{"id":248200,"date":"2023-03-17T06:00:09","date_gmt":"2023-03-16T22:00:09","guid":{"rendered":"\/\/m.iemloyee.com\/?p=248200"},"modified":"2023-03-15T16:38:36","modified_gmt":"2023-03-15T08:38:36","slug":"%e5%8d%97%e5%bc%80%e5%a4%a7%e5%ad%a6%e5%8d%9c%e6%98%be%e5%92%8c%e6%9c%80%e6%96%b0energychem%e7%bb%bc%e8%bf%b0%ef%bc%9a%e7%94%a8%e4%ba%8e%e5%85%88%e8%bf%9b%e6%b0%b4%e7%b3%bb%e7%a6%bb%e5%ad%90%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=248200","title":{"rendered":"\u5357\u5f00\u5927\u5b66\u535c\u663e\u548c\u6700\u65b0EnergyChem\u7efc\u8ff0\uff1a\u7528\u4e8e\u5148\u8fdb\u6c34\u7cfb\u79bb\u5b50\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6"},"content":{"rendered":"<p style=\"text-align: center;\"><strong><b>\u5357\u5f00\u5927\u5b66\u535c\u663e\u548c<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong><strong><b>\u6700\u65b0EnergyChem<\/b><\/strong><strong><b>\u7efc\u8ff0<\/b><\/strong><strong><b>\uff1a\u7528\u4e8e\u5148\u8fdb\u6c34\u7cfb\u79bb\u5b50\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6<\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>[\u5bfc\u8bfb]<\/b><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599(MOFs)\u5177\u6709\u6bd4\u8868\u9762\u79ef\u9ad8\u3001\u5b54\u9699\u7387\u53ef\u8c03\u3001\u6676\u4f53\u7ed3\u6784\u6709\u5e8f\u3001\u8010\u53d7\u6027\u7b49\u4f18\u70b9\uff0c\u5728\u7535\u5316\u5b66\u50a8\u80fd\u9886\u57df\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u7136\u800c\uff0c\u4e00\u4e9b\u5177\u6709\u9ad8\u7535\u5316\u5b66\u6027\u80fd\u7684MOFs\u901a\u5e38\u5728\u6c34\u6eb6\u6db2\u4e2d\u4e0d\u7a33\u5b9a\uff0c\u8fd9\u9650\u5236\u4e86\u5176\u5728\u6c34\u76f8\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\u4e2d\u7684\u53d1\u5c55\uff0c\u800c\u6c34\u76f8\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\u6bd4\u5728\u4f20\u7edf\u6709\u673a\u7535\u89e3\u6db2\u4e2d\u64cd\u4f5c\u66f4\u4fbf\u5b9c\u3001\u66f4\u5b89\u5168\u3001\u66f4\u5177\u6709\u79bb\u5b50\u5bfc\u7535\u6027\u3002\u4eba\u4eec\u901a\u8fc7\u6784\u5efa\u7a33\u5b9a\u7684MOFs\u6216\u63a7\u5236\u5316\u5b66\u6216\u70ed\u529b\u4f5c\u7528\u8bf1\u5bfc\u7684MOF\u884d\u751f\u8fc7\u7a0b\u6765\u4f18\u5316\u5176\u6027\u8d28\u548c\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u603b\u7ed3MOFs\u5728\u6c34\u7cfb\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u5c06\u662f\u6709\u76ca\u7684\u3002<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6210\u679c\u63a0\u5f71]<\/b><\/strong><\/p>\n<p><strong><b>\u8fd1\u65e5<\/b><\/strong><strong><b>\uff0c<\/b><\/strong><strong><b>\u5357\u5f00\u5927\u5b66\u535c\u663e\u548c\u6559\u6388<\/b><\/strong><strong><b>\u8bfe\u9898\u7ec4<\/b><\/strong><strong><b>\u7efc\u8ff0\u4e86MOFs\u5728\u6c34\u76f8\u6761\u4ef6\u4e0b\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u70ed\u7a33\u5b9a\u6027<\/b><\/strong>\u3002\u603b\u7ed3\u4e86MOFs\u8d85\u8fc7\u5176\u7a33\u5b9a\u6027\u65f6\u7684\u6f14\u5316\u8fc7\u7a0b\u3002\u6b64\u5916\uff0c\u672c\u6587\u8fd8\u5bf9\u6700\u8fd1\u5feb\u901f\u589e\u957f\u7684\u57fa\u4e8eMOF\u7684\u6c34\u7cfb\u79bb\u5b50\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6587\u732e\u8fdb\u884c\u4e86\u5168\u9762\u7684\u7efc\u8ff0\uff0c\u4e3a\u8bbe\u8ba1\u9ad8\u6027\u80fd\u7684\u6c34\u7cfb\u7535\u5316\u5b66\u5668\u4ef6\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002\u4e3aMOFs\u5e94\u7528\u4e8e\u6c34\u7cfb\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u63d0\u4f9b\u4e86\u5f53\u524d\u7684\u6311\u6218\u548c\u673a\u9047\u3002\u5e0c\u671b\u901a\u8fc7\u672c\u6587\u7684\u7efc\u8ff0\uff0c\u53d1\u6325MOFs\u7684\u4f18\u52bf\uff0c\u5f25\u8865\u5176\u4e0d\u8db3\uff0c\u4fc3\u8fdbMOFs\u5728\u6c34\u7cfb\u7535\u5316\u5b66\u5668\u4ef6\u4e2d\u7684\u53d1\u5c55\u3002\u76f8\u5173\u8bba\u6587\u4ee5\u9898\u4e3a\uff1a\u201c<em><i>Metal-organic