{"id":247939,"date":"2023-03-15T14:40:08","date_gmt":"2023-03-15T06:40:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=247939"},"modified":"2023-03-15T14:37:05","modified_gmt":"2023-03-15T06:37:05","slug":"%e3%80%90%e6%96%b0%e8%83%bd%e6%ba%90%e5%89%8d%e7%ba%bf%e3%80%91nat-commun-%e5%8f%8c%e5%8a%9f%e8%83%bd%e7%94%b5%e6%9e%81%e5%ae%9e%e7%8e%b0%e4%b8%80%e4%bd%93%e5%8c%96%e7%a8%80%e7%a1%9d%e9%85%b8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=247939","title":{"rendered":"Nat.Commun: \u53cc\u529f\u80fd\u7535\u6781\u5b9e\u73b0\u4e00\u4f53\u5316\u7a00\u785d\u9178\u76d0\u6355\u83b7\u3001\u6d53\u7f29\u548c\u9ad8\u6548\u8f6c\u5316\u4e3a\u6c28\u7684\u7b56\u7565"},"content":{"rendered":"<p style=\"text-align: center;\"><span style=\"color: #0000ff;\"><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n<p>\u00a0 \u785d\u9178\u76d0\u7531\u4e8e\u5176\u6d41\u52a8\u6027\u3001\u6c34\u6eb6\u6027\u548c\u6301\u4e45\u6027\uff0c\u957f\u671f\u4ee5\u6765\u4e00\u76f4\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u5e7f\u6cdb\u5b58\u5728\u5bfc\u81f4\u5bcc\u8425\u517b\u5316\u548c\u85fb\u7c7b\u7e41\u6b96\u7684\u5927\u578b\u6c61\u67d3\u7269\u3002\u785d\u9178\u76d0\u6c61\u67d3\u4e3b\u8981\u662f\u7531\u6d3b\u6027\u6c2e\u80a5\u7684\u8fc7\u5ea6\u4f7f\u7528\u548c\u519c\u4e1a\u5236\u9020\u7684\u6c2e\u6d41\u5931\u5f15\u8d77\u7684\u3002\u76ee\u524d\uff0c\u7814\u7a76\u4eba\u5458\u5df2\u7ecf\u63d0\u51fa\u4e86\u51e0\u79cd\u53bb\u9664\u785d\u9178\u76d0\u7684\u6c34\u51c0\u5316\u65b9\u6cd5\uff0c\u5305\u62ec\u79bb\u5b50\u4ea4\u6362\u6cd5\u548c\u53cd\u6e17\u900f\u6cd5\uff0c\u4f46\u8fd9\u4e9b\u65b9\u6cd5\u5f80\u5f80\u53d7\u5230\u9ad8\u80fd\u8017\u3001\u5e9f\u7269\u4ea7\u751f\u4ee5\u53ca\u9009\u62e9\u6027\u548c\u5bb9\u91cf\u7b49\u56e0\u7d20\u9650\u5236\u3002\u53e6\u5916\uff0c\u785d\u9178\u76d0\u76f8\u6bd4\u6c2e\u6c14\u66f4\u6709\u53ef\u80fd\u6210\u4e3a\u6c28\u751f\u4ea7\u7684\u4e00\u79cd\u6709\u524d\u9014\u7684\u6c2e\u6e90\u3002\u5728\u8fd9\u79cd\u80cc\u666f\u4e0b\uff0c\u5c06\u785d\u9178\u76d0\u7535\u5316\u5b66\u8f6c\u5316\u4e3a\u6c28\uff0c\u4f5c\u4e3a\u80fd\u6e90\u548c\u78b3\u5bc6\u96c6\u578bHaber-Bosch\u5de5\u827a\u7684\u4e00\u79cd\u53ef\u6301\u7eed\u7684\u66ff\u4ee3\u65b9\u6848\u3002\u785d\u9178\u76d0\u9ad8\u6548\u8f6c\u5316\u4e3a\u6c28\u4e3b\u8981\u5c40\u9650\u662f\u4f20\u8d28\u548c\u526f\u53cd\u5e94\u3002\u8fd1\u5e74\u6765\uff0c\u5c3d\u7ba1\u5728\u5b9e\u73b0\u7535\u5316\u5b66\u785d\u9178\u76d0\u8fd8\u539f\u65b9\u9762\u53d6\u5f97\u4e86\u663e\u8457\u5730\u8fdb\u5c55\uff0c\u4f46\u5927\u591a\u6570\u7535\u5316\u5b66\u7814\u7a76\u90fd\u4f7f\u7528\u8f83\u9ad8\u7684\u785d\u9178\u76d0\u6d53\u5ea6(10-1000 mM)\u6765\u8bc4\u4f30\u50ac\u5316\u5242\u548c\u88c5\u7f6e\u7684\u6027\u80fd\u3002\u7136\u800c\uff0c\u5728\u81ea\u7136\u73af\u5883\u7684\u5e9f\u6c34\u4e2d\uff0c\u785d\u9178\u76d0\u6d53\u5ea6\u901a\u5e38\u8981\u7a00\u5f97\u591a\u3002\u56e0\u6b64\uff0c\u5b9e\u73b0\u4e00\u4f53\u5316\u7a00\u785d\u9178\u76d0\u6355\u83b7\u3001\u6d53\u7f29\u548c\u9ad8\u6548\u8f6c\u5316\u4e3a\u6c28\u662f\u76ee\u524d\u6709\u5173\u785d\u9178\u76d0\u7684\u4e3b\u6d41\u7814\u7a76\u4e4b\u4e00\u3002<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><span