{"id":250491,"date":"2023-05-05T06:21:46","date_gmt":"2023-05-04T22:21:46","guid":{"rendered":"\/\/m.iemloyee.com\/?p=250491"},"modified":"2023-05-04T11:26:00","modified_gmt":"2023-05-04T03:26:00","slug":"%e8%a5%bf%e5%8d%97%e5%a4%a7%e5%ad%a6%e4%bd%95%e8%8d%a3%e5%b9%b8%e5%91%a8%e7%a3%8achem-sci-%ef%bc%9a%e4%ba%9a%e9%93%9c%e5%9f%ba%e5%8d%a4%e5%8c%96%e7%89%a9%e7%9a%84%e5%85%89%e7%89%a9%e7%90%86%e6%9c%ba","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=250491","title":{"rendered":"\u897f\u5357\u5927\u5b66\u4f55\u8363\u5e78&#038;\u5468\u78caChem. Sci.\uff1a\u4e9a\u94dc\u57fa\u5364\u5316\u7269\u7684\u5149\u7269\u7406\u673a\u5236\u53ca\u5355\u7ec4\u5206\u6696\u767d\u5149\u53d1\u5149\u4e8c\u6781\u7ba1\u7684\u5e94\u7528\u7814\u7a76"},"content":{"rendered":"<p>&nbsp;<\/p>\n<p>\u4e00\u3001\u5bfc\u8bfb<\/p>\n<p>&nbsp;<\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u94c5\u57fa\u5364\u5316\u7269\u9499\u949b\u77ff\u56e0\u5176\u4e30\u5bcc\u7684\u7ed3\u6784\u548c\u4f18\u5f02\u7684\u6027\u80fd\u800c\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u94c5\u7684\u56fa\u6709\u6bd2\u6027\u5bf9\u4eba\u4f53\u5065\u5eb7\u548c\u751f\u6001\u73af\u5883\u6784\u6210\u4e86\u4e25\u91cd\u7684\u5a01\u80c1\uff0c\u8fd9\u9650\u5236\u4e86\u94c5\u57fa\u5364\u5316\u7269\u9499\u949b\u77ff\u6750\u6599\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002\u4e3a\u89e3\u51b3Pb\u7684\u6bd2\u6027\u95ee\u9898\uff0c\u7814\u7a76\u8005\u4eec\u5c1d\u8bd5\u7528\u6bd2\u6027\u8f83\u4f4e\u6216\u65e0\u6bd2\u7684\u91d1\u5c5e\u9633\u79bb\u5b50\u6765\u4ee3\u66ff\u5364\u5316\u7269\u9499\u949b\u77ff\u6750\u6599\u4e2d\u7684\u94c5\uff0c\u4ece\u800c\u5f00\u53d1\u4e86\u591a\u79cd\u975e\u94c5\u6750\u6599\u3002<\/p>\n<p>\u5728\u4f17\u591a\u7684\u66ff\u4ee3\u8005\u4e2d\uff0c\u4e9a\u94dc\u57fa\u91d1\u5c5e\u5364\u5316\u7269\u6750\u6599\u56e0\u5176\u4ef7\u5ec9\u3001\u73af\u5883\u53cb\u597d\u548c\u4f18\u5f02\u7684\u5149\u5b66\u6027\u80fd\u800c\u53d1\u5c55\u8fc5\u901f\uff0c\u662f\u65b0\u4e00\u4ee3\u53d1\u5149\u6750\u6599\u7684\u4f18\u79c0\u5019\u9009\u8005\u4e4b\u4e00\u3002\u4f46\u94dc\u57fa\u5364\u5316\u7269\u6750\u6599\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u8fd8\u9762\u4e34\u4e00\u4e9b\u95ee\u9898\uff1a\uff081\uff09\u5927\u591a\u6570\u62a5\u9053\u7684\u5177\u6709\u9ad8PLQY\u7684Cu(\u2160)\u57fa\u5364\u5316\u7269\u662f\u84dd-\u7eff\u5149\u548c\u767d\u5149\u53d1\u5c04\u4f53\uff0c\u5177\u6709\u9ad8\u6548\u957f\u6ce2\u53d1\u5c04\u7684Cu(\u2160)\u57fa\u5364\u5316\u7269\u8fd8\u8f83\u5c11\u89c1\u4e8e\u62a5\u9053\uff1b\uff082\uff09\u5c11\u6570\u5177\u6709\u957f\u6ce2\u53d1\u5c04\u7684Cu(\u2160)\u57fa\u91d1\u5c5e\u5364\u5316\u7269\u88ab\u62a5\u9053\uff0c\u4f46\u5176\u901a\u5e38\u5177\u6709\u8f83\u7a84\u7684\u6fc0\u53d1\u5149\u8c31\uff0c\u96be\u4ee5\u6ee1\u8db3\u4