{"id":25024,"date":"2016-07-06T00:08:18","date_gmt":"2016-07-05T16:08:18","guid":{"rendered":"\/\/m.iemloyee.com\/?p=25024"},"modified":"2017-03-06T10:07:55","modified_gmt":"2017-03-06T02:07:55","slug":"%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6%e6%b7%b1%e7%a0%94%e9%99%a2%ef%bc%9a%e4%bc%a0%e7%bb%9f%e9%94%82%e7%94%b5%e6%b1%a0%e8%b4%9f%e6%9e%81%e6%9d%90%e6%96%99li4ti5o12%e5%ae%9e%e7%8e%b0%e6%96%b0%e7%aa%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=25024","title":{"rendered":"\u6e05\u534e\u5927\u5b66\u6df1\u7814\u9662\uff1a\u4f20\u7edf\u9502\u7535\u6c60\u8d1f\u6781\u6750\u6599Li4Ti5O12\u5b9e\u73b0\u65b0\u7a81\u7834"},"content":{"rendered":"
<\/p>\n
\u4f5c\u4e3a\u50a8\u80fd\u88c5\u7f6e\u7684\u4e00\u4e2a\u5178\u8303\u2014\u2014\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u56e0\u5176\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u9ad8\u529f\u7387\u5bc6\u5ea6\u7684\u7279\u70b9\u800c\u53d7\u5230\u5e7f\u6cdb\u7814\u7a76\u3002\u4f5c\u4e3a\u201c\u96f6\u5e94\u53d8\u201d\u6750\u6599\uff0c\u5c16\u6676\u77f3\u578b\u7684\u949b\u9178\u9502\uff08LTO\uff09\u5177\u6709\u5f88\u591a\u4f18\u70b9\uff1a1.\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4f53\u79ef\u51e0\u4e4e\u4e0d\u53d1\u751f\u53d8\u5316\uff0c\u5177\u6709\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd\uff1b2.\u79bb\u5b50\u6269\u6563\u901f\u7387\u8f83\u9ad8\uff0c\u6bd4\u78b3\u8d1f\u6781\u9ad8\u4e00\u4e2a\u6570\u91cf\u7ea7\uff0c\u53ef\u4ee5\u5feb\u901f\u5145\u7535\uff1b3.\u8f83\u9ad8\u7684\u5145\u653e\u7535\u5e73\u53f0\uff08~1.55V\uff09\u53ef\u4ee5\u907f\u514d\u7535\u89e3\u6db2\u7684\u5206\u89e3\uff0c\u7535\u6c60\u5b89\u5168\u6027\u80fd\u597d\u3002\u56e0\u6b64\uff0c\u4f5c\u4e3a\u8d1f\u6781\u6750\u6599\u7684\u949b\u9178\u9502\u80fd\u591f\u5927\u5e45\u5ea6\u63d0\u9ad8\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5b89\u5168\u6027\u3001\u5feb\u5145\u6027\u80fd\u548c\u4f7f\u7528\u5bff\u547d\uff0c\u5e76\u9010\u6e10\u6210\u4e3a\u5f53\u4eca\u793e\u4f1a\u7684\u7814\u7a76\u70ed\u70b9\u3002<\/p>\n
