{"id":249266,"date":"2023-03-28T06:20:46","date_gmt":"2023-03-27T22:20:46","guid":{"rendered":"\/\/m.iemloyee.com\/?p=249266"},"modified":"2023-03-27T13:38:23","modified_gmt":"2023-03-27T05:38:23","slug":"%e5%8d%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e5%9b%bd%e5%ae%b6%e5%ae%9e%e9%aa%8c%e5%ae%a4%e5%85%88%e8%bf%9b%e5%be%ae%e7%bb%93%e6%9e%84%e5%8d%8f%e5%90%8c%e5%88%9b%e6%96%b0%e4%b8%ad%e5%bf%83%e5%88%86%e5%ad%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=249266","title":{"rendered":"\u5357\u4eac\u5927\u5b66\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u5148\u8fdb\u5fae\u7ed3\u6784\u534f\u540c\u521b\u65b0\u4e2d\u5fc3\u5206\u5b50\u5c42\u6c89\u79ef\u6280\u672f\u539f\u4f4d\u6784\u7b51\u5bcc\u542bLiF\u7684SEI\u5b9e\u73b0\u9502\u91d1\u5c5e\u7535\u6c60\u7a33\u5b9a\u5faa\u73af"},"content":{"rendered":"<p>&nbsp;<\/p>\n<p>\u4e00\u3001 \u3010\u5bfc\u8bfb\u3011 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V vs. SHE)\u4e5f\u6bd4\u77f3\u58a8\u8d1f\u6781\u4f4e\uff0c\u56e0\u6b64\u88ab\u8ba4\u4e3a\u662f\u672a\u6765\u91cd\u8981\u7684\u9502\u7535\u7535\u6c60\u8d1f\u6781\u6750\u6599\u3002\u4f46\u662f\u5728\u6c89\u79ef\u548c\u8131\u9502\u8fc7\u7a0b\u4e2d\uff0c\u9502\u4e0e\u5e38\u7528\u7535\u89e3\u6db2\u5f62\u6210\u7684SEI\u5c42\uff0c\u5bb9\u6613\u53d1\u751f\u7834\u88c2\uff0c\u5bfc\u81f4\u91d1\u5c5e\u9502\u548c\u7535\u89e3\u6db2\u526f\u53cd\u5e94\u7684\u6301\u7eed\u8fdb\u884c\uff0c\u5bb9\u6613\u4ea7\u751f\u5c40\u57df\u975e\u5747\u5300\u6027\u3002\u9502\u7684\u975e\u5747\u5300\u6c89\u79ef\u6700\u540e\u4f1a\u5bfc\u81f4\u9502\u679d\u6676\u751f\u957f\u3002\u4e0d\u53d7\u63a7\u5236\u7684\u9502\u679d\u6676\u4e0d\u4ec5\u4f1a\u5f62\u6210\u4e0d\u53ef\u9006\u7684\u201c\u6b7b\u9502\u201d\uff0c\u5e93\u4ed1\u6548\u7387\u4f4e\uff0c\u5bb9\u91cf\u8870\u51cf\uff0c\u8fd8\u4f1a\u5f15\u53d1\u77ed\u8def\u7b49\u5b89\u5168\u4e8b\u6545\uff0c\u751a\u81f3\u9020\u6210\u707e\u96be\u6027\u7684\u7535\u6c60\u6545\u969c\u963b\u788d\u4e86\u5176\u5728\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u3002 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/p>\n<p>\u8fd1\u65e5\uff0c\u5357\u4eac\u5927\u5b66\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u5148\u8fdb\u5fae\u7ed3\u6784\u534f\u540c\u521b\u65b0\u4e2d\u5fc3\u7684\u674e\u7231\u4e1c\u6559\u6388\u548c\u4e2d\u79d1\u9662\u8fc7\u7a0b\u6240\u7684\u5f20\u4f1a\u521a\u7814\u7a76\u5458\u9886\u5bfc\u7684\u56e2\u961f\uff0c\u5408\u4f5c\u63d0\u51fa\u4e86\u5229\u7528\u5206\u5b50\u5c42\u6c89\u79ef\u6280\u672f\u539f\u4f4d\u6784\u7b51\u5bcc\u542bLiF\u7684SEI\uff0c\u5b9e\u73b0\u9502\u91d1\u5c5e\u7535\u6c60\u7a33\u5b9a\u5faa\u73af\u3002<\/p>\n<p>\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u5177\u6709\u5076\u6781\u77e9\u7684\u950c\u57fa\u5bf9\u82ef\u4e8c\u915a\uff08ZnHQ\uff09\u4e2d\u7684\u542b\u6c27\u5b98\u80fd\u56e2\u53ef\u4ee5\u4f5c\u4e3a\u4eb2\u6838\u57fa\u56e2\uff0c\u63d0\u4f9b\u591a\u4f59\u7684\u7535\u5b50\u52a0\u5feb\u53cc\u4e09\u6c1f\u7532\u78fa\u9170\u80fa\u9502\uff08LiTFSI\uff09\u964d\u89e3\uff0c\u5f97\u5230\u7684\u5bccLiF\u7684SEI\u53ef\u4fc3\u8fdbLi\u79bb\u5b50\u6269\u6563\uff0c\u5e76\u6291\u5236\u94dc\u8868\u9762\u9502\u679d\u72b6\u751f\u957f\u3002\u540c\u65f6\uff0c\u950c\u539f\u5b50\u7684\u4eb2\u9502\u6027\u53ef\u4ee5\u8bf1\u5bfc\u9502\u91d1\u5c5e\u7684\u6c89\u79ef\u3002\u6b64\u5916\uff0c\u591a\u5b54\u652f\u67b6\u548cCuNWs\u7684\u9ad8\u8868\u9762\u79ef\u964d\u4f4e\u4e86\u5c40\u90e8\u7535\u6d41\u5bc6\u5ea6\u5e76\u5ef6\u957f\u4e86\u6851\u5fb7\u65f6\u95f4\uff08Sand&#8217;s