{"id":248170,"date":"2023-03-17T06:03:15","date_gmt":"2023-03-16T22:03:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=248170"},"modified":"2023-03-15T17:04:01","modified_gmt":"2023-03-15T09:04:01","slug":"adv-mater-%ef%bc%9ani%e5%9f%ba%e5%8d%95%e5%8e%9f%e5%ad%90%e5%82%ac%e5%8c%96%e5%89%82%e7%94%a8%e4%ba%8e%e9%ab%98%e6%95%88%e7%94%9f%e7%89%a9%e8%b4%a8%e8%a1%8d%e7%94%9f%e7%89%a9%e8%bd%ac%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=248170","title":{"rendered":"Adv. Mater.\uff1aNi\u57fa\u5355\u539f\u5b50\u50ac\u5316\u5242\u7528\u4e8e\u9ad8\u6548\u751f\u7269\u8d28\u884d\u751f\u7269\u8f6c\u5316"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u751f\u7269\u8d28\u8d44\u6e90\u662f\u5229\u7528\u592a\u9633\u80fd\u901a\u8fc7CO2<\/sub>\u548c\u6c34\u7684\u5149\u5408\u4f5c\u7528\u4ea7\u751f\u7684\uff0c\u5728\u81ea\u7136\u73af\u5883\u4e2d\u5e7f\u6cdb\u53ef\u7528\u3002\u5728\u53ef\u6301\u7eed\u548c\u65e0\u5bb3\u73af\u5883\u5730\u5229\u7528\u81ea\u7136\u8d44\u6e90\u7684\u63a8\u52a8\u4e0b\uff0c\u5c06\u751f\u7269\u8d28\u548c\u751f\u7269\u8d28\u884d\u751f\u7269\u8f6c\u5316\u4e3a\u589e\u503c\u4ea7\u54c1\u7684\u610f\u4e49\u65e5\u76ca\u91cd\u5927\u3002\u6700\u91cd\u8981\u7684\u7b56\u7565\u4e4b\u4e00\u662f\u751f\u7269\u8d28\u884d\u751f\u591a\u5143\u9187\u7684C-C\u952e\u65ad\u88c2\uff0c\u4ee5\u5408\u6210\u6709\u4ef7\u503c\u7684\u7fb0\u57fa\u5316\u5408\u7269\uff0c\u5982\u919b\u3001\u4e59\u9178\u548c\u916e\u884d\u751f\u7269\u3002\u7531\u4e8e\u76f8\u5bf9\u8f83\u9ad8\u7684C-C\u952e\u80fd\uff0890 kcal mol-1<\/sup>\uff09\uff0cC-C\u952e\u65ad\u88c2\u5728\u70ed\u529b\u5b66\u4e0a\u662f\u96be\u4ee5\u8fdb\u884c\uff0c\u56e0\u6b64\u4f20\u7edf\u7684C-C\u94fe\u65ad\u88c2\u8fc7\u7a0b\u4e25\u91cd\u4f9d\u8d56\u4e8e\u6709\u6bd2\/\u6602\u8d35\u7684\u6c27\u5316\u5242\u6216\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u5e76\u4e14\u901a\u5e38\u4f34\u968f\u7740\u82db\u523b\u7684\u53cd\u5e94\u6761\u4ef6\u3002\u56e0\u6b64\uff0c\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u9009\u62e9\u6027C-C\u952e\u88c2\u89e3\u4f5c\u4e3a\u63d0\u5347\u751f\u7269\u8d28\u884d\u751f\u591a\u5143\u9187\u7684\u91cd\u8981\u5de5\u5177\u5907\u53d7\u77a9\u76ee\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u57fa\u4e8e\u6b64\uff0c\u82f1\u56fd\u4f26\u6566\u5927\u5b66\u5b66\u9662\u5510\u519b\u65fa\u6559\u6388\u4e0e\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u7269\u6240\u738b\u7231\u7434\u7814\u7a76\u5458\u8054\u5408<\/strong>\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u7531\u9650\u5236\u5728\u4e8c\u6c27\u5316\u949b\u8868\u9762\u7684\u954d\u5355\u539f\u5b50\u7ec4\u6210\u9ad8\u9009\u62e9\u6027\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u5c06\u7518\u6cb9\u8f6c\u5316\u4e3a\u9ad8\u4ef7\u503c\u4ea7\u54c1\u7f9f\u4e59\u919b\u3002\u5728\u5149\u7684\u9a71\u52a8\u4e0b\uff0c\u50ac\u5316\u5242\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u5229\u7528\u7a7a\u6c14\u4f5c\u4e3a\u7eff\u8272\u6c27\u5316\u5242\u8fdb\u884c\u53cd\u5e94\u3002\u4f18\u5316\u540e\u7684\u50ac\u5316\u5242\u5bf9\u7f9f\u4e59\u919b\u7684\u9009\u62e9\u6027\u8d85\u8fc760%\uff0c\u4ea7\u73871058 \u03bcmol\u00b7gCat<\/sub>-1<\/sup>\u00b7h-1<\/sup>\uff0c\u8f6c\u6362\u6570\u6bd4NiOx<\/sub>\u7eb3\u7c73\u7c92\u5b50\u4fee\u9970\u7684TiO2<\/sub>\u5149\u50ac\u5316\u5242\u9ad8\u8fd13\u500d\u3002\u4e0d\u540c\u7684\u7406\u5316\u6027\u8d28\u8868\u5f81\u63ed\u793a\u4e86\u5355\u539f\u5b50\u954d\u7684\u72ec\u7279\u529f\u80fd\uff0c\u5b83\u53ef\u4ee5\u663e\u8457\u4fc3\u8fdb\u6c27\u5438\u9644\u3001\u5145\u5f53\u7535\u5b50\u9631\u5e76\u52a0\u901f\u8d85\u6c27\u5316\u7269\u81ea\u7531\u57fa\u7684\u4ea7\u751f\uff0c\u4ece\u800c\u63d0\u9ad8\u5bf9\u7f9f\u4e59\u919b\u7684\u9009\u62e9\u6027\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cHighly selective transformation of biomass derivatives to valuable chemicals by single-atom photocatalyst Ni\/TiO2<\/sub><\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aAdv. Mater.<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010<\/strong>\u6838\u5fc3\u521b\u65b0\u70b9<\/strong>\u3011<\/strong><\/p>\n

