{"id":248575,"date":"2023-03-26T06:11:22","date_gmt":"2023-03-25T22:11:22","guid":{"rendered":"\/\/m.iemloyee.com\/?p=248575"},"modified":"2023-03-23T10:12:04","modified_gmt":"2023-03-23T02:12:04","slug":"acs-catalysis%ef%bc%9a%e7%a8%b3%e5%ae%9a%e6%b0%a7%e5%8c%96%e6%80%81sno2%e5%9c%a8%e5%a4%a7%e7%94%b5%e6%b5%81%e5%af%86%e5%ba%a6%e4%b8%8b%e5%ae%9e%e7%8e%b0%e9%ab%98%e9%80%89%e6%8b%a9%e6%80%a7co2%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=248575","title":{"rendered":"ACS Catalysis\uff1a\u7a33\u5b9a\u6c27\u5316\u6001SnO2\u5728\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5b9e\u73b0\u9ad8\u9009\u62e9\u6027CO2\u7535\u8fd8\u539f\u6210\u7532\u9178\u76d0"},"content":{"rendered":"<p>\u5f20\u7199\u7199<\/p>\n<p><strong>\u4e00\u3001 \u3010\u5bfc\u8bfb\u3011\u00a0 <\/strong><\/p>\n<p>\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94(CO<sub>2<\/sub>RR)\u6280\u672f\u53ef\u5e94\u7528\u4e8e\u9009\u62e9\u6027\u5730\u751f\u4ea7\u9ad8\u9644\u52a0\u503c\u5316\u5b66\u54c1\u548c\u4fc3\u8fdb\u78b3\u8db3\u8ff9\u95ed\u73af\u3002\u7532\u9178\u76d0\u662f\u5236\u836f\u3001\u51b6\u91d1\u548c\u71c3\u6599\u7535\u6c60\u7684\u91cd\u8981\u539f\u6599\uff0c\u662f\u4e00\u79cd\u6781\u5177\u5e94\u7528\u524d\u666f\u7684CO<sub>2<\/sub>RR\u4ea7\u54c1\u3002\u8fd1\u5e74\u6765\uff0c\u5404\u79cd\u7535\u50ac\u5316\u5242\u7684\u5e94\u7528\u4f7f\u5f97CO<sub>2<\/sub>RR\u5230\u7532\u9178\u7684\u53cd\u5e94\u8fbe\u5230\u4e86\u5f88\u9ad8\u7684\u6cd5\u62c9\u7b2c\u6548\u7387(FE<sub>formate<\/sub>)(&gt;80%)\u3002\u7136\u800c\uff0c\u901a\u5e38\u5728\u4f4e\u7535\u6d41\u5bc6\u5ea6(&lt; 200mA cm<sup>&#8211;<\/sup><sup>2<\/sup>) \u60c5\u51b5\u4e0b\uff0c\u7532\u9178\u76d0\u7684\u9009\u62e9\u6027\u8f83\u9ad8\u3002\u968f\u7740\u7535\u6d41\u5bc6\u5ea6\u589e\u5927\uff0c\u7ade\u4e89\u6790\u6c22\u53cd\u5e94(HER)\u52a0\u5267\uff0c\u4f7f\u5f97\u7532\u9178\u76d0\u7684FE<sub>formate<\/sub>\u964d\u4f4e\uff08&lt;50%\uff09\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u51fa\u80fd\u5728\u5de5\u4e1a\u6c34\u5e73\u7684\u5de5\u4f5c\u7535\u6d41\u5bc6\u5ea6(&gt;200 mA cm<sup>-2<\/sup>)\u6761\u4ef6\u4e0b\uff0c\u4fdd\u6301\u9ad8FE<sub>formate<\/sub> (&gt;70%) \u7684CO<sub>2<\/sub>\u8f6c\u5316\u5230\u7532\u9178\u7684\u7535\u50ac\u5316\u5242\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002<\/p>\n<p>\u9664\u4e86\u5177\u6709\u7ade\u4e89\u7684HER\u5916\uff0c\u7535\u50ac\u5316\u5242\u5728\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0bCO<sub>2<\/sub>RR\u7684\u7a33\u