{"id":250387,"date":"2023-05-15T06:06:34","date_gmt":"2023-05-14T22:06:34","guid":{"rendered":"\/\/m.iemloyee.com\/?p=250387"},"modified":"2023-05-12T14:06:45","modified_gmt":"2023-05-12T06:06:45","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2aem%e7%ba%a6%e6%9d%9f%e5%9c%a8%e6%8b%93%e6%89%91%e7%a2%b3%e7%bc%ba%e9%99%b7%e4%b8%ad%e7%9a%84%e8%b6%85%e7%bb%86fe2c%e7%ba%b3%e7%b1%b3%e5%9b%a2%e7%b0%87%e7%94%a8%e4%ba%8e","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=250387","title":{"rendered":"\u4e2d\u79d1\u9662AEM:\u7ea6\u675f\u5728\u62d3\u6251\u78b3\u7f3a\u9677\u4e2d\u7684\u8d85\u7ec6Fe2C\u7eb3\u7c73\u56e2\u7c07\u7528\u4e8e\u9ad8\u6548\u7535\u8fd8\u539f\u4e8c\u6c27\u5316\u78b3"},"content":{"rendered":"<p style=\"text-align: center;\"><span style=\"color: #0000ff;\"><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n<p>\u00a0 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style=\"text-align: center;\"><span style=\"color: #0000ff;\"><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/span><\/p>\n<p><strong>\u00a0 <\/strong>\u00a0<span style=\"color: #000000;\">\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u5b81\u6ce2\u6750\u6599\u6240\u9648\u4eae\u56e2\u961f\u91c7\u7528\u53cc\u91cd<\/span><span style=\"color: #000000;\">N-\u6d88\u9664\u7b56\u7565\u6765\u5408\u6210\u548c\u7a33\u5b9a\u5f88\u5c11\u62a5\u9053\u7684Fe<sub>2<\/sub>C\u7eb3\u7c73\u56e2\u7c07\uff08Fe<sub>2<\/sub>C-Cs@DC\uff09\uff0c\u5176\u5e73\u5747\u76f4\u5f84\u4e3a1.07 nm\uff0c\u88ab\u7ea6\u675f\u5728\u62d3\u6251\u78b3\u7f3a\u9677\u4e2d\u3002Fe<sub>2<\/sub>C-Cs@DC\u5728\u7535\u50ac\u5316CO<sub>2<\/sub>\u00a0RR\u4e0a\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong><em>Ultrafine Fe<sub>2<\/sub>C Iron Carbide Nanoclusters Trapped in Topological Carbon Defects for Efficient Electroreduction of Carbon Dioxide<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728<strong><em>Advanced Energy Materials<\/em><\/strong>\u4e0a\u3002<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250388\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/0-19.png\" alt=\"\" width=\"977\" height=\"330\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/0-19.png 977w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/0-19-300x101.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/0-19-768x259.png 768w\" sizes=\"(max-width: 977px) 100vw, 977px\" \/><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #0000ff;\"><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/span><\/p>\n<p><strong>\u00a0 \u00a01\u3001\u4f5c\u8005\u53d7\u5230\u53ccN\u6d88\u9664\u7b56\u7565\u7684\u542f\u53d1\uff0c\u6210\u529f\u5728\u7f3a\u9677\u78b3\u4e2d\u5408\u6210\u51fa\u8d85\u7ec6Fe<sub>2<\/sub>C\u7eb3\u7c73\u56e2\u7c07\u3002\u7531\u4e8e\u62d3\u6251\u78b3\u7f3a\u9677\u7684\u5b58\u5728\uff0c\u5f97\u5230\u7684Fe<sub>2<\/sub>C\u8d85\u7ec6\u56e2\u7c07\u7a33\u5b9a\u4e14\u5206\u5e03\u5747\u5300\u3002 \u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c Fe<sub>2<\/sub>C-Cs@DC\u53ef\u4ee5\u9a71\u52a88.53 mA cm<sup>-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u5728-0.7 V vs RHE\u4e0b\u4ea7\u751fCO\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a97.1%\u3002<\/strong><\/p>\n<p><strong>\u00a0 \u00a02\u3001DFT\u8ba1\u7b97\u8868\u660e\uff0c\u7eb3\u7c73Fe<sub>2<\/sub>C\u56e2\u7c07\u4e0eCO\u7684\u7ed3\u5408\u6bd4Fe\u7ed3\u6676\u8868\u9762\u4ee5\u53ca\u5176\u4ed6\u94c1\u78b3\u5316\u7269\u5f31\u5f97\u591a\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86CO\u89e3\u5438\u548c\u6574\u4e2aCO<sub>2<\/sub>RR\u8fc7\u7a0b\u3002<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #0000ff;\"><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250389\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/1-26.png\" alt=\"\" width=\"500\" height=\"331\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/1-26.