e0d\u540c\u6fc0\u53d1\u6761\u4ef6\u7684\u8981\u6c42\u3002\u6b64\u5916\uff0c\u800c\u5bf9\u4e8e\u7167\u660e\u5e94\u7528\u6765\u8bf4\uff0c\u7531\u5177\u6709\u5bbd\u5e26\u53d1\u5c04\u7684\u5355\u7ec4\u5206\u6750\u6599\u6240\u5236\u5907\u7684\u767d\u5149\u53d1\u5149\u4e8c\u6781\u7ba1\uff08WLED\uff09\u5668\u4ef6\u6709\u5229\u4e8e\u7b80\u5316\u8bbe\u5907\u7ed3\u6784\uff0c\u80fd\u591f\u907f\u514d\u7531\u6df7\u5408\u591a\u79cd\u8367\u5149\u7c89\u6240\u5f15\u8d77\u7684\u81ea\u5438\u6536\u3001\u53d1\u5149\u989c\u8272\u53ca\u8367\u5149\u5bff\u547d\u4e0d\u7a33\u5b9a\u73b0\u8c61\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u4e8c\u3001\u6210\u679c\u63a0\u5f71<\/p>\n<p>&nbsp;<\/p>\n<p>\u8fd1\u65e5\uff0c\u897f\u5357\u5927\u5b66\u4f55\u8363\u5e78\u6559\u6388\uff08Rongxing He\uff09\u548c\u5468\u78ca\u526f\u6559\u6388\uff08Lei Zhou\uff09\u56e2\u961f\u7b49\u4eba\u65b0\u5f00\u53d1\u4e86\u4e00\u7c7b\u96f6\u7ef4\uff080D\uff09\u6709\u673a-\u65e0\u673a\u6742\u5316\u4e9a\u94dc\u5364\u5316\u7269DPCu<sub>4<\/sub>X<sub>6<\/sub>\u00a0[DP = (C<sub>6<\/sub>H<sub>10<\/sub>N<sub>2<\/sub>)<sub>4<\/sub>(H<sub>2<\/sub>PO<sub>2<\/sub>)<sub>6<\/sub>; X = Cl, Br, I]\u3002\u7ed3\u6784\u5206\u6790\u663e\u793a\uff0c\u5728\u8fd9\u4e09\u79cd\u5316\u5408\u7269\u4e2d\u6b21\u78f7\u9178\u6839\u901a\u8fc7\u6c22\u952e\u548c\u5bf9\u82ef\u4e8c\u80fa\u9633\u79bb\u5b50\u76f8\u8fde\u5f62\u6210\u6709\u673a\u5c42\uff0c\u7a7a\u95f4\u5b64\u7acb[Cu<sub>4<\/sub>X<sub>6<\/sub>]<sup>2-<\/sup>\u56e2\u7c07\u4ece\u800c\u5f62\u6210\u96f6\u7ef4\u7ed3\u6784\u3002\u4e09\u79cd\u6750\u6599\u90fd\u5177\u6709\u8d85\u5bbd\u7684\u6fc0\u53d1\u548c\u53d1\u5c04\u5e26\uff0c\u5149\u81f4\u53d1\u5149\u6548\u7387\u63a5\u8fd1100%\u3002\u5b9e\u9a8c\u8868\u5f81\u548c\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u6c2f\u5316\u7269\u548c\u6eb4\u5316\u7269\u7684\u660e\u4eae\u53d1\u5149\u6e90\u4e8eSTE\uff0c\u800c\u7898\u5316\u7269\u7684\u9ad8\u6548\u53d1\u5c04\u5219\u5f52\u56e0\u4e8e\u5364\u5316\u7269\/\u91d1\u5c5e\u5bf9\u914d\u4f53\u7535\u8377\u8f6c\u79fb\uff08X\/MLCT\uff09\u548c\u56e2\u7c07\u4e2d\u5fc3\uff08<sup>3<\/sup>CC\uff09\u6fc0\u53d1\u6001\u7684\u534f\u540c\u4f5c\u7528\u3002\u6b64\u5916\uff0c\u5f97\u76ca\u4e8eDPCu<sub>4<\/sub>I<sub>6<\/sub>\u4f18\u5f02\u7684\u5149\u5b66\u6027\u80fd\uff08\u5bbd\u6fc0\u53d1\u548c\u53d1\u5c04\u5e26\uff09\u548c\u8f83\u597d\u7684\u7a33\u5b9a\u6027\uff0c\u7814\u7a76\u8005\u4f7f\u7528\u5355\u7ec4\u5206DPCu<sub>4<\/sub>I<sub>6<\/sub>\u7c89\u672b\u6210\u529f\u5236\u9020\u4e86\u663e\u8272\u6307\u6570\uff08CRI\uff09\u9ad8\u8fbe85.1\u7684WLED\uff0c\u8bc1\u660e\u4e86\u8fd9\u4e9b\u65b0\u6750\u6599\u7684\u5b9e\u9645\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<p>\u76f8\u5173\u6210\u679c\u4ee5\u201cPhotophysical Studies for Cu(\u2160)-Based Halides: Broad