5b9a\u6027\u66f4\u52a0\u5173\u952e\u3002\u4e00\u822c\u60c5\u51b5\u4e0b\uff0c\u9ad8\u6c27\u5316\u6001\u7684\u7535\u50ac\u5316\u5242\u5728\u9ad8\u8fd8\u539f\u7535\u4f4d\u7535\u89e3\u8fc7\u7a0b\u4e2d\u7ecf\u8fc7\u91cd\u6784\u88ab\u7535\u5316\u5b66\u8fd8\u539f\u4e3a\u5355\u8d28\u3002\u91d1\u5c5e\u76f8\u7535\u50ac\u5316\u5242\u4e00\u65b9\u9762\u5bfc\u81f4\u957f\u671f\u53cd\u5e94\u5931\u6d3b\uff0c\u53e6\u4e00\u65b9\u9762\u4e0d\u53ef\u907f\u514d\u5730\u9a71\u52a8HER\u8fdb\u4e00\u6b65\u964d\u4f4e\u7532\u9178\u76d0\u7684\u9009\u62e9\u6027\u3002\u56e0\u6b64\uff0c\u5408\u7406\u8bbe\u8ba1\u7535\u50ac\u5316\u5242\u5b9e\u73b0\u5728\u9ad8\u8d1f\u7535\u4f4d\u4e0b\u7a33\u5b9a\u7684\u9ad8\u6c27\u5316\u6001\u975e\u5e38\u91cd\u8981\u3002\u5177\u6709\u9ad8HER\u60f0\u6027\u7684\u9521\u57fa\u6750\u6599\u56e0\u5176\u73af\u5883\u53cb\u597d\u3001\u6027\u8d28\u4f18\u5f02\u800c\u6210\u4e3aCO<sub>2<\/sub>\u8f6c\u5316\u5230\u7532\u9178\u7684\u4e3b\u8981\u7535\u50ac\u5316\u5242\u3002\u9ad8\u6c27\u5316\u6001SnO<sub>2<\/sub>\u4e2d\u7684Sn\u56e0\u5176\u4f18\u5f02\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u88ab\u8ba4\u4e3a\u662f\u6d3b\u6027\u7269\u8d28\u3002\u7136\u800c\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a&gt;200 mA cm<sup>&#8211;<\/sup><sup>2<\/sup>\u65f6\uff0cSnO<sub>2<\/sub>\u4ecd\u4e0d\u53ef\u907f\u514d\u5730\u4f1a\u88ab\u8fd8\u539f\u4e3aSn\u91d1\u5c5e\u76f8\u800c\u53d1\u751f\u6d3b\u6027\u8870\u51cf\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\uff0c\u4ee5\u5f80\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u5f62\u8c8c\u63a7\u5236\u3001\u5c40\u90e8\u7578\u53d8\u3001\u6742\u539f\u5b50\u63ba\u6742\u3001\u548c\u7f3a\u9677\u5f15\u5165\u7b49\u591a\u79cd\u7b56\u7565\uff0c\u6765\u4fdd\u62a4\u7535\u50ac\u5316\u5242\u7684\u6c27\u5316\u6001\u548c\u4e3b\u76f8\u7ed3\u6784\u3002\u7136\u800c\uff0c\u53ea\u6709\u5c11\u6570\u7535\u50ac\u5316\u5242\u65e2\u80fd\u6ee1\u8db3\u5b9e\u9645\u7535\u6d41\u5bc6\u5ea6(&gt;200 mA cm<sup>&#8211;<\/sup><sup>2<\/sup>)\u8981\u6c42\uff0c\u540c\u65f6\u4fdd\u6301\u8f83\u9ad8\u7684FE<sub>formate<\/sub>\u3002<\/p>\n<p><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u4e54\u4e16\u748b\u6559\u6388\u548c\u90d1\u5c27\u526f\u6559\u6388\u7b49\u4eba\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u4e0d\u540c\u91d1\u5c5e\u5355\u539f\u5b50(Cu\u3001Bi\u548cPt)\u63ba\u6742\u7684SnO<sub>2<\/sub>\uff0c\u4ee5\u63a2\u7a76CO<sub>2<\/sub>RR\u8fc7\u7a0b\u4e2d\u539f\u5b50\u63ba\u6742\u7f3a\u9677\u5bf9SnO<sub>2<\/sub>\u4fdd\u62a4\u7684\u5f71\u54cd\u3002Cu\u63ba\u6742\u7684SnO<sub>2<\/sub>\u5728\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8868\u73b0\u51fa\u6700\u4f73\u7684CO<sub>2<\/sub>RR\u6d3b\u6027\uff0c\u7279\u522b\u662f\u5728500 