{"id":249218,"date":"2023-03-26T06:33:22","date_gmt":"2023-03-25T22:33:22","guid":{"rendered":"\/\/m.iemloyee.com\/?p=249218"},"modified":"2023-03-25T21:04:10","modified_gmt":"2023-03-25T13:04:10","slug":"%e6%b8%a4%e6%b5%b7%e5%a4%a7%e5%ad%a6%e9%84%82%e6%b6%9b%e6%9d%8e%e7%b4%a0%e9%9b%85chem-eng-j%e7%b2%be%e5%87%86%e8%b0%83%e6%8e%a7%e7%8b%ad%e7%bc%9d%e5%ad%94%e5%be%84%e6%9e%84%e5%bb%bacuii%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=249218","title":{"rendered":"\u6e24\u6d77\u5927\u5b66\u9102\u6d9b&#038;\u674e\u7d20\u96c5CHEM ENG J:\u7cbe\u51c6\u8c03\u63a7\u72ed\u7f1d\u5b54\u5f84\u6784\u5efaCu(II)\u7684\u9ad8\u6548\u9009\u62e9\u6027"},"content":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u674e\u7d20\u96c5<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u9102\u6d9b<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u6e24\u6d77\u5927\u5b66<\/p>\n<p>DOI\uff1ahttps:\/\/doi.org\/10.1016\/j.cej.2023.142547<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249219\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-49.png\" alt=\"\" width=\"677\" height=\"470\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-49.png 677w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-49-300x208.png 300w\" sizes=\"(max-width: 677px) 100vw, 677px\" \/><\/p>\n<p><strong>\u56fe\u5f62\u6458\u8981<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249220\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-46.png\" alt=\"\" width=\"1269\" height=\"1261\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-46.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-46-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-46-300x298.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-46-768x763.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-46-1024x1018.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p><strong>\u7814\u7a76\u80cc\u666f<\/strong><\/p>\n<p>\u5728\u4ee5\u5f80\u7684\u7814\u7a76\u4e2d\uff0c\u5df2\u7ecf\u5236\u5907\u4e86\u5bf9\u91cd\u91d1\u5c5e\u5177\u6709\u9ad8\u9009\u62e9\u6027\u7684\u5438\u9644\u6750\u6599\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u6750\u6599\u5927\u591a\u662f\u901a\u8fc7\u5f15\u5165\u7279\u5b9a\u7684\u5b98\u80fd\u56e2\u6765\u5b9e\u73b0\u5bf9\u91cd\u91d1\u5c5e\u7684\u9009\u62e9\u6027\u56de\u6536\u3002\u5f88\u5c11\u6709\u7814\u7a76\u805a\u7126\u4e8e\u6750\u6599\u672c\u8eab\u7684\u7ed3\u6784\u3002\u672c\u8bfe\u9898\u7ec4\u7814\u7a76\u53d1\u73b0\uff0c\u5229\u7528GO\u7eb3\u7c73\u7247\u5806\u53e0\u6548\u5e94\u548cSA\u4ea4\u8054\u53ef\u4ee5\u5236\u5907\u51fa\u5177\u6709\u88c2\u9699\u72b6\u7ed3\u6784\u7684\u6c14\u51dd\u80f6\u7403\uff0c\u5bf9\u5e73\u9762Cu(\u2161)\u7684\u9009\u62e9\u6027\u5438\u9644\u9ad8\u8fbe92.75%\u3002\u7814\u7a76\u53d1\u73b0\u6c14\u51dd\u80f6\u7403\u5bf9Cu(II)\u7684\u9009\u62e9\u6027\u5438\u9644\u6027\u80fd\u