{"id":247975,"date":"2023-03-19T06:15:12","date_gmt":"2023-03-18T22:15:12","guid":{"rendered":"\/\/m.iemloyee.com\/?p=247975"},"modified":"2023-03-16T14:35:50","modified_gmt":"2023-03-16T06:35:50","slug":"advanced-science%e8%bd%b4%e5%90%91po4%e9%85%8d%e4%bd%8d%e5%8d%95%e5%8e%9f%e5%ad%90co%e4%bf%83%e8%bf%9b%e7%94%b5%e5%8c%96%e5%ad%a6%e6%9e%90%e6%b0%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=247975","title":{"rendered":"Advanced Science:\u8f74\u5411PO4\u914d\u4f4d\u5355\u539f\u5b50Co\u4fc3\u8fdb\u7535\u5316\u5b66\u6790\u6c27"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u7535\u50ac\u5316\u6c27\u6790\u51fa\u53cd\u5e94\uff08OER\uff09\u662f\u6c34\u5206\u89e3\u3001CO2<\/sub>\u8fd8\u539f\u3001\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u7b49\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u7684\u91cd\u8981\u534a\u53cd\u5e94\u3002\u4e3a\u4e86\u89e3\u51b3\u5176\u8f83\u9ad8\u7684\u53cd\u5e94\u8fc7\u7535\u4f4d\u53ca\u8f83\u6162\u7684\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u9700\u8981\u5927\u529b\u5f00\u53d1\u5177\u6709\u9ad8\u6d3b\u6027\u7684\u7535\u50ac\u5316\u5242\u3002\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u5bf9OER\u53cd\u5e94\u5177\u6709\u8f83\u9ad8\u7684\u6d3b\u6027\uff0c\u5177\u6709\u5e73\u9762M1<\/sub>N4<\/sub>\u914d\u4f4d\u6784\u578b\u76843d-\u8fc7\u6e21\u91d1\u5c5e\u5355\u539f\u5b50\u50ac\u5316\u5242\uff0c\u56e0\u5176\u5177\u6709\u9ad8\u539f\u5b50\u5229\u7528\u7387\u53ca\u53ef\u63a7\u7684\u914d\u4f4d\u7ed3\u6784\uff0c\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u5176\u4e2d\uff0cCo1<\/sub>N4<\/sub>\u6d3b\u6027\u4f4d\u70b9\u5bf9OER\u53cd\u5e94\u7684\u4e2d\u95f4\u4f53\u5177\u6709\u8f83\u4e3a\u9002\u4e2d\u7684\u5438\u9644\u5f3a\u5ea6\uff0c\u6781\u5177\u7814\u7a76\u6f5c\u529b\u3002\u4f46\u5728OER\u53cd\u5e94\u8fc7\u7a0b\u4e2d\uff0cCo1<\/sub>N4<\/sub>\u6d3b\u6027\u4f4d\u70b9\u9700\u8981\u5bf9OH*<\/sup>\u4e2d\u95f4\u4f53\u8fdb\u884c\u8131\u6c22\u5f62\u6210O*<\/sup>\uff0c\u7531\u4e8eCo-O-H\u7ed3\u6784\u9178\u6027\u8f83\u5f31\uff0c\u5bfc\u81f4O-H\u7684\u65ad\u88c2\u7684\u53cd\u5e94\u80fd\u5792\u8f83\u9ad8\uff0c\u56e0\u6b64\u9650\u5236\u4e86Co1<\/sub>N4<\/sub>\u6d3b\u6027\u4f4d\u70b9\u7684OER\u6d3b\u6027\u3002\u901a\u8fc7\u5bf9Co1<\/sub>N4<\/sub>\u4f4d\u70b9\u6784\u5efa\u8f74\u5411\u914d\u4f4d\uff0c\u4f5c\u4e3a\u8f74\u5411\u914d\u4f53\u7684\u9178\u6027\u81ea\u7531\u57fa\u80fd\u591f\u4f5c\u4e3a\u6d3b\u6027\u4e2d\u5fc3\u5438\u9644\u542b\u6c22\u4e2d\u95f4\u4f53\u5e76\u901a\u8fc7\u7535\u79bb\u6548\u5e94\u91ca\u653e\u8d28\u5b50\uff0c\u4ece\u800c\u964d\u4f4eO*<\/sup>\u7684\u751f\u6210\u80fd\u5792\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u5b89\u5fbd\u5e08\u8303\u5927\u5b66\u6bdb\u4fca\u6770\u6559\u6388\u56e2\u961f\u63d0\u51fa\u5728CoPc@CNT\u4e2d\u7684Co1<\/sub>N4<\/sub>\u4f4d\u70b9\u4e0a\u5f15\u5165\u8f74\u5411\u7684PO4<\/sub>\u914d\u4f4d\uff0c\u901a\u8fc7\u8c03\u63a7\u53cd\u5e94\u8def\u5f84\uff0c\u63d0\u9ad8\u5176\u672c\u5f81OER\u6d3b\u6027\u3002\u8f74\u5411\u7684PO4<\/sub>\u914d\u4f4d\u76f4\u63a5\u53c2\u4e0eOER\u53cd\u5e94\u5faa\u73af\uff0c\u4ee5HPO4<\/sub>-Co1<\/sub>N4<\/sub>\u4e2d\u95f4\u4f53\u7684\u8131\u6c22\u8fc7\u7a0b\u53d6\u4ee3Co-O-H\u7684\u8131\u6c22\u8fc7\u7a0b\uff0c\u5927\u5e45\u964d\u4f4e\u4e86\u53cd\u5e94\u80fd\u5792\u3002\u5f53\u50ac\u5316\u5242\u4e2d\u4ec5\u542b2.7 wt.