frameworks for advanced aqueous ion batteries and supercapacitors<\/i><\/em>\u201d\u53d1\u8868\u5728<em><i>EnergyChem<\/i><\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248203\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-5.png\" alt=\"\" width=\"585\" height=\"330\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-5.png 585w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72471-5-300x169.png 300w\" sizes=\"(max-width: 585px) 100vw, 585px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6838\u5fc3\u521b\u65b0\u70b9]<\/b><\/strong><\/p>\n<ul>\n<li>\u63a2\u8ba8\u4e86MOFs\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u70ed\u89e3\u8fc7\u7a0b\uff0c\u4ee5\u6307\u5bfc\u5176\u5728\u6c34\u7cfb\u50a8\u80fd\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u3002<\/li>\n<li>\u7cfb\u7edf\u603b\u7ed3\u4e86MOFs\u53ca\u5176\u884d\u751f\u7269\u5728\u6c34\u7cfb\u79bb\u5b50\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u65b9\u9762\u7684\u6700\u65b0\u8fdb\u5c55\u3002<\/li>\n<li>\u4ecb\u7ecd\u4e86MOFs\u548cMOF\u884d\u751f\u7269\u5728\u6c34\u7cfb\u79bb\u5b50\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u5f53\u524d\u6311\u6218\u548c\u673a\u9047\u3002<\/li>\n<\/ul>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6570\u636e\u6982\u89c8]<\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u7684\u53ef\u884c\u6027<\/b><\/strong><\/li>\n<\/ul>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p>\u7a33\u5b9a\u6027\u662fMOF\u6750\u6599\u5e94\u7528\u4e8e\u7279\u6b8a\u9886\u57df\u7684\u91cd\u8981\u524d\u63d0\u3002\u56e0\u6b64\uff0c\u5728\u8fd9\u4e00\u6d3b\u6027\u9886\u57df\u5185\uff0c\u8bbe\u8ba1\u548c\u5408\u6210\u7a33\u5b9a\u7684MOFs\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u4e86\u89e3MOFs\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u53ca\u5176\u6f5c\u5728\u7684\u4f5c\u7528\u673a\u5236\uff0c\u5bf9\u4e8e\u5f00\u53d1\u80fd\u591f\u627f\u53d7\u5e38\u89c1\u5de5\u4e1a\u64cd\u4f5c\u6761\u4ef6\u7684MOF\u57fa\u6750\u6599\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u6c34\u3001\u9178\u3001\u78b1\u6216\u914d\u4f4d\u9634\u79bb\u5b50\u7684\u5b58\u5728\u4e25\u91cd\u963b\u788d\u4e86\u4e00\u4e9bMOFs\u7684\u5e94\u7528\u548c\u5546\u4e1a\u5316\u3002\u56e0\u6b64\uff0c\u4e86\u89e3MOFs\u5728\u5404\u79cd\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u548c\u4e0d\u7a33\u5b9a\u6027\uff0c\u5bf9\u4e8e\u5f00\u53d1\u9002\u7528\u4e8e\u6c34\u76f8\u80fd\u6e90\u5668\u4ef6\u7684MOF\u57fa\u6750\u6599\u5341\u5206\u5fc5\u8981\u3002\u7279\u522b\u5730\uff0c\u672c\u6587\u9700\u8981\u4e86\u89e3\u5b83\u4eec\u5728\u4e0d\u540c\u53cd\u5e94\u73af\u5883\u4e2d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u4ee5\u53ca\u5728\u6d3b\u5316\u548c\u5206\u89e3\u8fc7\u7a0b\u4e2d\u7684\u673a\u68b0\u7a33\u5b9a\u6027\u3002\u5728\u672c\u8282\u4e2d\uff0c\u672c\u6587\u4e3b\u8981\u5173\u6ce8\u5316\u5b66\u548c\/\u6216\u70ed\u7a33\u5b9a\u7684MOFs\u3002\u4e00\u4e9bMOFs\u7684\u4e0d\u7a33\u5b9a\u6027\u53ef\u80fd\u6709\u52a9\u4e8e\u521b\u9020\u65b0\u7684\u5177\u6709\u7279\u5b9a\u6027\u8d28\u7684\u591a\u5b54\u56fa\u4f53\uff0c\u5982\u57fa\u4e8e\u9009\u62e9\u6027\u964d\u89e3\u7684\u66f4\u5148\u8fdb\u7684\u6750\u6599\u548c\u7ed3\u6784\u3002\u56e0\u6b64\uff0c\u5373\u4f7f\u662f\u4e0d\u7a33\u5b9a\u7684MOFs\u4e5f\u53ef\u80fd\u662f\u5408\u6210\u7a33\u5b9a\u6027\u63d0\u9ad8\u7684\u6c34\u7cfb\u7535\u6781\u6750\u6599\u7684\u826f\u597d\u524d\u9a71\u4f53\u3002\u672c\u90e8\u