\u672c\u6587\u5236\u5907\u7a33\u5b9a\u6027\u826f\u597d\u7684\u50ac\u5316\u5242\u7528\u4e8e\u751f\u7269\u5e9f\u7269\u7518\u6cb9\u7684\u6c27\u5316\uff0c\u5176\u50ac\u5316\u751f\u4ea7\u7f9f\u4e59\u919b\u7684\u901f\u7387\u6bd4NiOx<\/sub>\/TiO2<\/sub>\u589e\u52a02\u500d\uff0c\u540c\u65f6\u9009\u62e9\u6027\u4e5f\u63d0\u9ad82\u500d\uff0c\u6700\u540e\u8fd8\u901a\u8fc7\u5b9e\u9a8c\u63ed\u793a\u5176\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u673a\u7406\u3002<\/p>\n

\u56db\u3001\u3010<\/strong>\u8bba\u6587\u63a0\u5f71<\/strong>\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1<\/strong>\u3001\u50ac\u5316\u5242\u9009\u62e9\u6027\u53ca\u7a33\u5b9a\u6027<\/strong> \u00a9 2023 WILEY<\/strong><\/p>\n

\uff08a\uff09\u7f9f\u4e59\u919b\u5728TiO2<\/sub>\u30010.5Ni\/TiO2<\/sub>-IM\u548c0.5Ni\/TO2<\/sub>-MS\u4e09\u79cd\u4e0d\u540c\u50ac\u5316\u5242\u4e0a\u7684\u6790\u51fa\u901f\u7387\u548c\u9009\u62e9\u6027\u3002<\/p>\n

\uff08b\uff09\u4e0d\u540c\u50ac\u5316\u5242\u4e0a\u7684\u4ea7\u7269\u53ca\u4ea7\u91cf\u3002<\/p>\n

\uff08c\uff09\u4e0d\u540c\u4ea7\u7269\u57280.5Ni\/TiO2<\/sub>-MS\u4e0a\u7684\u4ea7\u91cf\u968f\u65f6\u95f4\u53d8\u5316\u3002<\/p>\n

\uff08d\uff09\u4e00\u7cfb\u5217\u5bf9\u7167\u5b9e\u9a8c\u7684\u4ea7\u54c1\u4ee5\u53ca\u76f8\u5e94\u4ea7\u91cf\u3002<\/p>\n

\uff08e\uff090.5Ni\/TiO2<\/sub>-MS\u50ac\u5316\u52428\u4e2a\u5faa\u73af\u53cd\u5e94\u7684\u7a33\u5b9a\u6027\u8bd5\u9a8c\u3002<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2<\/strong>\u3001\u50ac\u5316\u5242\u7ec4\u6210<\/strong> \u00a9 2023 WILEY<\/strong><\/p>\n

