{"id":250185,"date":"2023-05-13T05:57:03","date_gmt":"2023-05-12T21:57:03","guid":{"rendered":"\/\/m.iemloyee.com\/?p=250185"},"modified":"2023-05-11T11:57:14","modified_gmt":"2023-05-11T03:57:14","slug":"aem%e5%88%86%e6%95%a3%e5%9c%a8mo2tic2tx-mos2%e5%bc%82%e8%b4%a8%e7%bb%93%e6%9e%84%e4%b8%8a%e7%9a%84%e5%88%86%e5%ad%90%e9%97%b4%e9%87%91%e5%b1%9e%e5%8d%95%e4%bd%8d%e7%82%b9%e9%85%8d%e5%90%88%e7%89%a9","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=250185","title":{"rendered":"AEM:\u5206\u6563\u5728Mo2TiC2Tx\/MoS2\u5f02\u8d28\u7ed3\u6784\u4e0a\u7684\u5206\u5b50\u95f4\u91d1\u5c5e\u5355\u4f4d\u70b9\u914d\u5408\u7269\u8bf1\u5bfc\u4fc3\u8fdb\u592a\u9633\u9a71\u52a8\u6c34\u5206\u89e3"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u00a0 \u00a0\u8fd1\u5e74\u6765\uff0c\u7531\u53ef\u518d\u751f\u80fd\u6e90\u9a71\u52a8\u7684\u7535\u50ac\u5316\u6c34\u5206\u89e3\u88ab\u8ba4\u4e3a\u662f\u5c06\u53ef\u518d\u751f\u7535\u529b\u8f6c\u5316\u4e3a\u53ef\u6301\u7eed\u6c22\u80fd\u7684\u4e00\u79cd\u6709\u524d\u9014\u7684\u65b9\u6cd5\u3002\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u548c\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u7684\u9634\u6781\u548c\u9633\u6781\u7535\u6781\u7684\u53d1\u5c55\uff0c\u5206\u522b\u51b3\u5b9a\u4e86\u7535\u89e3\u69fd\u88c5\u7f6e\u7684\u80fd\u91cf\u6548\u7387\u3002\u56e0\u6b64\uff0c\u4fc3\u8fdb\u6c34\u7684\u50ac\u5316\u5438\u9644\u548c\u6d3b\u5316\u4ee5\u52a0\u901fHER\u548cOER\u52a8\u529b\u5b66\u5bf9\u8fd9\u4e9b\u7cfb\u7edf\u81f3\u5173\u91cd\u8981\u3002\u867d\u7136\u94c2\u57fa\uff08Pt\uff09\u548cRu\/ Ir\u57fa\u6750\u6599\u5206\u522b\u5728HER\u548cOER\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u7684\u50ac\u5316\u80fd\u529b\uff0c\u4f46\u9ad8\u6602\u7684\u6210\u672c\u548c\u7a00\u6709\u6027\u9650\u5236\u4e86\u5b83\u4eec\u7684\u5e7f\u6cdb\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u63a2\u7d22\u4f4e\u6210\u672c\u3001\u9ad8\u6027\u80fd\u7684\u975e\u8d35\u91d1\u5c5eHER\/OER\u50ac\u5316\u5242\u5bf9\u4e8e\u53d1\u5c55\u65b0\u4e00\u4ee3\u9ad8\u6548\u7535\u89e3\u69fd\u6280\u672f\u662f\u5fc5\u8981\u7684\u3002\u5728\u6700\u8fd1\u62a5\u9053\u7684\u50ac\u5316\u5242\u4e2d\uff0c\u91d1\u5c5e\u915e\u83c1\uff08MPc<\/sub>\uff09\u5206\u5b50\u7531\u4e8e\u5176\u7279\u6b8a\u7684\u4e0d\u9971\u548c\u914d\u4f4dM-N4\u4f4d\u70b9\u5177\u6709\u826f\u597