{"id":249086,"date":"2023-04-11T06:21:46","date_gmt":"2023-04-10T22:21:46","guid":{"rendered":"\/\/m.iemloyee.com\/?p=249086"},"modified":"2023-04-07T16:21:56","modified_gmt":"2023-04-07T08:21:56","slug":"%e6%9c%80%e6%96%b0afm%e5%85%b7%e6%9c%89%e8%b0%83%e5%88%b6%e8%a1%a8%e9%9d%a2%e5%92%8c%e5%8f%af%e6%8e%a7%e5%af%86%e5%ba%a6%e7%9a%84%e9%87%91%e5%b1%9e%e7%ba%b3%e7%b1%b3%e5%9b%a2%e7%b0%87%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=249086","title":{"rendered":"\u6700\u65b0AFM:\u5177\u6709\u8c03\u5236\u8868\u9762\u548c\u53ef\u63a7\u5bc6\u5ea6\u7684\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7528\u4e8e\u901a\u7528pH\u9ad8\u6548\u6c34\u5206\u89e3"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u00a0 \u00a0\u8fd1\u5e74\u6765\uff0c\u63d0\u9ad8\u8fc7\u6e21\u91d1\u5c5e\uff08TM\uff09\u50ac\u5316\u5242\u7684\u539f\u5b50\u5229\u7528\u7387\u548c\u50ac\u5316\u7a33\u5b9a\u6027\u5bf9\u4e8e\u53ef\u6301\u7eed\u53d1\u5c55\u548c\u7ecf\u6d4e\u5316\u5b66\u81f3\u5173\u91cd\u8981\u3002\u5177\u6709\u6700\u5927\u539f\u5b50\u5229\u7528\u6548\u7387\u548c\u53ef\u8c03\u914d\u4f4d\u73af\u5883\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08SACs\uff09\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u4e0d\u540c\u7684\u7814\u7a76\u9886\u57df\u3002\u7136\u800c\uff0c\u56e0\u5176\u6613\u7f3a\u5931\u7684\u91d1\u5c5e-\u91d1\u5c5e\u952e\u548c\u6613\u53d7\u5f71\u54cd\u7684\u50ac\u5316\u6d3b\u6027\u7a33\u5b9a\u6027\u9650\u5236\u4e86\u5176\u5728\u5de5\u4e1a\u4e0a\u7684\u8fdb\u4e00\u6b65\u5e94\u7528\u3002\u76ee\u524d\u78b3\u57fa TMs \u7eb3\u7c73\u7c92\u5b50\uff08NP\uff0c\u5982 Pt\/C\u3001Pd\/C\u3001Ir\/C \u548c Rh\/C\uff09\u4ecd\u7136\u662f\u50a8\u80fd\u3001\u6709\u673a\u53cd\u5e94\u3001\u5149\u50ac\u5316\u548c\u7535\u50ac\u5316\u53cd\u5e94\u7684\u70ed\u95e8\u5019\u9009\u6750\u6599\u3002\u7136\u800c\uff0c\u78b3\u57fa\u7eb3\u7c73\u7c92\u5b50\u7684\u539f\u5b50\u5229\u7528\u7387\u4f4e\uff0c\u7a33\u5b9a\u6027\u5dee\uff0c\u4e0d\u80fd\u6ee1\u8db3\u4f4e\u6210\u672c\u548c\u53ef\u6301\u7eed\u5316\u5b66\u7684\u9700\u6c42\u3002\u9664SACs\u548cNPs\u5916\uff0c\u78b3\u57fa\u7eb3\u7c73\u56e2\u7c07(NCs)\u5177\u6709\u6bd4NPs\u66f4\u9ad8\u7684\u539f\u5b50\u5229\u7528\u7387\u4ee5\u53ca\u6bd4SACs\u66f4\u9ad8\u7684\u6d3b\u6027\u7a33\u5b9a\u6027\uff0c\u663e\u793a\u51fa\u72ec\u7279\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\u3002\u5f53\u4e0e\u975e\u91d1\u5c5e\u539f\u5b50\u914d\u4f4d\u65f6\uff0c\u7531\u4e8e\u540c\u65f6\