\uff08a-b\uff09TiO2<\/sub>\u30010.5Ni\/TiO2<\/sub>-IM\u548c0.5Ni\/TiO2<\/sub>-MS\u4e09\u79cd\u50ac\u5316\u5242\u7684XRD\u548cUV-vis\u5149\u8c31\u3002<\/p>\n

\uff08c\uff090.5Ni\/TiO2<\/sub>-MS\u7684TEM\u56fe\u50cf\u53ca\u76f8\u5e94\u7684EDS\u5143\u7d20mapping\u56fe\u50cf\u3002<\/p>\n

\uff08d\uff090.5Ni\/TiO2<\/sub>-MS\u7684HAADF-AC-STEM\u53ca\u76f8\u5e94\u7684EDS\u7ed3\u679c\u3002<\/p>\n

\u00a0<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3<\/strong>\u3001\u4e0d\u540c\u50ac\u5316\u5242\u7ed3\u6784\u5206\u6790<\/strong> \u00a9 2023 WILEY<\/strong><\/p>\n

\uff08a\uff090.5Ni\/TiO2<\/sub>-IM\u548c0.5Ni\/TiO2<\/sub>-MS\u7684Ni 2p3\/2<\/sub>\u7684XPS\u5149\u8c31\u3002<\/p>\n

\uff08b\uff09\u91d1\u5c5e\u954d\u3001NiO 0.5Ni\/TiO2<\/sub>-IM\u548c0.5Ni\/TiO2<\/sub>-MS\u7684Ni K-edge XANES\u5149\u8c31\u3002<\/p>\n

\uff08c\uff090.5Ni\/TiO2<\/sub>-MS\u7684Ni K-edge XANES\u5149\u8c31\u7684\u62df\u5408\u56fe\u6848\u3002<\/p>\n

\uff08d\uff09TiO2<\/sub>\u30010.5Ni\/TiO2<\/sub>-IM\u548c0.5Ni\/TiO2<\/sub>-MS\u7684O1s XPS\u5149\u8c31\u3002<\/p>\n

\u00a0<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4<\/strong>\u3001\u50ac\u5316\u5242\u9009\u62e9\u6027\u50ac\u5316\u539f\u7406<\/strong> \u00a9 2023 WILEY<\/strong><\/p>\n

\uff08a\uff09TiO2<\/sub>\u30010.5Ni\/TiO2<\/sub>-IM\u548c0.5Ni\/TiO2<\/sub>-MS\u7684O2<\/sub>-TPD\u66f2\u7ebf\u3002<\/p>\n

\uff08b\uff09\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b\uff0c0.5Ni\/TiO2<\/sub>-IM\u548c0.5Ni\/TiO2<\/sub>-MS\u7684Ni K-edge operando XANES\u5149\u8c31\u7ed3\u679c\u7684\u6570\u636e\u3002<\/p>\n

\uff08c-e\uff09\u7a7a\u6c14\u4e2d\u68c0\u6d4b0.5Ni\/TiO2<\/sub>-IM\u548c0.5Ni\/TiO2<\/sub>-MS\u4e2d1<\/sup>O2<\/sub>\u3001O2<\/sub>\u2022-<\/sup>\u4ee5\u53ca\u2022OH\u7684ESR\u5149\u8c31\u3002<\/p>\n

\uff08f\uff09\u4e0d\u540c\u6e05\u9664\u5242\u57280.5Ni\/TiO2<\/sub>-MS\u4e0a\u7518\u6cb9\u6c27\u5316\u4e3a\u7f9f\u4e59\u919b\u4ea7\u7387\u3002<\/p>\n