4e0e\u6c14\u51dd\u80f6\u7403\u4e2d\u72ed\u7f1d\u72b6\u5b54\u9699\u7684\u5bc6\u5ea6\u6709\u5173\u3002\u4ea4\u8054\u673a\u7406\u5206\u6790\u8868\u660e\uff0c\u901a\u8fc7\u8c03\u8282\u4ea4\u8054\u5bc6\u5ea6\u53ef\u4ee5\u83b7\u5f97\u72ed\u7f1d\u72b6\u5b54\u9699\u7684\u5bc6\u5ea6\u3002\u672c\u8bfe\u7ec4\u57fa\u4e8e\u4ef7\u952e\u7406\u8bba\uff0c\u901a\u8fc7\u5206\u6790\u6c14\u51dd\u80f6\u7403\u5b54\u5f84\u8c03\u8282\u5bf9\u5e73\u9762Cu(II)\u9009\u62e9\u6027\u5438\u9644\u6027\u80fd\u7684\u5f71\u54cd\uff0c\u8bba\u8bc1\u4e86SA\u4e0e\u78b1\u571f\u91d1\u5c5e\u79bb\u5b50\uff08Ca<sup>2+<\/sup>\u548cSr<sup>2+<\/sup>\uff09\u7684\u4ea4\u8054\u673a\u7406\u3002\u6211\u4eec\u8fd8\u53ef\u4ee5\u901a\u8fc7\u589e\u52a0\u6c14\u51dd\u80f6\u7403\u4e2d\u542b\u6c27\u5b98\u80fd\u56e2\u7684\u6d53\u5ea6\u6765\u6709\u6548\u8c03\u63a7\u6c14\u51dd\u80f6\u7403\u4e2d\u72ed\u7f1d\u72b6\u5b54\u9699\u7684\u5bc6\u5ea6\uff0c\u4ece\u800c\u9ad8\u6548\u5730\u5b8c\u6210Cu(II)\u7684\u9009\u62e9\u6027\u5438\u9644\u3002\u5c06\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u9897\u7c92\u5f15\u5165\u6c14\u51dd\u80f6\u7403\u5177\u6709\u4ee5\u4e0b\u4f18\u70b9\uff1a(1)\u51cf\u5c11\u6c27\u5316\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\u7684\u805a\u96c6\uff0c\u6709\u6548\u589e\u52a0\u5176\u6bd4\u8868\u9762\u79ef\uff1b(2)\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u9897\u7c92\u8868\u9762\u542b\u6709\u5927\u91cf\u7f9f\u57fa\uff0c\u65e2\u589e\u52a0\u4e86\u6c14\u51dd\u80f6\u7403\u5185\u90e8\u4e09\u7ef4\u7f51\u7edc\u7684\u4ea4\u8054\u5bc6\u5ea6\uff0c\u53c8\u4e3a\u91d1\u5c5e\u79bb\u5b50\u63d0\u4f9b\u4e86\u7ed3\u5408\u4f4d\u70b9\u3002ZrO<sub>2<\/sub>\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u6bd4Fe<sub>2<\/sub>O<sub>3<\/sub>\u3001Al<sub>2<\/sub>O<sub>3<\/sub>\u7b49\u5e38\u89c1\u91d1\u5c5e\u6c27\u5316\u7269\u66f4\u7a33\u5b9a\uff0c\u5176\u7a33\u5b9a\u6027\u3001\u65e0\u6bd2\u3001\u6bd4\u8868\u9762\u79ef\u5927\u3001\u542b\u6709\u4e30\u5bcc\u7684\u8868\u9762\u7f9f\u57fa\u7b49\u7279\u6027\u4f7f\u5176\u6210\u4e3a\u51c0\u6c34\u7406\u60f3\u7684\u5438\u9644\u6750\u6599\u3002\u7136\u800c\uff0cZrO<sub>2<\/sub>\u5728\u6c34\u6eb6\u6db2\u4e2d\u5bb9\u6613\u56e2\u805a\uff0c\u5bfc\u81f4\u6bd4\u8868\u9762\u79ef\u548c\u6d3b\u6027\u4f4d\u663e\u8457\u964d\u4f4e\uff0c\u5bf9\u76ee\u6807\u79bb\u5b50\u7684\u53bb\u9664\u7387\u964d\u4f4e\u3002\u540c\u65f6\uff0cZrO<sub>2<\/sub>\u91ca\u653e\u5230\u6c34\u4e2d\u53ef\u80fd\u4f1a\u5bf9\u81ea\u7136\u690d\u7269\u548c\u52a8\u7269\u9020\u6210\u6f5c\u5728\u5371\u5bb3\u3002\u56e0\u6b64\uff0c\u57fa\u4e8e\u6c27\u5316\u77f3\u58a8\u70ef\u7eb3\u7c73\u7247\u7684\u5806\u79ef\u6548\u5e94\u548c\u4e0eSA\u7684\u4ea4\u8054\uff0c\u5c06ZrO<sub>2<\/sub>\u5305\u88f9\u5728\u65e0\u5bb3\u73af\u4fdd\u7684\u6d77\u85fb\u9178\u94a0\u57fa\u8d28\u4e2d\uff0c\u5e76\u4e0eCa<sup>2+<\/sup>\u4ea4\u8054\uff0c\u6210\u529f\u5