u5b58\u5728\u91d1\u5c5e-\u91d1\u5c5e\u952e\u548c\u91d1\u5c5e-\u6742\u539f\u5b50\u952e\uff0cNCs\u53ef\u4ee5\u517c\u5177NPs\u548cSACs\u7684\u7279\u6027\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u7531\u4e8e\u539f\u5b50\u95f4\u7684\u5f3a\u91d1\u5c5e\u952e\u548c\u9ad8\u6e29\u4e0b\u7684\u9ad8\u8868\u9762\u80fd\uff0c\u5408\u6210\u8d85\u5747\u5300\u548c\u5bc6\u5ea6\u53ef\u63a7\u7684NCs\u4ecd\u7136\u5177\u6709\u6311\u6218\u6027\u3002\u56e0\u6b64\uff0c\u5408\u7406\u8bbe\u8ba1\u4e00\u79cd\u7b80\u5355\u3001\u6709\u6548\u4e14\u53ef\u6269\u5c55\u7684\u65b9\u6cd5\u6765\u5408\u6210\u5bc6\u5ea6\u53d7\u63a7\u4e14\u5206\u5e03\u5747\u5300\u7684NC\u662f\u81f3\u5173\u91cd\u8981\u7684\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/span><\/p>\n

\u00a0 \u00a0<\/strong>\u8fd1\u65e5\uff0c\u6210\u5747\u9986\u5927\u5b66\u00a0Hyoyoung Lee<\/a>\u6559\u6388\u56e2\u961f\u901a\u8fc7\u5171\u4ef7\u6709\u673a\u805a\u5408\u7269\uff08COP\uff09\u6210\u529f\u5408\u6210\u51fa\u4e00\u7cfb\u7c7b\u5177\u6709\u5bc6\u5ea6\u53ef\u63a7\u548c\u8868\u9762\u6c2e\u8c03\u63a7\u7684\u8fc7\u6e21\u91d1\u5c5e\uff08TM\uff09\u7eb3\u7c73\u56e2\u7c07\uff08NCs\uff09\u3002\u5176\u4e2dIr NCs \u5728\u9178\u6027\u548c\u78b1\u6027\u4ecb\u8d28\u4e2d\u5747\u8868\u73b0\u51fa\u4f18\u4e8e\u5546\u7528Pt\/C\u548cIr\/C\u7684\u6790\u6c22\u53cd\u5e94 \uff08HER\uff09\u548c\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u7535\u50ac\u5316\u6d3b\u6027\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u201cDensity-Controlled Metal Nanocluster with Modulated Surface for pH-Universal and Robust Water Splitting<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Functional Materials<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/span><\/p>\n

\u00a0 \u00a01<\/strong>\u3001\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u4ee5\u5c3a\u5bf8\u9650\u5236\u7684<\/strong>COP<\/strong>\u4f5c\u4e3a\u652f\u6491\uff0c\u5236\u5907\u8d85\u5747\u5300\u3001\u5bc6\u5ea6\u53ef\u63a7\u7684<\/strong>TMs NCs<\/strong>\u7684\u7b80\u5355\u6709\u6548\u7b56\u7565\u3002<\/strong>COP<\/strong>\u4e2d\u56fa\u5b9a\u5b54\u9699\u7ed3\u6784\u53ef\u4ee5\u9650\u5236<\/strong>TMs NCs<\/strong>\u7684\u751f\u957f\u548c\u8fc1\u79fb\u3002<\/strong><\/p>\n

