{"id":250368,"date":"2023-04-30T05:55:10","date_gmt":"2023-04-29T21:55:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=250368"},"modified":"2023-04-26T10:58:16","modified_gmt":"2023-04-26T02:58:16","slug":"%e6%97%a5%e6%9c%ac%e4%ba%ac%e9%83%bd%e5%a4%a7%e5%ad%a6jacs%ef%bc%9a%e4%b8%80%e7%a7%8d%e5%8f%af%e6%ba%b6%e6%80%a7%e9%87%91%e5%b1%9e-%e6%9c%89%e6%9c%ba%e7%ba%b3%e7%b1%b3%e7%ae%a1%e5%8f%8a%e5%85%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=250368","title":{"rendered":"\u65e5\u672c\u4eac\u90fd\u5927\u5b66JACS\uff1a\u4e00\u79cd\u53ef\u6eb6\u6027\u91d1\u5c5e-\u6709\u673a\u7eb3\u7c73\u7ba1\u53ca\u5176\u81ea\u7ec4\u88c5\u6676\u675f"},"content":{"rendered":"<p><strong>\u80cc\u666f\u4ecb\u7ecd\uff1a<\/strong><\/p>\n<p>\u7eb3\u7c73\u7ba1\u6750\u6599\u56e0\u5176\u72ec\u7279\u7535\u5b66\u548c\u7eb3\u7c73\u6d41\u4f53\u4f20\u8f93\u7b49\u7279\u6027\u800c\u5907\u53d7\u5173\u6ce8\u3002\u78b3\u7eb3\u7c73\u7ba1(CNTs)\u7684\u53d1\u73b0\u542f\u53d1\u4e86\u5404\u79cd\u6709\u673a\u548c\u65e0\u673a\u7eb3\u7c73\u7ba1\u7684\u5f00\u53d1\u3002\u7136\u800c\uff0c\u5927\u591a\u6570\u5173\u4e8e\u7eb3\u7c73\u7ba1\u7684\u7814\u7a76\u5c40\u9650\u4e8e\u805a\u96c6\u7684\u56fa\u6001\u800c\u4e0d\u662f\u6eb6\u6db2\u72b6\u6001\uff0c\u8fd9\u96be\u4ee5\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\u63a2\u7d22\u7eb3\u7c73\u7ba1\u7684\u7269\u7406\u548c\u5316\u5b66\u884c\u4e3a\u3002 \u6b64\u5916\uff0c\u9274\u4e8e\u8584\u819c\u5236\u5907\u53ca\u5176\u5e94\u7528\uff0c\u4e5f\u975e\u5e38\u9700\u8981\u5f97\u5230\u6eb6\u6db2\u72b6\u6001\u7684\u7eb3\u7c73\u7ba1\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u5185\u5728\u7684\u5f3a\u8303\u5fb7\u534e\u76f8\u4e92\u4f5c\u7528\u503e\u5411\u4e8e\u5236\u5907\u5f97\u5230\u7684\u7eb3\u7c73\u7ba1\u4ee5\u7d27\u5bc6\u5806\u53e0\u6216\u7f20\u7ed3\u7684\u5f62\u5f0f\u5b58\u5728\uff0c\u4f7f\u5b83\u4eec\u4e0d\u6eb6\u4e8e\u6709\u673a\u6eb6\u5242\u548c\u6c34\u3002\u4e3a\u4e86\u6eb6\u89e3CNTs\u53ca\u5404\u79cd\u5408\u6210\u7eb3\u7c73\u7ba1\uff0c\u901a\u5e38\u9700\u8981\u5c06\u5236\u5907\u7684\u7eb3\u7c73\u7ba1\u4e0e\u4e24\u4eb2\u6027\u5206\u5b50\u8fdb\u884c\u989d\u5916\u7684\u53cd\u5e94\u5b9e\u73b0\u8868\u9762\u4fee\u9970\uff0c\u4ece\u800c\u6539\u53d8\u7eb3\u7c73\u7ba1\u7684\u4eb2\u758f\u6c34\u6027\u800c\u8fbe\u5230\u53ef\u6eb6\u89e3\u7684\u76ee\u7684\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u5316\u5b66\u4fee\u9970\u4f1a\u5f71\u54cd\u539f\u59cb\u7eb3\u7c73\u7ba1\u7684\u8868\u9762\u7279\u6027\uff0c\u5e76\u4e14\u4fee\u9970\u540e\u7684\u8be6\u7ec6\u6676\u4f53\u7ed3\u6784\u5f80\u5f80\u4e0d\u6e05\u695a\u3002\u56e0\u6b64\uff0c\u8fd9\u96be\u4ee5\u76f4\u89c2\u6bd4\u8f83\u539f\u59cb\u7eb3\u7c73\u7ba1\u548c\u4fee\u9970\u540e\u7eb3\u7c73\u7ba1\u7684\u7ed3\u6784\u548c\u7279\u6027\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u6210\u679c\u7b80\u4ecb\uff1a<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u65e5\u672c\u4eac\u90fd\u5927\u5b66\u5317\u5ddd\u5b8f(Hiroshi