style=\"color: #0000ff;\"><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/span><\/p>\n<p>\u00a0 \u8fd1\u65e5\uff0c\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66\u9999\u69df\u5206\u6821Xiao Su\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u53cc\u529f\u80fd\u7535\u6781\uff08PANI-Co<sub>3<\/sub>O<sub>4<\/sub>\/CNT\uff09\uff0c\u8fd9\u79cd\u53cc\u529f\u80fd\u7535\u6781\u7531\u5177\u6709\u9ad8\u9009\u62e9\u6027\u6c27\u5316\u8fd8\u539f\u7535\u5316\u5b66\u5438\u9644\u785d\u9178\u76d0\u529f\u80fd\u7684\u805a\u82ef\u80fa\uff08PANI\uff09\u548c\u6c27\u5316\u94b4\u7535\u50ac\u5316\u5242\u7ec4\u6210\uff0c\u901a\u8fc7\u7535\u5316\u5b66\u65b9\u5f0f\u5b9e\u73b0\u785d\u9178\u76d0\u7684\u534f\u540c\u53cd\u5e94\u5206\u79bb\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5<strong>\u201c<em>Coupling nitrate capture with ammonia production through bifunctional redox-electrodes<\/em>\u201d<\/strong>\u4e3a\u9898\u53d1\u8868\u5728<strong><em>Nature Communications<\/em><\/strong>\u4e0a<strong>\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247940\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/0-22.png\" alt=\"\" width=\"694\" height=\"682\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/0-22.png 694w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/0-22-300x295.png 300w\" sizes=\"(max-width: 694px) 100vw, 694px\" \/><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #0000ff;\"><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/span><\/p>\n<p><strong>1<\/strong><strong>\u3001\u4f5c\u8005\u63d0\u51fa<\/strong><strong>\u5c06\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u805a\u5408\u7269\uff08\u805a\u82ef\u80fa\uff0c<\/strong><strong>PANI<\/strong><strong>\uff09\u4e0e\u8d1f\u8f7d\u5728\u78b3\u7eb3\u7c73\u7ba1\u4e0a\u7684<\/strong><strong>Co<sub>3<\/sub>O<sub>4<\/sub><\/strong><strong>\u50ac\u5316\u5242\u7ed3\u5408\u8d77\u6765\uff0c\u4f5c\u4e3a<\/strong><strong>\u7eb3<\/strong><strong>\u7c73\u7ed3\u6784\u7684\u53cc\u529f\u80fd\u7535\u5438\u9644\u5242\u548c\u7535\u50ac\u5316\u5242\u3002<\/strong>PANI-Co<sub>3<\/sub>O<sub>4<\/sub>\/CNT\u5b9e\u73b0\u4e00\u4f53\u5316<strong>\u7a00\u785d\u9178\u76d0\u6355\u83b7\u3001\u6d53\u7f29\u548c\u8f6c\u5316\u4e3a\u6c28\u7684\u534f\u540c\u8026\u5408\u3002<\/strong><\/p>\n<p><strong>2<\/strong><strong>\u3001<\/strong><strong>\u5f53\u4f7f\u7528\u542b\u6709<\/strong><strong>0.27 mM<\/strong><strong>\u6d53\u5ea6\u785d\u9178\u76d0\u7684\u519c\u4e1a\u5e9f\u6c34\uff0c\u8fd9\u79cd\u53cc\u529f\u80fd\u7535\u6781\u80fd\u591f\u5bcc\u96c6\u6d53\u5ea6\u4e3a<\/strong><strong>8<\/strong><strong>\u500d\u7684\u785d\u9178\u76d0\uff0c\u5236\u6c28\u4ea7\u7387\u63d0\u9ad8<\/strong><strong>24<\/strong><strong>\u500d\uff0c\u80fd\u6e90\u6548\u7387\u63d0\u9ad8<\/strong><strong>&gt;10<\/strong><strong>\u500d\u3002\u4f18\u4e8e\u5df2\u5728\u7c7b\u4f3c\u4f4e\u785d\u9178\u76d0\u6d53\u5ea6\u4e0b\u8bc4\u4f30\u7684\u5176\u4ed6\u7535\u50ac\u5316\u7cfb\u7edf\u3002<\/strong><\/p>\n<p