time\uff09\u3002\u56e0\u6b64CuNW@ZnHQ\u7535\u6781\u57281 mAh cm\u22122\u7684\u5bb9\u91cf\u4e0b\u8868\u73b0\u51fa\u8d85\u8fc77000\u5c0f\u65f6\u7684\u4f18\u5f02\u5faa\u73af\u80fd\u529b\uff0c\u5e76\u4e14\u5728\u9ad8\u8d1f\u8f7d\u5bb9\u91cf\uff0815 mAh cm\u20132\uff09\u4e0b\u53ef\u4ee5\u4fdd\u6301\u8d85\u8fc7300\u5c0f\u65f6\u3002\u6b64\u5916CuNW@ZnHQ\u4e0e\u4e09\u5143NCM523\u5236\u5907\u7684\u5168\u7535\u6c60\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5faa\u73af\u6027\uff0c1000\u6b21\u5faa\u73af\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a90%\u3002\u8be5\u6587\u7ae0\u53d1\u8868\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aAdvanced Energy Materials\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249267\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u9898\u56fe-10.png\" alt=\"\" width=\"1322\" height=\"395\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u9898\u56fe-10.png 1322w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u9898\u56fe-10-300x90.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u9898\u56fe-10-768x229.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u9898\u56fe-10-1024x306.png 1024w\" sizes=\"(max-width: 1322px) 100vw, 1322px\" \/><\/p>\n<p>\u00a0\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n<p>1.\u5177\u6709\u5076\u6781\u77e9\u7684ZnHQ\u5177\u6709\u5f3a\u4eb2\u6838\u6027\uff0c\u5bfc\u81f4\u5f62\u6210\u5bccLiF\u7684SEI\uff0c\u8fd9\u662f\u826f\u597d\u5faa\u73af\u6027\u80fd\u7684\u57fa\u7840\uff1b<\/p>\n<p>2. ZnHQ\u5c42\u8bf1\u5bfc\u53cd\u5e94\u548cLi\u79bb\u5b50\u901a\u91cf\u7684\u91cd\u65b0\u5206\u5e03\uff0c\u4fc3\u8fdbCuNW\u5468\u56f4\u9502\u91d1\u5c5e\u7684\u5747\u5300\u6c89\u79ef\uff1b<\/p>\n<p>3.\u9ad8\u8868\u9762\u79ef\u964d\u4f4e\u4e86\u5c40\u90e8\u7535\u6d41\u5bc6\u5ea6\uff0c\u6291\u5236\u4e86\u9502\u91d1\u5c5e\u7684\u679d\u6676\u751f\u957f\uff1b<\/p>\n<p>4.\u9502\u5316\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u950c\u539f\u5b50\u7531\u4e8e\u5176\u4eb2\u9502\u6027\u53ef\u63d0\u4f9b\u6210\u6838\u4f4d\u70b9\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249268\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-52.png\" alt=\"\" width=\"917\" height=\"681\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-52.png 917w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-52-300x223.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-52-768x570.png 768w\" sizes=\"(max-width: 917px) 100vw, 917px\" \/><\/p>\n<p><strong>\u56fe 1.