\u5242\u5206\u5b50\u3002<strong>(B)<\/strong>\u6eb6\u5242\u8bf1\u5bfc\u7684\u70f7\u57fa\u916f\u94fe\u9762\u5185\u8fd0\u52a8\u5bf98PZ\u5b54\u5f84\u7684\u5f71\u54cd\u3002<strong>(C)<\/strong>\u8bf4\u660e\u6eb6\u5242\u548c\u6e29\u5ea6\u5f15\u8d77\u7684\u70f7\u57fa\u916f\u94fe\u9762\u5916\u8fd0\u52a8\u5bf98PZ\u5b54\u5f84\u7684\u5f71\u54cd\u3002<strong>(D)<\/strong> 8PZ\u9aa8\u67b6\u5728150 K\u4e0b\u7684\u5b54\u5f84\u3002\u4e0d\u540c\u6eb6\u5242\u7684\u7f29\u5199\uff1aEA\uff0c\u4e59\u9178\u4e59\u916f\uff1bTOL\u3001\u7532\u82ef\uff1bDCM\uff0c\u4e8c\u6c2f\u7532\u70f7\uff1bACT\uff0c\u4e19\u916e\uff1bDMF\uff0cN\uff0cN-\u4e8c\u7532\u57fa\u7532\u9170\u80fa\u3002<strong>(E)<\/strong> 8PZ\u6846\u67b6\u5728150 K\u4e0b\u7684\u6570\u636e\u3002<strong>(F)<\/strong> 150\u548c220 K\u4e0bDcm@8Pz\u548cTOL@8Pz\u7684D1\u548cD3\u6570\u636e\u3002<strong>(G)<\/strong> TOL@8PZ\u5728150\u548c220 K\u7684\u5355\u6676\u7ed3\u6784\u3002\u4e3a\u4e86\u6e05\u6670\u8d77\u89c1\uff0c\u7701\u7565\u4e86\u90e8\u5206TPE-4PZ\u5206\u5b50\u7ed3\u6784\u3002\u00a9 2023 Elsevier Inc.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-250608 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/4-2.png\" alt=\"\" width=\"1024\" height=\"833\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/4-2.png 1024w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/4-2-300x244.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/4-2-768x625.png 768w\" sizes=\"(max-width: 1024px) 100vw, 1024px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4. <\/strong>\u4e3b\u5ba2\u4f53\u5171\u6676\u7ed3\u6784\u4e2d\u7684\u81ea\u9002\u5e94\u5ba2\u4f53\u5bb9\u7eb3\u3002<strong>(A)<\/strong> 3-\u70f7\u57fa\u567b\u5429\u57288PZ\u4e2d\u901a\u8fc7\u4e59\u916f\u94fe\u7684\u5c40\u90e8\u8fd0\u52a8\u5b9e\u73b0\u81ea\u9002\u5e94\u5bb9\u7eb3\u3002<strong>(B)<\/strong> 8PZ-SCX\u5728150 K\u4e0b\u7684SXRD\u7ed3\u6784\u3002\u4e3a\u4e86\u6e05\u6670\u8d77\u89c1\uff0c\u7701\u7565\u4e86\u90e8\u5206TPE-4PZ\u5206\u5b50\u7ed3\u6784\u548cH\u539f\u5b50\u3002<strong>(C)<\/strong> 8PZ-SC6\u5171\u6676\u7ed3\u6784\u4e2d\u4e3b\u5ba2\u4f53\u5206\u5b50\u95f4NCI\u533a\u57df\u7684\u5206\u5e03\u3002\u4e3b\u4f53\u548c\u5ba2\u4f53\u5206\u5b50\u5206\u522b\u5448\u84dd\u8272\u548c\u7c89\u7ea2\u8272\u3002\u4e3a\u4e86\u6e05\u6670\u8d77\u89c1\uff0c\u7701\u7565\u4e86\u51e0\u4e2a\u5ba2\u4f53\u5206\u5b50\u3002<strong>(D)<\/strong> 8PZ-SC6\u5171\u6676\u7ed3\u6784\u4e2d\u5ba2\u4f53\u5206\u5b50\u95f4NCI\u533a\u57df\u7684\u5206\u5e03\u3002\u8272\u7801\uff1a\u84dd\u8272\uff0cC\uff1b\u7c89\u7ea2\u8272\u3001S\uff1b\u767d\u8272\uff0cH\u3002<strong>(E)<\/strong> 8PZ-SC6\u7684\u88c5\u586b\u56fe\u3002\u82ef\u73af\u548c\u4e59\u70ef\u57fa\u6838\u4ee5\u53ca\u70f7\u57fa\u916f\u94fe\u7684C\u539f\u5b50\u5206\u522b\u5448\u84dd\u7eff\u8272\u548c\u9ec4\u8272\u3002TPE-4PZ\u5206\u5b50\u7684O\u539f\u5b50\u5448\u73ab\u7470\u8272\u3002\u8272\u7801\uff1a\u7c89\u7ea2\u8272\uff0cS\uff1b\u6d45\u7eff\u8272\uff0cC\uff0cH\u539f\u5b50\u5448\u767d\u8272\u3002\u00a9 2023 Elsevier Inc.