{"id":249523,"date":"2023-04-19T06:37:26","date_gmt":"2023-04-18T22:37:26","guid":{"rendered":"\/\/m.iemloyee.com\/?p=249523"},"modified":"2023-04-17T11:23:29","modified_gmt":"2023-04-17T03:23:29","slug":"%e8%8b%b1%e5%9b%bd%e7%89%9b%e6%b4%a5%e5%a4%a7%e5%ad%a6%e6%9c%80%e6%96%b0nature-energy%ef%bc%9a%e9%94%82-%e9%92%a0%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e6%b0%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=249523","title":{"rendered":"\u725b\u6d25\u5927\u5b66\u6700\u65b0Nature Energy\uff1a\u9502\/\u94a0\u79bb\u5b50\u7535\u6c60\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u4e2d\u6c27\u7684\u79bb\u57df\u7535\u5b50\u7a7a\u7a74"},"content":{"rendered":"<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><strong><b>[\u5bfc\u8bfb]<\/b><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u6b63\u6781\u4e2d\u7684\u6c27\u5316\u7269\u79bb\u5b50\u53ef\u4ee5\u5728\u9ad8\u7535\u538b\u4e0b\u50a8\u5b58\u7535\u8377\uff0c\u4e3a\u66f4\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u6761\u9014\u5f84\u3002\u7136\u800c\uff0c\u5728\u7ed9\u8fd9\u4e9b\u6b63\u6781\u5145\u7535\u65f6\uff0c\u88ab\u6c27\u5316\u7684\u6c27\u5316\u7269\u79bb\u5b50\u4f1a\u51dd\u7ed3\u5f62\u6210\u5206\u5b50O<sub>2<\/sub>\u88ab\u56f0\u5728\u6750\u6599\u4e2d\u3002\u56e0\u6b64\uff0c\u653e\u7535\u7535\u538b\u8fdc\u4f4e\u4e8e\u5145\u7535\u7535\u538b\uff0c\u5bfc\u81f4\u4e0d\u7406\u60f3\u7684\u7535\u538b\u6ede\u540e\u3002<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p style=\"text-align: right;\"><strong><b>[\u6210\u679c\u63a0\u5f71]<\/b><\/strong><\/p>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p><strong><b>\u5728\u8fd9\u9879\u7814\u7a76\u4e2d\uff0c\u82f1\u56fd\u725b\u6d25\u5927\u5b66Robert A. House<\/b><\/strong><strong><b>\u3001Peter G. Bruce<\/b><\/strong><strong><b>\u6559\u6388\u8bfe\u9898\u7ec4<\/b><\/strong><strong><b>\u901a\u8fc7\u5229\u7528\u5e26\u72b6\u6709\u5e8fNa<\/b><\/strong><strong><sub><b>0.6<\/b><\/sub><\/strong><strong><b>[Li<\/b><\/strong><strong><sub><b>0.2<\/b><\/sub><\/strong><strong><b>Mn<\/b><\/strong><strong><sub><b>0.8<\/b><\/sub><\/strong><strong><b>]O<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u4e2d\u88ab\u6291\u5236\u7684\u8fc7\u6e21\u91d1\u5c5e\u91cd\u6392\u6765\u6355\u83b7O<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>-\u5728O<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u5f62\u6210\u4e4b\u524d\u7684\u7535\u5b50\u7a7a\u7a74\u7684\u6027\u8d28<\/b><\/strong>\u3002\u7814\u7a76\u4eba\u5458\u53d1\u73b0\uff0c\u5728\u8fc7\u6e21\u91d1\u5c5e\u5c42\u4e2d\u5f62\u6210\u7684\u7535\u5b50\u7a7a\u7a74\u662f\u5728\u4e0e\u4e24\u4e2aMn(O-Mn<sub>2<\/sub>)\u914d\u4f4d\u7684\u6c27\u5316\u7269\u79bb\u5b50\u4e0a\u79bb\u57df\u7684\u3002\u8fdb\u4e00\u6b65\u5730\uff0c\u672