236\u5907\u51fa\u5177\u6709\u72ec\u7279\u72ed\u7f1d\u7ed3\u6784\u7684GZS\u6c14\u51dd\u80f6\u7403\uff0c\u660e\u786e\u4e86GZS\u7684\u5b54\u5f84\u4e0e\u5e73\u9762\u6c34\u5408\u94dc\u79bb\u5b50\u7684\u6784\u6548\u673a\u7406\u3002<\/p>\n<p><strong>\u6587\u7ae0\u7b80\u4ecb<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u8fbd\u5b81\u7701\u5316\u5de5\u6e05\u6d01\u751f\u4ea7\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u674e\u7d20\u96c5\u7855\u58eb\u7814\u7a76\u751f\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff0c\u9102\u6d9b\u6559\u6388\u4e3a\u901a\u8baf\u4f5c\u8005\u7684\u7814\u7a76\u6210\u679c\u300aPore size adjustment of sodium alginate-based composite aerogel spheres by zirconia for efficient selective removal of Cu(II)\u300b\u5728\u56fd\u9645\u8457\u540d\u671f\u520a\u300aChemical Engineering Journal\u300b\uff08IF=16.744\uff09\u53d1\u8868\u3002\u672c\u7bc7\u8bba\u6587\u5229\u7528GO\u7eb3\u7c73\u7247\u5806\u53e0\u6548\u5e94\u548cSA\u4ea4\u8054\u5236\u5907\u51fa\u5177\u6709\u72ed\u7f1d\u72b6\u7ed3\u6784\u7684\u6c14\u51dd\u80f6\u7403\uff0c\u518d\u901a\u8fc7\u589e\u52a0\u6c14\u51dd\u80f6\u7403\u4e2d\u542b\u6c27\u5b98\u80fd\u56e2\u7684\u6d53\u5ea6\u6765\u5b9e\u73b0\u5bf9\u72ed\u7f1d\u72b6\u5b54\u9699\u5b54\u5f84\u7684\u7cbe\u51c6\u8c03\u63a7\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u5e73\u9762\u6c34\u5408\u94dc\u79bb\u5b50\u7684\u9009\u62e9\u6027\u5438\u9644\u3002\u5438\u9644\u52a8\u529b\u5b66\u548c\u7b49\u6e29\u5b9e\u9a8c\u8868\u660e\uff0cGZS\u7684\u5438\u9644\u8fc7\u7a0b\u4e3a\u591a\u5206\u5b50\u5c42\u5438\u9644\uff0c\u6700\u5927\u5438\u9644\u91cf\u4e3a132.57 mg\/g\uff0c\u8868\u73b0\u51fa\u6bd4\u4ee5\u5f80\u540c\u7c7b\u5438\u9644\u6750\u6599\u66f4\u597d\u7684\u5438\u9644\u80fd\u529b\u3002FT-IR\u548cXPS\u673a\u7406\u5206\u6790\u8868\u660e\uff0cGZS\u5bf9Cu(II)\u826f\u597d\u7684\u9009\u62e9\u5438\u9644\u6027\uff0c\u53ef\u80fd\u4e0e\u9759\u7535\u529b\u3001\u79bb\u5b50\u4ea4\u6362\u548c\u7edc\u5408\u7684\u534f\u540c\u4f5c\u7528\u6709\u5173\u3002\u5229\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u7814\u7a76\u4e86GO\u3001ZrO<sub>2<\/sub>\u548cSA\u5728Cu(II)\u4e0a\u7684\u5438\u9644\u987a\u5e8f\u3002\u7efc\u4e0a\u6240\u8ff0\uff0cGZS\u5177\u6709\u9009\u62e9\u6027\u53bb\u9664\u6c34\u4f53\u4e2dCu(II)\u7684\u80fd\u529b\u3002<\/p>\n<p><strong>\u672c\u6587\u8981\u70b9<\/strong><\/p>\n<p>\u8981\u70b9\u4e00\uff1a\u5236\u5907\u6d41\u7a0b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249221\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-46.png\" alt=\"\" width=\"1269\" height=\"649\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-46.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-46-300x153.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-46-768x393.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-46-1024x524.