{"id":250502,"date":"2023-05-20T05:57:16","date_gmt":"2023-05-19T21:57:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=250502"},"modified":"2023-05-19T21:39:23","modified_gmt":"2023-05-19T13:39:23","slug":"edward-h-sargent%e6%95%99%e6%8e%88%e5%86%8d%e5%8f%91nature-catalysis%e7%ba%a7%e8%81%94co%e7%94%b5%e8%bf%98%e5%8e%9f-%e7%83%ad%e5%82%ac%e5%8c%96%ef%bc%8c%e9%80%89%e6%8b%a9%e6%80%a7%e5%90%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=250502","title":{"rendered":"Edward H. Sargent\u6559\u6388\u518d\u53d1Nature Catalysis:\u7ea7\u8054CO\u7535\u8fd8\u539f\u2014\u70ed\u50ac\u5316\uff0c\u9009\u62e9\u6027\u5408\u6210\u4e01\u70f7"},"content":{"rendered":"

\u4e00\u3001<\/strong> \u3010\u5bfc\u8bfb\u3011<\/strong>\u00a0 <\/strong><\/p>\n

\u63a7\u5236\u4eba\u4e3a\u6e29\u5ba4\u6c14\u4f53\u6392\u653e\u662f\u5e94\u5bf9\u5168\u7403\u6c14\u5019\u53d8\u5316\u7684\u91cd\u8981\u624b\u6bb5\u3002CO2<\/sub>\u7535\u50ac\u5316\u8fd8\u539f\uff08eCO2<\/sub>RR\uff09\u4e3aCO2<\/sub>\u51cf\u6392\u548c\u53ef\u518d\u751f\u80fd\u6e90\u8f6c\u5316\u4e3a\u9ad8\u9644\u52a0\u503c\u71c3\u6599\u53ca\u7cbe\u7ec6\u5316\u5b66\u54c1\u63d0\u4f9b\u4e86\u53ef\u884c\u7684\u9014\u5f84\u3002\u4ee5C4\u78b3\u6c22\u5316\u5408\u7269\u4e3a\u4f8b\uff0c\u5176\u5de5\u4e1a\u751f\u4ea7\u901a\u4f9d\u8d56\u4e8e\u50ac\u5316\u91cd\u6574\u3001\u539f\u6cb9\u84b8\u998f\u548c\u4f4e\u805a\u8fc7\u7a0b\uff0c\u8fd9\u4e9b\u8fc7\u7a0b\u9700\u8981\u5728\u9ad8\u6e29\uff08200-300\u00a0o<\/sup>C\uff09\u9ad8\u538b\uff081-3 MPa\uff09\u4e0b\u8fdb\u884c\u3002\u6bcf\u751f\u4ea7\u4e00\u5428C4\uff0c\u5c31\u4f1a\u6392\u653e\u4e24\u5428CO2<\/sub>\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cCO2<\/sub>\u7535\u8fd8\u539f\u65b9\u6cd5\u751f\u4ea7C4\u53ef\u4ee5\u5b9e\u73b0CO2<\/sub>\u7684\u6709\u6548\u5229\u7528\u548c\u78b3\u6392\u653e\u7684\u964d\u4f4e\u3002\u7136\u800c\uff0c\u76ee\u524dCO2<\/sub>\u7535\u8fd8\u539f\u5236C4\u7684\u751f\u4ea7\u6548\u7387\u8f83\u4f4e\uff0c\u6cd5\u62c9\u7b2c\u6548\u7387\u4f4e\u4e8e5%\uff0c\u7535\u6d41\u5bc6\u5ea6\u5c0f\u4e8e3 mA\/cm2<\/sup>\u3002\u6b64\u5916\uff0c\u4ea7\u54c1\u7eaf\u5ea6\u8f83\u4f4e\uff0c\u9700\u8981\u6dfb\u52a0\u989d\u5916\u7684\u5206\u79bb\u88c5\u7f6e\u4ee5\u63d0\u9ad8C4\u7684\u7eaf\u5ea6\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u5728\u4e0d\u7ecf\u8fc7\u5206\u79bb\u7684\u60c5\u51b5\u4e0b\u5236\u5f97\u9ad8\u7eaf\u5ea6\u7684C4\u4ea7\u54c1\u662f\u8be5\u6280\u672f\u5f53\u524d\u9762\u4e34\u7684\u6311\u6218\u3002<\/strong><\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u591a\u4f26\u591a&\u897f\u5317\u5927\u5b66Edward H. Sargent\u6559\u6388\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cdC1-C2-C4\u7ea7\u8054\u7cfb\u7edf\uff0c\u901a\u8fc7\u5c06C1\u7535\u89e3\u69fd\u548cC2<\/sub>H4<\/sub>\u805a\u5408\u53cd\u5e94\u5668\u7ed3\u5408\u8d77\u6765\uff0c\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u9009\u62e9\u6027\u5408\u6210\u4e01\u70f7\uff08C4<\/sub>H10<\/sub>\uff09\u3002\u8be5\u7cfb\u7edf\u4e2dC2<\/sub>H4<\/sub>\u8f6c\u5316\u738797%\uff0cCO\u5355\u7a0b\u8f6c\u5316\u738716.5%\uff0c\u5f97\u5230\u7684C4<\/sub>H10<\/sub>\u6d53\u5ea6\u4e3a30 wt%\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u201cSelective synthesis of butane from carbon monoxide using cascade electrolysis and thermocatalysis at ambient conditions<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Catalysis<\/em>\u4e0a\u3002<\/p>\n