Excitation Band and Highly Efficient Single-Component Warm White-Light-Emitting Diodes\u201d\u53d1\u8868\u5728Chemical Science\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250492\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u9898\u56fe.png\" alt=\"\" width=\"1091\" height=\"429\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u9898\u56fe.png 1091w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u9898\u56fe-300x118.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u9898\u56fe-768x302.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u9898\u56fe-1024x403.png 1024w\" sizes=\"(max-width: 1091px) 100vw, 1091px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u4e09\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li>\u4f5c\u8005\u901a\u8fc7\u5408\u7406\u9009\u62e9A\u4f4d\u6709\u673a\u9633\u79bb\u5b50\u548c\u4f18\u5316\u5408\u6210\u65b9\u6cd5\uff0c\u6210\u529f\u8bbe\u8ba1\u4e86\u4e00\u7c7b\u96f6\u7ef4\uff080D\uff09\u6709\u673a-\u65e0\u673a\u6742\u5316\u4e9a\u94dc\u5364\u5316\u7269\uff0c\u8fd9\u7c7b\u6750\u6599\u5177\u6709\u8d85\u5bbd\u7684PLE\/PL\u5149\u8c31\u4ee5\u53ca\u8fd1100%\u7684\u53d1\u5149\u6548\u7387\u3002<\/li>\n<li>\u4f5c\u8005\u901a\u8fc7\u5149\u8c31\u5206\u6790\u548c\u7406\u8bba\u8ba1\u7b97\u89e3\u91ca\u4e86\u7531\u4e8e\u5364\u7d20\u66ff\u6362\u9020\u6210\u7684\u5149\u7269\u7406\u673a\u5236\u7684\u8f6c\u53d8\u3002<\/li>\n<li>\u4f5c\u8005\u4f7f\u7528\u6240\u5408\u6210\u7684\u53d1\u5149\u6750\u6599\u6210\u529f\u5236\u9020\u4e86\u5355\u7ec4\u5206WLED\uff0c\u663e\u8272\u6307\u6570\uff08CRI\uff09\u53ef\u8fbe1\u3002<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p>\u56db\u3001\u6570\u636e\u6982\u89c8<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250493\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72471.png\" alt=\"\" width=\"1041\" height=\"717\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72471.png 1041w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72471-300x207.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72471-768x529.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72471-1024x705.png 1024w\" sizes=\"(max-width: 1041px) 100vw, 1041px\" \/><\/p>\n<p>\u56fe1. \u6cbf (a) <em><i>a<\/i><\/em>\u8f74\u548c (b) <em><i>b<\/i><\/em>\u8f74\u89c2\u5bdfDPCu<sub>4<\/sub>Cl<sub>6<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\uff08Cu\uff0c\u7d2b\u8272\uff1bCl\uff0c\u7c89\u8272\uff1bP\uff0c\u84dd\u8272\uff1bO\uff0c\u7ea2\u8272\uff1bC\uff0c\u68d5\u8272\uff1bN\uff0c\u9752\u8272\uff1bH\uff0c\u767d\u8272\uff09\u3002 (c) \u5355\u4e2a[Cu<sub>4<\/sub>Cl<sub>6<\/sub>]<sup>2-<\/sup>\u56e2\u7c07\u548c[C<sub>6<\/sub>H<sub>10<\/sub>N<sub>2<\/sub>]<sup>2+<\/sup>\u6709\u673a\u9633\u79bb\u5b50\u3002\u5176\u4e2d\u6bcf\u4e2a[C<sub>6<\/sub>H<sub>10<\/sub>N<sub>2<\/sub>]<sup>2+<\/sup>\u901a\u8fc7\u6c22\u952e\u4e0e\u516d\u4e2a[H<sub>2<\/sub>PO<sub>2<\/sub>]<sup>\uff0d<\/sup>\u9634\u79bb\u5b50\u76f8\u8fde\u3002 (d) DPCu<sub>4<\/sub>X<sub>6<\/sub>\u00a0(X = Cl, Br, I)\u7684PXRD\u548cSCXRD\u8c31\u56fe\u3002c2023 RSC<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250494\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72472.png\" alt=\"\" width=\"1270\" height=\"685\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72472.png 1270w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72472-300x162.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72472-768x414.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72472-1024x552.png 1024w\" sizes=\"(max-width: 1270px) 100vw, 1270px\" \/><\/p>\n<p>\u56fe2. DPCu<sub>4<\/sub>X<sub>6<\/sub>\u00a0(X = Cl, Br, I)\u5355\u6676\u5728 (a) 300 K\u548c (c) 80 K\u4e0b\u7684PLE\/PL\u5149\u8c31\u3002(b) DPCu<sub>4<\/sub>X<sub>6 <\/sub>(\u6c2f\u5316\u7269\uff1a\u7eff\u8272\uff1b\u6eb4\u5316\u7269\uff1a\u7ea2\u8272\uff1b\u7898\u5316\u7269\uff1a\u84dd\u8272)\u7684CIE\u5750\u6807\u3002(d) DPCu<sub>4<\/sub>X<sub>6<\/sub>\u00a0(X = Cl, Br)\u5355\u6676\u7684\u8870\u51cf\u5bff\u547d\u3002(e) DPCu<sub>4<\/sub>Cl<sub>6<\/sub>\u548c (f) DPCu<sub>4<\/sub>Br<sub>6<\/sub>\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684PL\u5149\u8c31\u3002c2023 RSC<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250495\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72473.png\" alt=\"\" width=\"1268\" height=\"742\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72473.png 1268w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72473-300x176.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72473-768x449.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72473-1024x599.png 1024w\" sizes=\"(max-width: 1268px) 100vw, 1268px\" \/><\/p>\n<p>\u56fe3. DPCu<sub>4<\/sub>I<sub>6<\/sub>\u5355\u6676\u5728\u5ba4\u6e29\u4e0b\u7684\u6fc0\u53d1\u548c\u53d1\u5c04\u6ce2\u957f\u76f8\u5173(a)PL\u548c(b)PLE\u5149\u8c31\u300280K\u65f6DPCu<sub>4<\/sub>I<sub>6<\/sub>\u00a0\u5355\u6676\u7684\u5f52\u4e00\u5316\u6fc0\u53d1\u548c\u53d1\u5c04\u6ce2\u957f\u76f8\u5173\u7684\u00a0(c) PL\u548c\u00a0(d) PLE\u5149\u8c31\u3002DPCu<sub>4<\/sub>I<sub>6<\/sub>\u5355\u6676\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u00a0(e) PLE\u548c\u00a0(f) PL \u5149\u8c31\u3002c2023 RSC<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250496\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72474.png\" alt=\"\" width=\"978\" height=\"781\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72474.png 978w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72474-300x240.