c\u5de5\u4f5c\u8ffd\u8e2a\u8fd9\u4e9b\u79bb\u57df\u7684\u7a7a\u7a74\u6001\uff0c\u56e0\u4e3a\u5b83\u4eec\u5728\u4e00\u6bb5\u65f6\u95f4\u5185\u9010\u6e10\u4ee5\u6355\u83b7\u5206\u5b50O2\u7684\u5f62\u5f0f\u5728\u7ed3\u6784\u4e2d\u5c40\u57df\u3002\u5982\u679c\u8981\u5b9e\u73b0\u771f\u6b63\u53ef\u9006\u7684\u9ad8\u538bO-\u6c27\u5316\u8fd8\u539f\u6b63\u6781\uff0c\u786e\u5b9a\u6c27\u5316\u7269\u79bb\u5b50\u4e0a\u7a7a\u7a74\u6001\u7684\u6027\u8d28\u662f\u5f88\u91cd\u8981\u7684\u3002\u76f8\u5173\u8bba\u6587\u4ee5\u9898\u4e3a\uff1a\u201c<em><i>Delocalized electron holes on oxygen in a battery cathode<\/i><\/em>\u201d\u53d1\u8868\u5728<em><i>Nature Energy<\/i><\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249524\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-4.png\" alt=\"\" width=\"723\" height=\"267\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-4.png 723w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72471-4-300x111.png 300w\" sizes=\"(max-width: 723px) 100vw, 723px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6838\u5fc3\u521b\u65b0\u70b9]<\/b><\/strong><\/p>\n<ul>\n<li>\u672c\u5de5\u4f5c\u53d1\u73b0\uff0c<strong><b>O-\u6c27\u5316\u8fd8\u539f<\/b><\/strong><strong><b>\u6b63\u6781<\/b><\/strong><strong><b>\u6750\u6599\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u4ece\u6c27\u5316\u7269\u79bb\u5b50\u4e2d\u53bb\u9664\u7535\u5b50\uff0c\u5bfc\u81f4O <\/b><\/strong><strong><em><b><i>2p<\/i><\/b><\/em><\/strong><strong><b>\u80fd\u5e26\u4e2d\u5f62\u6210\u79bb\u57df\u7535\u5b50\u7a7a\u7a74<\/b><\/strong>\u3002<\/li>\n<li>\u672c\u5de5\u4f5c\u8868\u660e\uff0c\u6c27\u5316\u79bb\u5b50\u4e0a\u5f62\u6210\u7684\u672a\u914d\u5bf9\u7535\u5b50\u5982\u679c\u79bb\u57df\u6bd4\u5c40\u57df\u66f4\u7a33\u5b9a\u3002\u5f62\u6210O<sub>2<\/sub>\u7684\u7f13\u6162\u6f14\u5316\u548c\u672c\u5de5\u4f5c\u4e4b\u524d\u7684\u8ba1\u7b97\u8868\u660e\u5728O<sub>2<\/sub>\u4e2d\u5f62\u6210\u5171\u4ef7\u53cc\u6c27\u952e\u5177\u6709\u5f88\u5f3a\u7684\u7a33\u5b9a\u6027\uff0c\u8fd9\u8868\u660e\u5355\u72ec\u7684\u79bb\u57df\u4e0d\u4f1a\u907f\u514d\u7535\u538b\u6ede\u540e\u3002<\/li>\n<li>\u672c\u5de5\u4f5c\u5bf9\u53ef\u9006O-\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u672c\u8d28\u7684\u7814\u7a76\u4e3a\u5f00\u53d1\u65b0\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u6b63\u6781\u63d0\u9ad8\u4e86\u6307\u5bfc\u3002<\/li>\n<\/ul>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6570\u636e\u6982\u89c8]<\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>Na0<\/b><\/strong><strong><sub><b>.6<\/b><\/sub><\/strong><strong><b>[Li<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>Mn<\/b><\/strong><strong><sub><b>0.8<\/b><\/sub><\/strong><strong><b>]O<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