\u7136\u800c\uff0c\u949b\u9178\u9502\u6750\u6599\u7684\u672c\u5f81\u79bb\u5b50\u548c\u7535\u5b50\u7535\u5bfc\u7387\u4ecd\u7136\u8f83\u4f4e\uff0c\u4e3a\u4e86\u5b9e\u73b0\u5176\u9ad8\u529f\u7387\u7279\u6027\uff0c\u7eb3\u7c73\u5c3a\u5ea6\u949b\u9178\u9502\u6750\u6599\u6210\u4e3a\u8fd1\u5e74\u7684\u7814\u7a76\u70ed\u70b9\u3002\u5236\u5907\u5355\u5206\u6563\u7eb3\u7c73\u7403\u5f62\u949b\u9178\u9502\u9897\u7c92\u662f\u964d\u4f4e\u949b\u9178\u9502\u6750\u6599\u4e0d\u53ef\u9006\u5bb9\u91cf\u7684\u5173\u952e\uff0c\u4f46\u662f\u5236\u5907\u5747\u4e00\u5355\u5206\u6563\u7684\u949b\u9178\u9502\u524d\u9a71\u4f53\u6750\u6599\u4ee5\u53ca\u7ef4\u6301\u5176\u70e7\u7ed3\u540e\u7684\u7403\u5f62\u5f62\u8c8c\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u540c\u65f6\uff0c\u76ee\u524d\u7eb3\u7c73\u524d\u9a71\u4f53\u7403\u5f62\u6750\u6599\u7684\u5236\u5907\u5b58\u5728\u4e00\u5b9a\u56f0\u96be\uff0c\u949b\u9178\u56db\u4e01\u916f\u7b49\u949b\u6e90\u9047\u6c34\u5f88\u5bb9\u6613\u56e2\u805a\uff0c\u4e0d\u5bb9\u6613\u63a7\u5236\u5176\u5f62\u8c8c\u4e14\u5747\u4e00\u6027\u4e0d\u597d\u3002\u867d\u7136\u901a\u8fc7\u5f15\u5165\u6a21\u7248\u6216\u8005\u6d3b\u6027\u5242\u80fd\u591f\u5408\u6210\u5355\u5206\u6563\u7684\u7eb3\u7c73\u7403\uff0c\u4f46\u662f\u70ed\u5904\u7406\u8fc7\u7a0b\u4e2d\u5176\u5f62\u8c8c\u7684\u7ef4\u6301\u4ecd\u7136\u662f\u4e00\u4e2a\u6025\u9700\u89e3\u51b3\u7684\u96be\u9898\u3002<\/p>\n
\u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u6df1\u5733\u7814\u7a76\u751f\u9662\u5eb7\u98de\u5b87\u6559\u6388\u3001\u674e\u5b9d\u534e\u6559\u6388\u3001\u8d3a\u8273\u5175\u6559\u6388\u7814\u7a76\u56e2\u961f\u4e0e\u4f50\u6cbb\u4e9a\u7406\u5de5\u5b66\u9662 Zhiqun Lin\u6559\u6388<\/strong>\u5408\u4f5c\u63d0\u51fa\u4e86\u4e00\u4e2a\u5341\u5206\u6709\u6548\u7684\u7b56\u7565\uff0c\u7528\u6c2e\u5316\u949b\u505a\u6c2e\u6e90\u6765\u5236\u5907\u5e73\u5747\u5c3a\u5bf8\u4e3a120 nm\u7684\u5355\u5206\u6563\u7eb3\u7c73\u7403\u5f62\u949b\u9178\u9502\u6750\u6599\u3002\u5176\u7535\u5316\u5b66\u500d\u7387\u6027\u80fd\u5341\u5206\u4f18\u8d8a\uff0c\u9996\u5148\uff0c\u6c2e\u5316\u949b\u5728\u53cc\u6c27\u6c34\uff0c\u6c28\u6c34\u4f5c\u7528\u4e0b\u6eb6\u89e3\u751f\u6210\u8fc7\u6c27\u5316\u949b\uff0c\u5728\u4e00\u4e2a\u7a33\u5b9a\u6e29\u5ea6\u7684\u5f3a\u78b1\u6027\u73af\u5883\u4e0b\uff0c\u53ef\u4ee5\u6210\u529f\u5408\u6210\u7531TiO2\/Li+\u7ec4\u6210\u7684\u5355\u5206\u6563\u524d\u9a71\u4f53\uff0c\u4f46\u662fpH\u503c\u7684\u964