Kitagawa)\u6559\u6388\u7b49\u4eba\u9996\u6b21\u5408\u6210\u4e86\u4e00\u79cd\u53ef\u6eb6\u6027\u91d1\u5c5e-\u6709\u673a\u7eb3\u7c73\u7ba1,\u00a0[Pt(en)(bpy)X]<sub>4<\/sub>(dbs)<sub>8<\/sub>\u00b7nH<sub>2<\/sub>O (en: ethylenediamine, bpy: 4,4&#8242;-bipyridine, dbs: dodecyl benzene sulfonate, X = I (\u5316\u5408\u7269<strong>1<\/strong>), Br (\u5316\u5408\u7269<strong>2<\/strong>)).\u3002\u56db\u6761\u91d1\u5c5e\u5364\u7d20\u6865\u63a5\u4e00\u7ef4\u94fe(MX-chain)\u901a\u8fc7\u6709\u673a\u914d\u4f53\u8fde\u63a5\u5f62\u6210\u7ba1\u72b6\u7ed3\u6784\u3002\u5176\u7ed3\u6784\u72ec\u7279\u4e4b\u5904\u5728\u4e8e\uff1a\u8be5\u7eb3\u7c73\u7ba1\u7531\u9633\u79bb\u5b50\u6027\u7eb3\u7c73\u7ba1\u7ba1\u6846\u67b6\u548c\u957f\u70f7\u57fa\u94fe\u9634\u79bb\u5b50\u7ec4\u6210\u3002\u5f97\u76ca\u4e8e\u7ed3\u6784\u6027\u7684\u957f\u70f7\u57fa\u94fe\uff0c\u8be5\u7eb3\u7c73\u7ba1\u4e0d\u4ec5\u80fd\u4ee5\u805a\u96c6\u56fa\u6001\u5f62\u5f0f\u5b58\u5728\uff0c\u4e5f\u80fd\u7a33\u5b9a\u6eb6\u89e3\u4e8e\u6709\u673a\u5a92\u4ecb\u800c\u65e0\u9700\u4efb\u4f55\u989d\u5916\u7684\u8868\u9762\u5316\u5b66\u4fee\u9970\uff0c\u8fd9\u4e0e\u4f20\u7edf\u7684\u7eb3\u7c73\u7ba1\u4f53\u7cfb\u660e\u663e\u4e0d\u540c\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u7535\u5b50\u663e\u5fae\u6280\u672f\u9996\u6b21\u76f4\u63a5\u89c2\u6d4b\u5230\u91d1\u5c5e-\u6709\u673a\u7eb3\u7c73\u7ba1\u7684\u7ba1\u675f\u7ed3\u6784\uff0c\u8fd9\u5f97\u76ca\u4e8e\u8be5\u7eb3\u7c73\u7ba1\u7684\u826f\u597d\u6eb6\u89e3\u6027\u53ca\u6eb6\u5242\u6325\u53d1\u65f6\u7684\u81ea\u7ec4\u88c5\u9a71\u52a8\u3002\u6700\u540e\uff0c\u4f5c\u8005\u4f7f\u7528\u7eb3\u7c73\u7ba1\u6eb6\u6db2\u5236\u5907\u4e86\u5355\u5206\u5b50\u3001\u53cc\u5206\u5b50\u5c42\u7684\u8584\u819c\uff0c\u4e3a\u672a\u6765\u7684\u8584\u819c\u5e94\u7528\u63d0\u4f9b\u53ef\u80fd\uff0c\u5982\u5728\u5149\u5b66\u8584\u819c\u3001\u79bb\u5b50\u4f20\u5bfc\u819c\u7b49\u9886\u57df\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<strong>Self-Assembled Crystalline Bundles in Soluble Metal\u2013Organic Nano-tubes<\/strong>\u201d\u53d1\u8868\u5728<strong><em>J. Am. Chem. Soc<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250369\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u9898\u56fe-12.png\" alt=\"\" width=\"1961\" height=\"475\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u9898\u56fe-12.png 1961w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u9898\u56fe-12-300x73.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u9898\u56fe-12-768x186.