5206\u8fd8\u603b\u7ed3\u4e86\u591a\u79cdMOFs\u5728\u6c34\u3001\u70ed\u3001\u9178\u3001\u78b1\u7b49\u5916\u754c\u523a\u6fc0\u4e0b\u5728\u50a8\u6c34\u8bbe\u5907\u4e2d\u7684\u8f6c\u5316\u60c5\u51b5\uff0c\u5e76\u8fdb\u4e00\u6b65\u8ba8\u8bba\u4e86\u53ef\u80fd\u7684\u964d\u89e3\u673a\u7406\u548c\u5404\u79cd\u884d\u751f\u4ea7\u7269\u3002\u7279\u522b\u5730\uff0c\u672c\u6587\u5f3a\u8c03\u4e86\u5229\u7528MOFs\u7684\u4e0d\u7a33\u5b9a\u6027\u5728\u5e38\u89c4\u5408\u6210\u65b9\u6cd5\u96be\u4ee5\u5236\u5907\u7684\u6781\u7aef\u60c5\u51b5\u4e0b\u5236\u9020\u5404\u79cd\u6750\u6599\u3002\u6b64\u5916\uff0c\u8ba8\u8bba\u4e86MOF\u6750\u6599\u5728\u4e00\u5b9a\u6761\u4ef6\u4e0b\u5b8c\u5168\u5206\u89e3\u4e3a\u91d1\u5c5e\u3001\u91d1\u5c5e\u78b3\u5316\u7269\u548c\u78b3\u6750\u6599\u3002\u5728\u8fd9\u4e9b\u60c5\u51b5\u4e0b\uff0c\u672c\u6587\u5c06\u63a2\u7d22MOFs\u7684\u4e0d\u7a33\u5b9a\u6027\u6216\u53cd\u5e94\u6027\u4ee5\u53ca\u964d\u89e3\u5728\u5f62\u6001\u548c\u7ec4\u6210\u53d8\u5316\u4e2d\u7684\u4f5c\u7528\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248204\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-5.png\" alt=\"\" width=\"588\" height=\"383\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-5.png 588w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72472-5-300x195.png 300w\" sizes=\"(max-width: 588px) 100vw, 588px\" \/><\/p>\n<p>\u56fe1.\u00a0(a)\u7fa7\u9178\u548c\u5421\u5511\u8fde\u63a5\u57fa\u7684pKa\u503c\uff0c(b)\u5143\u7d20\u5468\u671f\u8868\u4e2d\u7684\u91d1\u5c5e\u5206\u4e3a\u8f6f\u9178\u3001\u4e2d\u95f4\u8f6f\/\u786c\u9178\u548c\u786c\u9178\u3002(c) HSAB\u7406\u8bba\u6307\u5bfc\u4e0b\u6784\u5efa\u7a33\u5b9aMOFs\u7684\u7b56\u7565\u00a9 2023 Elsevier<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248205\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-5.png\" alt=\"\" width=\"449\" height=\"659\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-5.png 449w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72473-5-204x300.png 204w\" sizes=\"(max-width: 449px) 100vw, 449px\" \/><\/p>\n<p>\u56fe2.\u00a0(a) PDMS\u6d82\u5c42\u5728MOFs\u8868\u9762\u7684\u63d2\u56fe\u3002(b)\u539f\u59cbMOF-5\u548cPDMS\u5305\u8986MOF-5\u4e0d\u540c\u65f6\u95f4\u7684TEM\u7167\u7247\u548c\u7c89\u672bXRD\u56fe\u8c31\u00a9 2023 Elsevier<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><\/b><strong><b>\u7528\u4e8e\u6c34\u7cfb\u79bb\u5b50\u7535\u6c60\u7684MOFs<\/b><\/strong><\/li>\n<\/ul>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p>\u4f5c\u4e3a\u5177\u6709\u4ee3\u8868\u6027\u7684\u53ef\u5145\u7535\u7535\u6c60\uff0c\u542b\u6709\u6709\u673a\u7535\u89e3\u6db2\u7684\u9502\u79bb\u5b50\u7535\u6c60(LIBs)\u5177\u6709\u91cd\u91cf\u8f7b\u3001\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u548c\u4f7f\u7528\u5bff\u547d\u957f\u7b49\u4f18\u70b9\uff0c\u5728\u7535\u7f51\u50a8\u80fd\u3001\u7535\u52a8\u6c7d\u8f66\u548c\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u7b49\u9886\u57df\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u7136\u800c\uff0c\u6709\u673a\u7535\u89e3\u6db2\u7684\u6bd2\u6027\u548c\u6613\u71c3\u6027\u963b\u788d\u4e86\u5176\u8fdb\u4e00\u6b65\u5e94\u7528\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u6c34\u7cfb\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u5176\u66f4\u9ad8\u7684\u5b89\u5168\u6027\u548c\u8bb8\u591a\u5176\u4ed6\u4f18\u52bf\uff0c\u5982\u6210\u672c\u8f83\u4f4e\u3001\u73af\u5883\u53cb\u597d\u548c\u66f4\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u663e\u793a\u51fa\u5de8\u5927\u7684\u524d\u666f\u3002\u7136\u800c\uff0c\u6c34\u56fa\u6709\u7684\u7a84\u7535\u538b\u7a97\u53e3\u4ec5\u4e3a1.23 