{"id":250434,"date":"2023-05-02T06:14:03","date_gmt":"2023-05-01T22:14:03","guid":{"rendered":"\/\/m.iemloyee.com\/?p=250434"},"modified":"2023-04-27T15:16:38","modified_gmt":"2023-04-27T07:16:38","slug":"afm%ef%bc%9a%e6%8f%90%e9%ab%98%e5%9f%ba%e4%ba%8e%e5%8d%95%e5%b1%82%e5%88%86%e5%ad%90%e4%bf%ae%e9%a5%b0%e7%9a%84%e5%ae%bd%e5%b8%a6%e9%9a%99%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=250434","title":{"rendered":"AFM\uff1a\u63d0\u9ad8\u57fa\u4e8e\u5355\u5c42\u5206\u5b50\u4fee\u9970\u7684\u5bbd\u5e26\u9699\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u5e76\u83b7\u5f97\u8d85\u8fc725%\u7684\u5168\u9499\u949b\u77ff\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"<p>&nbsp;<\/p>\n<p>\u6709\u673a-\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60 (PSC) \u7684\u529f\u7387\u8f6c\u6362\u6548\u7387 (PCE) \u5df2\u8fbe\u5230 25.7%\u3002\u56e0\u6b64\u88ab\u8ba4\u4e3a\u662f\u4e0b\u4e00\u4ee3\u5149\u4f0f\u5e02\u573a\u7684\u4e3b\u5bfc\u8005\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5df2\u7ecf\u62a5\u9053\u4e86\u5e26\u9699\u5728 1.2 \u548c 2.3 eV \u4e4b\u95f4\u7684 PSCs\u3002\u867d\u7136\u5177\u6709\u7a84\u5e26\u9699\u503c\u7684\u5355\u7ed3 PSCs \u81ea 2014 \u5e74\u4ee5\u6765\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u7136\u800c\u4f5c\u4e3a\u9499\u949b\u77ff\u6750\u6599\u7684\u4e00\u5458\uff0c\u5bbd\u5e26\u9699\u9499\u949b\u77ff (WBG-PVK) \u4e5f\u4e0d\u5bb9\u5ffd\u89c6\uff0c\u56e0\u4e3a\u5b83\u5bf9\u4e8e\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u5f88\u91cd\u8981\u3002\u622a\u81f3\u76ee\u524d\uff0c\u9499\u949b\u77ff\/\u9499\u949b\u77ff\u4e32\u8054\u7684\u6548\u7387\u5df2\u8fbe\u523028%\u3002\u4e3a\u4e86\u63d0\u9ad8\u4e32\u8054\u7535\u6c60\u7684\u6548\u7387\uff0c\u5fc5\u987b\u63d0\u9ad8\u9876\u90e8\u548c\u5e95\u90e8\u7535\u6c60\u7684\u6548\u7387\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u65e5\u672c\u56fd\u7acb\u7535\u6c14\u901a\u4fe1\u5927\u5b66\u6c88\u9752\u6559\u6388 \uff08Qing Shen\uff09\u548c\u65e9\u702c\u4fee\u4e8c\u6559\u6388 \uff08Shuzi Hayase\uff09\u56e2\u961f\u5728Advanced Functional Materials\u4e0a\u53d1\u8868\u4e86\u9898\u76ee\u4e3a \u201cPerovskite Solar Cells Consisting of PTAA Modified with Monomolecular Layer and Application to All-Perovskite Tandem Solar Cells with Efficiency over 25%\u201d \u7684\u7814\u7a76\u6587\u7ae0\uff0c\u8be5\u6587\u7ae0\u62a5\u9053\u4e86\u4f7f\u7528\u4e00\u7cfb\u5217\u5177\u6709\u4e0d\u540c\u70f7\u57fa\u94fe\u957f\u5ea6\u7684\u5355\u5206\u5b50\u5c42\u6765\u4fee\u9970PTAA\u7a7a\u7a74\u4f20\u8f93\u5c42\uff0c\u63d0\u9ad8\u4e86\u57fa\u4e8ePTAA\u7684\u5bbd\u5e26\u9699\uff081.77eV\uff09\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u3002\u540c\u65f6\uff0c\u76f8\u5e94\u7684\u5168\u9499\u949b\u77ff\u53e0\u5c42\u7535\u6c60\u4e5f\u53d6\u5f97\u4e8625.24%\u7684\u6548\u7387\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250435\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u9898\u56fe-14.png\" alt=\"\" width=\"726\" height=\"391\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u9898\u56fe-14.png 726w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u9898\u56fe-14-300x162.png 300w\" sizes=\"(max-width: 726px) 100vw, 726px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250436\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe1-1.png\" alt=\"\" width=\"689\" height=\"365\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe1-1.png 