%\u7684Co\u65f6\uff0c\u542b\u6709\u8f74\u5411PO4<\/sub>\u914d\u4f4d\u7684P-CoPc@CNT\u50ac\u5316\u5242\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u5177\u6709300 mV\u7684\u53cd\u5e94\u8fc7\u7535\u4f4d\u53ca41.7 mV dec-1<\/sup>\u7684\u5854\u83f2\u5c14\u659c\u7387\uff0c\u76f8\u6bd4\u4e8e\u6ca1\u6709\u8f74\u5411PO4<\/sub>\u914d\u4f4d\u7684CoPc@CNT\u50ac\u5316\u5242\uff0cOER\u53cd\u5e94\u6d3b\u6027\u5f97\u5230\u4e86\u5927\u5e45\u63d0\u9ad8\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cAxial Phosphate Coordination in Co Single Atoms Boosts Electrochemical Oxygen Evolution<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aAdvanced Science<\/em>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

\u672c\u7814\u7a76\u901a\u8fc7\u5bf9Co1<\/sub>N4<\/sub>\u8fdb\u884c\u8f74\u5411\u914d\u4f4d\u8c03\u63a7\uff0c\u5f15\u5165\u4e86\u5177\u6709\u6d3b\u6027\u7684\u8f74\u5411PO4<\/sub>\u914d\u4f4d\u4f5c\u4e3a\u53cd\u5e94\u4f4d\u70b9\u53c2\u4e0e\u53cd\u5e94\uff0c\u76f4\u63a5\u901a\u8fc7\u6539\u53d8\u53cd\u5e94\u8def\u5f84\u964d\u4f4e\u4e86\u80fd\u5792\uff0c\u63d0\u9ad8\u50ac\u5316\u5242\u7684OER\u6d3b\u6027\u3002<\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1 (a) 6.6%P-CoPc@CNT<\/strong>\u7684\u5408\u6210\u793a\u610f\u56fe\uff1b<\/strong>(b) 6.6%P-CoPc@CNT<\/strong>\u7684<\/strong>TEM<\/strong>\u56fe\u50cf\uff1b<\/strong>(c,d) <\/strong>6.6%P-CoPc@CNT<\/strong>\u7684\u7403\u5dee\u6821\u6b63<\/strong>HAADF-STEM<\/strong>\u56fe\u50cf\u53ca<\/strong>EDS<\/strong>\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/strong>CoPc, CoPc@CNT, <\/strong>5.6%P-CoPc@CNT<\/strong> , <\/strong>6.6%P-CoPc@CNT<\/strong> , <\/strong>7.8%P-CoPc@CNT<\/strong>\u7684<\/strong> (e) XRD<\/strong>\u8c31\u56fe\u548c<\/strong> (f) <\/strong>\u62c9\u66fc\u5149\u8c31\uff1b<\/strong>(g) Pre<\/em>-CoPc@CNT, CoPc@CNT, <\/strong>6.6%P-CoPc@CNT<\/strong>\u7684\u6c34\u63a5\u89e6\u89d2\u3002<\/strong> \u00a9 2022 <\/strong>The Authors<\/strong>\u00a0<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\u56fe<\/strong>2 (a) P 2p XPS<\/strong>\u5149\u8c31\uff1b<\/strong>(b) Co 2p XPS<\/strong>\u5149\u8c31\uff1b<\/strong>(c) Co L<\/strong>\u8fb9<\/strong>XANES<\/strong>\u5149\u8c31\uff1b<\/strong>(d) Co K<\/strong>\u8fb9<\/strong>XANES<\/strong>\u5149\u8c31\uff1b<\/strong>(e) <\/strong>\u5085\u91cc\u53f6\u53d8\u6362\u5904\u7406\u7684<\/strong>Co<\/strong>\u7b94<\/strong>, CoPc, CoO, Co3<\/sub>O4<\/sub>, 6.6%P-CoPc@CNT<\/strong>\u7684<\/strong>EXAFS<\/strong>\u5149\u8c31\uff1b<\/strong>(f) 