V\uff0c\u9650\u5236\u4e86\u6c34\u7cfb\u7535\u6c60\u7684\u80fd\u91cf\u8f93\u51fa\u3002\u4f8b\u5982\uff0c\u4f20\u7edf\u7684\u94c5\u9178\u7535\u6c60\u548c\u954d\u9549\u7535\u6c60\u5206\u522b\u53ea\u80fd\u63d0\u4f9b30 Wh kg<sup>-1<\/sup>\u548c50 Wh kg<sup>-1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u6b64\u5916\uff0c\u5728\u6c34\u4e2d\u53d1\u751f\u7684\u526f\u53cd\u5e94\u964d\u4f4e\u4e86\u6c34\u7cfb\u7535\u6c60\u7684\u5faa\u73af\u5bff\u547d\uff0c\u4e25\u91cd\u963b\u788d\u4e86\u5176\u5927\u89c4\u6a21\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u8feb\u5207\u9700\u8981\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u53ef\u89c2\u7684\u500d\u7387\u6027\u80fd\u548c\u7a33\u5b9a\u6027\u7684\u9769\u547d\u6027\u6c34\u7cfb\u7535\u6c60\u4f53\u7cfb\u3002<\/p>\n<p>\u4e3a\u4e86\u63d0\u9ad8\u6c34\u7cfb\u7535\u6c60\u7684\u6027\u80fd\uff0c\u4eba\u4eec\u7814\u7a76\u4e86\u5404\u79cd\u7535\u6c60\u6750\u6599\uff0c\u5305\u62ecMOFs\u53ca\u5176\u884d\u751f\u7269\u3002\u4e0e\u4f20\u7edf\u7684\u5177\u6709\u6eb6\u89e3\u95ee\u9898\u7684\u6709\u673a\u7535\u6781\u76f8\u6bd4\uff0cMOFs\u7684\u6d3b\u6027\u6709\u673a\u57fa\u56e2\u901a\u8fc7\u91d1\u5c5e-\u914d\u4f53\u914d\u4f4d\u5171\u4ef7\u952e\u56fa\u5b9a\uff0c\u4ece\u800c\u6709\u6548\u5730\u63d0\u9ad8\u4e86\u7a33\u5b9a\u6027\u3002\u5728\u672c\u8282\u4e2d\uff0c\u672c\u6587\u91cd\u70b9\u4ecb\u7ecd\u4e86MOFs\u53ca\u5176\u884d\u751f\u7269\u5728\u4e0d\u540c\u6c34\u7cfb\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u5e94\u7528\uff0c\u5305\u62ec\u5355\u4ef7\u91d1\u5c5e\u79bb\u5b50Li<sup>+<\/sup>\u3001Na<sup>+<\/sup>\u3001K<sup>+<\/sup>\uff0c\u591a\u4ef7\u91d1\u5c5e\u79bb\u5b50Zn<sup>2+<\/sup>\u3001Ca<sup>2+<\/sup>\u3001Mg<sup>2+<\/sup>\u3001Al<sup>3+<\/sup>\u548c\u975e\u91d1\u5c5e\u79bb\u5b50H<sup>+<\/sup>\u3001NH<sup>4+<\/sup>\u3001Cl<sup>&#8211;<\/sup>\u3001OH<sup>&#8211;<\/sup>\u3002\u8ba8\u8bba\u4e86MOF\u76f8\u5173\u6750\u6599\u7684\u7ed3\u6784\u3001\u7269\u7406\u5316\u5b66\u6027\u8d28\u4e0e\u6c34\u7cfb\u7535\u6c60\u7535\u5316\u5b66\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u5927\u591a\u6570MOF\u6750\u6599\u88ab\u7528\u4f5c\u7535\u6781\uff0c\u800c\u4e00\u4e9b\u88ab\u7528\u4f5c\u529f\u80fd\u754c\u9762\u4fee\u9970\u5c42\u548c\u7535\u89e3\u8d28\uff0c\u7279\u522b\u662f\u5728\u950c\u57fa\u6c34\u7cfb\u7535\u6c60\u4e2d\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248206\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-5.png\" alt=\"\" width=\"1238\" height=\"555\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-5.png 1238w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-5-300x134.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-5-768x344.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72474-5-1024x459.png 1024w\" sizes=\"(max-width: 1238px) 100vw, 1238px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u56fe3. PBAs (a)\u65e0\u6c34\u548c(b)\u6709\u6c34\u7684\u6676\u4f53\u7ed3\u6784\u00a9 2023 Elsevier<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248213\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72479.png\" alt=\"\" width=\"1280\" height=\"427\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72479.png 1280w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72479-300x100.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72479-768x256.