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u65b9\u68481. \u5236\u5907GZS\u6c14\u51dd\u80f6\u7403\u7684\u539f\u7406\u56fe\u3002<\/p>\n<p>\u8981\u70b9\u4e8c\uff1aGS\u548cGZS\u7684\u5fae\u89c2\u5f62\u8c8c\u5bf9\u6bd4<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249222\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-39.png\" alt=\"\" width=\"1269\" height=\"1179\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-39.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-39-300x279.png 300w, 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(a-d) GS\u7684SEM\u56fe\u50cf\uff1b<\/p>\n<p>(e-h) GZS\u7684SEM\u56fe\u50cf\uff1b<\/p>\n<p>(i, j) GS\u548cGZS\u4ea4\u8054\u5bc6\u5ea6\u6a21\u578b\uff1b<\/p>\n<p>(k) GS\u548cGZS\u7684N<sub>2<\/sub>\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\uff1b<\/p>\n<p>(l, m) GS\u4e0eGZS\u5e73\u5747\u5b54\u5f84\u7684\u793a\u610f\u56fe\uff1b<\/p>\n<p>(n) GS\u548cGZS\u76f8\u5e94\u7684\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\u3002<\/p>\n<p>\u8981\u70b9\u4e09\uff1aGZS\u7684\u6210\u952e\u65b9\u5f0f<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249223\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-29.png\" alt=\"\" width=\"1269\" height=\"771\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-29.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-29-300x182.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-29-768x467.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-29-1024x622.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u56fe2. (a) GO\u3001SA\u548cGZS\u7684FT-IR\u5149\u8c31\uff1b<\/p>\n<p>(b) GS\u548cGZS\u7684TG\u66f2\u7ebf\uff1b<\/p>\n<p>(c) GS\u548cGZS\u7684\u603bXPS\u5149\u8c31\uff1b<\/p>\n<p>(d, e) GZS\u4e2dCa 2p\u548cZr 3d\u7684\u9ad8\u5206\u8fa8\u7387XPS\u5149\u8c31\uff1b<\/p>\n<p>(f) \u6d77\u85fb\u9178\u94a0\u7684\u53e4\u7f57\u7cd6\u919b\u9178\u57fa\u56e2\u548cCa<sup>2+<\/sup>\u5f62\u6210\u201c\u86cb\u76d2\u201d\u7ed3\u6784\uff1b<\/p>\n<p>(g) GZS\u7684\u6982\u8981\u63cf\u8ff0\u3002<\/p>\n<p>\u8981\u70b9\u56db\uff1aGZS\u7684\u5438\u9644\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249224\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-19.png\" alt=\"\" width=\"1269\" height=\"1364\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-19.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-19-279x300.png 279w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-19-768x825.