6.6%P-CoPc@CNT<\/strong>\u7684<\/strong>r<\/strong>\u7a7a\u95f4<\/strong>EXAFS<\/strong>\u62df\u5408\u66f2\u7ebf\uff0c\u5185\u5d4c\uff1a<\/strong>6.6%P-CoPc@CNT<\/strong>\u7684\u793a\u610f\u6a21\u578b<\/strong> \uff08<\/strong>C<\/strong>\uff1a\u68d5\u8272\uff0c<\/strong>N<\/strong>\uff1a\u7070\u8272\uff0c<\/strong>Co<\/strong>\uff1a\u84dd\u8272\uff0c<\/strong>P<\/strong>\uff1a\u6de1\u7d2b\u8272\uff1b<\/strong>O<\/strong>\uff1a\u7ea2\u8272\uff09\u3002<\/strong>\u00a9 2022 The Authors<\/strong>\u00a0<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\u56fe<\/strong>3 CoPc@CNT, 5.6%P-CoP@CNT, 6.6%P-CoPc@CNT, 7.8%P-CoPc@CNT<\/strong>\u7684<\/strong> (a) <\/strong>\u6781\u5316\u66f2\u7ebf\uff1b<\/strong>(b) <\/strong>\u5854\u83f2\u5c14\u66f2\u7ebf\uff1b<\/strong>(c) <\/strong>\u5948\u594e\u65af\u7279\u66f2\u7ebf\uff0c\u5185\u5d4c\uff1a\u62df\u5408\u7b49\u6548\u7535\u8def\uff1b<\/strong>(d) 6.6%P-CoPc@CNT<\/strong>\u5faa\u73af<\/strong>5000<\/strong>\u6b21\u524d\u540e\u7684\u6781\u5316\u66f2\u7ebf\uff0c\u5185\u5d4c\uff1a<\/strong>6.6%P-CoPc@CNT<\/strong>\u5728\u7535\u538b\u4e3a<\/strong>1.53 V vs.<\/em> RHE<\/strong>\u65f6\u7684<\/strong>i-t\u00ad<\/em><\/strong>\u66f2\u7ebf\u3002<\/strong>\u00a9 2022 <\/strong>The Authors<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>4 OER<\/strong>\u8fc7\u7a0b\u4e2d\u7535\u538b\u4e3a<\/strong>1.23 V vs.<\/em> RHE<\/strong>\u65f6<\/strong> (a) CoPc<\/strong>\u8868\u9762\u548c<\/strong> (b) PO4<\/sub>-CoPc<\/strong>\u8868\u9762\u7684\u81ea\u7531\u80fd\u53d8\u5316\u3002\u84dd\u8272\u3001\u6d45\u7d2b\u8272\u3001\u7070\u8272\u3001\u68d5\u8272\u3001\u7ea2\u8272\u548c\u767d\u8272\u7403\u5206\u522b\u4ee3\u8868<\/strong>Co<\/strong>\u3001<\/strong>P<\/strong>\u3001<\/strong>N<\/strong>\u3001<\/strong>C<\/strong>\u3001<\/strong>O<\/strong>\u548c<\/strong>H<\/strong>\u3002<\/strong>\u00a9 2022 The Authors<\/strong><\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u672c\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u901a\u8fc7\u5bf9\u5355\u539f\u5b50\u50ac\u5316\u5242\u8fdb\u884c\u8f74\u5411\u914d\u4f4d\u5de5\u7a0b\uff0c\u5f15\u5165\u65b0\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u6539\u53d8\u53cd\u5e94\u8def\u5f84\u4ece\u800c\u6539\u5584\u50ac\u5316\u5242\u6d3b\u6027\u7684\u7b56\u7565\u3002\u8fd9\u4e00\u7b56\u7565\u7684\u63d0\u51fa\u62d3\u5bbd\u4e86\u5bf9\u5355\u539f\u5b50\u7ed3\u6784\u4e0e\u53cd\u5e94\u6d3b\u6027\u95f4\u7684\u6784\u6548\u5173\u7cfb\u7684\u7814\u7a76\u601d\u8def\uff0c\u540c\u65f6\u4e5f\u4e3a\u5355\u539f\u5b50\u50ac\u5316\u6d3b\u6027\u7684\u4f18\u5316\u8bbe\u8ba1\u7684\u63d0\u4f9b\u4e86\u65b0\u7684\u65b9\u5411\u3002<\/p>\n

 <\/p>\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/advs.202206107<\/a><\/p>\n

\u672c\u6587\u7531MYu\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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