style=\"text-align: center;\"><span style=\"color: #0000ff;\"><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247941\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/1-39.png\" alt=\"\" width=\"1269\" height=\"717\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/1-39.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/1-39-300x170.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/1-39-768x434.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/1-39-1024x579.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1<\/strong> \u7a00\u785d\u9178\u76d0\u6355\u83b7\u548c\u8f6c\u5316\u7684\u987a\u5e8f\u548c\u96c6\u6210\u8def\u5f84\u3002(a) \u7269\u7406\u5316\u5b66\u51c0\u5316(\u79bb\u5b50\u4ea4\u6362\u3001\u53cd\u6e17\u900f\u548c\u7535\u6e17\u6790)\u548c\u7535\u5316\u5b66\u8f6c\u6362\u987a\u5e8f\u8def\u7ebf\u7684\u793a\u610f\u56fe\u3002(b) \u672c\u7814\u7a76\u4e2d\u63d0\u51fa\u7684\u4f7f\u7528\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7535\u5438\u9644\u5242\u548c\u91d1\u5c5e\u6c27\u5316\u7269\u7535\u50ac\u5316\u5242\u7684\u590d\u5408\u6750\u6599\u96c6\u6210\u785d\u9178\u76d0\u6355\u83b7\u3001\u4e0a\u5347\u6d53\u5ea6\u548c\u8f6c\u5316\u7684\u793a\u610f\u56fe\u3002 \u00a92023 The Author(s)<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247942\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/2-35.png\" alt=\"\" width=\"685\" height=\"517\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/2-35.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/2-35-300x226.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2<\/strong>\u53cc\u529f\u80fdPANI-Co<sub>3<\/sub>O<sub>4<\/sub>\/CNT\u7535\u6781\u793a\u610f\u56fe\u3002\u5728+0.4 V vs Ag\/AgCl\u9633\u6781\u5145\u7535\u65f6\uff0cPANI\u88ab\u6fc0\u6d3b(\u7fe1\u7fe0\u7eff)\uff0c\u5e76\u4f5c\u4e3a\u785d\u9178\u76d0\u7684\u7535\u5438\u9644\u5242\u3002\u5728\u9634\u6781\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0cPANI\u88ab\u8fd8\u539f\u4e3a\u767d\u7fe1\u7fe0\u7eff\u5f62\u5f0f\uff0c\u5e76\u91ca\u653e\u51fa\u5438\u9644\u7684\u785d\u9178\u76d0(\u22120.5 V vs Ag\/AgCl)\uff0c\u6216\u8005PANI\u518d\u751f\u4e0eCo<sub>3<\/sub>O<sub>4<\/sub>\u7684\u785d\u9178\u76d0\u7535\u8f6c\u5316\u4e3a\u6c28(\u22121.4 V vs Ag\/AgCl)\u3002\u00a92023 The Author(s)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247943\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/3-33.png\" alt=\"\" width=\"685\" height=\"547\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/3-33.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/3-33-300x240.