{"id":250482,"date":"2023-05-04T08:30:06","date_gmt":"2023-05-04T00:30:06","guid":{"rendered":"\/\/m.iemloyee.com\/?p=250482"},"modified":"2023-05-04T08:30:06","modified_gmt":"2023-05-04T00:30:06","slug":"%e5%8d%8e%e4%b8%ad%e7%a7%91%e5%a4%a7nature%ef%bc%9aco%e7%94%b5%e5%82%ac%e5%8c%96%e8%bf%98%e5%8e%9f%e5%88%b6%e5%a4%87%e4%b9%99%e9%85%b8%e7%9b%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=250482","title":{"rendered":"\u534e\u4e2d\u79d1\u5927Nature\uff1aCO\u7535\u50ac\u5316\u8fd8\u539f\u5236\u5907\u4e59\u9178\u76d0"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u4e59\u9178\u7684\u5e74\u4ea7\u91cf\u8d85\u8fc71800\u4e07\u5428\uff0c\u5e02\u573a\u4ef7\u503c\u63a5\u8fd110\u7f8e\u5143\u2009\u6bcf\u5e7410\u4ebf\u7f8e\u5143\u3002\u76f4\u63a5\u6c34\u76f8CO2<\/sub>\u7535\u8fd8\u539f\u5236\u5907\u4e59\u9178\u76d0\u8fbe\u5230\u4e8649%\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff08FE\uff09\uff0c\u4f46\u662f\u5177\u6709\u8f83\u5927\u7684\u80fd\u8017\u3002\u4e32\u8054\u4e8c\u6c27\u5316\u78b3\u7535\u8fd8\u539f\u53cd\u5e94\uff08CO2<\/sub>RR\uff09\u5df2\u7ecf\u663e\u793a\u51fa\u63d0\u9ad8\u7535\u538b\u548c\u4e59\u9178\u76d0\u76d0\u9009\u62e9\u6027\u7684\u6f5c\u529b\uff0c\u4f46\u4f53\u7cfb\u8fc7\u4e8e\u590d\u6742\u3002\u4eceCO\u5f00\u59cb\u51cf\u5c11\u4e86\u590d\u6742\u6027\uff0c\u56e0\u4e3a\u6bcf\u4e2aCO\u5206\u5b50\u6240\u9700\u7684\u7535\u5b50\u6570\u6bd4\u4eceCO2<\/sub>\u83b7\u5f97\u76f8\u540c\u7684\u4ea7\u7269\u5c11\u4e24\u4e2a\u3002\u5f53\u524d\u6700\u5148\u8fdb\u7684CO\u5230\u4e59\u9178\u76d0\u76d0\u7535\u8f6c\u5316\u6cd5\u5177\u6709\u4e0e\u76f4\u63a5CO2<\/sub>RR\u65b9\u6cd5\u76f8\u5f53\u7684FE\uff0c\u4f46\u5176\u5168\u7535\u6c60\u7535\u4f4d\u8981\u4f4e\u5f97\u591a\uff0c\u7ea6\u4e3a4 V\uff0c\u8868\u660e\u5177\u6709\u66f4\u4f4e\u7684\u6bcf\u5428\u4e59\u9178\u76d0\u94be\u603b\u80fd\u8017231GJ\u7684\u6f5c\u529b\u3002\u4e3a\u4e86\u7ecf\u6d4e\u53ef\u884c\u6027\uff0c\u4eba\u4eec\u7684\u76ee\u6807\u662f\u5728SOEC\u548cCO\u5230\u4e59\u9178\u76d0\u76d0\u53cd\u5e94\u5668\u4e4b\u95f4\u5b9e\u73b0\u76f8\u5f53\u9ad8\u7684FE\uff08>90%\uff09\u3002<\/p>\n