\u00a0 \u00a02<\/strong>\u3001<\/strong>Ir-COP<\/strong>\u50ac\u5316\u5242\u5728\u78b1\u6027\uff08<\/strong>HER<\/strong>\uff1a<\/strong>14.5 mV <\/strong>\u548c<\/strong> OER<\/strong>\uff1a<\/strong>230 mV<\/strong>\uff0c<\/strong>10 mA cm-2<\/sup><\/strong>\uff09\u548c\u9178\u6027\uff08<\/strong>HER<\/strong>\uff1a<\/strong>12.3 mV <\/strong>\u548c<\/strong> OER<\/strong>\uff1a<\/strong>242 mV<\/strong>\uff0c<\/strong>10 mA cm-2<\/sup>)<\/strong>\u4ecb\u8d28\u4e2d\u8868\u73b0\u51fa\u5353\u8d8a\u7684\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u4f18\u5f02\u7684<\/strong> HER <\/strong>\u548c<\/strong> OER <\/strong>\u6027\u80fd\u662f\u7531<\/strong> NCs <\/strong>\u7684\u9ad8\u8868\u9762\u539f\u5b50\u5229\u7528\u7387\u548c\u8868\u9762<\/strong> Ir <\/strong>\u539f\u5b50\u6539\u8fdb\u7684\u672c\u5f81\u6d3b\u6027\u5f15\u8d77\u7684\u3002\u800c\u826f\u597d\u7684\u7535\u50ac\u5316\u7a33\u5b9a\u6027\u662f\u7531\u4e8e<\/strong>Ir NCs<\/strong>\u4e0e\u78b3\u8f7d\u4f53\u4e4b\u95f4\u4ee5<\/strong>N<\/strong>\u539f\u5b50\u4e3a\u8fde\u63a5\u6865\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\u6240\u81f4\u3002<\/strong><\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/span><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1 Ir-COP \u7684\u5408\u6210\u548c\u7ed3\u6784\u8868\u5f81\u3002a\uff09\u4e0d\u540c\u7c92\u5f84Ir NPs\u7684\u539f\u5b50\u5229\u7528\u7387\u7814\u7a76\u3002b\uff09\u5236\u5907Ir-COP\u50ac\u5316\u5242\u7684\u793a\u610f\u56fe\u3002c) PDA\u3001TAPA \u548c Ir-COP \u7684 FTIR \u5149\u8c31\u3002d) \u70ed\u89e3\u5904\u7406\u524d\u540e Ir-COP \u7684\u7c89\u672b XRD \u56fe\u3002e) Ir-COP \u5728\u7a7a\u6c14\u4e2d\u7684 TGA \u66f2\u7ebf\u3002f\u2013h) Ir-COP \u5728\u4e0d\u540c\u653e\u5927\u500d\u6570\u4e0b\u7684 HRTEM\u3002i) Ir-COP \u7684 EDS \u5143\u7d20\u6620\u5c04\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2 <\/strong>Ir-COP \u7684\u4ef7\u6001\u548c\u914d\u4f4d\u73af\u5883\u8868\u5f81\u3002a) Ir-COP \u7684\u9ad8\u5206\u8fa8\u7387 XPS N1s \u5149\u8c31\u3002b) IrO2<\/sub>\u3001Ir-COP\u548cIr\/C\u7684\u9ad8\u5206\u8fa8\u7387XPS Ir 4f\u5149\u8c31\u3002c) Ir\u7b94\u3001Ir-COP\u548cIrO2<\/sub>\u7684Ir L3<\/sub>-edge XANES\u5149\u8c31\u3002d) Ir\u7b94\u3001Ir-COP\u548cIrO2<\/sub>\u7684\u5085\u91cc\u53f6\u53d8\u6362EXAFS\u5149\u8c31\u3002e\u2013g) Ir\u7b94\u3001Ir-COP \u548cIrO2<\/sub>\u7684WT-EXAFS\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3 <\/strong>Ir-COP \u5408\u6210\u7684\u673a\u7406\u7814\u7a76\u3002a\u2013e) Ir-COP \u5728\u4e0d\u540c\u9000\u706b\u6e29\u5ea6\u4e0b\u7684\u539f\u5b50\u5206\u8fa8\u7387 HAADF