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-19-953x1024.png 953w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u56fe3. (a) \u4e0d\u540cpH\u503c\u4e0bCu(\u2161)\u5728\u6eb6\u6db2\u4e2d\u7684\u5206\u5e03\uff1b<\/p>\n<p>(b) pH\u503c\u548cZeta\u7535\u4f4d\u5bf9GZS\u5bf9Cu(\u2161)\u53bb\u9664\u7387\u7684\u5f71\u54cd\uff1b<\/p>\n<p>(c) \u5438\u9644\u5242\u7528\u91cf\u5bf9GZS\u5bf9Cu(\u2161)\u53bb\u9664\u7387\u7684\u5f71\u54cd\uff1b<\/p>\n<p>(d) \u6e29\u5ea6\u5bf9GZS\u5bf9Cu(\u2161)\u53bb\u9664\u7387\u7684\u5f71\u54cd\uff1b<\/p>\n<p>(e) \u65f6\u95f4\u5bf9GZS\u5bf9Cu(\u2161)\u53bb\u9664\u7387\u7684\u5f71\u54cd\uff1b<\/p>\n<p>(f) \u6807\u51c6\u5316\u6548\u5e94\u7684\u6b63\u6001\u56fe\uff1b<\/p>\n<p>(h) \u53bb\u9664\u6548\u7387\u6807\u51c6\u5316\u6548\u5e94\u7684Pareto\u56fe\uff1b<\/p>\n<p>(g) \u5438\u9644Cu(II)\u7684\u4e3b\u8981\u5f71\u54cd\u66f2\u7ebf\uff1b<\/p>\n<p>(i) \u53bb\u9664Cu(\u2161)\u7684\u76f8\u4e92\u4f5c\u7528\u6548\u5e94\u56fe\u3002<\/p>\n<p>\u8981\u70b9\u4e94\uff1aGZS\u5bf9Cu(\u2161)\u7684\u9009\u62e9\u6027\u3001\u6297\u5e72\u6270\u6027\u3001\u7a33\u5b9a\u6027\u548c\u8010\u4e45\u6027<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249225\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72477-10.png\" alt=\"\" width=\"1269\" height=\"865\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72477-10.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72477-10-300x204.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72477-10-768x523.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72477-10-1024x698.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u56fe4. (a) GZS\u548cGS\u5bf9Cu(II)\u7684\u9009\u62e9\u6027\u53bb\u9664\u7387\uff1b<\/p>\n<p>(b) GZS\u5728\u6c34\u4e2d\u7684\u6297\u5e72\u6270\u80fd\u529b\uff1b<\/p>\n<p>(c) \u6c34\u6eb6\u6db2\u4e2dCu(II)\u548c\u7ade\u4e89\u79bb\u5b50\u5728GZS\u4e0a\u7684\u5206\u5e03\u7cfb\u6570\uff1b<\/p>\n<p>(d) \u6c34\u6eb6\u6db2\u4e2dCu(II)\u548c\u7ade\u4e89\u79bb\u5b50\u5728GZS\u4e0a\u7684\u9009\u62e9\u6027\u7cfb\u6570\uff1b<\/p>\n<p>(e) Cu(II)\u4e0e\u5176\u4ed6\u540c\u7c7b\u5438\u9644\u5242\u7684\u5438\u9644\u6027\u80fd\u6bd4\u8f83\uff1b<\/p>\n<p>(f) GZS\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n<p>(g) \u79bb\u5b50\u5f3a\u5ea6\u5bf9GZS\u548cGS\u6eb6\u80c0\u7387\u7684\u5f71\u54cd\u3002<\/p>\n<p>\u8981\u70b9\u516d\uff1a\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249226\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72478-7.png\" alt=\"\" width=\"1269\" height=\"728\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72478-7.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72478-7-300x172.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72478-7-768x441.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72478-7-1024x587.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u56fe5. \u4e94\u79cd\u8ba1\u7b97\u5206\u5b50\u6a21\u578b\u7684\u4f18\u5316\u7ed3\u5408\u80fd(a) \u548c\u952e\u957f(b)\uff1b<\/p>\n<p>ZrO<sub>2<\/sub>\u4e0eCu(II)\u7ed3\u5408\u4f18\u5316\u524d(c) \u548c(d) \u540eZr\u548cCu\u539f\u5b50\u7684PDOS\uff1b<\/p>\n<p>ZrO<sub>2<\/sub>\u4e0eCu(II)\u7ed3\u5408\u4f18\u5316\u524d(e) \u548c\u4f18\u5316\u540e(f) \u7684\u5206\u5b50\u6a21\u578b\u3002<\/p>\n<p>\u8981\u70b9\u4e03\uff1a\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249227\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72479-4.png\" alt=\"\" width=\"1269\" height=\"1071\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72479-4.