689w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe1-1-300x159.png 300w\" sizes=\"(max-width: 689px) 100vw, 689px\" \/><\/p>\n<p>\u56fe 1. a) \u7528\u4e8e\u8868\u9762\u6539\u6027\u7684\u5668\u4ef6\u7ed3\u6784\u548c\u5206\u5b50\u7ed3\u6784\u4ee5\u53ca\u5355\u5206\u5b50\u7684\u5316\u5b66\u7ed3\u6784\u3002 b) PTAA \u548c 4,3BuPACz \u4e4b\u95f4\u7684\u5316\u5b66\u76f8\u4e92\u4f5c\u7528\u793a\u610f\u56fe\u3002 c) \u5728\u7528\u5355\u5206\u5b50\u5c42\u4fee\u9970\u7684 PTAA \u4e0a\u751f\u957f\u7684 WBG \u9499\u949b\u77ff\u7684\u6676\u7c92\u5c3a\u5bf8\u5206\u5e03\u3002 d) \u5728\u7528\u5355\u5206\u5b50\u5c42\u4fee\u9970\u7684 PTAA \u4e0a\u751f\u957f\u7684 WBG \u9499\u949b\u77ff\u7684\u6676\u683c\u5e94\u53d8\u3002e) \u5728\u7528\u5355\u5206\u5b50\u5c42\u4fee\u9970\u7684 PTAA \u4e0a\u751f\u957f\u7684 WBG \u9499\u949b\u77ff\u7684 Urbach \u80fd\u91cf\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250437\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-39.png\" alt=\"\" width=\"915\" height=\"470\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-39.png 915w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-39-300x154.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-39-768x394.png 768w\" sizes=\"(max-width: 915px) 100vw, 915px\" \/><\/p>\n<p>\u56fe 2.\u5728 PTAA\uff0cPTAA\/3,3PrPACz\uff0cPTAA\/4,3BuPACz \u548c PTAA\/6,3HePACz\u57fa\u5e95\u4e0a\u5236\u9020\u7684PSC \u7684a) PCE \u7edf\u8ba1\u5206\u5e03\u56fe\uff0cb) J-V \u66f2\u7ebf\uff0c c) IPCE \u66f2\u7ebf\u548c\u00a0d)\u7a33\u6001\u6548\u7387\u968f\u65f6\u95f4\u7684\u53d8\u5316\u3002 e) \u5728 PTAA \u548c\u7528 4,3BuPACz \u6539\u6027\u7684 PTAA \u4e0a\u5236\u9020\u7684 PSC \u5728\u5ba4\u6e29\u4e0b\u50a8\u5b58\u5728\u5145\u6ee1\u6c2e\u6c14\u7684\u624b\u5957\u7bb1\uff08\u65e0\u5c01\u88c5\uff09\u4e2d\u7684 N2 \u7a33\u5b9a\u6027\u3002f) \u5728 PTAA \u548c\u7528 4,3BuPACz \u6539\u6027\u7684 PTAA \u4e0a\u5236\u9020\u7684\u672a\u5c01\u88c5 PSC \u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u5728\u9ed1\u6697\u4e2d\u4fdd\u6301\u5728 85 \u2103 \u7684\u6c2e\u6c14\u624b\u5957\u7bb1\u4e2d\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250438\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe3.png\" alt=\"\" width=\"665\" height=\"500\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe3.png 665w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe3-300x226.png 300w\" sizes=\"(max-width: 665px) 100vw, 665px\" \/><\/p>\n<p>\u56fe 3. a) \u5728 PTAA\uff0cPTAA\/3,3PrPACz\uff0cPTAA\/4,3BuPACz \u548c PTAA\/6,3HePACz\u57fa\u5e95\u4e0a\u5236\u9020\u7684PSC \u7684 <em><i>V<\/i><\/em><sub>OC<\/sub>\u00a0\u4e0e\u5149\u5f3a\u5ea6\u7684\u5173\u7cfb\uff0cb) TPV \u8870\u51cf\u66f2\u7ebf\u548c c) TPC \u8870\u51cf\u66f2\u7ebf\u3002 d) \u5668\u4ef6\u7684\u80fd\u5e26\u6392\u5e03\u793a\u610f\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250439\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-30.png\" alt=\"\" width=\"2642\" height=\"784\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-30.png 2642w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-30-300x89.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-30-768x228.