u7684\u65f6\u95f4\u76f8\u5173\u7535\u5316\u5b66\u884c\u4e3a<\/b><\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p>\u6c27\u8fd8\u539f\u6b63\u6781Na<sub>0.6<\/sub>[Li<sub>0.2<\/sub>Mn<sub>0.8<\/sub>]O<sub>2<\/sub>\u7684\u5236\u5907\u65b9\u6cd5\u540c\u4e0a\u3002Na<sub>0.6<\/sub>[Li<sub>0.2<\/sub>Mn<sub>0.8<\/sub>O<sub>2<\/sub>]\u662f\u7531P2\u5806\u79ef\u7684O<sub>2<\/sub>-\u79bb\u5b50(ABBA\u5806\u79ef,\u5176\u4e2dA\u548cB\u4ee3\u8868\u4e0d\u540c\u7684O<sub>2<\/sub>-\u5806\u79ef\u4f4d\u7f6e)\u5c42\u6784\u6210\u7684\u5c42\u72b6\u7ed3\u6784\uff0c\u5176\u4e2dLi\u548cMn\u5360\u636e\u4e00\u5bf9O<sub>2<\/sub>-\u5c42\u4e4b\u95f4\u7684\u516b\u9762\u4f53\u4f4d\u7f6e\uff0c\u5f62\u6210\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269(TMO<sub>2<\/sub>)\u7247\uff0c\u7531Na\u79bb\u5b50(\u56fe1a)\u5c42\u9694\u5f00\u3002Li\u548cMn\u79bb\u5b50\u5728\u6574\u4e2aTMO<sub>2<\/sub>\u5c42\u4e2d\u5448\u5e26\u72b6\u6392\u5217\u3002\u5728\u8fd9\u79cd\u6784\u578b\u4e2d\uff0c\u6c27\u5316\u7269\u79bb\u5b50\u4ee52\uff1a3\u7684\u6bd4\u4f8b\u7ed3\u5408\u5728TMO<sub>2<\/sub>\u7247\u5185\u7684\u4e24\u4e2aMn\u79bb\u5b50(\u548c\u4e00\u4e2aLi)\u4e0a\u3002\u56fe1b\u4e3aNa<sub>0.6<\/sub>[Li<sub>0.2<\/sub>Mn<sub>0.8<\/sub>]O<sub>2<\/sub>\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u9996\u6b21\u5faa\u73af\u7684\u7535\u5316\u5b66\u8d1f\u8f7d\u66f2\u7ebf\u3002Na\u5728\u5145\u7535\u65f6\u88ab\u53bb\u9664\uff0c\u653e\u7535\u65f6\u91cd\u65b0\u5d4c\u5165\u3002\u9996\u6b21\u5145\u7535\u65f6\u89c2\u5bdf\u5230\u7684\u9ad8\u538b\u5e73\u53f0\u5927\u591a\u5728\u540e\u7eed\u653e\u7535\u65f6\u8fd4\u56de\u3002\u8de8\u8d8a\u8fd9\u4e2a\u5e73\u53f0\uff0c\u5e26\u7535\u7ed3\u6784\u4ee5\u727a\u7272\u539f\u59cb\u6750\u6599\u4e3a\u4ee3\u4ef7\u4f5c\u4e3a\u7b2c\u4e8c\u76f8\u5f62\u6838\u5e76\u957f\u5927\u3002\u672c\u5de5\u4f5c\u4e4b\u524d\u7684\u7814\u7a76\u8868\u660e\uff0c\u8fd9\u79cd\u5e26\u7535\u76f8\u4fdd\u7559\u4e86\u5e26\u72b6\u6709\u5e8f\u7ed3\u6784\uff0c\u4f46Li\u79bb\u5b50\u4eceMn\u5c42\u7f6e\u6362\u5230\u76f8\u90bb\u7684\u5c42\u95f4\u3002TMO<sub>2<\/sub>\u5c42\u677f\u6ed1\u79fb\u5f62\u6210O<sub>2<\/sub>\u5806\u79ef\uff0cLi<sup>+<\/sup>\u88ab\u5bb9\u7eb3\u5728\u5c42\u677f\u95f4\u7684\u516b\u9762\u4f53\u4f4d\u7f6e\uff0c\u5728TM\u5c42\u4e2d\u7559\u4e0b\u5e26\u72b6\u6709\u5e8f\u6392\u5217\u7684\u9633\u79bb\u5b50\u7a7a\u4f4d\u3002<\/p>\n<p>\u7814\u7a76\u4e86Na<sub>0.6<\/sub>[Li<sub>0.2<\/sub>Mn<sub>0.8<\/sub>]O<sub>2<\/sub>\u7684\u7535\u5316\u5b66\u8d1f\u8f7d\u66f2\u7ebf\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff0c\u53d1\u73b0\u653e\u7535\u8fc7\u7a0b\u53d1\u751f\u4e86\u53d8\u5316\u3002\u5982\u679c\u7535\u6c60\u5728\u5145\u7535\u7ed3\u675f\u65f6\u5904\u4e8e\u9759\u606f\u72b6\u6001\uff0c\u968f\u7740\u65f6\u95f4\u7684\u589e\u