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3<\/strong> PANI-Co<sub>3<\/sub>O<sub>4<\/sub>\/CNT\u7684\u5f62\u6001\u8868\u5f81\u3002(a) PANI-Co<sub>3<\/sub>O<sub>4<\/sub>\/CNT\u7684\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c (SEM) \u56fe\u50cf\u3002(b) PANI-Co<sub>3<\/sub>O<sub>4<\/sub>\/CNT\u7684\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c (TEM) \u548c(c)\u9ad8\u89d2\u5ea6\u73af\u5f62\u6697\u573a\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c (HAADF-STEM) \u56fe\u50cf\u4ee5\u53ca\u76f8\u5e94\u7684\u80fd\u91cf\u8272\u6563\u5149\u8c31 (EDS) \u6620\u5c04\u56fe\u50cf\u3002\uff08d\uff09Co<sub>3<\/sub>O<sub>4<\/sub>\u7684\u9ad8\u5206\u8fa8\u7387 TEM (HRTEM) \u56fe\u50cf\u548c(e)\u76f8\u5e94\u7684\u5feb\u901f\u5085\u91cc\u53f6\u53d8\u6362\u56fe\u3002\u00a92023 The Author(s)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247944\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/4-32.png\" alt=\"\" width=\"685\" height=\"368\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/4-32.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/4-32-300x161.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4<\/strong> PANI \u79cd\u7c7b\u5bf9\u785d\u9178\u76d0\u9009\u62e9\u6027\u6355\u83b7\u7684\u7ed3\u6784\u5f71\u54cd\u3002\uff08a\uff09\u7531\u7535\u6781\u7535\u4f4d\u548c\u6eb6\u6db2pH \u503c\u7684\u53d8\u5316\u5f15\u8d77\u7684PANI \u7684\u6c27\u5316\u8fd8\u539f\u76f8\u4e92\u8f6c\u5316\u3002(b)\u00a0PANI\/CNT \u7535\u6781\u57280.5 M H<sub>2<\/sub>SO<sub>4<\/sub>\u4e2d\u7684\u5faa\u73af\u4f0f\u5b89\u56fe\u3002(c)\u4e0d\u540c pH \u503c\u548c\u7535\u6781\u7535\u4f4d\u4e0b\u7684\u785d\u9178\u76d0\u5438\u6536\u80fd\u529b\u70ed\u56fe (mg NO3<sup>\u2212<\/sup>g<sup>\u22121<\/sup> PANI)\u3002\uff08d\uff09\u5728\u4e0d\u540cpH\u503c\u548c\u7535\u6781\u7535\u4f4d\u4e0bPANI\u5bf9\u785d\u9178\u76d0\u7684\u5206\u79bb\u56e0\u5b50(SF)\u70ed\u56fe\u3002\u00a92023 The Author(s)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247945\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/5-25.png\" alt=\"\" width=\"685\" height=\"552\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/5-25.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/5-25-300x242.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5<\/strong> \u00a0PANI \u4e0e\u785d\u9178\u76d0\u7ed3\u5408\u7684\u7535\u5b50\u7ed3\u6784\u8ba1\u7b97\u3002\uff08a\uff09\u4e0e PANI \u7ed3\u5408\u7684NO<sup>3-<\/sup>\u00a0\/Cl<sup>&#8211;<\/sup>\u7684\u539f\u5b50\u5df4\u5fb7\u7535\u8377\u3002\uff08b\uff09\u785d\u9178\u76d0\u4e0e\u6c2f\u5316\u7269\u7684\u5206\u79bb\u56e0\u5b50\u4ee5\u53ca\u785d\u9178\u76d0\u548c\u6c2f\u5316\u7269\u5bf9\u56db\u79cd\u4e0d\u540cPANI\u7269\u79cd\u7684\u7ed3\u5408\u80fd(BEs)\u7684\u5dee\u5f02\u3002\uff08c\uff09NO3<sup>&#8211;<\/sup>\u4e0e PANI \u7684\u7fe0\u7eff\u4e9a\u80fa\u76d0 (ES)\u7ed3\u5408\u8868\u793a\u56fe\u3002\u00a92023 The Author(s)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247946\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/6-13.png\" alt=\"\" width=\"685\" height=\"503\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/6-13.