{"id":249958,"date":"2023-05-05T06:27:08","date_gmt":"2023-05-04T22:27:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=249958"},"modified":"2023-05-04T11:27:20","modified_gmt":"2023-05-04T03:27:20","slug":"%e5%93%88%e5%b0%94%e6%bb%a8%e5%b7%a5%e7%a8%8b%e5%a4%a7%e5%ad%a6-%e6%b8%a9%e5%b7%9e%e5%a4%a7%e5%ad%a6aem%e5%af%bc%e7%94%b5%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e4%b8%ad%e5%88%9b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=249958","title":{"rendered":"\u54c8\u5c14\u6ee8\u5de5\u7a0b\u5927\u5b66 & \u6e29\u5dde\u5927\u5b66AEM:\u5bfc\u7535\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e2d\u521b\u5efa\u53cc\u6d3b\u6027\u4f4d\u70b9\u4ee5\u5b9e\u73b0\u9ad8\u6548\u6c34\u5206\u89e3"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u00a0 \u00a0\u8fd1\u5e74\u6765\uff0c\u7531\u4e8e\u4e0d\u65ad\u589e\u957f\u7684\u80fd\u6e90\u9700\u6c42\u548c\u5316\u77f3\u71c3\u6599\u76f8\u5173\u7684\u73af\u5883\u95ee\u9898\uff0c\u6709\u6548\u5229\u7528\u53ef\u518d\u751f\u80fd\u6e90\u5df2\u6210\u4e3a\u5168\u7403\u80fd\u6e90\u7ecf\u6d4e\u4e2d\u4e00\u4e2a\u7d27\u8feb\u548c\u5fc5\u7136\u7684\u8d8b\u52bf\u3002\u7535\u5316\u5b66\u6c34\u5206\u89e3\u5177\u6709\u5de5\u827a\u7b80\u5355\uff0c\u4e0d\u4ea7\u751f\u5176\u4ed6\u526f\u4ea7\u7269\u7b49\u7279\u70b9\uff0c\u7b26\u5408\u6e05\u6d01\u6280\u672f\u7684\u8981\u6c42\u3002\u7136\u800c\uff0c\u4e24\u4e2a\u534a\u53cd\u5e94\uff0c\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u548c\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u7684\u7f13\u6162\u52a8\u529b\u5b66\u9650\u5236\u4e86\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u3002\u76ee\u524d\uff0c\u8d35\u91d1\u5c5ePt\u548cRu\/Ir\u6c27\u5316\u7269\u5206\u522b\u662fHER\u548cOER\u6700\u6d3b\u8dc3\u7684\u7535\u50ac\u5316\u5242\u3002\u4f46\u5176\u4ef7\u683c\u6602\u8d35\uff0c\u50a8\u91cf\u6709\u9650\uff0c\u963b\u788d\u4e86\u5176\u5927\u89c4\u6a21\u5e94\u7528\u3002\u56e0\u4e3a\uff0c\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63d0\u9ad8\u6c34\u5206\u89e3\u7684\u6548\u7387\uff0c\u9700\u8981\u5f00\u53d1\u51fa\u7528\u4e8eHER\u548cOER\u7684\u9ad8\u6027\u80fd\u548c\u6210\u672c\u6548\u76ca\u7684\u53cc\u529f\u80fd\u7535\u50ac\u5316\u5242\u3002<\/p>\n

\u00a0 \u00a0\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u5177\u6709\u4e30\u5bcc\u7684\u5468\u671f\u6027\u5b54\u9699\u7387\u3001\u53ef\u8c03\u529f\u80fd\u548c\u901a\u7528\u7684\u6846\u67b6\u62d3\u6251\u7ed3\u6784\u3002\u7279\u522b\u662f\uff0c\u5bfc\u7535\u6027MOF\u56e0\u5176\u6539\u5584\u4e86\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u5728\u50ac\u5316OER\u3001HER\u3001\u6c27\u8fd8\u539f\u53cd\u5e94\u548cCO2<\/sub>\u8fd8\u539f\u7b49\u5404\u79cd\u7535\u5316\u5b66\u53cd\u5e94\u65b9\u9762\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u8fc4\u4eca\u4e3a\u6b62\u62a5\u9053\u7684\u5927\u591a\u6570\u5bfc\u7535MOFs\u53ea\u80fd\u50ac\u5316\u5355\u4e00\u7684\u5316\u5b66\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5bfc\u7535MOF\u5728HER\u65b9\u9762\u4f18\u4e8e\u5546\u4e1aPt\/C\uff0c\u5728OER\u65b9\u9762\u4f18\u4e8eIrO2<\/sub>\/RuO2<\/sub>\uff0c\u4ecd\u7136\u5177\u6709\u5f88\u5927\u6311\u6218\u6027\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/span><\/p>\n