d\u7684\u50ac\u5316\u529f\u80fd\u800c\u5907\u53d7\u5173\u6ce8\u3002\u800c\u7535\u8d1f\u6027\u6c2e\u6709\u6548\u5730\u8c03\u8282\u7535\u5b50\u7ed3\u6784\u4ee5\u964d\u4f4e\u52a8\u529b\u5b66\u52bf\u5792\uff0c\u56e0\u6b64\u9002\u7528\u4e8e\u4e0d\u540c\u7c7b\u578b\u7684\u53cd\u5e94\u3002\u6b64\u5916\uff0c\u7814\u7a76\u53d1\u73b0MXene\uff08Mn+1<\/sub>Xn<\/sub>Tx<\/sub>, M\uff1a\u8fc7\u6e21\u91d1\u5c5e\uff0cX\uff1a\u78b3\uff0cT\uff1a\u8868\u9762\u5b98\u80fd\u56e2\uff09\u4e0a\u751f\u957f2D MoS2<\/sub>\u80fd\u6709\u6548\u5730\u4fc3\u8fdb\u91d1\u5c5e\u7279\u6027\u3001\u4f18\u5f02\u7684\u78c1\u6027\u548c\u9ad8\u673a\u68b0\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u53d7\u5230\u8fd9\u4e9b\u4f18\u70b9\u7684\u9f13\u821e\uff0c\u5408\u7406\u4f7f\u7528MPc<\/sub>\uff0cMoS2 <\/sub>\u548cMXene \u7eb3\u7c73\u7247\u7ed3\u5408\u7684\u5f02\u8d28\u7ed3\u6784\u5c06\u6709\u52a9\u4e8e\u63d0\u9ad8HER\u548cOER\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/span><\/p>\n

\u00a0<\/strong> \u00a0\u8fd1\u65e5\uff0c\u97e9\u56fd\u5168\u5317\u56fd\u7acb\u5927\u5b66Joong Hee Lee<\/a>\u548cDuy Thanh Tran<\/a>\u7b49<\/span>\u4eba\u5408\u7406\u5730\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u53cc\u91cd\u91d1\u5c5e\u5355\u4f4d\u70b9\u94c1\u915e\u83c1\uff08FePc<\/sub>\uff09\u548c\u9492\u57fa\u915e\u83c1\uff08VOPc<\/sub>\uff09\u5206\u6563\u7684Mo2<\/sub>TiC2<\/sub>Tx<\/sub> (MX)\/MoS2<\/sub>\u5f02\u8d28\u7ed3\u6784\u7684\u6742\u5316\u50ac\u5316\u5242\u3002\u8be5\u6742\u5316\u50ac\u5316\u5242\u5728HER\u548cOER\u4e2d\u5747\u5177\u6709\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u201cIntermolecular Metallic Single-Site Complexes Dispersed on Mo2<\/sub>TiC2<\/sub>Tx<\/sub>\/MoS2<\/sub> Heterostructure Induce Boosted Solar-Driven Water Splitting<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Energy Materials<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/span><\/p>\n

\u00a0 \u00a01<\/strong>\u3001\u4f5c\u8005\u5408\u7406\u8bbe\u8ba1\u4e86\u94c1\u915e\u83c1\uff08<\/strong>FePc<\/sub>\u00a0<\/strong>\uff09\u548c\u6c27\u5316\u9492\u915e\u83c1\uff08<\/strong>VOPc<\/sub><\/strong>\uff09\u7684\u5206\u5b50\u95f4\u91d1\u5c5e\u5355\u4f4d\u70b9\u590d\u5408\uff0c\u5b83\u4eec\u53cc\u91cd\u56fa\u5b9a\u5728<\/strong>3D<\/strong>\u5206\u5c42<\/strong>MoS2<\/sub><\/strong>\u6d82\u5c42<\/strong>MXene