{"id":248762,"date":"2023-03-16T08:32:45","date_gmt":"2023-03-16T00:32:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=248762"},"modified":"2023-03-16T08:32:45","modified_gmt":"2023-03-16T00:32:45","slug":"%e6%9c%80%e6%96%b0nature%ef%bc%9a%e8%9e%ba%e6%97%8b%e6%89%8b%e6%80%a7%e6%b0%a7%e9%8e%93%e7%a6%bb%e5%ad%90%e4%b8%ad%e7%ab%8b%e4%bd%93%e6%b0%a7%e7%9a%84%e6%8e%a7%e5%88%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=248762","title":{"rendered":"\u6700\u65b0Nature\uff1a\u87ba\u65cb\u624b\u6027\u6c27\u9393\u79bb\u5b50\u4e2d\u7acb\u4f53\u6c27\u7684\u63a7\u5236"},"content":{"rendered":"<p style=\"text-align: center;\"><strong><b>\u6700\u65b0Nature\uff1a\u87ba\u65cb\u624b\u6027\u6c27\u9393\u79bb\u5b50\u4e2d\u7acb\u4f53\u6c27\u7684\u63a7\u5236<\/b><\/strong><\/p>\n<p style=\"text-align: center;\">\u3010\u5bfc\u8bfb\u3011<\/p>\n<p>\u56db\u9762\u4f53\u78b3\u7acb\u4f53\u4e2d\u5fc3\u7684\u63a7\u5236\u4e00\u76f4\u662f\u73b0\u4ee3\u5408\u6210\u5316\u5b66\u7684\u4e00\u4e2a\u7126\u70b9\uff0c\u8fd9\u5f97\u76ca\u4e8e\u5b83\u4eec\u7684\u6784\u578b\u7a33\u5b9a\u6027\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u4e09\u53d6\u4ee3\u7684\u6c2e\u3001\u78f7\u548c\u786b\u5316\u5408\u7269\u4f1a\u53d1\u751f\u91d1\u5b57\u5854\u53cd\u8f6c\uff0c\u8fd9\u662f\u4e00\u79cd\u88ab\u5e7f\u6cdb\u5229\u7528\u7684\u57fa\u672c\u548c\u516c\u8ba4\u7684\u7acb\u4f53\u5316\u5b66\u73b0\u8c61\u3002\u7136\u800c\uff0c\u6c27\u9393\u79bb\u5b50- -\u5728\u4e00\u4e2a\u5e26\u6b63\u7535\u7684\u6c27\u539f\u5b50\u4e0a\u6709\u4e09\u4e2a\u53d6\u4ee3\u57fa\u7684\u5316\u5408\u7269- -\u7684\u7acb\u4f53\u5316\u5b66\u53d1\u5c55\u5f97\u5f88\u5dee\uff0c<strong><b>\u9664\u4e86\u4f5c\u4e3a\u6d3b\u6027\u4e2d\u95f4\u4f53\u5b58\u5728\u5916\uff0c\u6c27\u9393\u79bb\u5b50\u5728\u5408\u6210\u4e2d\u7684\u5e94\u7528\u5f88\u5c11<\/b><\/strong>\u3002\u6784\u578b\u7a33\u5b9a\u7684\u6c27\u9393\u79bb\u5b50\u7684\u4f8b\u5b50\u76ee\u524d\u6ca1\u6709\u62a5\u9053\uff0c\u5176\u4e2d\u6c27\u539f\u5b50\u662f\u552f\u4e00\u7684\u7acb\u4f53\u5316\u4e2d\u5fc3\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u6c27\u91d1\u5b57\u5854\u53cd\u8f6c\u7684\u52bf\u5792\u5f88\u4f4e\uff0c\u800c\u4e14\u6240\u6709\u7684\u6c27\u9393\u79bb\u5b50\u90fd\u662f\u9ad8\u5ea6\u53cd\u5e94\u7684\u3002<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u3010\u6210\u679c\u63a0\u5f71\u3011<\/p>\n<p><strong><b>\u4eca\u65e5\uff0c<\/b><\/strong><strong><b>\u82f1\u56fd\u725b\u6d25\u5927\u5b66Martin D. Smith\u3001Jonathan W. Burton\u8bfe\u9898\u7ec4\u4e0e\u7f8e\u56fd\u79d1\u7f57\u62c9\u591a\u5dde\u7acb\u5927\u5b66Robert S. Paton\u8bfe\u9898\u7ec4\u5408\u4f5c\uff0c\u63cf\u8ff0\u4e86\u4e00\u79cd\u87ba\u65cb\u624b\u6027\u4e09\u82b3\u57fa\u6c27\u9393\u79bb\u5b50\u7684\u8bbe\u8ba1\u3001\u5408\u6210\u548c\u8868\u5f81\uff0c\u901a\u8fc7\u51e0\u4f55\u9650\u5236\u9632\u6b62\u6c27\u5b64\u5bf9\u7684\u53cd\u8f6c\uff0c\u4f7f\u5176\u80fd\u591f\u4f5c\u4e3a\u6784\u578b\u7684\u51b3\u5b9a\u56e0\u7d20<\/b><\/strong>\u3002\u7ed3\u5408\u5408\u6210\u548c\u91cf\u5b50\u8ba1\u7b97\u65b9\u6cd5\uff0c\u63d0\u51fa\u4e86\u80fd\u591f\u751f\u6210\u6784\u578b\u7a33\u5b9a\u7684\u5ba4\u6e29\u53ef\u5206\u7684\u76d0\u7684\u8bbe\u8ba1\u539f\u5219\u3002\u672c\u5de5\u4f5c\u8bc1\u660e\u4e86\u53cd\u6f14\u7684\u80fd\u5792\u5927\u4e8e110\u2009k