{"id":249241,"date":"2023-04-13T06:05:30","date_gmt":"2023-04-12T22:05:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=249241"},"modified":"2023-04-12T14:05:42","modified_gmt":"2023-04-12T06:05:42","slug":"%e5%93%88%e5%b7%a5%e5%a4%a7%e8%81%94%e5%90%88%e9%bb%91%e9%be%99%e6%b1%9f%e5%a4%a7%e5%ad%a6%ef%bc%9apd3au%e5%82%ac%e5%8c%96%e5%89%82%e4%b8%8aco2%e8%bf%98%e5%8e%9f%e7%94%9f%e6%88%90%e7%94%b2%e9%85%b8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=249241","title":{"rendered":"\u54c8\u5de5\u5927\u8054\u5408\u9ed1\u9f99\u6c5f\u5927\u5b66\uff1aPd3Au\u50ac\u5316\u5242\u4e0aCO2\u8fd8\u539f\u751f\u6210\u7532\u9178\u7684\u663e\u5f0f\u6eb6\u5242\u6a21\u578b\u7406\u8bba\u7814\u7a76"},"content":{"rendered":"

\u4e00\u3001<\/strong> \u3010\u5bfc\u8bfb\u3011<\/strong>\u00a0 <\/strong><\/p>\n

\u968f\u7740\u4eba\u7c7b\u5de5\u4e1a\u5316\u6c34\u5e73\u7684\u4e0d\u65ad\u63d0\u9ad8\uff0cCO2<\/sub>\u6392\u653e\u4e0e\u6d88\u8017\u4e4b\u95f4\u7684\u5e73\u8861\u88ab\u6253\u7834\uff0c\u5bfc\u81f4\u4e00\u7cfb\u5217\u73af\u5883\u95ee\u9898\u3002\u76ee\u524d\uff0c\u51cf\u5c11CO2<\/sub>\u6392\u653e\u4e3b\u8981\u6709\u4e24\u79cd\u7b56\u7565\u3002\u4e00\u79cd\u662f\u6355\u6349\u4e8c\u6c27\u5316\u78b3\u5e76\u5c06\u5176\u5b58\u50a8\u5728\u7a33\u5b9a\u7684\u4ecb\u8d28\u4e2d\u3002\u53e6\u4e00\u79cd\u662f\u5c06CO2<\/sub>\u8f6c\u5316\u4e3a\u6709\u7528\u7684\u5316\u5b66\u54c1\u6216\u71c3\u6599\u3002\u7b2c\u4e8c\u79cd\u7b56\u7565\u7531\u4e8e\u5176\u5de8\u5927\u7684\u73af\u5883\u548c\u7ecf\u6d4e\u6548\u76ca\uff0c\u8fd1\u5e74\u6765\u8d8a\u6765\u8d8a\u53d7\u5230\u7814\u7a76\u8005\u7684\u5173\u6ce8\u3002\u8fd9\u4e9b\u65b9\u6cd5\u5305\u62ec\u5149\u50ac\u5316\u3001\u70ed\u50ac\u5316\u548c\u7535\u5b50\u50ac\u5316\uff0c\u5b83\u4eec\u662f\u5c06CO2<\/sub>\u8f6c\u5316\u4e3a\u6709\u4ef7\u503c\u4ea7\u54c1\u7684\u6709\u524d\u666f\u7684\u65b9\u6cd5\u3002\u5728\u8fd9\u4e9b\u65b9\u6cd5\u4e2d\uff0c\u7535\u5316\u5b66\u8fd8\u539fCO2<\/sub>\uff08CO2<\/sub>RR\uff09\u8fd1\u5e74\u6765\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u7531\u4e8e\u5177\u6709\u4e0d\u540c\u7684\u539f\u5b50\u6392\u5217\u548c\u7535\u5b50\u7ed3\u6784\u7684\u56fa\u4f53\u50ac\u5316\u5242\u5177\u6709\u4e0d\u540c\u7684\u50ac\u5316\u6027\u80fd\uff0c\u56e0\u6b64\uff0c\u5728\u539f\u5b50\u5c42\u9762\u7814\u7a76\u50ac\u5316\u5242\u4e0d\u540c\u6676\u9762\u4e0a\u7684\u53cd\u5e94\u673a\u5236\u6709\u52a9\u4e8e\u66f4\u597d\u5730