52a0\uff0c\u5728\u653e\u7535(\u56fe1c,d)\u65f6\uff0c\u5e73\u53f0\u7684\u957f\u5ea6\u9010\u6e10\u51cf\u5c0f\uff0c\u7535\u538b\u9010\u6e10\u964d\u4f4e\uff0c\u659c\u7387\u9010\u6e10\u589e\u5927\u3002\u8fd9\u4e9b\u89c2\u5bdf\u8868\u660e\uff0c\u5e26\u7535\u7269\u8d28\u7684\u7ed3\u6784\u6b63\u5728\u53d1\u751f\u4e0e\u65f6\u95f4\u76f8\u5173\u7684\u53d8\u5316\uff0c\u4f7f\u5f97Na\u5728\u968f\u540e\u7684\u653e\u7535\u8fc7\u7a0b\u4e2d\u91cd\u65b0\u63d2\u5165\u5230\u4e0d\u540c\u7684\u7ed3\u6784\u4e2d\u3002\u56e0\u6b64\uff0cNa<sub>0.6<\/sub>[Li<sub>0.2<\/sub>Mn<sub>0.8<\/sub>]O<sub>2<\/sub>\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6355\u83b7\u548c\u68c0\u6d4b\u6c27\u5316O\u539f\u5b50\u7684\u673a\u4f1a\uff0c\u8be5\u539f\u5b50\u8d1f\u8d23\u53ef\u9006\u7684\u3001\u9ad8\u538b\u7684O\u6c27\u5316\u8fd8\u539f\uff0c\u5728O\u539f\u5b50\u51dd\u7ed3\u6210O<sub>2<\/sub>\u4e4b\u524d\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249525\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-4.png\" alt=\"\" width=\"736\" height=\"511\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-4.png 736w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72472-4-300x208.png 300w\" sizes=\"(max-width: 736px) 100vw, 736px\" \/><\/p>\n<p>\u56fe1. Na<sub>0.6<\/sub>[Li<sub>0.2<\/sub>Mn<sub>0.8<\/sub>]O<sub>2<\/sub>\u7684\u7ed3\u6784\u548c\u7535\u5316\u5b66\u6027\u80fd\u7814\u7a76\u00a9 2023 Springer Nature Limited<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><\/b><strong><b>\u6c27\u5316\u6001O\u7684\u78c1\u6027<\/b><\/strong><\/li>\n<\/ul>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p>\u7136\u540e\u5bf9\u5145\u7535\u81f34.5\u2009V\u7684\u6837\u54c1\u8fdb\u884cSQUID\u6d4b\u91cf\uff0c\u5728\u8fdb\u884cSQUID\u6d4b\u91cf\u4e4b\u524d\uff0c\u4ece\u5176\u7ec6\u80de\u4e2d\u63d0\u53d6\u5e76\u7559\u4e0b\u4e0d\u540c\u7684\u65f6\u95f4\u3002\u56fe2 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loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249526\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-2.png\" alt=\"\" width=\"634\" height=\"362\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-2.png 634w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72473-2-300x171.png 300w\" sizes=\"(max-width: 634px) 100vw, 634px\" \/><\/p>\n<p>\u56fe2. SQUID\u78c1\u529b\u4eea\u00a9 2023 Springer Nature Limited<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249527\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-2.png\" alt=\"\" width=\"593\" height=\"579\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-2.png 593w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72474-2-300x293.png 300w\" sizes=\"(max-width: 593px) 100vw, 