J\u2009mol<sup>-1<\/sup>\uff0c\u5e76\u52fe\u52d2\u4e86\u5206\u8fa8\u7387\u8fc7\u7a0b\u3002<strong><b>\u636e\u6211\u4eec\u6240\u77e5\uff0c\u8fd9\u662f\u552f\u4e00\u4e00\u4e2a\u624b\u6027\u975e\u6d88\u65cb\u4e14\u6784\u578b\u7a33\u5b9a\u7684\u5206\u5b50\uff0c\u5176\u4e2d\u6c27\u539f\u5b50\u662f\u552f\u4e00\u7684\u7acb\u4f53\u4e2d\u5fc3<\/b><\/strong>\u3002\u76f8\u5173\u8bba\u6587\u4ee5\u9898\u4e3a\u201c<em><i>Control of stereogenic oxygen in a helically chiral oxonium ion<\/i><\/em>\u201d\u53d1\u8868\u5728<em><i>Nature<\/i><\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248763\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-33.png\" alt=\"\" width=\"710\" height=\"273\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-33.png 710w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-33-300x115.png 300w\" sizes=\"(max-width: 710px) 100vw, 710px\" \/><\/p>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p style=\"text-align: center;\">\u3010\u6570\u636e\u6982\u51b5\u3011<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248764\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-31.png\" alt=\"\" width=\"995\" height=\"445\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-31.png 995w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-31-300x134.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-31-768x343.png 768w\" sizes=\"(max-width: 995px) 100vw, 995px\" \/><\/p>\n<p><strong><b>\u56fe1. \u4e09\u53d6\u4ee3\u6742\u539f\u5b50\u7684\u91d1\u5b57\u5854\u53cd\u8f6c \u00a9 2023 The Authors<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248765\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-32.png\" alt=\"\" width=\"1046\" height=\"414\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-32.png 1046w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-32-300x119.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-32-768x304.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-32-1024x405.png 1024w\" sizes=\"(max-width: 1046px) 100vw, 1046px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>2<\/b><\/strong><strong><b>. \u7b2c\u4e00\u4ee3\u7acb\u4f53\u6c27\u5316\u5408\u7269\u7684\u5408\u6210\u8def\u7ebf\u53ca\u91cf\u5b50\u5316\u5b66\u8ba1\u7b97\u00a9 2023 The Authors<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248766\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-29.png\" alt=\"\" width=\"1041\" height=\"382\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-29.png 1041w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-29-300x110.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-29-768x282.