<\/strong>\u00a0MLD\u5236\u5907ZnHQ\u8fc7\u7a0b\u53ca\u8bf1\u5bfc\u7684\u5bcc\u542bLiF SEI\u4e0b\u7684\u5747\u5300\u9502\u6c89\u79ef\u8fc7\u7a0b\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249269\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-48.png\" alt=\"\" width=\"805\" height=\"837\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-48.png 805w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-48-289x300.png 289w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-48-768x799.png 768w\" sizes=\"(max-width: 805px) 100vw, 805px\" \/><\/p>\n<p><strong>\u56fe2<\/strong>. a\uff093D\u70e7\u7ed3\u94dc\uff0cb\uff09CuNW@ZnHQ\u548cc\uff093DCuNW@ZnHQ\u7684SEM\u56fe\u50cf; d\uff09ZnHQ\u6d82\u5c42CuNW\u7684TEM\u56fe\u50cf\uff1be\uff09 CuNW@ZnHQ\u7eb3\u7c73\u7ebf\u7684EDS\u5143\u7d20\u56fe\u50cf\uff1bf\uff09CuNW@ZnHQ\u7684SEM\u56fe\u50cf; g\uff09 P\u2212Cu\u548cCuNW\u7684ECSA\u56fe\uff1bh\uff09 P\u2212Cu\uff0cCuNW\uff0cCuNW@ZnHQ.i\uff09ZnHQ\u7684FTIR\u5149\u8c31\u3002ZnHQ:j\uff09C1s\u3001k\uff09O 1s\u548cl\uff09Zn 2p\u4fe1\u53f7\u7684XPS\u5149\u8c31<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249270\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-48.png\" alt=\"\" width=\"1000\" height=\"728\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-48.png 1000w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-48-300x218.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-48-768x559.png 768w\" sizes=\"(max-width: 1000px) 100vw, 1000px\" \/><\/p>\n<p><strong>\u56fe3.<\/strong>\u00a0\u591a\u5b54Cu\uff0cCuNW@ZnHQ\u548cCuNW\u7684\u7535\u5316\u5b66\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002a\uff091 mAh cm<sup>\u2212<\/sup><sup>2<\/sup>\u5bb9\u91cf\u548c0.5 mA cm<sup>\u2212<\/sup><sup>2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684Li\u9540\u5c42\u7535\u538b\u66f2\u7ebf\u3002Li\u5d4c\u5165\/\u8131\u51fa\u7684\u5e93\u4f26\u6548\u7387\uff1b b\uff090.5 mA cm<sup>\u2212<\/sup><sup>2<\/sup>\uff081 mAh cm<sup>\u2212<\/sup><sup>2<\/sup>\uff09\u548cc\uff092 mA cm<sup>\u2212<\/sup><sup>1<\/sup>\uff085 mAh cm<sup>\u20132<\/sup>\uff09\uff0c\u8131\u51fa\u671f\u95f4\u7684\u622a\u6b62\u7535\u538b\u4e3a1.0 V vs.Li<sup>+<\/sup>\/Li\u3002d\uff09\u5728\u5404\u79cd\u7535\u6d41\u5bc6\u5ea6\uff080.5\u81f35 mA cm<sup>\u2212<\/sup><sup>2<\/sup>\uff09\u4e0b\u7684\u500d\u7387\u6027\u80fd\u548c\u7535\u538b\u66f2\u7ebf\u3002e\uff09CuNW\u548cCuNW@ZnHQ\u5728\u7b2c10\u548c\u7b2c100\u4e2a\u5faa\u73af\u4e2d\u3002f\uff095 mA cm<sup>\u2212<\/sup><sup>2<\/sup>\uff0815 mAh cm<sup>\u2212<\/sup><sup>2<\/sup>\uff09\u548cg\uff0ch\uff091 mA cm<sup>\u2212<\/sup><sup>1<\/sup>\uff081 mAh cm<sup>\u20132<\/sup>\uff09\u4e0b\u7684\u65f6\u95f4-\u7535\u538b\u66f2\u7ebf<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249271\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-41.png\" alt=\"\" width=\"1000\" height=\"723\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-41.png 1000w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-41-300x217.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-41-768x555.png 768w\" sizes=\"(max-width: 1000px) 100vw, 1000px\" \/><\/p>\n<p><strong>\u56fe4.