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/1-26-300x199.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1 <\/strong>a) Fe<sub>2<\/sub>C-Cs@DC\u4f4e\u500dTEM\u7167\u7247\u3002b) Fe<sub>2<\/sub>C-Cs@DC\u5728\u9ad8\u500d\u653e\u5927\u4e0b\u7684TEM\u56fe\u50cf\u3002c) \u6839\u636e (b) \u7684\u76f8\u5e94\u7c92\u5ea6\u5206\u5e03\u3002d) Fe<sub>2<\/sub>C-Cs@DC\u4e2d\u7684Fe \u7c07\u7531\u7ea2\u8272\u5706\u5708\u663e\u793a\u3002(e) Fe<sub>2<\/sub>C-Cs@DC\u4e2d\u78b3\u7684 HRTEM \u56fe\u50cf\u3002(f) Fe<sub>2<\/sub>C-Cs@DC\u4e2d\u7684C\u3001N \u548c Fe\u5143\u7d20\u7684EDX\u56fe\u3002<strong>\u00a9 2023 Wiley<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250390\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/2-23.png\" alt=\"\" width=\"500\" height=\"377\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/2-23.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/2-23-300x226.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2<\/strong> a) Fe<sub>2<\/sub>C-Cs@DC\u548cFeN-Cs@NC\u7684XRD\u56fe\u3002b) Fe<sub>2<\/sub>C-Cs@DC\u548cFeN-Cs@NC\u7684N1s\u7684XPS\u5149\u8c31\u3002c) Fe<sub>2<\/sub>C-Cs@DC\u3001FeN-Cs@NC\u00a0\u3001Fe\u7b94\u548cFeOOH\u7684Fe K-edge XANES\u5149\u8c31\u3002(d) Fe<sub>2<\/sub>C-Cs@DC\u00a0\u3001FeN-Cs@NC\u548cFe\u7b94\u7684k3-weighted\u00a0EXAFS\u7684\u5085\u7acb\u53f6\u53d8\u6362\u5149\u8c31\u3002<strong>\u00a9 2023 Wiley<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250391\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/3-23.png\" alt=\"\" width=\"500\" height=\"255\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/3-23.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/3-23-300x153.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3 <\/strong>a) Fe<sub>2<\/sub>C-Cs@DC\u5728CO<sub>2<\/sub>\u9971\u548c\uff08\u5b9e\u7ebf\uff09\u548cAr\u9971\u548c\uff08\u865a\u7ebf\uff09\u76840.1 M KHCO<sub>3<\/sub>\u6c34\u6eb6\u6db2\u4e2d\u7684LSV\u3002b) CO\uff08\u7070\u8272\uff09\u548cH<sub>2<\/sub>\uff08\u7ea2\u8272\uff09\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u4ee5\u53caCO\u5728\u4e00\u5b9a\u8303\u56f4\u7684\u65bd\u52a0\u7535\u52bf\u4e0b\u7684\u90e8\u5206\u7535\u6d41\u3002c\uff09\u5728\u4e0d\u540c\u5e94\u7528\u7535\u4f4d\u4e0b\uff0c\u5404\u79cd\u50ac\u5316\u5242\u7684CO\u6cd5\u62c9\u7b2c\u6548\u7387\u3002d\uff09\u5728\u4e0d\u540c\u65bd\u52a0\u7535\u4f4d\u4e0b\uff0c\u5404\u79cd\u50ac\u5316\u5242\u7684CO\u90e8\u5206\u7535\u6d41\u5bc6\u5ea6\u3002e) Fe<sub>2<\/sub>C-Cs@DC\u548cFeN-Cs@NC\u5728 0.1 M KHCO<sub>3<\/sub>\u6c34\u6eb6\u6db2\u4e2dCO\u90e8\u5206\u7535\u6d41\u5bc6\u5ea6\u7684\u5854\u83f2\u5c14\u56fe\u3002f)\u00a0Fe<sub>2<\/sub>C-Cs@DC\u5728-0.7 V vs RHE\u7535\u4f4d\u4e0b24 h\u7684CO<sub>2<\/sub>RR\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<strong>\u00a9 2023 Wiley<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-250392\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/4-24.png\" alt=\"\" width=\"500\" height=\"320\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/4-24.