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72479-1024x342.png 1024w\" sizes=\"(max-width: 1280px) 100vw, 1280px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>\u56fe4. (a) Cu-HCF\u548cNi-HCF\u7684\u7535\u52bf\u4e0e\u6c34\u5408\u79bb\u5b50Stokes\u534a\u5f84\u7684\u5173\u7cfb\u3002(b) Na\u548cLi\u79bb\u5b50\u63d2\u5165FeFe(CN)<sub>6<\/sub>\u7684\u793a\u610f\u56fe\u00a9 2023 Elsevier<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248207\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-5.png\" alt=\"\" width=\"918\" height=\"656\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-5.png 918w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-5-300x214.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72475-5-768x549.png 768w\" sizes=\"(max-width: 918px) 100vw, 918px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u56fe5. (a) K<sub>2<\/sub>FeII[FeII(CN)<sub>6<\/sub>]\u00b7<sub>2<\/sub>H<sub>2<\/sub>O\u7eb3\u7c73\u7acb\u65b9\u4f53\u7684SEM\u7167\u7247\u3002(b) K<sub>2<\/sub>FeII [FeII(CN)<sub>6<\/sub>]\u00b7<sub>2<\/sub>H<sub>2<\/sub>O\u5728500\u30012000\u548c3000 mA g<sup>-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002(c)\u4e0d\u540c\u5145\u7535\/\u653e\u7535\u6001K<sub>2<\/sub>Fe\u2161[Fe\u2161(CN)<sub>6<\/sub>]\u00b7<sub>2<\/sub>H<sub>2<\/sub>O\u7684\u975e\u539f\u4f4dFTIR\u548c(d) EELS\u5206\u6790\u00a9 2023 Elsevier<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><\/b><strong><b>\u7528\u4e8e\u6c34\u7cfb\u8d85\u7ea7\u7535\u5bb9\u5668\u7684MOFs<\/b><\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p>\u8d85\u7ea7\u7535\u5bb9\u5668(SCs)\u5f15\u8d77\u4e86\u6781\u5927\u7684\u5173\u6ce8\uff0c\u9002\u7528\u4e8e\u67d0\u4e9b\u9700\u8981\u5927\u529f\u7387\u7684\u5e94\u7528\u3002\u5b83\u4eec\u901a\u5e38\u8868\u73b0\u51fa\u5feb\u901f\u5145\u653e\u7535\u3001\u9ad8\u529f\u7387\u80fd\u529b\u548c\u957f\u5bff\u547d\uff0c\u88ab\u8ba4\u4e3a\u662f\u5bf9\u7535\u6c60\u548c\u4f20\u7edf\u7535\u5bb9\u5668\u7684\u6539\u8fdb\u3002\u57fa\u4e8e\u4e0d\u540c\u7684\u7535\u8377\u5b58\u50a8\u673a\u5236\uff0c\u8d85\u7ea7\u7535\u5bb9\u5668\u53ef\u4ee5\u5206\u4e3a\u901a\u8fc7\u7535\u8377\u5438\u9644\u7684\u53cc\u7535\u5c42\u7535\u5bb9\u5668(EDLCs)\u548c\u901a\u8fc7\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u8d5d\u7535\u5bb9\u5668\u3002\u4e3a\u4e86\u5b9e\u73b0\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7535\u89e3\u6db2\u79bb\u5b50\u7684\u5feb\u901f\u5438\u9644\/\u8131\u9644\u6216\u5feb\u901f\u53ef\u9006\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u7535\u6781\u6750\u6599\u9700\u8981\u5177\u6709\u76f8\u5bf9\u77ed\u7684\u7535\u8377\/\u79bb\u5b50\u4f20\u8f93\u901a\u9053\u548c\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9(\u5438\u9644\/\u8131\u9644\u548c\u6c27\u5316\u8fd8\u539f)\u3002\u56e0\u6b64\uff0c\u7531\u4e8e\u591a\u5b54\u7ed3\u6784\u4e0e\u7535\u5b50\u548c\u79bb\u5b50\u7684\u52a8\u529b\u5b66\u8f6c\u79fb\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u5177\u6709\u5408\u9002\u7684\u5b54\u5f84\u5206\u5e03\u3001\u8f83\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u548c\u5408\u9002\u7684\u7535\u6d3b\u6027\u7269\u79cd\u4f4d\u7f6e\u7684\u7535\u6781\u6750\u6599\u8868\u73b0\u51fa\u66f4\u5927\u7684\u6bd4\u7535\u5bb9\u3002MOFs\u53ca\u5176\u884d\u751f\u6750\u6599\u7ee7\u627f\u4e86MOFs\u7684\u591a\u5b54\u7ed3\u6784\uff0c\u5177\u6709\u5927\u7684\u6bd4\u8868\u9762\u79ef(\u9ad8\u8fbe6000 