{"id":248872,"date":"2023-04-04T05:58:56","date_gmt":"2023-04-03T21:58:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=248872"},"modified":"2023-04-03T10:59:10","modified_gmt":"2023-04-03T02:59:10","slug":"%e4%b8%ad%e5%8d%97%e5%a4%a7%e5%ad%a6%e5%88%98%e6%95%8fangew-%e5%8e%9f%e5%ad%90%e5%b1%80%e9%83%a8%e7%94%b5%e5%9c%ba%e8%af%b1%e5%af%bc%e7%9a%84%e7%a2%b1%e6%80%a7%e6%9e%90%e6%b0%a2%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=248872","title":{"rendered":"\u4e2d\u5357\u5927\u5b66\u5218\u654fAngew :\u539f\u5b50\u5c40\u90e8\u7535\u573a\u8bf1\u5bfc\u7684\u78b1\u6027\u6790\u6c22\u53cd\u5e94\u754c\u9762\u6c34\u5b9a\u5411"},"content":{"rendered":"<p>\u56fe\u56fe<\/p>\n<ul>\n<li>\u3010\u5bfc\u8bfb\u3011<\/li>\n<\/ul>\n<p>\u78b1\u6c34\u7535\u89e3\u662f\u5927\u89c4\u6a21\u5236\u6c22\u7684\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u65b9\u6cd5\u3002\u5728\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\uff0c\u4f5c\u4e3a\u6c22\u6e90\u7684\u6c34\u7684\u89e3\u79bb\u901a\u5e38\u88ab\u8ba4\u4e3a\u662f\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u51b3\u901f\u6b65\u3002\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\u6c34\u7684\u7f13\u6162\u89e3\u79bb\u8fc7\u7a0b\u4e25\u91cd\u9650\u5236\u4e86HER\u7684\u52a8\u529b\u5b66\u3002\u901a\u5e38\uff0cH<sub>2<\/sub>O\u5728\u50ac\u5316\u5242\u548c\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u754c\u9762\u5904\u7684\u53d6\u5411\uff0c\u5305\u62ec\u5438\u9644\u6784\u578b\uff08O<sub>-down<\/sub>\u6216H<sub>-down<\/sub>\uff09\u548cH<sub>2<\/sub>O\u7684H-O-H\u952e\u89d2\uff0c\u53ef\u4ee5\u76f4\u63a5\u5f71\u54cd\u89e3\u79bb\u8fc7\u7a0b\u3002\u56e0\u6b64\uff0c\u8c03\u8282\u754c\u9762H<sub>2<\/sub>O\u7684\u53d6\u5411\u4ee5\u4fc3\u8fdbH<sub>2<\/sub>O\u7684\u89e3\u79bb\u662f\u63d0\u9ad8HER\u6d3b\u6027\u7684\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u65b9\u6cd5\u3002<\/p>\n<p>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/p>\n<p>\u8fd1\u65e5\uff0c\u4e2d\u5357\u5927\u5b66\u5218\u654f\u6559\u6388\u5229\u7528IrRu\u53cc\u5f02\u6838\u5355\u539f\u5b50\u4f4d\u70b9\uff08IrRu-DSACs\uff09\u8bbe\u8ba1\u4e86\u539f\u5b50\u4e0d\u5bf9\u79f0\u7684\u5c40\u90e8\u7535\u573a\uff0c\u4ee5\u8c03\u8282H<sub>2<\/sub>O\u7684\u5438\u9644\u6784\u578b\u548c\u53d6\u5411\uff0c\u4ece\u800c\u4f18\u5316\u5176\u79bb\u89e3\u8fc7\u7a0b\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u63a2\u7d22\u5355\u539f\u5b50\u4f4d\u70b9\u5728\u78b1\u6027\u6790\u6c22\u53cd\u5e94\u4e2d\u7684\u4f5c\u7528\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u9014\u5f84\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Atomically Local Electric Field Induced Interface Water Reorientation for Alkaline Hydrogen Evolution Reaction<\/strong>\u201d\u4e3a\u9898\u5728<em>Angewandte Chemie International Edition<\/em>\u4e0a\u53d1\u8868\u3002<\/p>\n<p>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n<p>\u221a\u901a\u8fc7IrRu\u53cc\u5947\u5355\u539f\u5b50\u4f4d\u70b9\uff08IrRu-DSACs\uff09\u8bbe\u8ba1\u4e86\u539f\u5b50\u4e0d\u5bf9\u79f0\u7684\u5c40\u90e8\u7535\u573a\uff0c\u4ee5\u8c03\u8282H2O\u7684\u5438\u9644\u6784\u578b\u548c\u53d6\u5411\uff0c\u5728\u78b1\u6027HER\u8fc7\u7a0b\u4e2d\u572810mA\/cm<sup>2<\/sup>\u4e0b\u8868\u73b0\u51fa10mV\u7684\u8d85\u4f4e\u8fc7\u7535\u52bf\uff0c\u5e76\u4e14\u57281A\/cm<sup>2<\/sup>\u4e0b\u5728300\u5c0f\u65f6\u5185\u5728MEA\u4e2d\u8868\u73b0\u51fa\u8d85\u9ad8\u7a33\u5b9a\u6027\u3002<\/p>\n<p>\u00a0\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248873\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/1-14.jpg\" alt=\"\" width=\"1084\" height=\"862\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/1-14.jpg 1084w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/1-14-300x239.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/1-14-768x611.