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u9898\u56fe-12-1024x248.png 1024w\" sizes=\"(max-width: 1961px) 100vw, 1961px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56fe\u6587\u5bfc\u8bfb\uff1a<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250370\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/Scheme1.png\" alt=\"\" width=\"723\" height=\"227\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/Scheme1.png 723w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/Scheme1-300x94.png 300w\" sizes=\"(max-width: 723px) 100vw, 723px\" \/><\/p>\n<p><strong>Scheme 1.<\/strong>\u00a0\u57fa\u4e8e\u81ea\u4e0b\u800c\u4e0a\u65b9\u6cd5\u7684\u53ef\u6eb6\u6027\u91d1\u5c5e-\u6709\u673a\u7eb3\u7c73\u7ba1\u7684\u6784\u5efa\u7b56\u7565<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250371\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-42.png\" alt=\"\" width=\"1268\" height=\"934\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-42.png 1268w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-42-300x221.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-42-768x566.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-42-1024x754.png 1024w\" sizes=\"(max-width: 1268px) 100vw, 1268px\" \/><\/p>\n<p><strong>Fi<\/strong><strong>gure 1.<\/strong>\u00a0\u7eb3\u7c73\u7ba1\u7684\u56fa\u6001\u7ed3\u6784\u89e3\u6790\u3002(a)\u5316\u5408\u7269<strong>1<\/strong>\u7684PXRD\u53ca\u5176Rietveld\u62df\u5408\u3002(b)\u5316\u5408\u7269<strong>1<\/strong>\u548c<strong>2<\/strong>\u7684\u6f2b\u53cd\u5c04\u5149\u8c31\u3002(c)\u5316\u5408\u7269<strong>1<\/strong>\u7684\u6676\u4f53\u5806\u79ef\u7ed3\u6784\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250372\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-38.png\" alt=\"\" width=\"693\" height=\"541\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-38.png 693w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-38-300x234.png 300w\" sizes=\"(max-width: 693px) 100vw, 693px\" \/><\/p>\n<p><strong>Fi<\/strong><strong>gure 2. <\/strong>\u4e0d\u540c\u6d53\u5ea6\u7684\u5316\u5408\u7269<strong>1<\/strong>\u548c<strong>2<\/strong>\u5728\u6c2f\u4eff\u6eb6\u6db2\u4e2d\u7684IVCT(inter-valence charge-transfer\uff0c\u4ef7\u95f4\u7535\u8377\u8f6c\u79fb)\u5438\u5149\u5ea6\u6bd4\u8f83\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250373\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-33.png\" alt=\"\" width=\"723\" height=\"914\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-33.png 723w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-33-237x300.png 237w\" sizes=\"(max-width: 723px) 100vw, 723px\" \/><\/p>\n<p><strong>Fi<\/strong><strong>gure 3. <\/strong>\u7eb3\u7c73\u7ba1\u675f\u7ed3\u6784\u89c2\u5bdf\u3002(a)\u5316\u5408\u7269<strong>1<\/strong>\u548c(b)<strong>2<\/strong>\u7684HRTEM\u56fe\u50cf(\u6bd4\u4f8b\u5c3a\uff1a20 