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\u00a0<\/strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

1<\/strong>\u3001\u4f5c\u8005\u7ed3\u5408\u4e86\u7535\u5316\u5b66\u8fd8\u539f\u548c\u70ed\u50ac\u5316\u53cd\u5e94\u5668\uff0c\u5b9e\u73b0\u4e86\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u4ece<\/strong>CO<\/strong>\u9009\u62e9\u6027\u5408\u6210\u4e01\u70f7\uff0c\u8be5\u7ea7\u8054\u7cfb\u7edf\u7684\u9009\u62e9\u6027\u4e3a<\/strong>43%<\/strong>\uff0c\u7ea7\u8054\u4ea7\u7387\u4e3a<\/strong>24 mM<\/strong> h-1<\/sup><\/strong>\u3002<\/strong><\/p>\n

2<\/strong>\u3001<\/strong>CO<\/strong>\u53ef\u4ee5\u63d0\u9ad8<\/strong>C2<\/sub>H4<\/sub><\/strong>\u7684\u4e8c\u805a\u9009\u62e9\u6027\uff0c\u4f7f<\/strong>C4<\/sub>H10<\/sub><\/strong>\u7684\u9009\u62e9\u6027\u8fbe\u5230<\/strong>95%<\/strong>\u3002\u4f5c\u8005\u53d1\u73b0\uff0c\u589e\u52a0<\/strong>CO<\/strong>\u8986\u76d6\u5ea6\u6709\u5229\u4e8e<\/strong>C2<\/sub>H4<\/sub><\/strong>\u4e8c\u805a\u53cd\u5e94\u548c<\/strong>*Cx<\/sub>Hy<\/sub><\/strong>\u7684\u52a0\u6c22\u8fc7\u7a0b\uff0c\u540c\u65f6\u7834\u574f<\/strong>*C4<\/sub>H9<\/sub><\/strong>\u4e2d\u95f4\u4f53\u7684\u7a33\u5b9a\u6027\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86<\/strong>C4<\/sub>H10<\/sub><\/strong>\u7684\u9009\u62e9\u6027\u751f\u6210\u3002<\/strong><\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

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\u56fe<\/strong>1\u00a0 <\/strong>\u5e38\u89c4\u9014\u5f84\u548c\u7ea7\u8054\u7cfb\u7edf\u751f\u4ea7<\/strong>C4<\/strong>\u793a\u610f\u56fe\u3002<\/strong>a<\/strong>\uff09\u539f\u6cb9\u84b8\u998f\u751f\u4ea7<\/strong>C4<\/strong>\u3002<\/strong>b<\/strong>\uff09<\/strong>eCO2<\/sub>RR<\/strong>\u751f\u4ea7<\/strong>C4<\/strong>\u3002<\/strong>c<\/strong>\uff09\u7535\u5316\u5b66<\/strong>–<\/strong>\u70ed\u5316\u5b66\u7ea7\u8054\u751f\u4ea7<\/strong>C4<\/strong>\u6982\u5ff5\u548c\u6548\u7387\u5b9a\u4e49\u793a\u610f\u56fe\u3002<\/strong>\u00a9<\/strong> Springer Nature<\/strong><\/p>\n