593px\" \/><\/p>\n<p>\u56fe3. <sup>17<\/sup>O\u6838\u78c1\u5171\u632f\u8c31\u548cDFT\u6a21\u62df\u7684\u7535\u5b50\u81ea\u65cb\u5bc6\u5ea6\u00a9 2023 Springer Nature Limited<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249528\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72475-1.png\" alt=\"\" width=\"582\" height=\"521\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72475-1.png 582w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72475-1-300x269.png 300w\" sizes=\"(max-width: 582px) 100vw, 582px\" \/><\/p>\n<p>\u56fe4. <sup>17<\/sup>O\u6838\u78c1\u5171\u632f\u968f\u65f6\u95f4\u6f14\u5316\u00a9 2023 Springer Nature Limited<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><\/b><strong><b>\u6c27\u5316\u6001O\u7684\u5149\u8c31\u8868\u5f81<\/b><\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p>\u5bf9O\u7684K\u8fb9\u8fdb\u884c\u4e86\u5149\u8c31\u7814\u7a76\uff0c\u63a2\u7a76\u4e86\u9759\u7f6e\u4e00\u5929\u548c\u4e00\u4e2a\u6708\u540e\u5e26\u7535\u6750\u6599\u4e2dO\u7684\u7535\u5b50\u7ed3\u6784\u3002\u91c7\u7528\u9ad8\u5206\u8fa8\u5171\u632f\u975e\u5f39\u6027X\u5c04\u7ebf\u6563\u5c04(RIXS)\u548c\u8f6fX\u5c04\u7ebf\u6563\u5c04(XAS)\u5206\u522b\u6d4b\u91cf\u4e86\u586b\u5145\u548c\u7a7aO <em><i>2p<\/i><\/em>\u6001\u3002\u901a\u8fc7\u6536\u96c6\u6a2a\u8de8O K\u8fb9\u7f18\u7684\u4e00\u7cfb\u5217\u4e0d\u540c\u6fc0\u53d1\u80fd\u91cf(y\u8f74)\u4e0b\u7684\u53d1\u5c04\u5149\u8c31(x\u8f74)\u5f97\u5230O RIXS\u56fe\u8c31(\u56fe5a)\u3002\u4f4d\u4e8e528\u2009eV\u5904\u7684\u7279\u5f81\u5728XAS\u4e2d\u5f88\u660e\u663e\uff0c\u5f52\u5c5e\u4e8e\u7535\u8377\u8fc7\u7a0b\u4e2d\u5728\u6676\u683cO\u4e0a\u5f62\u6210\u7684\u7535\u5b50\u7a7a\u7a74\u3002\u5728RIXS\u56fe\u4e2d\u7684\u8fd9\u4e2a\u6fc0\u53d1\u80fd\u91cf\u4e0b\uff0c\u89c2\u5bdf\u5230\u4ee5\u5f39\u6027\u7ebf\u4e0b\u65b91\u2009eV\u4e3a\u4e2d\u5fc3\u7684\u5f3a\u70c8\u80fd\u91cf\u635f\u5931\u7279\u5f81\uff0c\u4e0eO-Mn<sub>2<\/sub>\u6001\u90e8\u5206\u8017\u5c3d\u5e26\u4e2d\u7684\u5269\u4f59\u7535\u5b50\u6709\u5173\u3002\u8fd8\u6709\u8bc1\u636e\u8868\u660e\u53d1\u5c04\u5f3a\u5ea6\u57280~1\u2009eV\u80fd\u91cf\u635f\u5931\u4e4b\u95f4\uff0c\u5c06\u8fd9\u4e00\u7279\u5f81\u4e0e\u5f39\u6027\u7ebf\u8054\u7cfb\u8d77\u6765\uff0c\u8868\u660e\u8be5\u6ce2\u6bb5\u4e00\u76f4\u5230\u8d39\u7c73\u80fd\u7ea7\u90fd\u5b58\u5728\u7535\u5b50\u6001\uff0c\u652f\u6301\u8fd9\u4e9b\u65b0\u7684O <em><i>2p<\/i><\/em>\u7535\u5b50\u6001\u79bb\u57df\u7684\u7ed3\u8bba\u3002<\/p>\n<p>\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5bf9\u4e8e\u4e00\u4e2a\u6708\u7684\u6837\u54c1\uff0c\u5728XAS\u548cRIXS\u56fe\u4e2d\u770b\u5230\u7684528\u2009eV\u7279\u5f81\u7684\u5f3a\u5ea6\u6709\u660e\u663e\u7684\u4e0b\u964d\uff0c\u5e76\u4e14\u5728531.5\u2009eV\u533a\u57df\u6709\u4e00\u4e9b\u5f3a\u5ea6\u589e\u957f\u7684\u8bc1\u636e\u3002\u901a\u8fc7\u5728\u8be