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-30-1024x304.png 1024w\" sizes=\"(max-width: 2642px) 100vw, 2642px\" \/><\/p>\n<p>\u56fe4 a) \u5168\u9499\u949b\u77ff\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u7684\u7ed3\u6784\u3002 b) \u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u7684 J-V \u66f2\u7ebf\u548c c) IPCE \u66f2\u7ebf\u3002<\/p>\n<p>\u603b\u4e4b\uff0c\u4f5c\u8005\u5408\u6210\u4e86\u51e0\u79cd\u65b0\u7684\u5355\u5c42\u5206\u5b50\uff083,3PrPACz\u30014,3BuPACz \u548c 6,3HePACz\uff09\uff0c\u5e76\u8bc4\u4f30\u4e86\u5176\u4f5c\u4e3a PTAA \u4fee\u9970\u5c42\u7684\u6548\u679c\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5177\u6709\u56db\u4e2a\u78b3\u4f5c\u4e3a\u95f4\u9694\u57fa\u56e2\u7684 \u5355\u5c42\u5206\u5b50\u7ed9\u51fa\u4e86\u6700\u597d\u7684\u7ed3\u679c\u3002 \u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u5f15\u51654,3BuPACz\u540e\uff0c\u9499\u949b\u77ff\u8584\u819c\u7684\u8d28\u91cf\uff08\u6676\u7c92\u5c3a\u5bf8\u548c\u9488\u5b54\u5bc6\u5ea6\uff09\u6709\u660e\u663e\u6539\u5584\u3002\u5355\u5c42\u5206\u5b50\u7684\u5f15\u5165\u51cf\u5c11\u4e86\u5668\u4ef6\u4e2d\u7684\u975e\u8f90\u5c04\u590d\u5408\uff0c\u964d\u4f4e\u4e86\u9499\u949b\u77ff\u548c HTL \u4e4b\u95f4\u7684\u80fd\u5e26\u5dee\u8ddd\uff0c\u4fc3\u8fdb\u4e86 HTL \u7684\u7535\u8377\u6536\u96c6\u3002 \u6700\u540e\uff0c\u57fa\u4e8e4,3BuPACz \u4fee\u9970\u7684 PSC \u5b9e\u73b0\u4e86 16.57% \u7684PCE\uff0c\u540c\u65f6\u4e32\u8054\u592a\u9633\u80fd\u7535\u6c60\u7684 PCE \u4e3a 25.24%\u3002 \u8fd9\u9879\u5de5\u4f5c\u8868\u660e\uff0c\u7528 \u5355\u5206\u5b50\u5c42\u4fee\u9970PTAA \u53ef\u4ee5\u63d0\u9ad8\u5bbd\u5e26\u9699\u7684 Pb-PSC\u7684\u6548\u7387\u3002<\/p>\n<p>\u76f8\u5173\u8bba\u6587\u53d1\u8868\u5728 Advanced Functional Materials\u4e0a\uff0c\u65e5\u672c\u56fd\u7acb\u7535\u6c14\u901a\u4fe1\u5927\u5b66\u535a\u58eb\u751f\u6bd5\u6b22(ORCID: 0000-0001-7680-9816)\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff0c\u65e9\u702c\u4fee\u4e8c\u6559\u6388\u548c\u6c88\u9752\u6559\u6388(ORCID: 0000-0001-8359-3275)\u4e3a\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n<p><u>\u6587\u732e\u94fe\u63a5<\/u><\/p>\n<p>Citation: Bi, H., Fujiwara, Y., Kapil, G., Tavgeniene, D., Zhang, Z., Wang, L., Ding, C., Sahamir, S. R., Baranwal, A. K., Sanehira, Y., Takeshi, K., Shi, G., Bessho, T., Segawa, H., Grigalevicius, S., Shen, Q., Hayase, S., Perovskite Solar Cells Consisting of PTAA Modified with Monomolecular Layer and Application to All-Perovskite Tandem Solar Cells with Efficiency over 25%. Adv. Funct. Mater. 2023, 2300089. https:\/\/doi.org\/10.1002\/adfm.202300089<\/p>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; \u6709\u673a-\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60 (PSC) \u7684\u529f\u7387\u8f6c\u6362\u6548\u7387 (PCE) \u5df2\u8fbe\u5230 25.7%\u3002\u56e0\u6b64\u88ab\u8ba4\u4e3a\u662f\u4e0b\u4e00\u4ee3\u5149\u4f0f\u5e02\u573a\u7684\u4e3b\u5bfc\u8005\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5df2\u7ecf\u62a5\u9053\u4e86\u5e26&#8230;<\/p>\n","protected":false},"author":41672,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-250434","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250434"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/41672"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=250434"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250434\/revisions"}],"predecessor-version":[{"id":250440,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250434\/revisions\/250440"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=250434"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=250434"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=250434"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}