\u7406\u89e3\u7ed3\u6784-\u6d3b\u6027\u5173\u7cfb\uff0c\u4ece\u800c\u63d0\u9ad8\u50ac\u5316\u5242\u7684\u6d3b\u6027\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u5468\u6b23\u8bfe\u9898\u7ec4\u548c\u9ed1\u9f99\u6c5f\u5927\u5b66\u674e\u660e\u971e\u8bfe\u9898\u7ec4\u91c7\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7814\u7a76\u4e86Pd3<\/sub>Au\u5408\u91d1\u4e0d\u540c\u8868\u9762\u4e0aCO2<\/sub>\u8fd8\u539f\u4e3a\u7532\u9178\u7684\u673a\u5236\uff0c\u5e76\u63ed\u793a\u4e86\u50ac\u5316\u5242\u529f\u51fd\u6570\u548cd-\u5e26\u4e2d\u5fc3\u5dee\u5f02\u4e0e\u8fc7\u7535\u4f4d\u4e4b\u95f4\u7684\u6f5c\u5728\u5173\u7cfb\u3002\u7535\u5b50\u7ed3\u6784\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u50ac\u5316\u5242\u7684\u8868\u9762\u7c97\u7cd9\u5ea6\u548c\u7535\u5b50\u7ed3\u6784\u5171\u540c\u51b3\u5b9a\u4e86CO2<\/sub>\u8fd8\u539f\u4e3a\u7532\u9178\u7684\u50ac\u5316\u6d3b\u6027\u3002\u540c\u65f6\uff0c\u53d1\u73b0\u50ac\u5316\u5242\u8868\u9762\u51c0\u7535\u8377\u4e0eHER\u6d3b\u6027\u4e4b\u95f4\u5b58\u5728\u826f\u597d\u7684\u7ebf\u6027\u5173\u7cfb\u3002\u5177\u6709\u8f83\u4f4e\u8868\u9762\u51c0\u7535\u8377\u7684Pd3<\/sub>Au\uff08110\uff09\u8868\u9762\u53ef\u4ee5\u6709\u6548\u6291\u5236HER\u3002\u6c34\u6eb6\u6db2\u4e2d\u52a8\u6001\u6c22\u952e\u7f51\u7edc\u662f\u51b3\u5b9a\u53cd\u5e94\u673a\u5236\u7684\u5173\u952e\uff0c\u53cd\u6620\u4e86\u6c34\u5206\u5b50\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u4f5c\u7528\uff0c\u8868\u660e\u5728\u8ba1\u7b97\u53cd\u5e94\u673a\u5236\u65f6\u4f7f\u7528\u663e\u5f0f\u6eb6\u5242\u6a21\u578b\u6a21\u62df\u6eb6\u5242\u5316\u6548\u5e94\u7684\u91cd\u8981\u6027\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cTheoretical study on the reduction mechanism of CO2<\/sub> to HCOOH on Pd3Au: an explicit solvent model is essential\u201d\u53d1\u8868\u5728Journal of Materials Chemistry A<\/em>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u00a0<\/strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

\u672c\u7814\u7a76\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u63ed\u793a\u4e86Pd3<\/sub>Au\u5408\u91d1\u4e0d\u540c\u8868\u9762\u4e0aCO2<\/sub>\u8fd8\u539f\u4e3a\u7532\u9178\u7684\u673a\u5236\uff0c\u5e76\u5f3a\u8c03\u4e86\u91c7\u7528\u663e\u5f0f\u6eb6\u5242\u6a21\u578b\u6a21\u62df\u6eb6\u5242\u5316\u6548\u5e94\u5728\u8ba1\u7b97\u53cd\u5e94\u673a\u5236\u4e2d\u7684\u91cd\u8981\u6027\u3002<\/p>\n