5\u6fc0\u53d1\u80fd\u91cf\u4e0b\u8fdb\u884cRIXS\u7ebf\u626b\u63cf\uff0c\u8fdb\u4e00\u6b65\u63a2\u6d4b\u4e86531.5\u2009eV\u5904\u7684\u7279\u5f81\u3002\u5728\u56fe5b\u4e2d\u5f97\u5230\u7684RIXS\u8c31\u7ebf\u626b\u63cf\u63ed\u793a\u4e86\u5206\u5b50O<sub>2<\/sub>\u6c14\u4f53\u5171\u6709\u7684\u4e24\u4e2a\u4e3b\u8981\u7279\u5f81\uff0c\u4e00\u4e2a\u57287.5\u2009eV\u80fd\u91cf\u635f\u5931\u5904\u7684\u5bbd\u5cf0\u548c\u4e00\u7cfb\u5217\u5728\u80fd\u91cf\u635f\u59310-2\u2009eV\u4e4b\u95f4\u7684\u5c16\u5cf0\uff0c\u8fd9\u4e24\u4e2a\u5c16\u5cf0\u7684\u5f3a\u5ea6\u90fd\u968f\u65f6\u95f4\u800c\u589e\u957f\u3002\u8fd9\u4e9b\u7279\u5f81\u53ca\u5176\u5f3a\u5ea6\u968f\u65f6\u95f4\u7684\u53d8\u5316\u4e5f\u89c1\u4e8e\u56fe5a\u4e2d\u7684RIXS\u56fe\u4e2d\uff0c\u5e76\u901a\u8fc7\u865a\u7ebf\u533a\u57df\u51f8\u663e\u51fa\u6765\u3002\u5728528\u2009eV\u5904\u7684\u7279\u5f81\u968f\u65f6\u95f4\u7684\u51cf\u5c0f\u548c531.5\u2009eV\u5904\u7684\u7279\u5f81\u968f\u65f6\u95f4\u7684\u589e\u52a0\u53cd\u6620\u4e86\u6c27\u5316\u7684\u6c27\u5316\u7269\u79bb\u5b50\u5411\u6355\u83b7\u7684\u5206\u5b50O<sub>2<\/sub>\u7684\u8870\u51cf\uff0c\u8fd9\u4e0eSQUID\u548c17O\u6838\u78c1\u5171\u632f\u7684\u6570\u636e\u4e00\u81f4\u3002\u5c3d\u7ba1\u7279\u5f81\u7684\u5f3a\u5ea6\u53d1\u751f\u4e86\u53d8\u5316\uff0c\u4f46\u8fdb\u5c55\u4e2d\u7684\u5cf0\u95f4\u8ddd\u4ecd\u7136\u4e0e\u56fe5c\u548cBirge-Sponer\u56fe(\u56fe5d)\u6240\u793a\u7684\u76f8\u540c\u3002\u8fd9\u4e9b\u5cf0\u6765\u81ea\u4e8eO<sub>2<\/sub>\u5206\u5b50\u5411\u4e0d\u540c\u632f\u52a8\u80fd\u7ea7\u7684\u8dc3\u8fc1\uff0c\u4e0e\u4e4b\u524d\u5728\u5176\u4ed6\u7cfb\u7edf\u4e2d\u6355\u83b7O<sub>2<\/sub>\u7684RIXS\u6570\u636e\u4e00\u81f4\u3002\u95f4\u8ddd\u968f\u65f6\u95f4\u53d8\u5316\u7684\u4e0d\u8db3\u8868\u660eO<sub>2<\/sub>\u7684\u952e\u5408\u6027\u8d28\u4fdd\u6301\u4e0d\u53d8\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249529\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72476-1.png\" alt=\"\" width=\"778\" height=\"524\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72476-1.png 778w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72476-1-300x202.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72476-1-768x517.png 768w\" sizes=\"(max-width: 778px) 100vw, 778px\" \/><\/p>\n<p>\u56fe5. \u6c27K\u8fb9\u5149\u8c31\u00a9 2023 Springer Nature Limited<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><\/b><strong><b>O\u4e0a\u7684\u79bb\u57df\u7535\u5b50\u7a7a\u7a74<\/b><\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p>\u5728\u5927\u591a\u6570\u5df2\u77e5\u7684\u6c27\u5316\u7269\u6b63\u6781\u6750\u6599\u4e2d\uff0c\u968f\u7740\u6c27\u5316\u7269\u79bb\u5b50\u7684\u6c27\u5316\uff0c\u8fc7\u6e21\u91d1\u5c5e\u8fc1\u79fb\u548cO-O\u4e8c\u805a\u5316\u53d1\u751f\uff0c\u8fd9\u4f7f\u5f97\u5efa\u7acbO 