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\u56fe<\/strong>2\u00a0 C4<\/sub>H10<\/sub><\/strong>\u751f\u6210\u673a\u7406\u7684\u7814\u7a76\u3002<\/strong>a<\/strong>\uff09\u4e0d\u540c<\/strong>CO2<\/sub>\/C2<\/sub>H4<\/sub>-H2<\/sub>O<\/strong>\u6bd4\u4f8b\u4e0b\u7684<\/strong>C4<\/strong>\u9009\u62e9\u6027\u3002<\/strong>b<\/strong>\uff09\u4e0d\u540c<\/strong>CO\/C2<\/sub>H4<\/sub>-H2<\/sub>O<\/strong>\u6bd4\u4f8b\u4e0b\u7684<\/strong>C4<\/strong>\u9009\u62e9\u6027\u3002<\/strong>c<\/strong>\uff09<\/strong>CO<\/strong>\u8986\u76d6\u5ea6\u4e3a<\/strong>0 ML<\/strong>\u548c<\/strong>1\/2 ML<\/strong>\u65f6<\/strong>C2<\/sub>H4<\/sub><\/strong>\u4e0e<\/strong>C4<\/sub>H10<\/sub><\/strong>\uff08\u5b9e\u7ebf\uff09\u548c<\/strong>C4<\/sub>H8<\/sub><\/strong>\uff08\u865a\u7ebf\uff09\u7684\u53cd\u5e94\u80fd\u91cf\u56fe\u3002<\/strong>\u00a9<\/strong> Springer Nature<\/strong><\/p>\n

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\u56fe<\/strong>3\u00a0 <\/strong>\u7ea7\u8054\u7cfb\u7edf\u751f\u4ea7<\/strong>C4<\/strong>\u3002<\/strong>a<\/strong>\uff09\u4ece<\/strong>CO2<\/sub>\/CO<\/strong>\u751f\u4ea7<\/strong>C4<\/strong>\u7684\u7ea7\u8054\u7cfb\u7edf\u793a\u610f\u56fe\u3002<\/strong>b<\/strong>\uff09<\/strong>100 mA<\/strong> cm-2<\/sup><\/strong>\u65f6<\/strong>eCO2<\/sub>RR<\/strong>\u548c<\/strong>eCORR<\/strong>\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u548c\u5355\u7a0b\u8f6c\u5316\u7387\u3002<\/strong> c<\/strong>\uff09\u4ece<\/strong>CO2<\/sub>\/CO<\/strong>\u751f\u4ea7<\/strong>C4<\/strong>\u7684\u4e8c\u805a\u548c\u7ea7\u8054\u9009\u62e9\u6027\u3002<\/strong>d<\/strong>\uff09\u4ece<\/strong>CO2<\/sub>\/CO<\/strong>\u751f\u4ea7<\/strong>C4<\/strong>\u7684\u539f\u6599\u6c14\u548c\u4ea7\u7269\u3002<\/strong>e<\/strong>\uff09<\/strong>eCO2<\/sub>RR<\/strong>\u548c<\/strong>eCORR<\/strong>\u4e2d<\/strong>CO<\/strong>\uff0c<\/strong>C2<\/sub>H4<\/sub><\/strong>\u548c<\/strong>H2<\/sub><\/strong>\u7684\u6bd4\u4f8b\u3002<\/strong>f<\/strong>\uff09\u4e24\u79cd\u7ea7\u8054\u7cfb\u7edf\u4e2d\uff08<\/strong>CO2<\/sub><\/strong>\u2192<\/strong>C4<\/strong>\uff0c<\/strong>CO<\/strong>\u2192<\/strong>C4<\/strong>\uff09<\/strong>C4<\/sub>H8<\/sub><\/strong>\u548c<\/strong>C4<\/sub>H10<\/sub><\/strong>\u7684\u76f8\u5bf9\u542b\u91cf\uff08\u76f8\u6bd4<\/strong>C2<\/sub>H4<\/sub><\/strong>\uff09\u3002<\/strong>\u00a9<\/strong> Springer Nature<\/strong><\/p>\n

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\u56fe<\/strong>4\u00a0 eCO-to-C4<\/strong>\u7ea7\u8054\u7cfb\u7edf\u7684\u6027\u80fd\u3002<\/strong>a<\/strong>\uff09\u4e0d\u540c<\/strong>CO<\/strong>\u6d41\u91cf\u4e0b\u7684<\/strong>C2<\/sub>H4<\/sub><\/strong>\u8f6c\u5316\u7387\u3002<\/strong>b<\/strong>\uff09\u4e0d\u540c<\/strong>CO<\/strong>\u6d41\u91cf\u4e0b\u7684\u7ea7\u8054\u9009\u62e9\u6027\u548c<\/strong>CO<\/strong>\u8f6c\u5316\u7387\u3002<\/strong>c<\/strong>\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u7ea7\u8054\u9009\u62e9\u6027\u548c\u7535\u6c60\u7535\u4f4d\u3002<\/strong>d<\/strong>\uff09<\/strong>40 h<\/strong>\u5185<\/strong>C4<\/sub>H10<\/sub><\/strong>\u7684\u7ea7\u8054\u9009\u62e9\u6027\u548c\u7535\u6c60\u7535\u4f4d\u3002<\/strong>e<\/strong>\uff09\u65b0\u9c9c\u50ac\u5316\u5242\u548c\u56de\u6536\u50ac\u5316\u5242\u7ea7\u8054\u9009\u62e9\u6027\u548c<\/strong>C2<\/sub>H4<\/sub><\/strong>\u8f6c\u5316\u7387\u7684\u6bd4\u8f83\u3002<\/strong>f<\/strong>\uff09<\/strong>eCO-to-C4<\/strong>\u7ea7\u8054\u7cfb\u7edf\u7684\u5faa\u73af\u6027\u80fd\u3002<\/strong>\u00a9<\/strong> Springer Nature<\/strong><\/p>\n