STEM\u3002f) Ir-COP\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5085\u91cc\u53f6\u53d8\u6362EXAFS\u5149\u8c31\u3002g) \u5e73\u5747Ir\u7c92\u5f84\u4e0e\u9000\u706b\u6e29\u5ea6\u4e4b\u95f4\u7684\u5173\u7cfb\u3002h) Ir\u5e73\u5747\u7c92\u5f84\u4e0eIr\u8d1f\u8f7d\u91cf\u7684\u5173\u7cfb\u3002i)\u5408\u6210Ir-COP\u50ac\u5316\u5242\u7684\u673a\u7406\u7814\u7a76\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4 <\/strong>\u5236\u5907\u7684\u5404\u79cd TM NC\u3002a) Ru-COP \u7684HRTEM\u3002b) Ru-COP \u7684\u7c92\u5ea6\u5206\u5e03\u3002c) Ru-COP \u7684EDS\u5143\u7d20\u6620\u5c04\u3002d) Rh-COP\u7684HRTEM\u3002e) Rh-COP\u7684\u7c92\u5ea6\u5206\u5e03\u3002f) Rh-COP\u7684EDS\u5143\u7d20\u6620\u5c04\u3002g) Pd-COP \u7684HRTEM\u3002h) Pd-COP\u7684\u7c92\u5ea6\u5206\u5e03\u3002i) Pd-COP \u7684EDS\u5143\u7d20\u6620\u5c04\u3002j) Ru\/Ir-COP\u7684HRTEM\u3002k) Ru\/Ir-COP \u7684EDS\u5143\u7d20\u6620\u5c04\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5 <\/strong>Ir-COP \u50ac\u5316\u5242\u5728\u78b1\u6027\u548c\u9178\u6027\u6761\u4ef6\u4e0b\u7684HER\u6027\u80fd\u3002a) Ir-COP\u3001COP\u3001Ir\/C \u548cPt\/C\u57281\u00a0M\u00a0KOH\u4e2d\u7684LSV\u3002b) Ir-COP\u3001Ir\/C\u548cPt\/C\u57281\u00a0M\u00a0KOH\u4e2d10 mA cm-2<\/sup>\u7684\u8fc7\u7535\u52bf\u548c\u8d28\u91cf\u6d3b\u6027\u7684\u6bd4\u8f83\u3002c) Ir-COP\u3001Ir\/C\u548cPt\/C\u57281 M\u00a0KOH \u4e2d\u7684Tafel \u56fe\u3002d) Ir-COP\u3001Ir\/C \u548c Pt\/C \u4e0e\u5176\u4ed6\u6700\u8fd1\u62a5\u9053\u7684\u78b1\u6027\u4ecb\u8d28\u4e2dHER \u7535\u50ac\u5316\u5242\u7684TOF\u503c\u6bd4\u8f83\u3002e) Ir-COP\u3001COP\u3001Ir\/C\u548cPt\/C\u57280.5\u00a0M\u00a0H2<\/sub>SO4<\/sub>\u4e2d\u7684 LSV \u66f2\u7ebf\u3002f) Ir-COP\u3001Ir\/C \u548c Pt\/C \u57280.5\u00a0M\u00a0H2<\/sub>SO4<\/sub>\u4e2d10 mA cm\u22122<\/sup>\u7684\u8fc7\u7535\u52bf\u548c\u8d28\u91cf\u6d3b\u6027\u7684\u6bd4\u8f83\u3002g) Ir-COP\u3001Ir\/C \u548c Pt\/C \u5728 0.5\u00a0M\u00a0H2<\/sub>SO4<\/sub>\u4e2d\u7684 Tafel \u56fe\u3002h) Ir-COP\u3001Ir\/C\u548cPt\/C \u4e0e\u5176\u4ed6\u6700\u8fd1\u62a5\u9053\u7684\u9178\u6027\u4ecb\u8d28\u4e2dHER \u7535\u50ac\u5316\u5242\u7684TOF\u503c\u6bd4\u8f83\u3002i) Ir-COP\u3001Ir\/C \u548c Pt\/C \u57281 M\u00a0KOH\u4e2d\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u00a0\u3002j) Ir-COP\u3001Ir\/C \u548c Pt\/C \u57280.5\u00a0M\u00a0H2<\/sub>SO4<\/sub>\u4e2d\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>6 <\/strong>Ir-COP \u50ac\u5316\u5242\u5728\u78b1\u6027\u548c\u9178\u6027\u6761\u4ef6\u4e0b\u7684OER\u548c\u6574\u4f53\u6c34\u5206\u89e3\u6027\u80fd\u3002a) Ir-COP\u3001COP\u3001Ir\/C\u548cIrO\u00a02\u57281\u00a0M\u00a0KOH\u4e2d\u7684LSV\u66f2\u7ebf\u3002b)\u00a0Ir-COP\u3001Ir\/C\u548c IrO2<\/sub>\u57281\u00a0M\u00a0KOH\u4e2d\u768410 mA cm-2<\/sup>\u8fc7\u7535\u4f4d\u548c300 mV TOF\u7684\u6bd4\u8f83\u3002c) Ir-COP\u3001Ir\/C\u548cIrO2<\/sub>\u57281\u00a0M\u00a0KOH\u4e2d\u7684Tafel\u56fe\u3002d)\u53cc\u7535\u6781\u7535\u6c60\u57281\u00a0M\u00a0KOH\u4e2d\u6574\u4f53\u6c34\u5206\u89e3\u7684LSV\u66f2\u7ebf\u3002e) Ir-COP\u3001COP\u3001Ir\/C\u548cIrO2<\/sub>\u57280.5\u00a0M\u00a0H2<\/sub>SO4<\/sub>\u4e2d\u7684LSV \u66f2\u7ebf\u3002f) 10 mA cm\u22122<\/sup>\u65f6\u7684\u8fc7\u7535\u52bf\u6bd4\u8f83\u4ee5\u53ca0.5\u00a0M\u00a0H2<\/sub>SO4<\/sub>\u4e2dIr-COP\u3001Ir\/C\u548c IrO2<\/sub>\u5728300 mV\u65f6\u7684TOF\u503c\u3002g) Ir-COP\u3001Ir\/C\u548cIrO2<\/sub>\u57280.5\u00a0M\u00a0H2<\/sub>SO4<\/sub>\u4e2d\u7684 Tafel \u56fe\u3002h) \u53cc\u7535\u6781\u7535\u6c60\u57280.5\u00a0M\u00a0H2<\/sub>SO4<\/sub>\u4e2d\u6574\u4f53\u6c34\u5206\u89e3\u7684LSV\u66f2\u7ebf\u3002i) Ir-COP\u548cIr\/C\u57281\u00a0M\u00a0KOH\u4e2d\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u00a0\u3002j) Ir-COP\u548cIr\/C\u57280.5\u00a0M\u00a0H2<\/sub>SO4<\/sub>\u4e2d\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u00a0\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>7 <\/strong>HER\u548cOER\u50ac\u5316\u673a\u5236\u7814\u7a76\u3002a) \u57fa\u4e8eHER\u6a21\u578b\u7684Ir\/C\u548cIr-COP\u7684\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u3002b) Ir\/C, c) Ir-COP \u57fa\u4e8eHER\u6a21\u578b\u7684PDOS\u3002d) HER\u5728Ir\/C\u548c Ir-COP\u4e0a\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u56fe\u3002e) \u57fa\u4e8eOER \u6a21\u578b\u7684Ir\/C \u548cIr-COP \u7684\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u3002f) Ir\/C\u548cg) Ir-COP\u57fa\u4e8eOER\u6a21\u578b\u7684PDOS\u3002h) Ir\/C\u548cIr-COP \u4e0aOER\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u56fe\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

 <\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/span><\/p>\n

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 <\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a<\/strong>https:\/\/doi.org\/10.1002\/adfm.202211192<\/a><\/p>\n

\u672c\u6587\u7531K . L\u64b0\u7a3f\u3002<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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