d\u4f4e\u4f1a\u5bfc\u81f4\u524d\u9a71\u4f53\u7403\u8fdb\u4e00\u6b65\u957f\u5927\u3002\u8fd9\u8bf4\u660e\u6c22\u6c27\u6839\u79bb\u5b50\u5bf9\u4e8e\u51cf\u7f13\u8fc7\u6c27\u5316\u949b\u7684\u5206\u89e3\u4ee5\u53ca\u524d\u9a71\u4f53\u7403\u7684\u805a\u96c6\u957f\u5927\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u6709\u8da3\u7684\u662f\uff0c\u901a\u8fc7\u539f\u4f4d\u7c98\u63a5\u5728TiO2\/Li+\u7eb3\u7c73\u7403\u8868\u9762\u5747\u4e00\u7684\u805a\u4e59\u70ef\u5421\u54af\u70f7\u916e(PVP)\u5c42\u5728\u70ed\u5904\u7406\u8fc7\u7a0b\u4e2d\uff0c\u5f88\u597d\u5730\u7ef4\u6301\u4e86\u5176\u5355\u5206\u6563\u7403\u5f62\u7ed3\u6784\u548c\u5f62\u8c8c\uff0c\u83b7\u5f97\u4e86\u6027\u80fd\u4f18\u5f02\u7684\u7c92\u5f84\u7ea6\u4e3a120 nm\u5355\u5206\u6563\u591a\u5b54\u7403\u5f62\u949b\u9178\u9502\uff0c\u4e14\u632f\u5b9e\u5bc6\u5ea6\u8fbe\u52301.1 g\/cm3\u3002\u7535\u5316\u5b66\u7814\u7a76\u8868\u660e\uff0c\u5176\u5177\u6709\u975e\u5e38\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff0c\u598210 C\u5145\u653e\u7535\u6bd4\u5bb9\u91cf\u8fbe\u5230151.1 mAh\/g\uff0c\u751a\u81f3\u572880 C\u4e0b\u5145\u653e\u7535\u4ecd\u7136\u80fd\u591f\u8fbe\u5230108.9 mAh\/g\u3002\u53e6\u5916\uff0c\u572810 C\u7684\u5145\u653e\u7535\u901f\u7387\u4e0b\uff0c\u5faa\u73af500\u6b21\u540e\u5176\u5bb9\u91cf\u4ecd\u4fdd\u630192.6%\uff0c\u4f53\u73b0\u4e86\u4f18\u5f02\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/p>\n \u56fe1<\/strong> \uff08a\uff09TiO2<\/sub>\/Li+<\/sup>\u7eb3\u7c73\u7403\u4ee5\u53ca\u5fae\u7403\u7684\u5408\u6210\u8fc7\u7a0b\u539f\u7406\u56fe\u3002\uff08b\uff09\u524d\u9a71\u6db2PH\u503c\u5728\u52a0\u5165LiOH\u00b7 H2<\/sub>O\u4ee5\u53caLiAc\u00b72H2<\/sub>O\u65f6\u968f\u52a0\u70ed\u65f6\u95f4\u7684\u53d8\u5316\u3002<\/p>\n \u56fe2<\/strong> \u57280.25 g TiN\u548cLiAc\u00b72H2<\/sub>O\u4e2d\u5206\u522b\u6dfb\u52a0\uff08a,b\uff096 mL\uff08c,d\uff0912 mL\u4ee5\u53ca\uff08e,f\uff0918 mL \u7684\u6c28\u6c34\u5408\u6210\u7684TiO2<\/sub>\/Li+<\/sup>\u7eb3\u7c73\u7403\u7684\u626b\u9762\u7535\u955c\u56fe<\/p>\n \u56fe3 <\/strong>\u4e0d\u540c\u7684\u524d\u9a71\u6db2\uff08a,c,e,g\uff09\u4ee5\u53ca\u5408\u6210\u7684LTO-PVP-0\uff0cLTO-PVP-50\uff0cLTO-PVP-100\u4ee5\u53caLTO-PVP-150\u7eb3\u7c73\u7403\uff08b,d,f,h\uff09\u3002\u63d2\u56fe\u4e3a\u5bf9\u5e94\u7684\u653e\u5927\u56fe\u3002\uff080,50,100,150\u5206\u522b\u4e3a\u4e0d\u540c\u8d28\u91cf\u7684PVP\uff09<\/p>\n \u56fe4<\/strong> \uff08a\uff09\u524d\u9a71\u6db2\u4ee5\u53ca\uff08b\uff09LTO-PVP-0\uff0cLTO-PVP-50\uff0cLTO-PVP-100\uff0cLTO-PVP-150\u572877 K\u4e0b\u7684N\u5438\u9644\/\u8131\u9644\u7b49\u6e29\u7ebf\u3002\uff08\u63d2\u56fe\u4e3a\u5b54\u5f84\u5206\u5e03\u56fe\uff09\u3002\uff08c\uff09\u56db\u79cd\u4ea7\u7269\u76f8\u5e94\u7684\u6bd4\u8868\u9762\u79ef\u3002\uff08d\uff09LTO-PVP-0\uff0cLTO-PVP-50\uff0cLTO-PVP-100\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\u8c31\u3002<\/p>\n \u56fe5<\/strong> \u4e0d\u540c\u5f62\u8c8c\u7684LTO\u7684\u5408\u6210\u8fc7\u7a0b\u539f\u7406\u56fe<\/p>\n \u56fe6<\/strong> \uff08a,b\uff09LTO-PVP-50\u4ee5\u53ca\uff08c,d\uff09LTO-PVP-100\u7eb3\u7c73\u7403\u7684\u900f\u5c04\u7535\u955c\u56fe<\/p>\n \u56fe7 <\/strong>LTO-PVP-50\u548cLTO-PVP-100\u7eb3\u7c73\u7403\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\uff08a,b\uff09\u5145\/\u653e\u7535\u66f2\u7ebf\uff0c\uff08c\uff09\u4e0d\u540c\u500d\u7387\u6027\u80fd\u4e0b\u7684\u7535\u8377\u5bb9\u91cf\u4ee5\u53ca\uff08d\uff09\u5145\u653e\u7535\u901f\u7387\u4e3a10 C\u4e0b\u7684\u5faa\u73af\u7279\u6027\u3002<\/p>\n \u56fe8<\/strong> \uff08a\uff09\u7ecf\u4e09\u6b21\u5faa\u73af\u540e\u7684LTO-PVP-50\u548cLTO-PVP-100\u7eb3\u7c73\u7403\u7684\u7535\u5316\u5b66\u963b\u6297\u56fe\u8c31\uff08\u63d2\u56fe\u4e3a\u5b9e\u90e8\u7535\u963bZ\u2019\u4e0e\u03c9-1\/2\u5728\u4f4e\u9891\u533a\u7684\u5173\u7cfb\u56fe\u4ee5\u53ca\u76f8\u5e94\u7684\u7b49\u6548\u7535\u8def\u6a21\u578b\uff09\u3002\uff08b\uff09LTO-PVP-50\u548cLTO-PVP-100\u7eb3\u7c73\u7403\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/p>\n \u672c\u5de5\u4f5c\u5f00\u8f9f\u4e86\u4e00\u6761\u5355\u5206\u6563\u7eb3\u7c73\u591a\u5b54\u7403\u5f62\u949b\u9178\u9502\u53ef\u63a7\u5236\u5907\u7684\u65b0\u9053\u8def\uff0c\u4e14\u517c\u5177\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u3001\u9ad8\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u3001\u957f\u5faa\u73af\u5bff\u547d\uff0c\u5177\u6709\u4f18\u5f02\u7684\u4ea7\u4e1a\u5316\u524d\u666f\u3002<\/p>\n<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n