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loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249530\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72477-1.png\" alt=\"\" width=\"526\" height=\"557\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72477-1.png 526w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/04\/\u56fe\u72477-1-283x300.png 283w\" sizes=\"(max-width: 526px) 100vw, 526px\" \/><\/p>\n<p>\u56fe6. O\u4e0a\u7684\u79bb\u57df\u7535\u5b50\u7a7a\u7a74\u00a9 2023 Springer Nature Limited<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6210\u679c\u542f\u793a]<\/b><\/strong><\/p>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0cO-\u6c27\u5316\u8fd8\u539f\u6b63\u6781\u6750\u6599\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u4ece\u6c27\u5316\u7269\u79bb\u5b50\u4e2d\u79fb\u9664\u7535\u5b50\uff0c\u5bfc\u81f4O <em><i>2p<\/i><\/em>\u5e26\u4e2d\u5f62\u6210\u79bb\u57df\u7535\u5b50\u7a7a\u7a74\u3002\u8fd9\u4e9b\u5316\u5408\u7269\u901a\u8fc7O <em><i>2p<\/i><\/em>\u6001\u79bb\u57df\u5230\u4ec5\u7531\u4e24\u4e2aMn\u79bb\u5b50(O-Mn<sub>2<\/sub>)\u914d\u4f4d\u7684\u8fc7\u6e21\u91d1\u5c5e\u5c42\u4e2d\u7684\u7a7a\u4f4d\u9633\u79bb\u5b50\u4f4d\u70b9\u3002\u8fd9\u79cd\u914d\u4f4d\u4f5c\u7528\u53d1\u751f\u5728\u8702\u7a9d\u72b6\u6709\u5e8f\u6750\u6599\u4e2d\u7684\u6bcf\u4e2a\u6c27\u4e0a\uff0c\u5b83\u4eec\u6784\u6210\u4e86\u5927\u591a\u6570\u5c42\u72b6O-\u6c27\u5316\u8fd8\u539f\u6b63\u6781\u3002\u901a\u8fc7\u7814\u7a76Na<sub>0.6<\/sub>[Li<sub>0.2<\/sub>Mn<sub>0.8<\/sub>]O<sub>2<\/sub>\uff0c<strong><b>\u8fd9\u4e9bO <\/b><\/strong><strong><em><b><i>2p<\/i><\/b><\/em><\/strong><strong><b>\u6001\u88abO-Mn<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>\u533a\u57df\u5206\u79bb\u6210O-Mn<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u6761\u5e26\uff0c\u6291\u5236\u4e86\u8fc7\u6e21\u91d1\u5c5e\u8fc1\u79fb\uff0c\u4ece\u800c\u6291\u5236\u4e86O<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u7684\u5f62\u6210\uff0c\u5e76\u4e14<\/b><\/strong><strong><b>\u672c\u5de5\u4f5c<\/b><\/strong><strong><b>\u80fd\u591f\u6355\u83b7\u8fd9\u4e9b\u6001\u5728\u6c27\u5316\u6001O\u4e0a\uff0c\u8868\u660e\u5b83\u4eec\u5728\u672c\u8d28\u4e0a\u662f\u79bb\u57df\u7684<\/b><\/strong>\u3002\u6b64\u5916\uff0c\u968f\u7740\u65f6\u95f4\u7684\u63a8\u79fb\uff0c\u672c\u5de5\u4f5c\u9075\u5faa\u8fd9\u4e9b\u79bb\u57df\u7535\u5b50-\u7a7a\u7a74\u6001\uff0c\u56e0\u4e3a\u5b83\u4eec\u51dd\u7ed3\u5f62\u6210\u5206\u5b50O<sub>2<\/sub>\uff0c\u7531\u4e8e\u7f13\u6162\u7684\u8fc7\u6e21\u91d1\u5c5e\u65e0\u5e8f\u5316\u800c\u88ab\u6355\u83b7\u5230\u7ed3\u6784\u4e2d\u3002\u672c\u5de5\u4f5c\u7684\u7ed3\u679c\u8868\u660e\uff0c\u6c27\u5316\u79bb\u5b50\u4e0a\u5f62\u6210\u7684\u672a\u914d\u5