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/1-14-1024x814.jpg 1024w\" sizes=\"(max-width: 1084px) 100vw, 1084px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1<\/strong> \uff08a\uff09 CoP\u548cIrRu DSACs\u7684\u7535\u8377\u5bc6\u5ea6\u5206\u6790\u3002\uff08b\uff09\u901a\u8fc7\u4ece\u5934\u7b97\u5206\u5b50\u52a8\u529b\u5b66\uff08AIMD\uff09\u6a21\u62df\u6a21\u62df\u7684\u754c\u9762H<sub>2<\/sub>O\u53d6\u5411\uff0c\u4ee5\u53ca\u754c\u9762\u5904\u5438\u9644\u7684H<sub>2<\/sub>O\u5206\u5b50\u5728z\u65b9\u5411\u4e0a\u7684\u7edf\u8ba1H\u548cO\u5206\u5e03\u8ddd\u79bb\uff08c\uff09\u3002\u901a\u8fc7DFT\u8ba1\u7b97\u7684CoP\u548cIrRu DSACs\u4e0aH<sub>2<\/sub>O\u89e3\u79bb\u8fc7\u7a0b\uff08d\uff09\u7684\u80fd\u5792\u548c\u7ed3\u6784\u3002<strong>\u00a9 2022\u00a0<\/strong><strong>Zhongnan University<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248874\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/2-4.jpg\" alt=\"\" width=\"1102\" height=\"1138\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/2-4.jpg 1102w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/2-4-291x300.jpg 291w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/2-4-768x793.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/2-4-992x1024.jpg 992w\" sizes=\"(max-width: 1102px) 100vw, 1102px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2 <\/strong>\u00a0\uff08a\uff09 IrRu DSACs\u7684STEM\u56fe\u50cf\u3002\uff08a1\uff09\u662fIrRu DSACs\u7684\u4f4e\u5206\u8fa8STEM\u56fe\u50cf\u3002\u77e9\u5f62\u6807\u8bb0\u5177\u6709\u4e0d\u540c\u66b4\u9732\u9762\u7684IrRu DSAC\u7684\u653e\u5927\u533a\u57df\u3002\uff08a2\uff09\u662f\u5177\u67090.26nm\u7684\u6676\u683c\u8ddd\u79bb\u7684CoP\u7684\u653e\u5927\u9762\u79ef\u3002\uff08a3\uff09\u662f\u5177\u67090.5nm\u7684\u6676\u683c\u8ddd\u79bb\u7684CoP\u7684\u653e\u5927\u9762\u79ef\u3002\uff08b\uff09 IrRu DSACs\u4e2dIr-Ru\u5bf9\u7684\u539f\u5b50\u5206\u5e03\u3002\u9876\u90e8\u662fIr\u539f\u5b50\u548cRu\u539f\u5b50\u4e4b\u95f4\u8ddd\u79bb\u7684\u96c6\u5408\u3002\u5e95\u90e8\u662fIr\u548cRu\u539f\u5b50\u8ddd\u79bb\u7684\u7edf\u8ba1\u6570\u636e\u3002\uff08c\uff09 Ir SAC\u7684Ir L\u8fb9\u7f18\u3001Ir\u7b94\u548cIrRu DSAC\u3002\uff08d\uff09 Ru SAC\u7684Ru K\u8fb9\u7f18\u3001Ru\u7b94\u548cIrRu DSAC\u3002\u6240\u9009\u533a\u57df\u79ef\u5206\u5fae\u5206\u76f8\u4f4d\u5bf9\u6bd4STEM\uff08e\uff09\uff0c\u5bf9\u5e94\u7684\u91cf\u5316\u7535\u8377\u5bc6\u5ea6\uff08f\uff09\u3002IrRu DSACs\u4e2dIr-Ru\u5bf9\u7684\u603b\u7535\u573a\u548c\u7535\u8377\u53d8\u5316\uff08g\uff09\u3002<strong>\u00a9 2022\u00a0<\/strong><strong>Zhongnan University<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248875\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/3-5.jpg\" alt=\"\" width=\"1088\" height=\"561\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/3-5.jpg 1088w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/3-5-300x155.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/3-5-768x396.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/3-5-1024x528.jpg 1024w\" sizes=\"(max-width: 1088px) 100vw, 1088px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3<\/strong>\u00a0 IrRu DSACs\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\uff08a\uff09\u548c\u62c9\u66fc\u5149\u8c31\u76f8\u5e94\u7279\u5b9a\u5cf0\u6bd4\u5cf0\u5f3a\u5ea6\uff08b\uff09\u53ca\u754c\u9762\u6c34\u7ed3\u6784\u6f14\u53d8\uff08c\uff09\u3002CoP\uff08d\uff09\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u548c\u548c\u62c9\u66fc\u5149\u8c31\u76f8\u5e94\u7279\u5b9a\u5cf0\u6bd4\u5cf0\u5f3a\u5ea6\uff08e\uff09\u548c\u754c\u9762\u6c34\u7ed3\u6784\u6f14\u53d8\uff08f\uff09\u3002<strong>\u00a9 2022\u00a0<\/strong><strong>Zhongnan University<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248876\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/4-3.jpg\" alt=\"\" width=\"1153\" height=\"635\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/4-3.jpg 1153w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/4-3-300x165.