\uff08g\uff09\u4e0d\u540c\u6e05\u9664\u5242\u5bf90.5Ni\/TiO2<\/sub>-IM\u7518\u6cb9\u8f6c\u5316\u7387\u7684\u5f71\u54cd\u3002<\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u4e00\u79cd\u6709\u6548\u7684\u7b56\u7565\uff0c\u5728\u5149\u7167\u9a71\u52a8\u7684\u73af\u5883\u6761\u4ef6\u4e0b\uff0c\u5bf9\u751f\u7269\u5e9f\u7269\u7518\u6cb9\u8fdb\u884c\u9ad8\u9009\u62e9\u6027\u7684C-C\u88c2\u89e3\uff0c\u4ea7\u751f\u6709\u4ef7\u503c\u7684\u4ea7\u54c1\u7f9f\u4e59\u919b\u3002\u4e0e\u5728NiOx<\/sub>\/TiO2<\/sub>\u4e0a\u89c2\u5bdf\u5230\u7684\u5f88\u5c11\u7684\u50ac\u5316\u4f5c\u7528\u4e0d\u540c\uff0c\u4f18\u5316\u7684\u5355\u539f\u5b50\u5149\u50ac\u5316\u52420.5Ni\/TiO2<\/sub>-MS\u5bfc\u81f4\u7f9f\u4e59\u919b\u751f\u6210\u901f\u7387\u589e\u52a02\u500d\uff081058 \u03bcmol g-1<\/sup> h-1<\/sup>\uff09\uff0c\u66f4\u91cd\u8981\u7684\u662f\u9009\u62e9\u6027\u63d0\u9ad8\u4e862\u500d\uff08\u7ea660.1%\uff09\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u88c5\u8f7d\u954d\u7269\u79cd\u7684\u50ac\u5316\u5242\u5177\u6709\u826f\u597d\u7684\u7a33\u5b9a\u6027\u3002\u8fdb\u4e00\u6b65\u901a\u8fc7operando XANES\u53ef\u4ee5\u6e05\u695a\u5730\u89c2\u5bdf\u5230\u5728\u5149\u7167\u4e0b\u7535\u5b50\u4eceTiO2<\/sub>\u6d41\u5411Ni\u5355\u539f\u5b50\u3002\u57fa\u4e8e\u7ed3\u6784\u5206\u6790\u548c\u5149\u8c31\u6d4b\u91cf\uff0c\u8be5\u50ac\u5316\u5242\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u5bf9\u7518\u6cb9\u7684\u9009\u62e9\u6027C-C\u88c2\u89e3\u7684\u5353\u8d8a\u6d3b\u6027\u53ef\u4ee5\u5f52\u56e0\u4e8e\u6c27\u7684\u5f31\u5316\u5b66\u5438\u9644\u548cNi\u5355\u539f\u5b50\u4e0a\u7684\u6709\u6548\u7535\u5b50\u8f6c\u79fb\uff0c\u4ece\u800c\u6709\u6548\u5730\u4ea7\u751f\u8d85\u6c27\u81ea\u7531\u57fa\uff0c\u5c06\u9009\u62e9\u6027\u8f6c\u79fb\u5230\u7f9f\u4e59\u919b\u3002\u672c\u7814\u7a76\u63d0\u4f9b\u4e86\u5bf9\u5f02\u8d28\u5355\u539f\u5b50\u5149\u50ac\u5316\u7684\u89c1\u89e3\uff0c\u5e76\u53ef\u4f5c\u4e3a\u8bbe\u8ba1\u539f\u5219\u666e\u904d\u5e94\u7528\u4e8e\u5149\u50ac\u5316\u6709\u673a\u5408\u6210\uff0c\u4ee5\u63d0\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aHighly selective transformation of biomass derivatives to valuable chemicals by single-atom photocatalyst Ni\/TiO2<\/sub><\/a> (Adv. Mater.<\/em> 2023<\/strong>, DOI: 10.1002\/adma.202209646)<\/p>\n

\u672c\u6587\u7531\u8d5b\u6069\u65af\u4f9b\u7a3f\u3002<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u751f\u7269\u8d28\u8d44\u6e90\u662f\u5229\u7528\u592a\u9633\u80fd\u901a\u8fc7CO2\u548c\u6c34\u7684\u5149\u5408\u4f5c\u7528\u4ea7\u751f\u7684\uff0c\u5728\u81ea\u7136\u73af\u5883\u4e2d\u5e7f\u6cdb\u53ef\u7528\u3002\u5728\u53ef\u6301\u7eed\u548c\u65e0\u5bb3\u73af\u5883\u5730\u5229\u7528\u81ea\u7136\u8d44\u6e90\u7684\u63a8\u52a8\u4e0b\uff0c\u5c06\u751f\u7269\u8d28\u548c\u751f\u7269\u8d28\u884d\u751f\u7269\u8f6c\u5316\u4e3a…<\/p>\n","protected":false},"author":36791,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-248170","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/248170"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/36791"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=248170"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/248170\/revisions"}],"predecessor-version":[{"id":248182,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/248170\/revisions\/248182"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=248170"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=248170"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=248170"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}