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250609 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/5-1.png\" alt=\"\" width=\"1276\" height=\"552\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/5-1.png 1276w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/5-1-300x130.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/5-1-768x332.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/5-1-1024x443.png 1024w\" sizes=\"(max-width: 1276px) 100vw, 1276px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5. <\/strong>\u4e3b\u5ba2\u4f53\u5171\u6676\u7684\u6e29\u5ea6\u4f9d\u8d56\u53d1\u5149\u884c\u4e3a\u3002<strong>(A)<\/strong> 8PZ-SCX\u4e3b\u5ba2\u4f53\u5171\u6676\u7684\u53d1\u5c04\u5149\u8c31\u53ca\u5176\u7ed3\u6784\u8f6c\u53d8\u540e\u7684\u53d1\u5c04\u5149\u8c31\uff08\u5728365 nm\u6fc0\u53d1\u4e0b\uff09\u3002<strong>(B)<\/strong> 8PZ-SCX\u5171\u6676\u7684\u62a5\u8b66\u6e29\u5ea6\u3002<strong>(C)<\/strong> 8PZ-SC6\u7684\u6e29\u5ea6\u4f9d\u8d56PXPD\u8c31\u3002(D) TD-DFT\u8ba1\u7b97\u7684\u57fa\u4e8e8PZ-SC6\u5171\u6676\u7ed3\u6784\u7684\u5206\u5b50\u80fd\u7ea7\u3002\u00a9 2023 Elsevier Inc.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-250610 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/6-1.png\" alt=\"\" width=\"595\" height=\"817\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/6-1.png 595w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/6-1-218x300.png 218w\" sizes=\"(max-width: 595px) 100vw, 595px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>6. <\/strong><strong>\u5728\u5fae\u5c3a\u5ea6\u53d1\u5149\u70ed\u62a5\u8b66\u5668\u548c\u903b\u8f91\u7f16\u7a0b\u591a\u91cd\u4fe1\u606f\u52a0\u5bc6\u4e2d\u7684\u5e94\u7528\u793a\u8303\u3002<\/strong><\/p>\n<p>(<strong>A)<\/strong> 8PZ-SCX\u5171\u6676\u4f5c\u4e3a\u53d1\u5149\u6e29\u5ea6\u62a5\u8b66\u5668\u7684\u793a\u610f\u56fe\u3002<strong>(B)<\/strong> 8PZ-SC6\u5171\u6676\u5728\u65e5\u5149(\u4e0a)\u548c350 nm\u7d2b\u5916\u5149(\u4e0b)\u4e0b\u70ed\u5904\u7406\uff08\u6807\u5c3a\u6746\uff0c200 mm\uff09\u540e\u7684\u56fe\u50cf\u3002<strong>(C)<\/strong> \u53cc\u8f93\u5165\u7ec4\u5408\uff08NOT\u3001AND\u548cOR\u903b\u8f91\u51fd\u6570\u7684\u7ec4\u5408\uff09\u903b\u8f91\u95e8\u3002\u8f93\u51651\u548c\u8f93\u51652\u5206\u522b\u4ee3\u886860\u2103\u548c170\u2103\u52a0\u70ed\uff0c\u8f93\u51fa\u4e3a\u53d1\u5149\u989c\u8272\u3002<strong>(D)<\/strong>\u903b\u8f91\u95e8\u7684\u771f\u503c\u8868\u3002\u00a9 2023 Elsevier Inc.<\/p>\n<p style=\"text-align: center;\"><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u6784\u5efa\u4e86\u9996\u4f8b\u5177\u6709\u5c40\u57df\u52a8\u529b\u5b66\u7684FHOF\uff0c\u901a\u8fc7\u5f15\u5165\u67d4\u8f6f\u7684\u4e59\u916f\u94fe\u6765\u5b9e\u73b0\u81ea\u9002\u5e94\u7684\u5ba2\u4f53\u5bb9\u7eb3\u3002\u5f53\u54cd\u5e94\u5404\u79cd\u5916\u754c\u523a\u6fc0\u5982\u6eb6\u5242\u548c\u6e29\u5ea6\u65f6\uff0c\u4e59\u916f\u94fe\u4f1a\u53d1\u751f\u5c40\u90e8\u8fd0\u52a8\uff0c\u5305\u62ec\u9762\u5185\u548c\u9762\u5916\u8fd0\u52a8\uff0c\u8fd9\u53ef\u4ee5\u6709\u6548\u5730\u8c03\u82828PZ\u7684\u5b54\u5f84\uff0c\u800c\u4e0d\u4f1a\u663e\u8457\u6539\u53d8\u7ec6\u80de\u4f53\u79ef\u548c\u5206\u5b50\u7ec4\u88c5\u5f62\u5f0f\u3002\u901a\u8fc7\u5c40\u90e8\u52a8\u529b\u5b66\uff0c8PZ\u53ef\u4ee5\u9002\u5e94\u4e00\u7cfb\u5217\u70f7\u57fa\u94fe\u957f\u53d8\u5316\u8f83\u5927\u76843-\u70f7\u57fa\u567b\u5429\uff0c\u8fdb\u4e00\u6b65\u5236\u5907\u51fa\u9002\u7528\u4e8eSXRD\u5206\u6790\u768410\u79cd\u4e3b\u5ba2\u4f53\u5171\u6676\uff0c\u5b83\u4eec\u5177\u6709\u53ef\u7f16\u7a0b\u7684\u6e29\u5ea6\u4f9d\u8d56\u53d1\u5149\u7279\u6027\uff0c\u5728\u5fae\u5c3a\u5ea6\u53d1\u5149\u70ed\u62a5\u8b66\u548c\u903b\u8f91\u7f16\u7a0b\u7684\u591a\u91cd\u4fe1\u606f\u52a0\u5bc6\u65b9\u9762\u663e\u793a\u51fa\u5de8\u5927\u7684\u6f5c\u529b\u3002\u5c06\u5177\u6709\u5c40\u57df\u52a8\u529b\u5b66\u7684\u67d4\u6027HOFs\u4f5c\u4e3a\u4e3b\u4f53\u5e94\u7528\u4e8e\u4e3b\u5ba2\u4f53\u5171\u6676\u4e5f\u4e3a\u529f\u80fd\u6027\u5171\u6676\u7684\u5236\u5907\u63d0\u4f9b\u4e00\u79cd\u6709\u4ef7\u503c\u7684\u7b56\u7565\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u52a0\u6df1\u4e86\u6211\u4eec\u5bf9HOFs\u7684\u6846\u67b6\u7ed3\u6784\u548c\u7075\u6d3b\u6027\u4e4b\u95f4\u5173\u7cfb\u7684\u7406\u89e3\uff0c\u800c\u4e14\u4e3a\u8bbe\u8ba1\u5177\u6709\u4e30\u5bcc\u5e94\u7528\u7684\u672a\u6765\u591a\u529f\u80fdFHOFs\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6709\u5e0c\u671b\u7684\u9014\u5f84\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5\uff1a<\/strong><strong><a href=\"https:\/\/doi.org\/10.1016\/j.chempr.2023.01.013\">https:\/\/doi.org\/10.1016\/j.chempr.2023.01.013<\/a><\/strong><\/p>\n<p><strong>\u672c\u6587\u7531<\/strong><strong>charfreen<\/strong><strong>\u64b0\u7a3f<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Chem. :\u6c22\u952e\u6709\u673a\u6846\u67b6\u4e2d\u7684\u5c40\u57df\u52a8\u529b\u5b66\uff0c\u7528\u4e8e\u53ef\u7f16\u7a0b\u53d1\u5149\u7684\u81ea\u9002\u5e94\u5ba2\u4f53\u5bb9\u7eb3 charfreen \u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u00a0 \u00a0 \u00a0 \u00a0\u4f5c\u4e3a\u4e00\u7c7b\u65b0\u5174\u7684\u529f\u80fd\u591a\u5b54\u6750\u6599\uff0c\u6c22\u952e\u6709\u673a\u9aa8&#8230;<\/p>\n","protected":false},"author":50229,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-250604","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250604"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/50229"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=250604"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250604\/revisions"}],"predecessor-version":[{"id":251224,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250604\/revisions\/251224"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=250604"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=250604"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=250604"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}