Mo2<\/sub>TiC2<\/sub>Tx<\/sub><\/strong>\uff08<\/strong>MX\/MoS2<\/sub><\/strong>\uff09\u4e0a\u5f62\u6210\u5f02\u8d28\u7ed3\u6784\u4f5c\u4e3a\u9ad8\u6027\u80fd\u53cc\u529f\u80fd\u7535\u50ac\u5316\u5242\u3002\u826f\u597d\u7684\u7ec4\u7ec7\u7ed3\u6784\u5177\u6709\u4e0d\u5bfb\u5e38\u7684\u914d\u4f4d\u73af\u5883\u548c\u7535\u5b50\u5c40\u57df\u5316\uff0c\u663e\u8457\u5730\u589e\u5f3a\u4e86\u6c34\u7684\u5438\u9644\u548c\u6d3b\u5316\uff0c\u4ece\u800c\u52a0\u901f\u4e86<\/strong>HER<\/strong>\u548c<\/strong>OER<\/strong>\u7684\u52a8\u529b\u5b66\u3002<\/strong><\/p>\n

\u00a0 \u00a02<\/strong>\u3001\u8fd9\u79cd\u50ac\u5316\u5242\u53ea\u9700\u8981\u5c0f\u81f3<\/strong>17.4<\/strong>\u548c<\/strong>300 mV<\/strong>\u7684\u8fc7\u7535\u4f4d\u6765\u5206\u522b\u9a71\u52a8<\/strong>HER<\/strong>\u7684<\/strong>10 mA cm-2<\/sup><\/strong>\u548c<\/strong>OER<\/strong>\u7684<\/strong>50 mA cm\u20132<\/sup><\/strong>\u3002\u7406\u8bba\u7814\u7a76\u9884\u6d4b\uff0c\u9762\u5bf9\u9762\u53cc\u5206\u5b50\u50ac\u5316\u5242\u7684\u5f62\u6210\u53ef\u4ee5\u663e\u8457\u5730\u8bf1\u5bfc\u7535\u5b50\u91cd\u6784\uff0c\u5e76\u968f\u540e\u8c03\u6574\u5409\u5e03\u65af\u81ea\u7531\u5438\u9644\u80fd\u4ee5\u5f71\u54cd<\/strong>HER<\/strong>\u548c<\/strong>OER<\/strong>\u6027\u80fd\u3002<\/strong>\u00a0<\/strong><\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/span><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1 <\/strong>a) MX\/MoS2<\/sub>\u00a0-FePc<\/sub>VOPc<\/sub>\u6742\u5316\u7269\u5408\u6210\u7684\u793a\u610f\u56fe\uff1bb) MX\uff0cc\u3001d) MX\/MoS2<\/sub>-FePc<\/sub>VOPc<\/sub>\u7684 FE-SEM \u56fe\u50cf\uff1be) TEM \u548c f) MoS2<\/sub>-FePc<\/sub>VOPc<\/sub>\u90e8\u5206\u7684HR-TEM \u7167\u7247\uff1bg) HR-TEM \u56fe\u50cf\u548c h) \u5728MoS2<\/sub>-FePc<\/sub>VOPc<\/sub>\u7684\u5c0f\u533a\u57df\u5176\u76f8\u5e94\u7684 ImageJ \u8f6f\u4ef6\u5904\u7406\u56fe\u50cf\uff1bi) MX\/MoS2<\/sub>-FePc<\/sub>VOPc<\/sub>\u6742\u5316\u7269\u7684STEM-EDS\u6620\u5c04\u56fe\u50cf\uff1bj) MX\u3001MX\/MoS2<\/sub>\u548c MX\/MoS2<\/sub>-FePc<\/sub>VOPc<\/sub>\u7684XRD\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2<\/strong> a) FePc<\/sub>\u3001VOPc<\/sub>\u3001MX\/MoS2<\/sub>\u548cMXMoS2<\/sub>-FePc<\/sub>VOPc<\/sub>\u7684\u62c9\u66fc\u5149\u8c31\uff1bb) Mo3d\u3001c) S2p\u3001d) Ti2p\u3001e) C1s \u548c f) O1s \u7684 HR-XPS \u5149\u8c31\uff0c\u5206\u522b\u6765\u81ea MX (i)\u3001MX\/MoS2<\/sub> (ii) \u548c MX\/MoS2<\/sub>-FePc<\/sub>VOPc<\/sub> (iii);\u00a0MoS2<\/sub>-FePc<\/sub>VOPc<\/sub>\u4e2d g) Fe2p\u3001h) V2p \u548c i) Ni 1s + Mo 3p\u7684\u9ad8\u5206\u8fa8\u7387\u5149\u8c31\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3 <\/strong>a) \u57281.0 M\u00a0KOH\u4e2dHER LSV \u66f2\u7ebf\uff1bb) HER\u7684Tafel\u659c\u7387\uff1bc) MX\/MoS2<\/sub>-FePc<\/sub>VOPc<\/sub>\u572810\u548c100 mA cm-2<\/sup>\u4e0bHER\u7684\u8ba1\u65f6\u5b89\u57f9\u7a33\u5b9a\u6027\uff1bd) \u57281.0 M\u00a0KOH\u4e2dOER LSV \u66f2\u7ebf\uff1be) OER\u7684Tafel\u659c\u7387\uff1bf) MX\/MoS2<\/sub>-FePc<\/sub>VOPc<\/sub>\u572850\u548c100 mA cm-2<\/sup>\u4e0bOER\u7684\u8ba1\u65f6\u5b89\u57f9\u7a33\u5b9a\u6027\uff1bg) CV\u5206\u6790\uff1bh) Cdl<\/sub>\uff1bi) EIS\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4<\/strong> a)\u53ef\u89c6\u5316\u7684MoS2<\/sub>-FePc<\/sub>VOPc<\/sub>\u5177\u6709\u4e0d\u540c\u76f8\u7ed3\u6784\u7684\u7eafMoS2<\/sub>\u00a0(i), mono FePc<\/sub>\u00a0(ii), VOPc<\/sub>\u00a0(iv), \u03c0\u00a0–\u00a0\u03c0 \u5806\u53e0 FePc<\/sub>-VOPc\u00a0<\/sub>(v), \u03c0-\u03c0\u5806\u53e0VOPc<\/sub>-FePc<\/sub>\u00a0(iii)\u57281T,2H-MoS2<\/sub>\u8868\u9762\uff1bb,c)\u4e0d\u540c\u76f8\u7ed3\u6784\u7684\u0394G\u00a0H*\uff1bd) \u0394G\u00a0H*\u7684\u6bd4\u8f83\u5728\u4e0d\u540c\u6d3b\u6027\u4f4d\u70b9\u4e4b\u95f4\uff1be) DFT\u6cd5\u8ba1\u7b97\u7684\u4e0d\u540c\u76f8\u7ed3\u6784\u6d3b\u6027\u91d1\u5c5e\u4e2d\u5fc3\u7684OER\u81ea\u7531\u80fd\u56fe\uff1bf) (v) MoS2<\/sub>\/FePc<\/sub>VOP<\/sub>\u76f8\u7ed3\u6784\u7684OER\u673a\u7406\uff1bg) \u4e0d\u540c\u76f8\u7ed3\u6784\u7684DOS\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5<\/strong> a) MX\/MoS2<\/sub>-FePc<\/sub>VOPc<\/sub> (+,\u2212)\u57281.0\u00a0M\u00a0KOH\u6eb6\u6db2\u4e2d\u4e0d\u540c\u64cd\u4f5c\u6e29\u5ea6\u4e0b\u7684\u6574\u4f53\u6c34\u5206\u89e3\uff1bb) \u64cd\u4f5c\u6e29\u5ea6\u548cKOH\u6d53\u5ea6\u5bf9\u7535\u89e3\u69fd\u6027\u80fd\u7684\u5f71\u54cd\uff1bc) \u7535\u89e3\u69fd\u5728 7.0\u00a0M\u00a0KOH \u548c 75 \u00b0C \u4e0b\u5728 10 \u548c 50 mA cm-2<\/sup>\u4e0b\u957f\u671f\u8fd0\u884c\u7684\u8ba1\u65f6\u5b89\u57f9\u7a33\u5b9a\u6027\uff1bd) 7.0 M\u00a0KOH 75 \u00b0C\u592a\u9633\u80fd\u9a71\u52a8\u6c34\u5206\u89e3\u7cfb\u7edf\u793a\u610f\u56fe\uff1be)\u592a\u9633\u80fd\u7535\u6c60\u7684J-V\u66f2\u7ebf\u548c\u7cfb\u7edf\u5728 7.0\u00a0M\u00a0KOH \u548c 75 \u00b0C \u4e0b\u7684 LSV \u54cd\u5e94\uff1bf) \u7cfb\u7edf\u57287.0\u00a0M KOH\u548c\u4e0d\u540c\u6e29\u5ea6\u4e0b\u5b9e\u73b0\u7684 STH \u6548\u7387\u6bd4\u8f83\uff1bg) \u7cfb\u7edf\u5728\u592a\u9633\u8f90\u5c04\u5f00\/\u5173\u6a21\u578b\u4e0b\u7684\u7535\u6d41\u54cd\u5e94\uff1bh) \u592a\u9633\u80fd\u9a71\u52a8\u6c34\u5206\u89e3\u7cfb\u7edf\u5728\u592a\u9633\u8f90\u5c04\u5f00\/\u5173\u6a21\u578b\u4e0b\u8fde\u7eed\u8fd0\u884c20\u5c0f\u65f6\u7684\u8ba1\u65f6\u5b89\u57f9\u7a33\u5b9a\u6027\u66f2\u7ebf\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

 <\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/span><\/p>\n

\u00a0 \u00a0\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u63d0\u51fa\u5e76\u6210\u529f\u5b9e\u73b0\u4e86\u4e00\u79cd\u5229\u7528\u5206\u6563\u5728Mo2<\/sub>TiC2<\/sub>Tx<\/sub> (MX)\/MoS2<\/sub>\u5f02\u8d28\u7ed3\u6784\u4e0a\u7684\u5206\u5b50\u95f4\u914d\u5408\u7269\u5f00\u53d1\u9ad8\u6548\u7535\u50ac\u5316\u5242\u7684\u6709\u6548\u6982\u5ff5\u3002\u8be5\u50ac\u5316\u5242\u5177\u6709\u91d1\u5c5e\u5355\u4f4d\u70b9\u914d\u5408\u7269\u548cMX\/MoS2<\/sub>\u5f02\u8d28\u7ed3\u6784\u7684\u591a\u91cd\u4f18\u52bf\uff0c\u5e76\u4e14\u5c42\u53e0\u6742\u5316\u7ed3\u6784\u53ef\u4ee5\u4ea7\u751f\u72ec\u7279\u7684\u534f\u540c\u6548\u5e94\uff0c\u8bf1\u5bfc\u7535\u5b50\u91cd\u65b0\u914d\u7f6e\u548c\u5206\u5e03\uff0c\u4ee5\u53ca\u9002\u5f53\u8c03\u8282\u80fd\u5792\u548c\u5438\u9644\/\u89e3\u5438\uff0c\u4ece\u800c\u4fc3\u8fdbHER\u548cOER\u7684\u50ac\u5316\u6d3b\u6027\u3002\u56e0\u6b64\uff0c\u8fd9\u9879\u7814\u7a76\u4e3a\u8bbe\u8ba1\u57fa\u4e8e\u6709\u673a\u91d1\u5c5e\u5206\u5b50\u548c\u65e0\u673a\u6d3b\u6027\u6750\u6599\u7684\u65b0\u578b\u7535\u50ac\u5316\u5242\u7528\u4e8e\u6c34\u5206\u89e3\u6280\u672f\u751f\u4ea7\u7eff\u8272\u6c22\u6c14\u63d0\u4f9b\u4e86\u6f5c\u5728\u7684\u6307\u5bfc\u3002<\/strong><\/span><\/span><\/p>\n

\u00a0<\/strong><\/span><\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a<\/strong>https:\/\/doi.org\/10.1002\/aenm.202203844<\/a><\/p>\n

\u672c\u6587\u7531K . L\u64b0\u7a3f\u3002<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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