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/4-3-768x423.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/4-3-1024x564.jpg 1024w\" sizes=\"(max-width: 1153px) 100vw, 1153px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4<\/strong> \u6240\u5236\u5907\u7684\u50ac\u5316\u5242\u7684\u7535\u5316\u5b66\u6781\u5316\u66f2\u7ebf\uff08a\uff09\u3001Tafel\u56fe\uff08b\uff09\u548c10mA\/cm<sup>2<\/sup>\u4e0b\u7684\u8fc7\u7535\u4f4d\u3002\uff08c\uff09\u3001\uff08d\uff09Ir-Ru DSACs\u57281.4\u548c0.3 A\/cm<sup>2<\/sup>\u7684\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u52a0\u901f\u964d\u89e3\u66f2\u7ebf\u3002\uff08e\uff09 DSAC\u91c7\u7528\u7684MEA\u6a21\u578b\u8bd5\u9a8c\u3002\uff08f\uff09 IrRu DSACs\u5728MEA\u4e2d\u57281A\/cm<sup>2<\/sup>\u4e0b\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<strong>\u00a9 2022\u00a0<\/strong><strong>Zhongnan University<\/strong><\/p>\n<p>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/p>\n<p>\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0cIrRu DSAC\u88ab\u8bbe\u8ba1\u4e3a\u4ea7\u751f\u539f\u5b50\u4e0d\u5bf9\u79f0\u7684\u5c40\u90e8\u7535\u573a\uff0c\u7528\u4e8e\u8c03\u8282H<sub>2<\/sub>O\u7684\u5438\u9644\u6784\u578b\u548c\u53d6\u5411\uff0c\u4ece\u800c\u4fc3\u8fdb\u78b1\u6027HER\u3002\u5bf9\u4e8e\u78b1\u6027HER\uff0c\u6240\u83b7\u5f97\u7684IrRu DSACs\u572810mA\/cm<sup>2<\/sup>\u4e0b\u8868\u73b0\u51fa10mV\u7684\u8d85\u4f4e\u8fc7\u7535\u52bf\uff0c\u5e76\u4e14\u57281A\/cm<sup>2<\/sup>\u4e0b\u5728300\u5c0f\u65f6\u5185\u5728MEA\u4e2d\u8868\u73b0\u51fa\u8d85\u9ad8\u7a33\u5b9a\u6027\u3002\u5b9a\u91cf\u7ed3\u679c\u8868\u660e\uff0cIrRu DSACs\u5177\u67094.00e\/\u00c5<sup>2<\/sup>\u7684\u7535\u8377\u5bc6\u5ea6\u503c\uff0c\u8fd9\u5bfc\u81f4\u4e86\u5f3a\u7684\u539f\u5b50\u5c40\u57df\u5316\u7535\u573a\u3001\u754c\u9762H<sub>2<\/sub>O\u7684\u91cd\u65b0\u53d6\u5411\uff0c\u4fc3\u8fdb\u4e86H<sub>2<\/sub>O\u7684\u89e3\u79bb\uff0c\u4ece\u800c\u83b7\u5f97\u66f4\u597d\u7684HER\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u539f\u5b50\u5c40\u57df\u7535\u573a\u8bf1\u5bfc\u7684\u6c34\u53d6\u5411\u662f\u5b9e\u73b0\u9ad8HER\u6d3b\u6027\u7684\u6709\u6548\u9014\u5f84\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1ahttps:\/\/doi.org\/10.1002\/anie.202300873<\/p>\n<p>\u672c\u6587\u7531\u56fe\u56fe\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u56fe\u56fe \u3010\u5bfc\u8bfb\u3011 \u78b1\u6c34\u7535\u89e3\u662f\u5927\u89c4\u6a21\u5236\u6c22\u7684\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u65b9\u6cd5\u3002\u5728\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\uff0c\u4f5c\u4e3a\u6c22\u6e90\u7684\u6c34\u7684\u89e3\u79bb\u901a\u5e38\u88ab\u8ba4\u4e3a\u662f\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u51b3\u901f\u6b65\u3002\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\u6c34\u7684\u7f13\u6162\u89e3\u79bb\u8fc7\u7a0b&#8230;<\/p>\n","protected":false},"author":50318,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-248872","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/248872"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/50318"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=248872"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/248872\/revisions"}],"predecessor-version":[{"id":248877,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/248872\/revisions\/248877"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=248872"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=248872"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=248872"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}