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-29-1024x376.png 1024w\" sizes=\"(max-width: 1041px) 100vw, 1041px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3<\/b><\/strong><strong><b>. \u7acb\u4f53\u6c27\u5316\u5408\u7269\u7684\u5408\u6210\u4e0e\u7ed3\u6784\u7814\u7a76\u00a9 2023 The Authors<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248767\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-22.png\" alt=\"\" width=\"626\" height=\"553\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-22.png 626w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-22-300x265.png 300w\" sizes=\"(max-width: 626px) 100vw, 626px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4<\/b><\/strong><strong><b>. \u542boxepin\u7684\u6c27\u9393\u79bb\u5b50\u5bf9\u6620\u4f53\u8f6c\u5316\u7684\u673a\u7406\u6982\u8ff0\u00a9 2023 The Authors<\/b><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\">\u3010\u6210\u679c\u542f\u793a\u3011<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u7efc\u4e0a\u6240\u8ff0\uff0c<\/b><\/strong><strong><b>\u672c\u5de5\u4f5c\u901a\u8fc7<\/b><\/strong><strong><b>\u4e00\u79cd\u87ba\u65cb\u624b\u6027\u4e09\u82b3\u57fa\u6c27\u9393\u79bb\u5b50\u7684\u8bbe\u8ba1\u3001\u5408\u6210\u548c\u8868\u5f81<\/b><\/strong><strong><b>\uff0c\u5b9e\u73b0\u4e86\u7acb\u4f53\u6c27\u7684\u63a7\u5236<\/b><\/strong>\u3002\u4e3a\u4e86\u7814\u7a76\u6742\u539f\u5b50\u7684\u540c\u4e00\u6027\u5982\u4f55\u5f71\u54cd\u53cd\u8f6c\u52bf\u5792\uff0c\u6211\u4eec\u8ba1\u7b97\u7814\u7a76\u4e86\u8fd9\u4e00\u7c7b\u6c27\u9393\u79bb\u5b50\u53ca\u5176\u6c2e\u7c7b\u4f3c\u7269\u3002\u8ba1\u7b97\u5f97\u5230\u7684\u4e09\u82b3\u57fa\u6c27\u9393\u79bb\u5b50\u7684\u53cd\u8f6c\u52bf\u5792\u7cfb\u7edf\u6027\u5730\u9ad8\u4e8e\u4e09\u82b3\u80fa\u79bb\u5b50\u3002\u8fd9\u53ef\u4ee5\u57fa\u4e8e\u6742\u539f\u5b50\u7684\u6297\u518d\u6742\u5316\u80fd\u529b\u5408\u7406\u5316\uff0c\u5728\u6c27\u9393\u79bb\u5b50\u4e2d\u8fd9\u4e00\u80fd\u529b\u66f4\u5927\u3002\u5bf9\u4e8e\u542b\u6c2e\u7c7b\u4f3c\u7269\uff0c\u53cd\u8f6c\u7684TS\u7ed3\u6784\u4e2d\u5b58\u5728\u66f4\u5927\u7684\u5b64\u5bf9\u7535\u5b50\u79bb\u57df\u3002\u8fd9\u4e0e\u4e8c\u6c22\u4e8c\u82ef\u5e76\u6c27\u6742\u55b9\u5549\u6c27\u9393\u548c\u4e8c\u6c22\u4e8c\u82ef\u5e76\u6c2e\u6742\u55b9\u5549\u4f53\u7cfb\u7684\u8ba1\u7b97\u4e00\u81f4\uff0c\u8868\u660e\u52bf\u5792\u9ad8\u5ea6\u53d6\u51b3\u4e8e\u73af\u7ed3\u6784\u63d0\u4f9b\u7684\u51e0\u4f55\u7ea6\u675f\u548c\u6742\u539f\u5b50\u7684\u8eab\u4efd\u3002\u636e\u4e86\u89e3\uff0c\u672c\u5de5\u4f5c\u5408\u6210\u7684\u87ba\u65cb\u624b\u6027\u6c27\u9393\u79bb\u5b50\u662f\u552f\u4e00\u4e00\u4e2a\u624b\u6027\u975e\u6d88\u65cb\u4e14\u6784\u578b\u7a33\u5b9a\u7684\u5206\u5b50\uff0c\u5176\u4e2d\u6c27\u539f\u5b50\u662f\u552f\u4e00\u7684\u7acb\u4f53\u4e2d\u5fc3\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/www.nature.com\/articles\/s41586-023-05719-z<\/p>\n<p>\u672c\u6587\u7531\u6e29\u534e\u4f9b\u7a3f\u3002<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6700\u65b0Nature\uff1a\u87ba\u65cb\u624b\u6027\u6c27\u9393\u79bb\u5b50\u4e2d\u7acb\u4f53\u6c27\u7684\u63a7\u5236 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