{"id":249537,"date":"2023-04-06T08:19:37","date_gmt":"2023-04-06T00:19:37","guid":{"rendered":"\/\/m.iemloyee.com\/?p=249537"},"modified":"2023-04-06T08:48:47","modified_gmt":"2023-04-06T00:48:47","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e6%9c%80%e6%96%b0nature%ef%bc%9a%e5%9f%ba%e4%ba%8elacl3%e7%9a%84%e9%94%82%e8%b6%85%e7%a6%bb%e5%ad%90%e5%af%bc%e4%bd%93%e5%8f%af%e4%b8%8e%e9%94%82%e9%87%91%e5%b1%9e%e5%85%bc","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=249537","title":{"rendered":"\u4e2d\u79d1\u5927&#038;\u6d59\u5de5\u5927\u6700\u65b0Nature\uff1a\u57fa\u4e8eLaCl3\u7684\u9502\u8d85\u79bb\u5b50\u5bfc\u4f53\u53ef\u4e0e\u9502\u91d1\u5c5e\u517c\u5bb9"},"content":{"rendered":"<p style=\"text-align: center;\"><strong>\u4e00\u3001<\/strong> <strong>\u3010\u5bfc\u8bfb\u3011<\/strong><strong>\u00a0 <\/strong><\/p>\n<p>\u5168\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\uff08ASSLMBs\uff09\u7684\u4f7f\u7528\u53ef\u4ee5\u89e3\u51b3\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5b89\u5168\u548c\u80fd\u91cf\u5bc6\u5ea6\u95ee\u9898\u3002\u4f5c\u4e3aASSLMBs\u7684\u91cd\u8981\u7ec4\u6210\u90e8\u5206\uff0c\u5c3d\u7ba1\u56fa\u6001\u7535\u89e3\u8d28\uff08SEs\uff09\u76f4\u63a5\u5f71\u54cd\u7535\u6c60\u6027\u80fd\uff0c\u4f46\u6ca1\u6709\u5355\u4e2aSE\u5177\u6709ASSLMBs\u6240\u9700\u7684\u6240\u6709\u6027\u8d28\uff0c\u5305\u62ec\u9ad8\u79bb\u5b50\u5bfc\u7535\u6027\u3001\u7528\u4e8e\u4eb2\u5bc6\u56fa\u4f53-\u56fa\u4f53\u63a5\u89e6\u7684\u8f6f\u6676\u683c\u548c\u5bbd\u7535\u5316\u5b66\u7a97\u53e3\u3002\u7f3a\u4e4f\u8fd9\u4e9b\u5c5e\u6027\u5bfc\u81f4\u5148\u524d\u62a5\u9053\u7684\u65e0\u673aSEs\u5b58\u5728\u7535\u6781\u517c\u5bb9\u6027\u95ee\u9898\uff0c\u9650\u5236\u5b83\u4eec\u5728ASSLMBs\u4e2d\u7684\u5b9e\u9645\u4f7f\u7528\u3002\u56e0\u6b64\uff0c\u5177\u5907ASSLMBs\u7535\u6781\u517c\u5bb9\u6027\u6240\u9700\u7279\u6027\u7684\u9502\u8d85\u79bb\u5b50\u5bfc\u4f53\u5907\u53d7\u671f\u5f85\u3002\u4e5f\u5c31\u662f\u8bf4\uff0c\u65e0\u673a\u8d85\u79bb\u5b50\u5bfc\u4f53\u5177\u6709\u9ad8\u79bb\u5b50\u5bfc\u7535\u6027\u548c\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u4f46\u5176\u4e0e\u9502\u91d1\u5c5e\u7535\u6781\u7684\u754c\u9762\u76f8\u5bb9\u6027\u5dee\uff0c\u963b\u788d\u4e86\u5728\u5168\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u4e2d\u79d1\u5927\u59da\u5b8f\u658c\u6559\u6388\uff0c\u674e\u9707\u5b87\u6559\u6388\u8054\u5408\u6d59\u6c5f\u5de5\u4e1a\u5927\u5b66\u9676\u65b0\u6c38\u6559\u6388\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8eLaCl<sub>3<\/sub>\u7684\u9502\u8d85\u79bb\u5b50\u5bfc\u4f53\uff0c\u4e0e\u9502\u91d1\u5c5e\u7535\u6781\u5177\u6709\u826f\u597d\u7684\u754c\u9762\u517c\u5bb9\u6027\u3002\u76f8\u5bf9\u4e8eLi<sub>3<\/sub>MCl<sub>6<\/sub>\uff08M = Y\uff0cIn\uff0cSc\u548cHo\uff09\u7535\u89e3\u8d28\u6676\u683c\uff0cUCl<sub>3<\/sub>\u578bLaCl<sub>3<\/sub>\u6676\u683c\u5177\u6709\u5927\u578b\u4e00\u7ef4\u901a\u9053\uff0c\u53ef\u5b9e\u73b0\u5feb\u901f\u7684Li<sup>+<\/sup>\u4f20\u5bfc\uff0c\u5e76\u901a\u8fc7Ta\u63ba\u6742\u76f8\u4e92\u8fde\u63a5La\u7a7a\u4f4d\uff0c\u5f62\u6210\u4e09\u7ef4Li<sup>+<\/sup>\u8fc1\u79fb\u7f51\u7edc\u3002\u7ecf\u8fc7\u4f18\u5316\u7684Li<sub>0.388<\/sub>Ta<sub>0.238<\/sub>La<sub>0.475<\/sub>Cl<sub>3<\/sub>\u7535\u89e3\u8d28\uff0c\u572830\u2103\u65f6\u5177\u67093.02 mS cm<sup>-1<\/sup>\u7684Li<sup>+<\/sup>\u5bfc\u7535\u7387\u548c0.197 