\u00a0 \u00a0<\/strong>\u8fd1\u65e5\uff0c\u54c8\u5c14\u6ee8\u5de5\u7a0b\u5927\u5b66\u9648\u7389\u91d1\uff0c\u8d75\u8d62\u8425\uff0c\u6731\u6625\u73b2\u4ee5\u53ca\u6e29\u5dde\u5927\u5b66\u4fb4\u672f\u96f7\u6559\u6388\u7b49\u4eba\u63d0\u51fa\u4e00\u9505\u6eb6\u5242\u70ed\u7b56\u7565\uff0c\u5728\u78b3\u5e03\uff08CC\uff09\u4e0a\u5408\u6210\u8d35\u91d1\u5c5e\uff08Ru\u3001Ir\u3001Rh\uff09\u63ba\u6742\u7684 Co-CAT NRAs \u7528\u4e8e\u6c34\u5206\u89e3\u3002\u5176\u4e2d\uff0cRuCo-CAT\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u53cc\u529f\u80fd\u6d3b\u6027\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u201cCreating Dual Active Sites in Conductive Metal-Organic Frameworks for Efficient Water Splitting<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Energy Materials<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/span><\/p>\n

\u00a0 \u00a01<\/strong>\u3001\u4f5c\u8005\u901a\u8fc7\u4e00\u9505\u6eb6\u5242\u70ed\u6cd5\u6210\u529f\u7684\u5728<\/strong>CC <\/strong>\u57fa\u677f\u4e0a\u4f7f\u7528\u8d35\u91d1\u5c5e<\/strong> (Ru<\/strong>\u3001<\/strong>Ir<\/strong>\u3001<\/strong>Rh) <\/strong>\u63ba\u6742\u5408\u6210\u51fa\u53cc\u6d3b\u6027\u4f4d\u70b9\u53cc\u529f\u80fd\u7535\u50ac\u5316\u5242\u3002\u5b9e\u9a8c\u7ed3\u679c\u548c\u7406\u8bba\u8ba1\u7b97\u5747\u8868\u660e\uff0c\u63ba\u6742\u91d1\u5c5e\u548c<\/strong>Co <\/strong>\u539f\u5b50\u7684\u7535\u5b50\u7ed3\u6784\u90fd\u53d1\u751f\u4e86\u8c03\u6574\uff0c\u5bfc\u81f4\u63ba\u6742<\/strong>Co-CAT NRA<\/strong>\u4e2d\u5b58\u5728\u53cc\u6d3b\u6027\u4f4d\u70b9\uff0c\u4ece\u800c\u72ec\u7acb\u50ac\u5316<\/strong>HER<\/strong>\u548c<\/strong>OER<\/strong>\u3002<\/strong><\/p>\n