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72474-768x613.png 768w\" sizes=\"(max-width: 978px) 100vw, 978px\" \/><\/p>\n<p>\u56fe4. (a) DPCu<sub>4<\/sub>Cl<sub>6<\/sub>\u548c (b) DPCu<sub>4<\/sub>I<sub>6<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\u3002(c) DPCu<sub>4<\/sub>Cl<sub>6<\/sub>\u548c(d) DPCu<sub>4<\/sub>I<sub>6<\/sub>\u7684\u6295\u5f71\u6001\u5bc6\u5ea6\u3002c2023 RSC<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250497\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72475.png\" alt=\"\" width=\"1269\" height=\"435\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72475.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72475-300x103.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72475-768x263.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72475-1024x351.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u56fe5. DPCu<sub>4<\/sub>Cl<sub>6 <\/sub>(a)\uff0cDPCu<sub>4<\/sub>Br<sub>6<\/sub>(b)\u548cDPCu<sub>4<\/sub>I<sub>6 <\/sub>(c)\u4e2d\u7684\u5149\u7269\u7406\u8fc7\u7a0b\u793a\u610f\u56fe\u3002c2023 RSC<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250498\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72476.png\" alt=\"\" width=\"939\" height=\"780\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72476.png 939w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72476-300x249.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/05\/\u56fe\u72476-768x638.png 768w\" sizes=\"(max-width: 939px) 100vw, 939px\" \/><\/p>\n<p>\u56fe6. (a) \u7528445 nm\u84dd\u5149\u82af\u7247\u6fc0\u53d1DPCu<sub>4<\/sub>I<sub>6<\/sub>\u7c89\u672b\u5236\u5907\u7684WLED\u5668\u4ef6\u7684\u53d1\u5149\u5149\u8c31\u3002\u63d2\u56fe\u5c55\u793a\u4e86WLED\u65ad\u7535(\u5de6)\u548c\u901a\u7535(\u53f3)\u7684\u7167\u7247\u3002 (b) WLED\u7684CIE\u5750\u6807\u3002 (c) \u9a71\u52a8\u7535\u6d41\u76f8\u5173\u7684\u7535\u81f4\u53d1\u5149\u5149\u8c31\u3002 (d) WLED\u572820 mA\u9a71\u52a8\u7535\u6d41\u4e0b\u6301\u7eed9\u5c0f\u65f6\u7684\u53d1\u5c04\u7a33\u5b9a\u6027\u3002\u63d2\u56fe\u663e\u793a\u4e86WLED\u5668\u4ef6\u5728\u4e0d\u540c\u65f6\u6bb5\u5de5\u4f5c\u65f6\u7684\u76f8\u5bf9\u53d1\u5149\u5f3a\u5ea6\u3002c2023 RSC<\/p>\n<p>&nbsp;<\/p>\n<p>\u4e94\u3001\u6210\u679c\u542f\u793a<\/p>\n<p>&nbsp;<\/p>\n<p>\u7efc\u4e0a\uff0c\u4f5c\u8005\u901a\u8fc7\u5408\u7406\u7684\u7ed3\u6784\u8bbe\u8ba1\uff0c\u6210\u529f\u5408\u6210\u4e86\u4e09\u79cd\u65b0\u578b\u96f6\u7ef4\u94dc\u57fa\u91d1\u5c5e\u5364\u5316\u7269DPCu<sub>4<\/sub>X<sub>6<\/sub>\uff08X=Cl\uff0cBr\uff0cI\uff09\u3002\u4e09\u79cd\u65b0\u5408\u6210\u7684\u5364\u5316\u7269\u5177\u6709\u7c7b\u4f3c\u7684\u7ed3\u6784\uff0c\u4f46\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u5149\u5b66\u6027\u8d28\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\u8868\u660e\uff0c\u5728DPCu<sub>4<\/sub>Cl<sub>6<\/sub>\u548cDPCu<sub>4<\/sub>Br<sub>6<