eV\u7684\u4f4e\u6fc0\u6d3b\u80fd\u3002\u5b83\u8fd8\u751f\u6210\u4e86\u68af\u5ea6\u754c\u9762\u949d\u5316\u5c42\uff0c\u7528\u4e8e\u7a33\u5b9aLi\u91d1\u5c5e\u7535\u6781\u8fdb\u884c\u957f\u671f\u5faa\u73af\u3002\u5f53\u76f4\u63a5\u4e0e\u672a\u6d82\u5c42\u7684LiNi<sub>0.5<\/sub>Co<sub>0.2<\/sub>Mn<sub>0.3<\/sub>O<sub>2<\/sub>\u6b63\u6781\u548c\u88f8\u9732\u7684Li\u91d1\u5c5e\u8d1f\u6781\u76f8\u8026\u5408\u65f6\uff0cLi<sub>0.388<\/sub>Ta<sub>0.238<\/sub>La<sub>0.475<\/sub>Cl<sub>3<\/sub>\u7535\u89e3\u8d28\u80fd\u591f\u4f7f\u56fa\u6001\u7535\u6c60\u4ee54.35 V\u7684\u622a\u6b62\u7535\u538b\u548c1 mAh cm<sup>-2<\/sup>\u4ee5\u4e0a\u7684\u9762\u79ef\u5bb9\u91cf\u8fd0\u884c100\u591a\u4e2a\u5468\u671f\u3002\u6b64\u5916\u8fd8\u5c55\u793a\u4e86\u9567\u7cfb\u91d1\u5c5e\u6c2f\u5316\u7269\uff08LnCl3\uff1bLn = La\u3001Ce\u3001Nd\u3001Sm\u548cGd\uff09\u4e2d\u7684\u5feb\u901fLi<sup>+<\/sup>\u4f20\u5bfc\uff0c\u8fd9\u8868\u660eLnCl<sub>3<\/sub>\u56fa\u6001\u7535\u89e3\u8d28\u7cfb\u7edf\u53ef\u4ee5\u63d0\u4f9b\u8fdb\u4e00\u6b65\u7684\u4f20\u5bfc\u6027\u548c\u5b9e\u7528\u6027\u53d1\u5c55\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cA LaCl<sub>3<\/sub>-based lithium superionic conductor compatible with lithium metal\u201d\u53d1\u8868\u5728<em>Nature<\/em>\u4e0a\u3002<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249538\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-5.png\" alt=\"\" width=\"1116\" height=\"651\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-5.png 1116w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-5-300x175.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-5-768x448.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-5-1024x597.png 1024w\" sizes=\"(max-width: 1116px) 100vw, 1116px\" \/><\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u00a0<\/strong><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u8fd9\u9879\u7814\u7a76\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8eLaCl<sub>3<\/sub>\u7684\u9502\u8d85\u79bb\u5b50\u5bfc\u4f53\uff0c\u5177\u6709\u4e0e\u9502\u91d1\u5c5e\u7535\u6781\u826f\u597d\u7684\u754c\u9762\u517c\u5bb9\u6027\uff0c\u53ef\u7528\u4e8e\u5b9e\u73b0\u5b89\u5168\u4e14\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u5168\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u00a0<\/strong><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-249539 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-6.png\" alt=\"\" width=\"415\" height=\"379\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-6.png 415w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-6-300x274.png 300w\" sizes=\"(max-width: 415px) 100vw, 415px\" \/><\/strong><\/p>\n<p>\u56fe1:\u57fa\u4e8eLaCl<sub>3<\/sub>\u6676\u683c\u7684Li<sup>+<\/sup>\u8d85\u79bb\u5b50\u5bfc\u4f53\u7ed3\u6784\u6a21\u578b\u53ca\u5176Li<sup>+<\/sup>\u8fc1\u79fb\u673a\u7406\u3002 @2023 Springer Nature<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-249540 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-5.png\" alt=\"\" width=\"415\" height=\"535\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-5.png 415w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-5-233x300.png 233w\" sizes=\"(max-width: 415px) 100vw, 415px\" \/><\/p>\n<p>\u56fe2:Li<sub>x<\/sub>Ta<sub>y<\/sub>La<sub>z<\/sub>Cl<sub>3<\/sub>\u4e2dLi<sup>+<\/sup>\u7684\u7535\u5bfc\u7387\u548cLi<sup>+<\/sup>\u5316\u5b66\u73af\u5883\u7684\u8bc6\u522b\u3002 \u00a0@2023 Springer Nature<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-249541 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-3.png\" alt=\"\" width=\"415\" height=\"418\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-3.png 