\u00a0 \u00a02<\/strong>\u3001<\/strong>RuCo-CAT NRAs<\/strong>\u53ea\u9700\u8981<\/strong>38 mV<\/strong>\u7684\u8fc7\u7535\u4f4d\u6765\u9a71\u52a8<\/strong>10 mA cm\u22122<\/sup><\/strong>\u7684<\/strong>HER<\/strong>\uff0c\u8fd9\u6bd4<\/strong>Pt\/C<\/strong>\u57fa\u51c6\uff08<\/strong>46 mV<\/strong>\uff09\u8981\u4f4e\u3002\u6b64\u5916\uff0c\u53ea\u9700\u8981<\/strong>200 mV<\/strong>\u7684\u8fc7\u7535\u4f4d\u5c31\u53ef\u4ee5\u9a71\u52a8<\/strong>10 mA cm\u22122<\/sup><\/strong>\u7684<\/strong>OER<\/strong>\uff0c\u8fd9\u4f18\u4e8e<\/strong>RuO2<\/sub><\/strong>\u57fa\u51c6\u7684\u50ac\u5316\u6d3b\u6027\uff08<\/strong>370 mV<\/strong>\uff09\u3002\u53cc\u529f\u80fd<\/strong>RuCo-CAT NRAs<\/strong>\u7ec4\u88c5\u7684\u7535\u89e3\u69fd\u53ea\u9700\u8981\u4f4e\u81f3<\/strong>1.47 V<\/strong>\u7684\u7535\u6c60\u7535\u538b\u5c31\u80fd\u63d0\u4f9b<\/strong>10 mA cm\u22122<\/sup><\/strong>\uff0c\u8fd9\u662f\u8fc4\u4eca\u4e3a\u6b62\u62a5\u9053\u7684\u6700\u597d\u53cc\u529f\u80fd\u6d3b\u6027\u50ac\u5316\u5242\u4e4b\u4e00\u3002<\/strong><\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/span><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1 <\/strong>a) RuCo-CAT \u7684\u5408\u6210\u56fe\u548c\u5206\u5b50\u5806\u79ef\u6a21\u578b\u3002b) RuCo-CAT\u3001Co-CAT \u7684 XRD \u56fe\u3002c) \u5728CC\u57fa\u677f\u4e0a\u751f\u957f\u7684 RuCo-CAT\u7684SEM \u56fe\u50cf\u3002d) RuCo-CAT\u7684HRTEM \u56fe\u50cf\u3002e) RuCo-CAT \u7684TEM\u56fe\u50cf\u548c\u76f8\u5e94\u7684\u5143\u7d20\u6620\u5c04\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2 <\/strong>a) RuCo-CAT\u3001Co-CAT\u7684 XPS \u5149\u8c31\u3002b) Ru 3p \u7684XPS\u5149\u8c31\u3002c) Co 2p \u7684XPS\u5149\u8c31\u3002d) Ru\u7b94\u3001RuO2<\/sub>\u3001RuCl3<\/sub>\u548cRuCo-CAT\u7684\u5f52\u4e00\u5316Ru K-edge XANES \u5149\u8c31\u3002e) RuCo-CAT\u7684\u5085\u7acb\u53f6\u53d8\u6362EXAFS (FT-EXAFS) \u5149\u8c31\u3002(f) EXAFS\u62df\u5408\u7ed3\u679c\u3002g) RuCo-CAT\u3001Ru\u7b94\u3001RuCl3<\/sub>\u548c RuO2<\/sub>\u7684EXAFS\u4fe1\u53f7\u7684 WT\u00a0\u3002h) \u5f52\u4e00\u5316\u7684 Co K-edge XANES \u5149\u8c31\u3002i) RuCo-CAT\u3001Co-CAT\u3001CoO\u3001Co2<\/sub>O3<\/sub>\u548cCo\u7b94\u7684EXAFS\u4fe1\u53f7\u7684WT\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3<\/strong> a) RuCo-CAT\/CC\u3001RhCo-CAT\/CC\u3001IrCo-CAT\/CC\u3001Co-CAT\/CC \u548c\u5546\u7528 Pt\/C\/CC \u57281.0 M KOH\u4e2d\u7684HER LSV\u56fe.\u00a0b)\u00a0MCo-CAT\/CC \u548cPt\/C\u50ac\u5316\u5242\u5728100 mA cm-2<\/sup>\u65f6\u8fc7\u7535\u4f4d\u7684\u6bd4\u8f83\u3002c) \u50ac\u5316\u5242\u7684HER Tafel\u3002 d)\u00a0RuCo-CAT\/CC\u3001RhCo-CAT\/CC\u3001IrCo-CAT\/CC \u548c Co-CAT\/CC \u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u5bf9HER\u7684Cdl<\/sub>\u503c\u3002e) EIS \u6570\u636e\u3002f) MCo-CAT\/CC\u5728HER\u8fc7\u7a0b\u4e2d\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4<\/strong> a) RuCo-CAT\/CC\u3001RhCo-CAT\/CC\u3001IrCo-CAT\/CC\u3001Co-CAT\/CC \u548c\u5546\u7528 Pt\/C\/CC \u57281.0 M KOH\u4e2d\u7684OER LSV \u56fe\u3002\u00a0b)\u00a0MCo-CAT\/CC\u50ac\u5316\u5242\u572850 mA cm-2<\/sup>\u65f6\u8fc7\u7535\u4f4d\u7684\u6bd4\u8f83\u3002c) \u50ac\u5316\u5242\u7684OER Tafel\u3002d)\u00a0RuCo-CAT\/CC\u3001RhCo-CAT\/CC\u3001IrCo-CAT\/CC\u548cCo-CAT\/CC\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u5bf9OER\u7684Cdl<\/sub>\u503c\u3002e) EIS\u3002f) MCo-CAT\/CC\u5728OER\u8fc7\u7a0b\u4e2d\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5<\/strong> \u00a0a) RuCo-CAT\u548cCo-CAT\u7684DFT\u8ba1\u7b97\u5efa\u6a21\u3002b) H2<\/sub>O\u7684\u5438\u9644\u80fd\uff0cc) H2<\/sub>O \u89e3\u79bb\u7684\u80fd\u91cf\u56fe\uff0c\u548c d) RuCo-CAT \u4e0a\u7684Ru\u3001Co \u4f4d\u70b9\u548cCo-CAT\u4e0a\u7684Co\u4f4d\u70b9\u7684H\u5438\u9644\u81ea\u7531\u80fd\u56fe\u3002e) \u5bf9\u4e8eRuCo-CAT \u4e0a\u7684Ru\u3001Co\u4f4d\u70b9\u548cCo-CAT\u4e0a\u7684Co \u4f4d\u70b9\u7684OER\uff0c DFT\u8ba1\u7b97\u0394G\u3002f) \u673a\u7406\u5206\u6790\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>6<\/strong> a)\u4f7f\u7528RuCo-CAT\u4f5c\u4e3a\u9633\u6781\u548cRuCo-CAT\u4f5c\u4e3a\u6c34\u7535\u89e3\u9634\u6781\u7684\u53cc\u7535\u6781\u7535\u6c60\u793a\u610f\u56fe\u3002b) RuCo-CAT||RuCo-CAT \u548cPt\/C||RuO2<\/sub>\u57281.0 M KOH\u7535\u89e3\u8d28\u4e2d\u7684\u6574\u4f53\u6c34\u7535\u89e3\u6027\u80fd\u3002c) RuCo-CAT||RuCo-CAT\u5bf9\u57281.0 M KOH\u4e2d\u6574\u4f53\u6c34\u7535\u89e3\u7684\u8ba1\u65f6\u7535\u4f4d\u66f2\u7ebf\u3002d)\u57281.0 M KOH \u7535\u89e3\u8d28\u4e2d\uff0c\u572810 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u6765\u81eaRuCo-CAT||RuCo-CAT\u5bf9\u7684\u6d4b\u91cf\uff08\u70b9\uff09\u548c\u7406\u8bba\uff08\u5b9e\u7ebf\uff09\u6c14\u6001\u4ea7\u7269\u3002e)\u6bd4\u8f83\u57281.0 M KOH\u7535\u89e3\u8d28\u4e2dRuCo-CAT||RuCo-CAT\u5bf9\u548c\u5176\u4ed6\u81ea\u652f\u6491\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u6574\u4f53\u6c34\u7535\u89e3\u8fbe\u523010 mA cm-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u6240\u9700\u7684\u7535\u538b\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