\/sub>\u5355\u6676\u4e2d\uff0c\u72ec\u7279\u7684\u6676\u4f53\u7ed3\u6784\u548c\u5f3a\u70c8\u7684\u7535\u5b50-\u58f0\u5b50\u8026\u5408\u4fc3\u8fdb\u81ea\u9677\u6001\u7684\u5f62\u6210\uff0c\u4ece\u800c\u5bfc\u81f4\u4e86PLQY\u8fd1\u4e4e100%\u7684\u660e\u4eae\u7684\u9ec4\u8272\/\u6a59\u8272\u53d1\u5c04\u3002\u7531\u4e8e\u5364\u7d20\u66ff\u4ee3\u5f15\u8d77\u7684\u7ed3\u6784\u53d8\u5316\uff0cDPCu<sub>4<\/sub>I<sub>6<\/sub>\u5355\u6676\u5728\u4f4e\u6e29\u4e0b\u8868\u73b0\u51fa\u53cc\u5e26\u53d1\u5c04\uff0c\u8fd9\u5f52\u56e0\u4e8e<sup>3<\/sup>CC\u548cX\/MLCT\u6fc0\u53d1\u6001\u7684\u534f\u540c\u6548\u5e94\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u901a\u8fc7\u7ed3\u5408DPCu<sub>4<\/sub>I<sub>6<\/sub>\u7c89\u672b\u548c\u84dd\u5149\u82af\u7247\uff0c\u5236\u9020\u51fa\u4e86CRI\u53ef\u8fbe85.1\u7684\u5355\u7ec4\u5206WLED\uff0c\u663e\u793a\u4e86\u6240\u83b7\u65b0\u6750\u6599\u5728\u56fa\u4f53\u53d1\u5149\u5e94\u7528\u4e2d\u7684\u5de8\u5927\u6f5c\u529b\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5408\u7406\u8bbe\u8ba1\u5177\u6709\u5bbd\u6fc0\u53d1\/\u53d1\u5c04\u5e26\u7684\u91d1\u5c5e\u5364\u5316\u7269\u63d0\u4f9b\u4e86\u65b0\u7684\u89c1\u89e3\uff0c\u5bf9\u5f00\u53d1\u9ad8\u6027\u80fd\u53d1\u5149\u6750\u6599\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u539f\u6587\u8be6\u60c5\uff1aShuigen Zhou, Yihao Chen, Kailei Li, Xiaowei Liu, Ting Zhang, Wei Shen, Ming Li, Lei Zhou* and Rongxing He*,\u00a0Photophysical Studies for Cu(\u2160)-Based Halides: Broad Excitation Band and Highly Efficient Single-Component Warm White-Light-Emitting Diodes.<\/p>\n<p>https:\/\/doi.org\/10.1039\/D3SC01762A<\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; \u4e00\u3001\u5bfc\u8bfb &nbsp; \u8fd1\u5e74\u6765\uff0c\u94c5\u57fa\u5364\u5316\u7269\u9499\u949b\u77ff\u56e0\u5176\u4e30\u5bcc\u7684\u7ed3\u6784\u548c\u4f18\u5f02\u7684\u6027\u80fd\u800c\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u94c5\u7684\u56fa\u6709\u6bd2\u6027\u5bf9\u4eba\u4f53\u5065\u5eb7\u548c\u751f\u6001\u73af\u5883\u6784\u6210\u4e86\u4e25\u91cd&#8230;<\/p>\n","protected":false},"author":41672,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-250491","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250491"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/41672"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=250491"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250491\/revisions"}],"predecessor-version":[{"id":250499,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250491\/revisions\/250499"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=250491"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=250491"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=250491"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}