mA cm<sup>&#8211;<\/sup><sup>2<\/sup>\u4e0b\u4e5f\u80fd\u4fdd\u630181%\u7684FE<sub>formate<\/sub>\u3002<\/p>\n<p>\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\u4ee5\u201c<strong>Stabilizing Oxidation State of SnO<sub>2<\/sub> for Highly Selective CO<sub>2<\/sub> Electroreduction to Formate at Large Current Densities<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520a<em>ACS Catalysis<\/em>\u4e0a\u3002<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248576\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/1-8.png\" alt=\"\" width=\"1232\" height=\"343\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/1-8.png 1232w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/1-8-300x84.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/1-8-768x214.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/1-8-1024x285.png 1024w\" sizes=\"(max-width: 1232px) 100vw, 1232px\" \/><\/strong><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>1.\u63d0\u51fa\u4e86\u4e00\u79cd\u539f\u5b50\u63ba\u6742\u7b56\u7565(\u901a\u8fc7Cu, Bi\u6216Pt)\u6765\u89e6\u53d1SnO<sub>2<\/sub>\u6676\u683c\u4e2d\u6c27\u7a7a\u4f4d\uff08O<sub>v<\/sub>\uff09\u7684\u51fa\u73b0\uff0c\u5e76\u5728CO<sub>2<\/sub>RR\u8fc7\u7a0b\u4e2d\u7a33\u5b9aSnO<sub>2<\/sub>\u7684\u6c27\u5316\u6001\u3002\u5728\u5546\u4e1a\u6d41\u52a8\u6c60\u4e2d\uff0c\u6700\u4f18Cu- SnO<sub>2<\/sub>\u53ef\u4ee5\u5728\u9ad8\u8fbe500 mA cm<sup>&#8211;<\/sup><sup>2<\/sup>\u7684\u5bbd\u7535\u6d41\u5bc6\u5ea6\u8303\u56f4\u5185\u4fdd\u6301&gt;80%\u7684\u9ad8\u7532\u9178\u6cd5\u62c9\u7b2c\u6548\u7387\u548c\u7ea650~60%\u7684\u7535\u6c60\u80fd\u91cf\u6548\u7387\uff0c\u8d85\u8fc7\u4e86\u5927\u591a\u6570\u5df2\u62a5\u9053\u7684\u5de5\u4f5c\u3002<\/p>\n<p>2.\u539f\u4f4d\u5149\u8c31\u6d4b\u91cf\u548c\u53d7\u63a7\u7535\u5316\u5b66\u6d4b\u8bd5\u8868\u660e\uff0c\u7531Cu\/Bi\/Pt\u5355\u539f\u5b50\u63ba\u6742\u5f15\u5165\u7684O<sub>v<\/sub>\u662f\u7a33\u5b9aSnO<sub>2<\/sub>\u3001\u4fc3\u8fdb\u7532\u9178\u76f8\u5173<sup>*<\/sup>OCHO\u53cd\u5e94\u4e2d\u95f4\u4f53\u5438\u9644\u7684\u5173\u952e\u3002\u5728\u4e00\u7cfb\u5217\u63ba\u6742SnO<sub>2<\/sub>\u50ac\u5316\u5242\u4e0a\u5efa\u7acb\u4e86O<sub>v<\/sub>\u6d53\u5ea6\u4e0eCO<sub>2<\/sub>\u5230\u7532\u9178\u76d0\u8f6c\u5316\u7684\u5b9a\u6027\u5173\u7cfb\u3002<\/p>\n<p><strong>\u00a0<\/strong><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011 <\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248577\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/2-9.png\" alt=\"\" width=\"615\" height=\"876\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/2-9.png 615w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/2-9-211x300.png 211w\" sizes=\"(max-width: 615px) 100vw, 615px\" \/><\/strong><\/p>\n<p><strong>\u56fe1 <\/strong><strong>\u7ed3\u6784\u8868\u5f81\u3002<\/strong><strong>\u00a9 2023 American Chemical Society<\/strong><\/p>\n<p>(a)\u5408\u6210\u9884\u50ac\u5316\u5242\u7684\u5236\u5907\u539f\u7406\u56fe\u3002(b) Cu-SnO<sub>2<\/sub>\u7684\u539f\u5b50\u5206\u8fa8\u7387HAADF-STEM\u56fe\u50cf(\u5de6)\u548cEELS\u5143\u7d20\u6620\u5c04\u56fe\u50cf(\u53f3)\u3002(c) SnO<sub>2<\/sub>\u3001Cu-SnO<sub>2<\/sub>\u3001Bi-SnO<sub>2<\/sub>\u548cPt-SnO<sub>2<\/sub>\u9884\u50ac\u5316\u5242\u7684\u62c9\u66fc\u5149\u8c31(\u5de6)\u548c\u4e0d\u540c\u91cfCu\u63ba\u6742SnO<sub>2<\/sub>\u7684\u62c9\u66fc\u5149\u8c31(\u53f3)\u3002(d) CO<sub>2<\/sub>RR \u540eSnO<sub>2<\/sub>\u3001Cu-SnO<sub>2<\/sub>\u3001Bi-SnO<sub>2<\/sub>\u548cPt-SnO<sub>2<\/sub>\u50ac\u5316\u5242\u7684\u62c9\u66fc\u5149\u8c31\u3002(e) CO<sub>2<\/sub>RR\u540eSnO<sub>2<\/sub>\u548cCu-SnO<sub>2<\/sub>\u7684O 1s XPS\u8c31\u3002<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248578\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/3-10.png\" alt=\"\" width=\"540\" height=\"685\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/3-10.png 540w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/3-10-236x300.png 236w\" sizes=\"(max-width: 540px) 100vw, 540px\" \/><\/strong><\/p>\n<p><strong>\u56fe2 CO<sub>2<\/sub>RR\u6027\u80fd\u3002\u00a9 2023 American Chemical Society<\/strong><\/p>\n<p>(a) Cu-SnO<sub>2<\/sub>\u50ac\u5316\u5242\u57281M KOH\u6eb6\u6db2\u4e2d\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u4ea7\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u3002(b) 1M KOH\u6eb6\u6db2\u4e2d\uff0c\u7eafSnO<sub>2<\/sub>\u50ac\u5316\u5242\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u4ea7\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u3002(c) Cu-SnO<sub>2<\/sub>\u5728200 mA cm<sup>-2<\/sup>(\u4e0a)\u548c500 mA