m<sup>2<\/sup>\u00a0g<sup>-1<\/sup>\u00a0)\u548c\u5e7f\u6cdb\u7684\u6c27\u5316\u8fd8\u539f\u4e2d\u5fc3\u3002\u8fd9\u4e9b\u5141\u8bb8\u5b83\u4eec\u4e3aSCs\u63d0\u4f9b\u8db3\u591f\u7684\u5438\u9644\u548c\u53cd\u5e94\u4f4d\u70b9\uff0c\u4ee5\u53ca\u6709\u524d\u9014\u7684\u7535\u6781\u6750\u6599\u3002\u6b64\u5916\uff0c\u53ef\u4ee5\u901a\u8fc7\u8c03\u63a7MOFs\u548cMOF\u884d\u751f\u7269\u6765\u8bbe\u8ba1\u7535\u5bb9\u578b\u548c\u7535\u6c60\u578b\u7535\u6781\u6750\u6599\uff0c\u5236\u5907\u5177\u6709\u5927\u7535\u538b\u7a97\u53e3\u548c\u4f18\u5f02\u6027\u80fd\u7684\u975e\u5bf9\u79f0\u7535\u5bb9\u5668\u3002<\/p>\n<p>\u5728\u8fc7\u53bb\u7684\u5341\u51e0\u5e74\u4e2d\uff0c\u4eba\u4eec\u5bf9MOFs\u53ca\u5176\u884d\u751f\u7269\u5728SCs\u4e2d\u7684\u5e94\u7528\u8fdb\u884c\u4e86\u5927\u91cf\u7684\u7814\u7a76\u3002\u76ee\u524d\u5b58\u5728\u4e00\u4e9b\u6311\u6218\uff0c\u5982\u5b54\u9053\u5c3a\u5bf8\u5bf9\u79bb\u5b50\u63d2\u5165\u7684\u7a7a\u95f4\u4f4d\u963b\u3001\u90e8\u5206MOFs\u4e0e\u7535\u89e3\u8d28\u4e0d\u76f8\u5bb9\u3001\u7f3a\u4e4f\u5bfc\u7535\u6027\u7b49\u3002\u5e78\u8fd0\u7684\u662f\uff0c\u8fd9\u4e9b\u53ef\u4ee5\u901a\u8fc7\u8bbe\u8ba1MOFs\u3001MOF\u590d\u5408\u6750\u6599\u548cMOF\u884d\u751f\u7269\u6765\u89e3\u51b3\u3002\u5176\u4e2d\uff0cM-BTC MOFs\u3001M-BDC MOFs\u548cZIFs\u662f\u7814\u7a76\u6700\u591a\u7684MOFs\u6750\u6599\uff0c\u5b83\u4eec\u7ed3\u6784\u76f8\u5bf9\u7a33\u5b9a\uff0c\u5408\u6210\u8def\u7ebf\u7b80\u5355\u3002\u7531\u4e8e\u8be5\u9886\u57df\u7684\u5feb\u901f\u53d1\u5c55\u548c\u7814\u7a76\u5174\u8da3\u7684\u4e0d\u65ad\u589e\u957f\uff0c\u4e0d\u53ef\u80fd\u5c06\u6240\u6709\u76f8\u5173\u5de5\u4f5c\u90fd\u5305\u542b\u5728\u672c\u7efc\u8ff0\u4e2d\u3002\u5728\u8fd9\u4e00\u90e8\u5206\uff0c\u672c\u6587\u4e3b\u8981\u8ba8\u8bba\u548c\u603b\u7ed3\u4e86MOFs\u548cMOF\u884d\u751f\u7269\u4f5c\u4e3aSC\u7535\u6781\u7684\u4e00\u4e9b\u53d1\u5c55\u91cc\u7a0b\u7891\u548c\u6700\u65b0\u7814\u7a76\u3002<strong><b>\u672c\u6587<\/b><\/strong><strong><b>\u7b80\u8981\u8ba8\u8bba\u4e86\u4e24\u4e2a\u65b9\u9762\uff1aMOFs\u53ca\u5176\u590d\u5408\u6750\u6599\u76f4\u63a5\u7528\u4f5cSC\u7535\u6781\u6750\u6599\u548cMOF\u884d\u751f\u7684\u65e0\u673a\u529f\u80fd\u6750\u6599\u7528\u4f5cSC\u7535\u6781\uff0c\u5305\u62ec\u78b3\u6750\u6599\u3001\u91d1\u5c5e\u6c27\u5316\u7269\/\u6c22\u6c27\u5316\u7269\u548c\u91d1\u5c5e\u786b\u5316\u7269<\/b><\/strong>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248208\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-1.png\" alt=\"\" width=\"1260\" height=\"658\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-1.png 1260w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-1-300x157.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-1-768x401.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72476-1-1024x535.png 1024w\" sizes=\"(max-width: 1260px) 100vw, 1260px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u56fe6. (a) M<sub>2<\/sub>[CuPc(NH)<sub>8<\/sub>]\u7684\u7ed3\u6784\u793a\u610f\u56fe\u3002(b) M<sub>2<\/sub>[CuPc(NH)<sub>8<\/sub>]\u7684XRD\u56fe\u8c31\u3002(c)\u6839\u636eGCD\u56fe\u8c31\u8ba1\u7b97M<sub>2<\/sub>[CuPc(NH)<sub>8<\/sub>]\u7535\u6781\u7684\u6bd4\u7535\u5bb9\u3002(d) M<sub>2<\/sub>[CuPc(NH)<sub>8<\/sub>]\u7535\u6781\u572810 A g<sup>-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u548cCE\u3002\u63d2\u56fe\u662fNi<sub>2<\/sub>[CuPc(NH)<sub>8<\/sub>]\u7535\u6781\u7684\u524d\u4e94\u6761\u548c\u540e\u4e94\u6761GCD\u66f2\u7ebf\u00a9 2023 Elsevier<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248210\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72477.png\" alt=\"\" width=\"576\" height=\"660\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72477.png 576w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72477-262x300.png 262w\" sizes=\"(max-width: 576px) 100vw, 576px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u56fe7. (a)\u56db\u901a\u9053\u6db2\u6ef4\u5fae\u6d41\u63a7\u5408\u6210E-BP\/ZIF-67\u3002(b)\u660e\u786e\u7684\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784E-BP\/ZIF-67\u7684\u5408\u6210\u673a\u7406\u3002\u5948\u594e\u65af\u7279\u56fe\u548c\u7b49\u6548\u7535\u8def\u6a21\u578b\u3002(d) 