415w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-3-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-3-298x300.png 298w\" sizes=\"(max-width: 415px) 100vw, 415px\" \/><\/p>\n<p>\u56fe3:Li<sub>0.388<\/sub>Ta<sub>0.238<\/sub>La<sub>0.475<\/sub>Cl<sub>3 <\/sub>SE\u5bf9Li\u91d1\u5c5e\u7535\u6781\u7684\u754c\u9762\u7a33\u5b9a\u6027\u3002 @2023 Springer Nature<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-249542 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-3.png\" alt=\"\" width=\"415\" height=\"470\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-3.png 415w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-3-265x300.png 265w\" sizes=\"(max-width: 415px) 100vw, 415px\" \/><\/p>\n<p>\u56fe\u56fe4:Li\/Li<sub>0.388<\/sub>Ta<sub>0.238<\/sub>La<sub>0.475<\/sub>Cl<sub>3<\/sub>\/NCM523 ASSLMB\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002@2023 Springer Nature<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u603b\u8a00\u4e4b\uff0c\u672c\u7814\u7a76\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8eLaCl<sub>3<\/sub>\u7684\u9502\u8d85\u79bb\u5b50\u5bfc\u4f53\uff0c\u5177\u6709\u72ec\u7279\u7684UCl3\u578b\u7ed3\u6784\u3002\u7ecf\u8fc7\u4f18\u5316\u7684Li<sub>0.388<\/sub>Ta<sub>0.238<\/sub>La<sub>0.475<\/sub>Cl<sub>3<\/sub>\u56fa\u6001\u7535\u89e3\u8d28\u5177\u6709\u9ad8\u79bb\u5b50\u5bfc\u7535\u6027\u548c\u4f18\u5f02\u7684\u7535\u6781\u517c\u5bb9\u6027\uff0c\u5728\u53ef\u5b9e\u73b01.16 mAh cm<sup>-2<\/sup>\u9762\u79ef\u5bb9\u91cf\u4e0b\uff0c\u4f7f\u5f97Li\/Li<sub>0.388<\/sub>Ta<sub>0.238<\/sub>La<sub>0.475<\/sub>Cl<sub>3<\/sub>\/NCM523\u5168\u7535\u6c60\u7a33\u5b9a\u5faa\u73af\u3002\u6b64\u7814\u7a76\u4e0d\u4ec5\u5c55\u793a\u4e86\u57fa\u4e8eLaCl<sub>3<\/sub>\u7684\u56fa\u6001\u7535\u89e3\u8d28\u7684\u7535\u6781\u517c\u5bb9\u6027\uff0c\u8fd8\u542f\u53d1\u4e86\u57fa\u4e8eLnCl<sub>3<\/sub>\u6676\u683c\u7684\u5168\u65b0UCl<sub>3<\/sub>\u578b\u56fa\u6001\u7535\u89e3\u8d28\u4f53\u7cfb\uff08Ln = La\u3001Ce\u3001Nd\u3001Sm\u548cGd\uff09\uff0c\u53ef\u63d0\u4f9b\u591a\u79cd\u5143\u7d20\u63ba\u6742\u9009\u62e9\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u539f\u6587\u8be6\u60c5\uff1a Yin, YC., Yang, JT., Luo, JD. et al. A LaCl<sub>3<\/sub>-based lithium superionic conductor compatible with lithium metal. <em>Nature<\/em> 616, 77\u201383 (2023).<\/p>\n<p>https:\/\/doi.org\/10.1038\/s41586-023-05899-8<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001 \u3010\u5bfc\u8bfb\u3011\u00a0 \u5168\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\uff08ASSLMBs\uff09\u7684\u4f7f\u7528\u53ef\u4ee5\u89e3\u51b3\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5b89\u5168\u548c\u80fd\u91cf\u5bc6\u5ea6\u95ee\u9898\u3002\u4f5c\u4e3aASSLMBs\u7684\u91cd\u8981\u7ec4\u6210\u90e8\u5206\uff0c\u5c3d\u7ba1\u56fa\u6001\u7535\u89e3\u8d28\uff08SEs\uff09&#8230;<\/p>\n","protected":false},"author":48614,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-249537","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/249537"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/48614"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=249537"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/249537\/revisions"}],"predecessor-version":[{"id":249549,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/249537\/revisions\/249549"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=249537"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=249537"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=249537"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}