<\/strong>\u00a0LiTFSI\u964d\u89e3\u7684\u673a\u7406\u5206\u6790\uff1aCuNW\u548cCuNW@ZnHQ\uff1aa\uff09C 1s\u548cb\uff09F 1s\u4fe1\u53f7\u3002c\uff09 LiTFSI\u548cZnHQ\u8868\u9762\u7684\u9759\u7535\u52bf\u5206\u5e03\u3002d\uff09 \u5e26\u8d1f\u7535\u8377\u7684ZnHQ\u5728Cu\u4e0a\u7684\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u56fe\u3002LiTFSI\u5206\u89e3\u4e4b\u524d\u548c\u4e4b\u540e\u7684e\uff09\u548cf\uff09\u7684\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u56fe\u3002AIMD\u6a21\u62df\u5feb\u7167g\uff090 fs\uff0ch\uff09150 fs\uff0ci\uff09275 fs\uff0c\u548cj\uff09475 fs\u00a0\u00a92023 Advanced Energy Materials<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249272\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-30.png\" alt=\"\" width=\"996\" height=\"703\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-30.png 996w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-30-300x212.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-30-768x542.png 768w\" sizes=\"(max-width: 996px) 100vw, 996px\" \/><\/p>\n<p><strong><b>\u56fe5. <\/b><\/strong>\u591a\u7269\u7406\u573a\u6a21\u62df\u4e0d\u540c\u7ed3\u6784\u6761\u4ef6\u4e0b\u6c89\u79ef\u9502\u7684\u5f62\u6001\u53d8\u5316\uff1aa\uff09CuNW\uff0cd\uff09CuNW@ZnHQ\u548cg\uff09\u94dc\u7b94\u6c89\u79ef\u9502\u5bb9\u91cf\u4e3a2.0 mAh cm<sup>\u2212<\/sup><sup>2<\/sup>\u7684\u9502\u540e\u7684SEM\u56fe\u50cf\u3002b\uff09\u7528COMSOL\u6a21\u62dfCuNW\u7535\u89e3\u8d28\u754c\u9762\u5904Li<sup>+<\/sup>\u901a\u91cf\u7684\u6d41\u7ebf\u65b9\u5411CuNW@ZnHQ\u548ch\uff09\u94dc\u7b94\u3002COMSOL\u6a21\u62df\u7535\u89e3\u8d28\u754c\u9762\u7684\u5c40\u90e8\u7535\u6d41\u5bc6\u5ea6\u5206\u5e03\uff0cc\uff09CuNW\uff0cf\uff09CuNW@ZnHQ\u548ci\uff09\u94dc\u7b94<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-249273\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-20.png\" alt=\"\" width=\"740\" height=\"732\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-20.png 740w, 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\u9502\u5316\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u950c\u539f\u5b50\u7531\u4e8e\u5176\u4eb2\u9502\u6027\u53ef\u63d0\u4f9b\u6210\u6838\u4f4d\u70b9\u3002\u56e0\u6b64\uff0c\u5236\u5907\u76843DCuNW@ZnHQ\u7535\u6781\u5728\u534a\u7535\u6c60\u4e2d\u5b9e\u73b0\u4e86\u8d85\u9ad8\u7684\u5e93\u4ed1\u6548\u7387\uff08300\u6b21\u5faa\u73af\u7684\u5e93\u4ed1\u6548\u7387\u4e3a99%\uff09\uff0c\u57fa\u4e8eLi@CuNW@ZnHQ\u590d\u5408\u7535\u6781\u7684\u5bf9\u79f0\u7535\u6c60\u5bff\u547d\u8d85\u8fc77000\u5c0f\u65f6\u3002\u6b64\u5916\uff0cNCM|Li@ CuNW@ZnHQ\u5168\u7535\u6c60\u80fd\u5b9e\u73b0350 Wh kg<sup>\u22121<\/sup>\u7684\u6bd4\u80fd\u91cf\u548c1000\u6b21\u5faa\u73af\u3002\u8fd9\u9879\u5de5\u4f5c\u8868\u660e\uff0cMLD\u6539\u6027\u591a\u5b54\u94dc\u7eb3\u7c73\u7ebf\u4e3a\u4e0b\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\u91d1\u5c5e\u8d1f\u6781\u96c6\u6d41\u4f53\u63d0\u4f9b\u4e86\u65b0\u7684\u7b56\u7565\u3002<\/p>\n<p>\u539f\u6587\u8be6\u60c5\uff1ahttps:\/\/doi.org\/10.1002\/aenm.202204002<\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; \u4e00\u3001 \u3010\u5bfc\u8bfb\u3011 \u00a0 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