nm)\u3002(c) <strong>1<\/strong>\u7684HAADF-STEM \u56fe\u50cf(\u6bd4\u4f8b\u5c3a\uff1a20 nm)\u3002(d) <strong>1<\/strong>\u7684\u5c0f\u7eb3\u7c73\u7ba1\u675f\u7684HAADF-STEM \u56fe\u50cf(\u6bd4\u4f8b\u5c3a\uff1a50 nm)\u3002(e)\u5355\u5c42\u7eb3\u7c73\u7ba1\u675f\u7ed3\u6784\u793a\u610f\u56fe\u3002(f)\u6cbf<em>b<\/em>\u8f74\u7684\u5355\u7eb3\u7c73\u7ba1\u6a21\u578b\u89c6\u56fe\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-250374\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-29.png\" alt=\"\" width=\"727\" height=\"963\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-29.png 727w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-29-226x300.png 226w\" sizes=\"(max-width: 727px) 100vw, 727px\" \/><\/p>\n<p><strong>Fi<\/strong><strong>gure 4. <\/strong>(a)\u7eb3\u7c73\u7ba1\u7684\u8584\u819c\u5236\u5907\u793a\u610f\u56fe\u3002(b, d)\u5316\u5408\u7269<strong>1<\/strong>\u548c(c, e) <strong>2<\/strong>\u8584\u819c\u7684AFM\u56fe\u50cf\u53ca\u9ad8\u5ea6\u66f2\u7ebf\u3002\u57fa\u677f\uff1a\u7845\u7247\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u5c0f\u7ed3\u4e0e\u5c55\u671b\uff1a<\/strong><\/p>\n<p>\u4f5c\u8005\u5c55\u793a\u4e86\u53ef\u6eb6\u6027\u91d1\u5c5e-\u6709\u673a\u7eb3\u7c73\u7ba1\u7684\u7b2c\u4e00\u4e2a\u4f8b\u5b50\u3002X\u5c04\u7ebf\u6280\u672f\u548c\u5149\u5b66\u6d4b\u8bd5\u63ed\u793a\u4e86\u7ba1\u72b6\u7ed3\u6784\u3002 \u7531\u4e8e\u7ed3\u6784\u4e2d\u9634\u79bb\u5b50\u90e8\u5206\u5b58\u5728\u957f\u70f7\u57fa\u94fe\uff0c\u7ba1\u72b6\u7ed3\u6784\u4e0d\u4ec5\u53ef\u4ee5\u5728\u56fa\u6001\u800c\u4e14\u53ef\u4ee5\u5728\u6eb6\u6db2\u72b6\u6001\u4e0b\u5b9e\u73b0\uff0c\u800c\u65e0\u9700\u4efb\u4f55\u989d\u5916\u7684\u8868\u9762\u5316\u5b66\u4fee\u9970\uff0c\u8fd9\u662f\u7b2c\u4e00\u6b21\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u7535\u5b50\u663e\u5fae\u955c\u7814\u7a76\u548c\u8584\u819cAFM\u6280\u672f\u76f4\u63a5\u89c2\u5bdf\u5230\u7eb3\u7c73\u7ba1\u7684\u81ea\u7ec4\u88c5\u6676\u675f\u3002\u8fd9\u662f\u9996\u6b21\u5728\u91d1\u5c5e-\u6709\u673a\u7eb3\u7c73\u7ba1\u4f53\u7cfb\u4e2d\u76f4\u63a5\u89c2\u5bdf\u5230\u7ba1\u675f\u7ed3\u6784\u3002\u8fd9\u9879\u5de5\u4f5c\u5c06\u6709\u52a9\u4e8e\u7814\u7a76\u7eb3\u7c73\u7ba1\u675f\u6216\u72ec\u7acb\u7eb3\u7c73\u7ba1\u901a\u9053\u4e2d\u7684\u4f20\u8d28\u884c\u4e3a\uff0c\u4ee5\u53ca\u5e7f\u6cdb\u7684\u8584\u819c\u5e94\u7528\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u539f\u6587\u8be6\u60c5\uff1a<\/p>\n<p><a href=\"https:\/\/doi.org\/10.1021\/jacs.3c02252\"><u>https:\/\/doi.org\/10.1021\/jacs.3c02252<\/u><\/a><\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u80cc\u666f\u4ecb\u7ecd\uff1a 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