cm<sup>&#8211;<\/sup><sup>2<\/sup>(\u4e0b)\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u8bd5\u9a8c\u3002\u7535\u89e3\u6db2\u6bcf\u5c0f\u65f6\u66f4\u65b0\u4e00\u6b21\u3002(d)\u4e0e\u5176\u4ed6\u62a5\u9053\u7684Sn\u57fa\u50ac\u5316\u5242\u76f8\u6bd4\uff0cCu-SnO<sub>2<\/sub>\u7684\u603b\u7535\u6d41\u5bc6\u5ea6\u548cFE<sub>formate<\/sub>\u3002(e)\u7eafSnO<sub>2<\/sub>\u3001Cu-SnO<sub>2<\/sub>\u3001Bi-SnO<sub>2<\/sub>\u548cPt-SnO<sub>2<\/sub>\u7684FE<sub>formate<\/sub>\u6bd4\u8f83\u3002(f) \u7eafSnO<sub>2<\/sub>\u30010.6Cu-SnO<sub>2<\/sub>\u30012Cu-SnO<sub>2<\/sub>\u548c13Cu-SnO<sub>2<\/sub>\u7684FE<sub>formate<\/sub>\u6bd4\u8f83\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248579\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/4-7.png\" alt=\"\" width=\"521\" height=\"776\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/4-7.png 521w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/4-7-201x300.png 201w\" sizes=\"(max-width: 521px) 100vw, 521px\" \/><\/strong><\/p>\n<p><strong>\u56fe3 \u673a\u5236\u7684\u63a2\u7d22\u3002\u00a9 2023 American Chemical Society<\/strong><\/p>\n<p>(a) D<sub>2<\/sub>O\u5236\u5907\u76840.1 M KHCO<sub>3<\/sub>\u9971\u548cCO<sub>2<\/sub>\u7535\u89e3\u8d28\u4e2d\uff0cCu-SnO<sub>2<\/sub>(\u5de6)\u548cSnO<sub>2<\/sub>(\u53f3)\u5728\u4e0d\u540c\u7535\u4f4d\u4e0b\u7684\u539f\u4f4dATR-IR\u7ed3\u679c\u3002(b) Cu-SnO<sub>2<\/sub>(\u5de6)\u548cSnO<sub>2<\/sub>(\u53f3)\u5728\u4e0d\u540c\u9634\u6781\u7535\u4f4d\u4e0b\u7684\u539f\u4f4d\u62c9\u66fc\u7ed3\u679c\u3002(c)\u4f4e\/\u9ad8\u8fd8\u539f\u7535\u4f4d\u4e0bCO<sub>2<\/sub>RR\u8fc7\u7a0b\u4e2dCu-SnO<sub>2<\/sub>\u548cSnO<sub>2<\/sub>\u7684\u5438\u9644\u884c\u4e3a\u548c\u6750\u6599\u8f6c\u5316\u793a\u610f\u56fe\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248580\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/5-3.png\" alt=\"\" width=\"849\" height=\"562\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/5-3.png 849w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/5-3-300x199.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/5-3-768x508.png 768w\" sizes=\"(max-width: 849px) 100vw, 849px\" \/>\u56fe4 \u7ed3\u6784-\u529f\u80fd\u5173\u7cfb\u7684\u6784\u5efa\u3002<\/strong><strong>\u00a9 2023 A<\/strong><strong>merican Chemical Society<\/strong><\/p>\n<p>SnO<sub>2<\/sub>\u3001Cu-SnO<sub>2<\/sub>\u3001Bi-SnO<sub>2<\/sub>\u548cPt-SnO<sub>2<\/sub> (a) \u4ece-0.6 V<sub>RHE<\/sub>\u53d8\u5316\u5230-1.4 V<sub>RHE <\/sub><sup>*<\/sup>OCHO\u5438\u9644\u5cf0\u9762\u79ef\u548c(b)\u5728300 mA