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72479-4-300x253.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72479-4-768x648.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72479-4-1024x864.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u56fe6. (a) GZS\u5438\u9644\u524d\u540e\u7684FT-IR\u5149\u8c31\uff1b<\/p>\n<p>(b) GZS\u5438\u9644\u540e\u7684EDS\uff08\u5185\u5d4cCu(II)\u7684\u6620\u5c04\u56fe\uff09\uff1b<\/p>\n<p>(c) GZS\u5438\u9644\u540eCa<sup>2+<\/sup>\u7684\u6620\u5c04\u56fe\uff1b<\/p>\n<p>(d) GZS\u5438\u9644\u540e\u7684\u603bXPS\u5149\u8c31\uff1b<\/p>\n<p>(e, f) GZS\u5438\u9644\u540e\u7684Cu 2p\u548cZr 3d\u7684\u9ad8\u5206\u8fa8\u7387XPS\u5149\u8c31\uff1b<\/p>\n<p>(g-i) GZS\u5438\u9644\u524d\u540eCa 2p\u3001C 1s\u548cO 1s\u7684\u9ad8\u5206\u8fa8\u7387XPS\u5149\u8c31\u3002<\/p>\n<p><strong>\u7ed3\u8bba<\/strong><\/p>\n<p>\u672c\u5de5\u4f5c\u901a\u8fc7\u7b80\u5355\u7684\u6eb6\u80f6-\u51dd\u80f6\u6cd5\u548c\u51b7\u51bb\u5e72\u71e5\u6280\u672f\uff0c\u6210\u529f\u5236\u5907\u4e86\u7531GO\u3001ZrO<sub>2<\/sub>\u548cSA\u7ec4\u6210\u7684\u4e09\u7ef4\u591a\u5b54\u6c14\u51dd\u80f6\u7403GZS\u3002\u6240\u5236\u5907\u7684GZS\u5bf9Cu(II)\u5177\u6709\u826f\u597d\u7684\u9009\u62e9\u6027\u5438\u9644\u6027\u80fd\uff0c\u8fd9\u662f\u7531\u4e8e\u6c14\u51dd\u80f6\u7403\u5177\u6709\u81f4\u5bc6\u6709\u5e8f\u7684\u72ed\u7f1d\u72b6\u5b54\u9699\u7ed3\u6784\uff0c\u5bf9\u5e73\u9762Cu(II)\u5177\u6709\u8f83\u5f3a\u7684\u4eb2\u548c\u529b\u3002Cu(II)\u7684\u6700\u5927\u5438\u9644\u91cf\u4e3a132.57 mg\/g\uff0c\u5438\u9644\u8fc7\u7a0b\u7b26\u5408Freundlich\u7b49\u6e29\u7ebf\u548c\u51c6\u4e8c\u7ea7\u52a8\u529b\u5b66\u6a21\u578b\u3002\u540c\u65f6\uff0cGZS\u5177\u6709\u826f\u597d\u7684\u5438\u9644\u6027\u80fd\u548c\u91cd\u590d\u4f7f\u7528\u6027\u80fd\u3002\u5728\u542b\u6709\u5e72\u6270\u79bb\u5b50\u7684\u4f53\u7cfb\u4e2d\uff0c\u5faa\u73af\u5229\u75287\u6b21\u540e\uff0cCu(II)\u7684\u5438\u9644\u91cf\u4ecd\u4fdd\u6301\u572875%\u4ee5\u4e0a\u3002\u56e0\u6b64\uff0cGZS\u5177\u6709\u751f\u4ea7\u5de5\u827a\u7b80\u5355\u3001\u5438\u9644\u6027\u80fd\u597d\u3001\u5316\u5b66\u7a33\u5b9a\u6027\u9ad8\u7b49\u4f18\u70b9\uff0c\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u9ad8\u6548\u9009\u62e9\u6027\u5438\u9644Cu(II)\u7684\u6750\u6599\u3002<\/p>\n<p><strong>\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249232\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u724710-4.png\" alt=\"\" width=\"200\" height=\"266\" \/><\/p>\n<p><strong>\u901a\u8baf\u4f5c\u8005<\/strong> <strong>\u9102\u6d9b\uff1a<\/strong>\u535a\u58eb\uff0c\u6559\u6388\uff0c\u7855\u58eb\u7814\u7a76\