100 m V s<sup>-1<\/sup>\u4e0b\u7684CV\u66f2\u7ebf\u3002(e) 0.5 A g<sup>-1<\/sup>\u4e0b\u7684GCD\u66f2\u7ebf\u3002(f)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u7535\u5bb9\u00a9 2023 Elsevier<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-248211\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72478.png\" alt=\"\" width=\"674\" height=\"658\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72478.png 674w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/03\/\u56fe\u72478-300x293.png 300w\" sizes=\"(max-width: 674px) 100vw, 674px\" \/><\/p>\n<p>\u56fe8. (a)\u78b3\u5e03\u652f\u6491\u7684\u4e09\u7ef4\u81ea\u679d\u72b6ZnCo<sub>2<\/sub>O<sub>4<\/sub>@NC\u7eb3\u7c73\u5899\u9635\u5217\u7684\u5236\u5907\u793a\u610f\u56fe\u3002(b)\u57282.0 M KOH\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u6d4b\u8bd5\u7684CTs\u3001Co<sub>3<\/sub>O<sub>4<\/sub>@NC\/CTs\u3001ZnCo<sub>2<\/sub>O<sub>4<\/sub>\/CTs\u548cZnCo<sub>2<\/sub>O<sub>4<\/sub>@NC\/CTs\u7535\u6781\u7684CV\u3001(c)\u5145\u653e\u7535\u66f2\u7ebf\u548c(d) EIS\u5206\u6790\u3002(b)\u7684\u63d2\u56fe\u662f\u6765\u81ea\u539f\u59cbCT\u7684CV\u66f2\u7ebf\u3002(e)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u9762\u79ef\u5bb9\u91cf\u503c\u3002(f)\u957f\u671f\u5faa\u73af\u6027\u80fd\u53ca\u7b2c1\u300110K\u5faa\u73af\u7684\u5145\u653e\u7535\u66f2\u7ebf\u63d2\u56fe\u00a9 2023 Elsevier<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><\/b><strong><b>\u7ed3\u8bba\u4e0e\u5c55\u671b<\/b><\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7efc\u8ff0\u4e86MOFs\u53ca\u5176\u884d\u751f\u7269\u5728\u53ef\u5145\u7535\u79bb\u5b50\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7b49\u6c34\u7cfb\u50a8\u80fd\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u3002\u7531\u4e8eMOF\u57fa\u7535\u6781\u6750\u6599\u7684\u7a33\u5b9a\u6027\u662f\u6c34\u76f8\u50a8\u80fd\u5668\u4ef6\u5e94\u7528\u7684\u5148\u51b3\u6761\u4ef6\uff0c\u56e0\u6b64\u672c\u6587\u9996\u5148\u5bf9MOFs\u7684\u5316\u5b66\u7a33\u5b9a\u6027(\u6c34\u3001\u9178\u3001\u78b1\u7a33\u5b9a\u6027)\u548c\u70ed\u7a33\u5b9a\u6027\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u5206\u6790\u3002\u6839\u636eHSAB\u539f\u7406\uff0c\u603b\u7ed3\u51fa\u7a33\u5b9a\u7684MOFs\uff0c\u5305\u62ec\u9ad8\u4ef7\u91d1\u5c5e\u57faMOFs\u548c\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\u3002\u5728MOFs\u9aa8\u67b6\u4e0a\u9644\u7740\u758f\u6c34\u57fa\u56e2\u6216\u5305\u8986\u758f\u6c34\u6750\u6599\u53ef\u4ee5\u63d0\u9ad8MOFs\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u3002MOF\u884d\u751f\u7269\u7531\u4e8e\u5176\u591a\u5b54\u7ed3\u6784\u7684\u53ef\u63a7\u6027\uff0c\u901a\u8fc7\u8c03\u8282\u5176\u5fae\u89c2\u7ed3\u6784\u548c\u5f62\u8c8c\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002\u6b64\u5916\uff0cMOFs\u884d\u751f\u7684\u67d4\u6027\u7535\u6781\u5728\u67d4\u6027\u57fa\u5e95\u4e0a\u5177\u6709\u8f83\u9ad8\u7684\u673a\u68b0\u7a33\u5b9a\u6027\uff0c\u53ef\u7528\u4e8e\u67d4\u6027\u5668\u4ef6\u7684\u5236\u5907\u3002<\/p>\n<p>\u5c3d\u7ba1\u53d6\u5f97\u4e86\u91cd\u8981\u8fdb\u5c55\uff0c\u57fa\u4e8eMOF\u7684\u6c34\u5b58\u50a8\u88c5\u7f6e\u7684\u7814\u7a76\u4ecd\u5904\u4e8e\u5b9e\u9a8c\u5ba4\u7814\u7a76\u7684\u65e9\u671f\u9636\u6bb5\u3002\u4ece\u5b9e\u9645\u5e94\u7528\u7684\u6700\u7ec8\u76ee\u6807\u6765\u770b\uff0c<strong><b>\u4e0d\u53ef\u907f\u514d\u7684\u95ee\u9898\u662f\u5728\u4fdd\u8bc1\u6c34\u76f8\u80fd\u6e90\u5668\u4ef6\u6027\u80fd\u5e73\u8861\u7684\u540c\u65f6\u5408\u7406\u5229\u7528MOFs<\/b><\/strong>\u3002\u6700\u540e\uff0c\u5bf9MOF\u57fa\u6750\u6599\u5728