\u00a0<\/strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5e9e\u5143\u6770\u6559\u6388\u3001\u52a0\u62ff\u5927\u591a\u4f26\u591a\u5927\u5b66<\/strong>Edward H. Sargent<\/strong>\u9662\u58eb\u548c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u9ea6\u7acb\u5f3a\u6559\u6388\u7b49\u4eba<\/strong>\u5408\u6210\u4e86Cu-in-Ag\uff08Cu\u7ea6\u53601%\uff09\u5408\u91d1\u6750\u6599\uff08Cu\/Ag-DA\uff09\uff0c\u53d1\u73b0\u5728\u9ad8*<\/sup>CO\u6d53\u5ea6\uff0c10 atm\u538b\u529b\u4e0b\uff0c\u4eceCO\u7535\u5408\u6210\u4e59\u9178\u76d0\u5177\u6709\u9ad8\u5ea6\u9009\u62e9\u6027\u3002Operando X\u5c04\u7ebf\u5438\u6536\u5149\u8c31\u8868\u660e\uff0c\u539f\u4f4d\u4ea7\u751f\u7684\u94dc\u7c07\u7531\u5c0f\u4e8e4\u4e2a\u539f\u5b50\u4f5c\u4e3a\u6d3b\u6027\u4f4d\u70b9\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0c\u4e0e\u4e4b\u524d\u6700\u597d\u7684\u62a5\u9053\u76f8\u6bd4\uff0c\u5728\u4eceCO\u7535\u8fd8\u539f\u53cd\u5e94\u4e2d\u89c2\u5bdf\u5230\u7684\u6240\u6709\u5176\u4ed6\u4ea7\u7269\u4e2d\uff0c\u4e59\u9178\u7684\u9009\u62e9\u6027\u589e\u52a0\u4e86\u4e00\u4e2a\u6570\u91cf\u7ea7\u3002\u7ed3\u5408\u50ac\u5316\u5242\u8bbe\u8ba1\u548c\u53cd\u5e94\u5668\u5de5\u7a0b\uff0c\u7814\u7a76\u4eba\u5458\u5b9e\u73b0\u4e86CO-to-\u4e59\u9178\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a91%\uff0c\u5728\u8fde\u7eed\u5de5\u4f5c820h\u540e\uff0c\u6cd5\u62c9\u8fbe\u6548\u7387\u4ecd\u4e3a85%\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cConstrained C2<\/sub> adsorbate orientation enables CO-to-acetate electroreduction<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aNature<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>1\u00a0 CO-to-<\/strong>\u4e59\u9178\u76d0\u7535\u50ac\u5316\u5242\u8bbe\u8ba1<\/strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>2 \u00a0Cu\/Ag-DA<\/strong>\u7eb3\u7c73\u7c92\u7684\u7ed3\u6784\u5206\u6790<\/strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>3 \u00a0XAS<\/strong>\u5206\u6790<\/strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>4 \u00a0<\/strong>\u5728\u538b\u529b\u4e0b<\/strong>Cu\/Ag-DA<\/strong>\u6750\u6599\u7684<\/strong>CO<\/strong>\u7535\u8fd8\u539f<\/strong> \u00a9 2023 Springer Nature<\/strong><\/p>\n

\u56db\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u672c\u7814\u7a76\u5c06\u7406\u8bba\u6307\u5bfc\u7684\u50ac\u5316\u5242\u7b56\u7565\u548c\u53cd\u5e94\u5668\u8bbe\u8ba1\u7ed3\u5408\u8d77\u6765\uff0c\u4ee5\u8c03\u8282\u50ac\u5316\u5242\u7684\u5fae\u73af\u5883\u3002\u7814\u7a76\u4eba\u5458\u53d1\u73b0\uff0c\u5c06Cu\/Ag-DA\u50ac\u5316\u5242\u6750\u6599\u4e0e\u9ad8\u538bCO\u6c14\u4f53\u76f8\u7ed3\u5408\u4f1a\u5bfc\u81f4\u5bf9\u5355\u9f7f*<\/sup>C=C=O\u5438\u9644\u7269\u7684\u504f\u597d\uff0c\u4ece\u800c\u5728\u9ad8*<\/sup>CO\u6d53\u5ea6\u4e0b\u9009\u62e9\u6027\u5730\u751f\u6210\u4e59\u9178\uff0c\u5bfc\u81f4\u751f\u6210\u4e59\u9178\u7684FE\u8fbe\u523091%\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1aConstrained C2<\/sub> adsorbate orientation enables CO-to-acetate electroreduction<\/a> (Nature<\/em>, 2023<\/strong>, DOI: 10.1038\/s41586-023-05918-8)<\/p>\n

\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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