u751f\u5bfc\u5e08\u3002\u8fbd\u5b81\u7701\u5316\u5de5\u6e05\u6d01\u751f\u4ea7\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\uff0c\u8fbd\u5b81\u7701\u6bdb\u76ae\u7eff\u8272\u5236\u9020\u4ea7\u4e1a\u6280\u672f\u521b\u65b0\u6218\u7565\u8054\u76df\u7406\u4e8b\u957f\uff0c\u6e24\u6d77\u5927\u5b66\u73af\u5883\u7814\u7a76\u9662\u526f\u9662\u957f\uff0c\u6e24\u6d77\u5927\u5b66\u73af\u5883\u5de5\u7a0b\u4e13\u4e1a\u5e26\u5934\u4eba\u3002\u7814\u7a76\u5174\u8da3\uff1a\u5316\u5de5\u6e05\u6d01\u751f\u4ea7\u5de5\u827a\uff0c\u571f\u58e4\u4e0e\u6c34\u6c61\u67d3\u4fee\u590d\u6280\u672f\u3001\u78b3\u4e2d\u548c\u5de5\u827a\u6280\u672f\u5f00\u53d1\u53ca\u949b\u57fa\u529f\u80fd\u6750\u6599\u7684\u5236\u5907\u5de5\u827a\u53ca\u5e94\u7528\u3002\u5728<em>ACS Appl Mater Interfaces<\/em>\uff0c<em>J Hazard Mater<\/em><em>\uff0c<\/em><em>CHEM ENG J<\/em><em>\uff0c<\/em><em>Sep Purif Technol<\/em><em>\uff0c<\/em><em>J CLEAN PROD<\/em><em>\uff0c<\/em><em>Mater. Today Chem<\/em><em>\uff0c<\/em><em>SCI TOTAL ENVIRON<\/em>\u7b49\u56fd\u9645\u8457\u540d\u671f\u520a\u4e0a\u4ee5\u7b2c\u4e00\/\u901a\u8baf\u4f5c\u8005\u53d1\u8868SCI\u6536\u5f55\u8bba\u658743\u7bc7(\u4e2d\u79d1\u9662\u4e00\u533a\u8bba\u658713\u7bc7)\uff0c\u5176\u4e2d\u9ad8\u7eaf\u949b\u7684\u5236\u5907\u53ca\u7eaf\u5316\u673a\u7406\u3001\u72ed\u7f1d\u9650\u57df\u9009\u62e9\u6027\u5438\u9644\u94dc\u79bb\u5b50\u548c\u77f3\u58a8\u70ef\/TiO<sub>2<\/sub>\u754c\u9762\u7535\u5b50\u8f6c\u79fb\u673a\u5236\u7b49\u7814\u7a76\u884c\u4e1a\u9996\u6b21\u62a5\u9053\u3002\u4e3b\u6301\/\u53c2\u4e0e\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u53ca\u7701\u90e8\u7ea7\u4ee5\u4e0a\u9879\u76ee24\u9879\uff0c\u6a2a\u5411\u9879\u76ee12\u9879\uff0c\u5408\u540c\u91d1\u989d1044\u4e07\u3002\u4ee5\u7b2c\u4e00\u53d1\u660e\u4eba\u83b7\u5f97\u6388\u6743\u53d1\u660e\u4e13\u522913\u9879\uff0c\u5355\u9879\u4e13\u5229\u8f6c\u5316\u989d\u5ea6\u8d85100\u4e07\u3002\u53d1\u5e03\u6d59\u6c5f\u7701\u56e2\u4f53\u6807\u51c67\u9879\uff0c\u4f01\u4e1a\u6807\u51c642\u9879\uff0c\u5728\u4f01\u4e1a\u5efa\u7acb\u201c20\u4e07\u6807\u5f20\u725b\u76ae\u9769\u6e05\u6d01\u5316\u751f\u4ea7\u5173\u952e\u6280\u672f\u7814\u7a76\u4e0e\u96c6\u6210\u793a\u8303\u201d\u751f\u4ea7\u7ebf\u4e00\u6761\uff0c\u6e05\u6d01\u5316\u6807\u51c65\u7bc7\u8bba\u6587\u88ab\u884c\u4e1a\u6743\u5a01\u6742\u5fd7\u300a\u4e2d\u56fd\u76ae\u9769\u300b\u4e13\u9898\u62a5\u9053\uff0c\u5411\u884c\u4e1a\u6280\u672f\u63a8\u5e7f\u3002<\/p>\n<p>\u7535\u5b50\u90ae\u7bb1\uff1aetao@bhu.edu.cn<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249233\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u724711-2.png\" alt=\"\" width=\"200\" height=\"300\" \/><\/p>\n<p><strong>\u7b2c\u4e8c\u4f5c\u8005<\/strong> <strong>\u6768\u59dd\u5b9c\uff1a<\/strong>\u6e24\u6d77\u5927\u5b66\u73af\u5883\u5de5\u7a0b\u4e13\u4e1a\u6559\u6388\uff0c\u7855\u58eb\u7814\u7a76\u751f\u5bfc\u5e08\u3002\u7814\u7a76\u5174\u8da3\uff1a\u571f\u58e4\u4fee\u590d\u6280\u672f\u548c\u56fa\u4f53\u5e9f\u7269\u8d44\u6e90\u5316\u3002\u5728<em>J