 <\/p>\n

 <\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/span><\/p>\n

\u00a0 \u00a0\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u4e00\u9505\u6eb6\u5242\u70ed\u6cd5\u5c55\u793a\u4e86\u4e00\u79cd\u5728\u5bfc\u7535 MOF \u4e2d\u6784\u5efa\u7528\u4e8e\u6c34\u5206\u89e3\u7684\u53cc\u6d3b\u6027\u4f4d\u70b9\u7684\u6709\u6548\u7b56\u7565\u3002\u8fd9\u9879\u7814\u7a76\u7ed3\u679c\u5f3a\u8c03\u4e86\u5bfc\u7535 MOF\u53ef\u4ee5\u4f5c\u4e3a\u9ad8\u6548\u7684\u6c34\u5206\u89e3\u53cc\u529f\u80fd\u50ac\u5316\u5242\uff0c\u800cMOF\u4e2d\u8bbe\u8ba1\u53cc\u6d3b\u6027\u4f4d\u70b9\u662f\u5f00\u53d1\u53ef\u7528\u4e8e\u80fd\u91cf\u8f6c\u6362\u548c\u5b58\u50a8\u9886\u57df\u5404\u79cd\u5e94\u7528\u7684\u53cc\u529f\u80fd\u50ac\u5316\u5242\u7684\u6709\u6548\u65b9\u6cd5\u4e4b\u4e00\u3002<\/strong><\/p>\n

\u00a0<\/strong><\/p>\n

\u00a0<\/strong><\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a<\/strong> https:\/\/doi.org\/10.1002\/aenm.202204177<\/a><\/p>\n

\u672c\u6587\u7531K . L\u64b0\u7a3f\u3002<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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