\u00a0<\/strong><\/p>\n

\u00a0<\/strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1. \u5728\u6700\u4f73\u5438\u9644\u4f4d\u70b9\u5904\u4f18\u5316\u5f97\u5230\u7684\u53cd\u5e94\u4e2d\u95f4\u4f53\uff08CO2<\/sub>\u3001COOH*<\/sup>\u3001HCOO*<\/sup> \u548c HCOOH*<\/sup>\uff09\u5728\uff08a\uff09Pd3<\/sub>Au\uff08100\uff09\u3001\uff08b\uff09Pd3<\/sub>Au\uff08110\uff09\u3001\uff08c\uff09Pd3<\/sub>Au\uff08111\uff09\u548c\uff08d\uff09Pd3<\/sub>Au\uff08211\uff09\u8868\u9762\u4e0a\u7684\u7ed3\u6784\u3002\u00a9 Royal Society of Chemistry 2023<\/p>\n

\"\"<\/p>\n

\u56fe2. \u4e0d\u540cPd3<\/sub>Au\u8868\u9762\u4e0a\u5404\u79cd\u4e2d\u95f4\u4f53\u7684\uff08a\uff09\u5438\u9644\u80fd\u548c\uff08b\uff09\u51c0\u7535\u8377\u3002\u00a9 Royal Society of Chemistry 2023<\/p>\n

\"\"<\/p>\n

\u56fe3. \uff08a\uff09\u4e0d\u540cPd3<\/sub>Au\u8868\u9762\u4e0aHER\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u3002 \uff08b\uff09\u8868\u9762\u51c0\u7535\u8377\u4e0e\u5409\u5e03\u65af\u81ea\u7531\u80fd\uff08\u0394GH*<\/sub>\uff09\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u00a9 Royal Society of Chemistry 2023<\/p>\n

\"\"<\/p>\n

\u56fe4. \u4e0d\u540cPd3<\/sub>Au\u8868\u9762\u6700\u6709\u5229\u8def\u5f84\u7684\u80fd\u91cf\u56fe\uff08a\uff09\u5728\u96f6\u7535\u6781\u7535\u52bf\u4e0b\u548c\uff08b\uff09\u5728\u4e0d\u540c\u7535\u6781\u7535\u52bf\u4e0b\u3002\u00a9 Royal Society of Chemistry 2023<\/p>\n

\"\"<\/p>\n

\u56fe5. CO2<\/sub>RR\u548cHER\u4e4b\u95f4\u7684\u8fc7\u7535\u4f4d\u5173\u7cfb\u3002\u00a9 Royal Society of Chemistry 2023<\/p>\n

\"\"<\/p>\n

\u56fe6. \u4e0d\u540c\u8868\u9762\u8fc7\u7535\u4f4d\u4e0e\uff08a\uff09COOH*<\/sup>\/HCCO*<\/sup>\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u80fd\u4ee5\u53ca\uff08b\uff09\u529f\u51fd\u6570\u4e0ed-\u5e26\u4e2d\u5fc3\u5dee\u5f02\u4e4b\u95f4\u7684\u5173\u7cfb\u3002 (c) \u4e0d\u540cPd3<\/sub>Au\u8868\u9762\u7684\u6295\u5f71\u6001\u5bc6\u5ea6\u56fe\u548cd-\u5e26\u4e2d\u5fc3\u3002\u00a9 Royal Society of Chemistry 2023<\/p>\n

\"\"<\/p>\n

\u56fe7. \u4e0d\u540c\u6c34\u5206\u5b50\u60c5\u51b5\u4e0bCO2<\/sub> + H+<\/sup> + e\u2212<\/sup> \u2192 COOH*<\/sup>\u7684\u80fd\u5792\u3002\u00a9 Royal Society of Chemistry 2023<\/p>\n