Hazard Mater<\/em><em>\uff0c<\/em><em>J CLEAN PROD<\/em><em>\uff0c<\/em><em>ACS Appl Mater Interfaces<\/em><em>\uff0c<\/em><em>Sep Purif Technol<\/em><em>\uff0c<\/em><em>Mater. Today Chem<\/em><em>\uff0c<\/em><em>J. Alloys Compd<\/em>\u7b49\u56fd\u9645\u8457\u540d\u671f\u520a\u4e0a\u4ee5\u7b2c\u4e00\/\u901a\u8baf\u4f5c\u8005\u53d1\u8868SCI\u6536\u5f55\u8bba\u658715\u7bc7\uff0c\u62c5\u4efb\u300a<em>Journal of Alloys and Compounds<\/em>\u300b\uff0c\u300a<em>Journal of Cleaner Production<\/em>\u300b\uff0c\u300a<em>Journal of Polymers and the Environment<\/em>\u300b\u7b49SCI\u77e5\u540d\u671f\u520a\u5ba1\u7a3f\u4eba\u3002<\/p>\n<p>\u7535\u5b50\u90ae\u7bb1\uff1ayangshuyi@bhu.edu.cn<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-249234\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u724712-1.png\" alt=\"\" width=\"200\" height=\"286\" \/><\/p>\n<p><strong>\u7b2c\u4e00\u4f5c\u8005<\/strong> <strong>\u674e\u7d20\u96c5\uff1a<\/strong>\u6e24\u6d77\u5927\u5b66\u5316\u5b66\u5de5\u827a\u4e13\u4e1a\u7855\u58eb\u7814\u7a76\u751f\u3002\u7814\u7a76\u5174\u8da3\uff1a\u529f\u80fd\u5438\u9644\u6750\u6599\u7684\u5f00\u53d1\u4e0e\u5e94\u7528\u3002\u76ee\u524d\u5728<em>CHEM ENG J<\/em>\u671f\u520a\u4e0a\u53d1\u8868SCI\u6536\u5f55\u8bba\u65871\u7bc7\u3002<\/p>\n<p>\u7535\u5b50\u90ae\u7bb1\uff1a2012518720@qq.com<\/p>\n<p><strong>\u6587\u7ae0\u4fe1\u606f<\/strong><\/p>\n<p>Suya Li, Shuyi Yang, Liang Chen, Xin Hao, Tao E<sup>*<\/sup>, Yun Li<sup> **<\/sup>. Pore size adjustment of sodium alginate-based composite aerogel spheres by zirconia for efficient selective removal of Cu(II).<strong><em> Chemical Engineering Journal <\/em><\/strong>DOI: https:\/\/doi.org\/10.1016\/j.cej.2023.142547<\/p>\n<p>\u4f9b\u7a3f\u4eba\uff1a\u6e24\u6d77\u5927\u5b66\uff1a\u674e\u7d20\u96c5<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u674e\u7d20\u96c5 \u901a\u8baf\u4f5c\u8005\uff1a\u9102\u6d9b \u901a\u8baf\u5355\u4f4d\uff1a\u6e24\u6d77\u5927\u5b66 DOI\uff1ahttps:\/\/doi.org\/10.1016\/j.cej.2023.142547 \u56fe\u5f62\u6458\u8981 \u7814\u7a76&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-249218","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/249218"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=249218"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/249218\/revisions"}],"predecessor-version":[{"id":249235,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/249218\/revisions\/249235"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=249218"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=249218"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=249218"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}