cm<sup>&#8211;<\/sup><sup>2<\/sup>\u4e0bFE<sub>formate<\/sub>\u7684\u6bd4\u8f83\u3002(c) \u4e0d\u540c\u5355\u539f\u5b50\u63ba\u6742\u7684SnO<sub>2<\/sub>\u7684<sup>*<\/sup>OCHO\u5438\u9644\u80fd\u529b\u4e0eCO<sub>2<\/sub>RR\u5230\u7532\u9178\u8f6c\u5316\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb(\u5728300 mA cm<sup>&#8211;<\/sup><sup>2<\/sup>\u4e0b\u7684FE<sub>formate<\/sub>\u4e3a\u4ee3\u8868)\u3002(d) Cu\u63ba\u6742\u91cf\u4e0eO<sub>v<\/sub>\u63ba\u6742\u91cf\u7684\u5173\u7cfb\u3002(e) O<sub>v<\/sub>\u91cf\u4e0e<sup>*<\/sup>OCHO\u5cf0\u9762\u79ef\u5728-0.6 V<sub>RHE<\/sub>\u5230-1.4 V<sub>RHE<\/sub>\u4e4b\u95f4\u7684\u53d8\u5316\u5173\u7cfb\u3002 (f)O<sub>v<\/sub>\u91cf\u548cCO<sub>2<\/sub>RR\u5230\u7532\u9178\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb(\u5728400 mA cm<sup>&#8211;<\/sup><sup>2<\/sup>\u4e0b\u7684FE<sub>formate<\/sub>\u4e3a\u4ee3\u8868)\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u4f5c\u8005\u5f00\u53d1\u4e86\u4e00\u79cd\u5355\u539f\u5b50\u63ba\u6742\u7b56\u7565\u6765\u4f18\u5316SnO<sub>2<\/sub>\u7684CO<sub>2<\/sub>RR\u6027\u80fd\uff0c\u5b9e\u73b0\u5728\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u751f\u4ea7\u7532\u9178\u3002\u5373\u4f7f\u5728500 mA cm<sup>&#8211;<\/sup><sup>2<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u901a\u8fc7Cu\u63ba\u6742\u4e5f\u80fd\u8fbe\u523080%\u4ee5\u4e0a\u7684FE<sub>formate<\/sub>\u3002\u5c06\u7535\u50ac\u5316\u7ed3\u679c\u4e0e\u5149\u8c31\u6d4b\u91cf\u76f8\u7ed3\u5408\uff0cCu-SnO<sub>2<\/sub>\u4f18\u8d8a\u7684CO<sub>2<\/sub>RR\u6027\u80fd\u4e0e\u4e24\u4e2a\u5173\u952e\u56e0\u7d20\u7d27\u5bc6\u76f8\u5173:\u4e00\u662fCu\u63ba\u6742\u7684\u6210\u5206\u4f18\u52bf\uff0c\u6709\u5229\u4e8eCO<sub>2<\/sub>\u7684\u6d3b\u5316\u548cSnO<sub>2<\/sub>\u5728CO<sub>2<\/sub>RR\u8fc7\u7a0b\u4e2d\u7684\u7a33\u5b9a\u6027;\u4e8c\u662f\u66b4\u9732\u7684O<sub>v<\/sub>\u4e2d\u6240\u83b7\u5f97\u7684\u5438\u9644\u4f18\u52bf\uff0c\u534f\u52a9\u7532\u9178\u76f8\u5173\u4e2d\u95f4\u4f53<sup>*<\/sup>OCHO\u5728\u542b\u6709\u7f3a\u9677\u7684Cu-SnO<sub>2<\/sub>\u8868\u9762\u4e0a\u6b63\u786e\u5438\u9644\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u8bbe\u8ba1\u6ee1\u8db3\u5b9e\u9645\u9700\u6c42\u7684CO<sub>2<\/sub>RR\u7535\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u601d\u8def\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.3c00123<\/p>\n<p>\u672c\u6587\u7531\u5f20\u7199\u7199\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5f20\u7199\u7199 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