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\u56fe<\/strong>5\u00a0 C4<\/strong>\u751f\u4ea7\u7684\u78b3\u8db3\u8ff9\u548c\u80fd\u6e90\u6210\u672c\u8bc4\u4f30\u3002<\/strong>a<\/strong>\uff09\u80fd\u6e90\u6210\u672c\u8bc4\u4f30\u3002<\/strong>b<\/strong>\uff09\u78b3\u8db3\u8ff9\u8bc4\u4f30\u3002<\/strong>\u00a9<\/strong> Springer Nature<\/strong><\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u4f5c\u8005\u91c7\u7528<\/strong>CO2<\/sub>\/CO<\/strong>\u7535\u8fd8\u539f\u548c<\/strong>C2<\/sub>H4<\/sub><\/strong>\u4e8c\u805a\u53cd\u5e94\u76f8\u7ed3\u5408\u7684\u7ea7\u8054\u7cfb\u7edf\uff0c\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u9009\u62e9\u6027\u751f\u4ea7<\/strong>C4<\/strong>\u3002\u8be5\u7cfb\u7edf\u4f7f\u7528\u53ef\u518d\u751f\u7535\u529b\u9a71\u52a8<\/strong>CO2<\/sub><\/strong>\u8fd8\u539f\uff0c\u540c\u65f6\u964d\u4f4e\u4e86\u7cfb\u7edf\u7684\u5206\u79bb\u6210\u672c\uff0c\u8fd9\u4e3a\u7535\u529b\u9a71\u52a8\u7684<\/strong>CO2<\/sub><\/strong>\u8fd8\u539f\u6269\u5c55\u5230\u9ad8\u5206\u5b50\u91cf\u4ea7\u7269\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u9014\u5f84\u3002\u53e6\u5916\uff0c\u4ece\u7535\u5316\u5b66\u53cd\u5e94\u5668\u4e2d\u63d0\u53d6\u4ea7\u7269\u5e76\u76f4\u63a5\u5bf9\u5176\u8fdb\u884c\u5347\u7ea7\uff0c\u8fd9\u4e00\u6982\u5ff5\u5728\u7fb0\u57fa\u5316\u53cd\u5e94\uff08\u6c22\u7532\u9170\u5316\u3001\u70f7\u6c27\u7fb0\u5316\u548c\u6c28\u57fa\u7fb0\u5316\uff09\u4e2d\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u524d\u666f\u3002<\/strong><\/p>\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1ahttps:\/\/doi.org\/10.1038\/s41929-023-00937-0<\/p>\n

\u672c\u6587\u7531\u5e0c\u6069\u65af\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001 \u3010\u5bfc\u8bfb\u3011\u00a0 \u63a7\u5236\u4eba\u4e3a\u6e29\u5ba4\u6c14\u4f53\u6392\u653e\u662f\u5e94\u5bf9\u5168\u7403\u6c14\u5019\u53d8\u5316\u7684\u91cd\u8981\u624b\u6bb5\u3002CO2\u7535\u50ac\u5316\u8fd8\u539f\uff08eCO2RR\uff09\u4e3aCO2\u51cf\u6392\u548c\u53ef\u518d\u751f\u80fd\u6e90\u8f6c\u5316\u4e3a\u9ad8\u9644\u52a0\u503c\u71c3\u6599\u53ca\u7cbe\u7ec6\u5316\u5b66\u54c1\u63d0\u4f9b\u4e86…<\/p>\n","protected":false},"author":50320,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2,67],"tags":[1903,3118,2548,3431],"class_list":["post-250502","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","category-zhoubao","tag-nature","tag-3118","tag-2548","tag-co2"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250502"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/50320"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=250502"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250502\/revisions"}],"predecessor-version":[{"id":251132,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250502\/revisions\/251132"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=250502"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=250502"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=250502"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}