bf9\u7535\u5b50\u5982\u679c\u79bb\u57df\u6bd4\u5c40\u57df\u66f4\u7a33\u5b9a\u3002\u5f62\u6210O<sub>2<\/sub>\u7684\u7f13\u6162\u6f14\u5316\u548c\u672c\u5de5\u4f5c\u4e4b\u524d\u7684\u8ba1\u7b97\u8868\u660eO<sub>2<\/sub>\u4e2d\u5171\u4ef7\u53cc\u6c27\u952e\u7684\u5f62\u6210\u5177\u6709\u5f88\u5f3a\u7684\u7a33\u5b9a\u6027\uff0c\u8fd9\u8868\u660e\u5355\u72ec\u7684\u79bb\u57df\u4e0d\u4f1a\u907f\u514d\u7535\u538b\u6ede\u540e\u3002\u6700\u7ec8\uff0c\u5728O\u4e0a\u5f62\u6210\u7a7a\u7a74\u6001\u4e14\u4e0d\u8f6c\u5316\u4e3aO<sub>2<\/sub>\u7684O-\u6c27\u5316\u8fd8\u539f\u6b63\u6781\u6709\u671b\u5f97\u5230\u771f\u6b63\u53ef\u9006\u7684\u6b63\u6781(\u5373\u4ee5\u76f8\u540c\u7684\u9ad8\u538b\u653e\u7535\u4f5c\u4e3a\u5145\u7535)\u3002\u7406\u89e3\u53ef\u9006O-\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u672c\u8d28\u53ef\u4ee5\u89e3\u9501\u65b0\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u6b63\u6781\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u7b2c\u4e00\u4f5c\u8005\uff1aRobert A. House<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1aRobert A. House\u3001Peter G. Bruce<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u82f1\u56fd\u725b\u6d25\u5927\u5b66<\/p>\n<p>\u8bba\u6587doi\uff1a<a href=\"https:\/\/doi.org\/10.1038\/s41560-023-01211-0\"><u>https:\/\/doi.org\/10.1038\/s41560-023-01211-0<\/u><\/a><\/p>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7531\u6e29\u534e\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; [\u5bfc\u8bfb] &nbsp; \u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u6b63\u6781\u4e2d\u7684\u6c27\u5316\u7269\u79bb\u5b50\u53ef\u4ee5\u5728\u9ad8\u7535\u538b\u4e0b\u50a8\u5b58\u7535\u8377\uff0c\u4e3a\u66f4\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u6761\u9014\u5f84\u3002\u7136\u800c\uff0c\u5728\u7ed9\u8fd9\u4e9b\u6b63\u6781\u5145\u7535\u65f6\uff0c\u88ab\u6c27&#8230;<\/p>\n","protected":false},"author":34419,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,4,2],"tags":[5039,3755,1709,2668],"class_list":["post-249523","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-ganhuo","category-keji","tag-5039","tag-3755","tag-1709","tag-2668"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/249523"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/34419"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=249523"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/249523\/revisions"}],"predecessor-version":[{"id":249882,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/249523\/revisions\/249882"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=249523"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=249523"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=249523"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}