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/4-24-300x192.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4<\/strong> a) \u4e24\u79cd\u4e0d\u540c\u89c2\u70b9\u4e0b\u7814\u7a76\u7684\u7c07\u6a21\u578b\u3002\u4e24\u4e2a\u6f5c\u5728\u7684\u53cd\u5e94\u4f4d\u70b9\u4ee5\u5706\u5708\u7a81\u51fa\u663e\u793a\u3002b) CO<sub>2<\/sub>RR\u8fc7\u7a0b\u5728\u5404\u79cd\u542b\u94c1\u6a21\u578b\u4e0a\u7684\u81ea\u7531\u80fd\u5206\u5e03\u3002c) \u5404\u79cdFe \u53cd\u5e94\u4f4d\u70b9\u7684d\u5e26\u4e2d\u5fc3\u3002d\uff09\u5404\u79cd\u53cd\u5e94\u4f4d\u70b9\u7684\u89e3\u5438\u80fd\u548cd\u5e26\u4e2d\u5fc3\u3002e) Fe\u5468\u56f4\u5404\u79cdC\u539f\u5b50\u7684p\u5e26\u4e2d\u5fc3\u3002<strong>\u00a9 2023 Wiley<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><span style=\"color: #0000ff;\"><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/span><\/p>\n<p><strong>\u00a0 \u00a0\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u6210\u529f\u5730\u5728\u78b3\u57fa\u6750\u6599\u4e0a\u5236\u5907\u51fa\u5e73\u5747\u5c3a\u5bf8\u4e3a1.07 nm\u3001\u53d7\u62d3\u6251\u78b3\u7f3a\u9677\u5f3a\u914d\u4f4d\u7ea6\u675f\u7684Fe<sub>2<\/sub>C\u7eb3\u7c73\u56e2\u7c07\u3002Fe<sub>2<\/sub>C-Cs@DC\u5177\u6709\u9ad8\u6548\u7684\u5b9a\u5411\u9009\u62e9\u6027\uff0c\u6709\u671b\u8fdb\u4e00\u6b65\u4fc3\u8fdb\u94c1\u57fa\u6750\u6599\u5728CO<sub>2<\/sub>RR\u9886\u57df\u7684\u7814\u53d1\u548c\u5e94\u7528\u3002\u53e6\u5916\uff0c\u8fd9\u9879\u7814\u7a76\u4e5f\u4e3a\u5176\u4ed6\u76f8\u5173\u9886\u57df\u5408\u7406\u8bbe\u8ba1\u8fc7\u6e21\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\u7684\u7ed3\u6784\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u7eb3\u7c73\u56e2\u7c07\u7b56\u7565\u3002<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5\uff1a<\/strong><a href=\"https:\/\/doi.org\/10.1002\/aenm.202204391\">https:\/\/doi.org\/10.1002\/aenm.202204391<\/a><\/p>\n<p>\u672c\u6587\u7531K . L\u64b0\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u00a0 \u00a0\u8fd1\u5e74\u6765\uff0c\u7531\u53ef\u518d\u751f\u80fd\u6e90\u9a71\u52a8\u7684\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94\uff08CO2RR\uff09\u53ef\u4ee5\u901a\u8fc7\u6355\u83b7\u548c\u5206\u79bb\u5927\u6c14\u4e2d\u7684\u4e8c\u6c27\u5316\u78b3\u751f\u4ea7\u589e\u503c\u5316\u5b66\u54c1\uff0c\u4ece\u800c\u7f13\u89e3\u6c61\u67d3\u6c14\u4f53\u5bf9\u6c14\u5019\u7684\u5371\u5bb3&#8230;<\/p>\n","protected":false},"author":48789,"featured_media":250388,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[5053],"class_list":["post-250387","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-5053"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250387"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/48789"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=250387"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250387\/revisions"}],"predecessor-version":[{"id":250870,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/250387\/revisions\/250870"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/250388"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=250387"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=250387"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=250387"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}