\u6c34\u4f53\u7cfb\u4e2d\u7684\u8fdb\u4e00\u6b65\u7814\u7a76\u8fdb\u884c\u4e86\u5c55\u671b\uff1a<\/p>\n<ul>\n<li><b><\/b><strong><b>MOFs\u7684\u5316\u5b66\/\u70ed\u7a33\u5b9a\u6027\u7814\u7a76\u4e00\u76f4\u662f\u70ed\u95e8\u7684\u7814\u7a76\u8bfe\u9898\uff0c\u4f46\u5173\u4e8eMOFs\u7684\u7a33\u5b9a\u6027\u548c\u6027\u80fd\u4e24\u65b9\u9762\u7684\u8be6\u7ec6\u5de5\u4f5c\u8f83\u5c11<\/b><\/strong>\u3002\u5c3d\u7ba1MOF\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u7684\u7a33\u5b9a\u6027\u548c\u76f8\u53d8\u8fc7\u7a0b\u7684\u4e00\u4e9b\u8868\u5f81\u6280\u672f\u5df2\u7ecf\u5f97\u5230\u5e94\u7528\uff0c\u4f46\u5e76\u4e0d\u662f\u6240\u6709\u57fa\u4e8eMOF\u7684\u6c34\u7cfb\u50a8\u5b58\u7cfb\u7edf\u7684\u5de5\u4f5c\u90fd\u89e3\u91ca\u4e86MOFs\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u7684\u7a33\u5b9a\u6027\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u7684\u9a71\u52a8\u4e0b\uff0cMOFs\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u7684\u7a33\u5b9a\u6027\u53ef\u80fd\u9762\u4e34\u66f4\u5927\u7684\u6311\u6218\u3002\u56e0\u6b64\uff0cMOFs\u5728\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u7a33\u5b9a\u6027\u548c\u5206\u5b50\u6c34\u5e73\u4e0a\u7684\u53d8\u5316\u503c\u5f97\u6df1\u5165\u7814\u7a76\u3002<\/li>\n<li><b><\/b><strong><b>\u9664\u4e86\u6c34\u7cfbZIBs\uff0c\u5927\u591a\u6570\u6c34\u7cfb\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u5176\u76f8\u5bf9\u7a33\u5b9a\u7684\u7ed3\u6784\uff0c\u5df2\u7ecf\u91c7\u7528PBAs\u4f5c\u4e3a\u7535\u6781\u6750\u6599<\/b><\/strong>\u3002\u5373\u4f7f\u5728\u6c34\u7cfbZIBs\u4e2d\uff0cMOF\u76f8\u5173\u7535\u6781\u7684\u5e94\u7528\u4e5f\u4e3b\u8981\u96c6\u4e2d\u5728V\u548cMn\u57faMOFs\u4e0a\u3002<strong><b>\u56e0\u6b64\uff0c\u9700\u8981\u63a2\u7d22\u66f4\u591a\u7684\u53cd\u5f0fMOFs\u548cMOF\u884d\u751f\u7269\uff0c\u4ee5\u5b9e\u73b0\u66f4\u597d\u7684\u7535\u6c60\u6027\u80fd\uff0c\u6ee1\u8db3\u4e0d\u540c\u6c34\u7cfb\u7535\u6c60\u4f53\u7cfb\u7684\u529f\u80fd\u9700\u6c42<\/b><\/strong>\u3002\u5bf9\u4e8eMOF\u57fa\u6c34\u7cfb\u7535\u6c60\u7535\u6781\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u7684\u7a33\u5b9a\u6027\uff0cMOFs\u7684\u7ed3\u6676\u6027\u548c\u8868\u9762\u6548\u5e94\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u4e3a\u4e86\u589e\u5f3a\u5176\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u9664\u4e86\u63d0\u9ad8\u7ed3\u6676\u5ea6\u5916\uff0c\u8bbe\u8ba1\u5728MOFs\u4e0a\u5305\u8986\u4fdd\u62a4\u5c42\u7684\u6838\u58f3\u7ed3\u6784\u53ef\u80fd\u4f1a\u589e\u52a0\u5176\u7a33\u5b9a\u6027\uff0c\u5e76\u4e14\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u5c0f\u4f53\u79ef\u53d8\u5316\u4f7f\u5305\u8986\u6210\u4e3a\u53ef\u80fd\u3002\u9664\u4e86\u6d3b\u6027\u6750\u6599\u7684\u4f18\u5316\uff0c\u5bf9\u6c34\u7cfb\u7535\u89e3\u6db2\u5982\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\u548c\u529f\u80fd\u6dfb\u52a0\u5242\u7684\u63a2\u7d22\u4e5f\u5c06\u5f52\u529f\u4e8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Kong\u3001Mingren Cheng<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u535c\u663e\u548c<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u5357\u5f00\u5927\u5b66<\/p>\n<p>\u8bba\u6587doi\uff1a<\/p>\n<p>https:\/\/doi.org\/10.1016\/j.enchem.2022.100090<\/p>\n<p>\u672c\u6587\u7531\u6e29\u534e\u4f9b\u7a3f\u3002<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5357\u5f00\u5927\u5b66\u535c\u663e\u548c\u6559\u6388\u6700\u65b0EnergyChem\u7efc\u8ff0\uff1a\u7528\u4e8e\u5148\u8fdb\u6c34\u7cfb\u79bb\u5b50\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6 [\u5bfc\u8bfb] &nbsp; 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