\"\"<\/p>\n

\u56fe8. Pd3<\/sub>Au\uff08111\uff09\u4e0a\u6d89\u53ca\u5230\uff08a\uff09\u3001\uff08b\uff09COOH*<\/sup> \u2192 HCOOH\uff0c\uff08c\uff09\u548c\uff08d\uff09HCOO*<\/sup> \u2192 HCOOH\u7684\u521d\u59cb\u3001\u8fc7\u6e21\u548c\u6700\u7ec8\u72b6\u6001\u7684\u4f18\u5316\u7ed3\u6784\u3002\u00a9 Royal Society of Chemistry 2023<\/p>\n

\"\"<\/p>\n

\u56fe9. Pd3Au\uff08111\uff09\u4e0a\u7ed3\u6784\u6f14\u53d8\u7684\u4ee3\u8868\u6027\u5feb\u7167\uff1a\uff08a\uff09\u3001\uff08b\uff09COOH*<\/sup> \u2192 HCOOH\uff0c\uff08c\uff09\u548c\uff08d\uff09HCOO*<\/sup> \u2192 HCOOH\u3002\u00a9 Royal Society of Chemistry 2023<\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f7f\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7814\u7a76\u4e86Pd3<\/sub>Au\uff08111\uff09\u3001\uff08100\uff09\u3001\uff08110\uff09\u548c\uff08211\uff09\u8868\u9762\u4e0aCO2<\/sub>\u8fd8\u539f\u4e3aHCOOH\u7684\u53cd\u5e94\u673a\u5236\uff0c\u63a2\u8ba8\u4e86\u4e0d\u540c\u8868\u9762\u50ac\u5316\u6d3b\u6027\u5dee\u5f02\u7684\u672c\u8d28\uff0c\u5e76\u63ed\u793a\u4e86\u8ba1\u7b97\u4e2d\u663e\u5f0f\u6eb6\u5242\u6a21\u578b\u7684\u5fc5\u8981\u6027\u3002Pd3<\/sub>Au\u4e0d\u540c\u8868\u9762\u4e0a\u7535\u8377\u5206\u5e03\u7684\u5dee\u5f02\u662f\u5bfc\u81f4\u50ac\u5316\u6d3b\u6027\u5dee\u5f02\u7684\u539f\u56e0\u4e4b\u4e00\u3002 Pd3<\/sub>Au\uff08211\uff09\u548c\uff08111\uff09\u8868\u9762\u5bf9CO2<\/sub>\u8fd8\u539f\u4e3a\u7532\u9178\u5177\u6709\u826f\u597d\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u4e14\u80fd\u5f88\u597d\u5730\u6291\u5236HER\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u50ac\u5316\u5242\u7684\u8868\u9762\u7c97\u7cd9\u5ea6\u548c\u7535\u5b50\u7ed3\u6784\u5171\u540c\u51b3\u5b9a\u50ac\u5316\u6d3b\u6027\u3002\u6c34\u6eb6\u5242\u4e2d\u7684\u6c22\u952e\u7f51\u7edc\u6709\u52a9\u4e8e\u7a33\u5b9a\u4e2d\u95f4\u4f53\u5e76\u4fc3\u8fdb\u6c34\u4e2d\u6c22\u7684\u8f6c\u79fb\u3002\u5b83\u662f\u51b3\u5b9a\u53cd\u5e94\u673a\u5236\u7684\u5173\u952e\uff0c\u5e76\u53cd\u6620\u4e86\u6c34\u5206\u5b50\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u4f5c\u7528\u3002\u603b\u7684\u6765\u8bf4\uff0c\u8fd9\u9879\u5de5\u4f5c\u63ed\u793a\u4e86Pd3<\/sub>Au\u4e0d\u540c\u8868\u9762\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5e76\u4e3a\u5176\u4ed6\u7535\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u7406\u8bba\u6307\u5bfc\u3002<\/p>\n

 <\/p>\n

\u539f\u6587\u8be6\u60c5\uff1aZheng, M., Zhou, X., Wang, Y., Chen, G., and Li, M. (2023). Theoretical study on the reduction mechanism of CO2<\/sub> to HCOOH on Pd3<\/sub>Au: an explicit solvent model is essential. Journal of Materials Chemistry A.<\/p>\n

Doi: 10.1039\/d2ta08552f.<\/p>\n","protected":false},"excerpt":{"rendered":"

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