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/6-13-300x220.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>6<\/strong> \u00a0\u4f7f\u7528 PANI-Co<sub>3<\/sub>O<sub>4<\/sub>\/CNT \u590d\u5408\u6750\u6599\u8fdb\u884c\u53cd\u5e94\u5206\u79bb\u3002\uff08a\uff09PANI\/CNT \u548c PANI-Co<sub>3<\/sub>O<sub>4<\/sub>\/CNT\u590d\u5408\u6750\u6599\u5728\u4e0d\u540cCo<sub>3<\/sub>O<sub>4<\/sub>\u8d1f\u8f7d\u91cf\u4e0b\u7684\u785d\u9178\u76d0\u5438\u6536\u80fd\u529b\u3002(b)\u5728\u5404\u79cd\u7535\u6781\u7535\u4f4d\u4e0b\u91ca\u653e\u5230 0.1 M NaCl \u4e2d1\u5c0f\u65f6\u540e\uff0c\u4ee5\u785d\u9178\u76d0\u3001\u4e9a\u785d\u9178\u76d0\u548c\u94f5\u7684\u5f62\u5f0f\u56de\u6536\u7684\u6c2e\u7269\u79cd\u7684\u767e\u5206\u6bd4\u3002(c) CNT\u3001PANI\/CNT \u548c PANI-Co<sub>3<\/sub>O<sub>4<\/sub>\/CNT\u7535\u6781\u8fdb\u884c\u4e00\u4e2a\u5b8c\u6574\u7684\u7535\u5438\u9644\u548c\u518d\u751f\u5faa\u73af\u540e\uff0c\u785d\u9178\u76d0\u5438\u6536\u80fd\u529b\uff08\u5de6y\u8f74\uff09\u548c\u6c2e\u7269\u79cd\u56de\u6536\u767e\u5206\u6bd4\uff08\u53f3 y \u8f74\uff09\u3002(d) \u5b8c\u6574\u5faa\u73af\u7535\u5438\u9644\uff08+0.4 V vs Ag\/AgCl\uff09\u548c\u91ca\u653e\uff08-1.4 V vs Ag\/AgCl\uff09\u540e\u518d\u751f\u7535\u89e3\u8d28\u7684<sup>1<\/sup>H-NMR \u5149\u8c31\u3002\u00a92023 The Author(s)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247947\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/7-3.png\" alt=\"\" width=\"685\" height=\"719\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/7-3.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/7-3-286x300.png 286w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>7<\/strong> \u00a0\u5206\u79bb\u3001\u6d53\u7f29\u3001\u8f6c\u5316\u548c\u80fd\u91cf\u5206\u6790\u7684\u96c6\u6210\u3002(a)\u5904\u7406\u7a00\u785d\u9178\u76d0\u6d41\u7684\u4e24\u79cd\u60c5\u51b5\u7684\u793a\u610f\u56fe\u3002\u5728\u65b9\u6848 A \u4e2d\uff0c\u7535\u50ac\u5316\u5242\u76f4\u63a5\u7535\u50ac\u5316\u7a00\u785d\u9178\u76d0\u8fdb\u6599\u3002\u5728\u65b9\u6848 B \u4e2d\uff0c\u4e3a\u4e86\u514b\u670d\u4f4e\u785d\u9178\u76d0\u6d53\u5ea6\u548c\u7535\u5bfc\u7387\uff0c\u8fdb\u884c\u4e86\u4e00\u4e2a\u5b8c\u6574\u7684\u5438\u9644\u548c\u518d\u751f\u5faa\u73af\u4ee5\u4ea7\u751f\u6d53\u7f29\u7684\u5c40\u90e8\u785d\u9178\u76d0\u6d41\uff0c\u7136\u540e\u53ef\u4ee5\u901a\u8fc7\u540c\u4e00\u7535\u6781\u5bf9\u5176\u8fdb\u884c\u7535\u50ac\u5316\u3002(b)\u518d\u751f\u6548\u7387\uff08\u785d\u9178\u76d0\u56de\u6536\/\u785d\u9178\u76d0\u5438\u9644\uff09\u5728 -0.5 V \u76f8\u5bf9\u4e8e Ag\/AgCl \u91ca\u653e\u5230\u542b\u6709\u5404\u79cd\u521d\u59cb\u785d\u9178\u76d0\u6d53\u5ea6\u7684 0.1 M NaCl \u540e\u6d4b\u91cf\u3002(c) \u65b9\u6848B\u4e2d\u5438\u9644\uff0820 mL\uff09\u548c\u89e3\u5438\uff081 mL\uff09\u5b8c\u6574\u5faa\u73af\u524d\u540e\u7a00\u91ca\u6392\u6c34\u8fdb\u6599\u548c\u63a5\u6536\u6eb6\u6db2\u7684\u785d\u9178\u76d0\u6d53\u5ea6\u3002 (d) PANI-Co<sub>3<\/sub>O<sub>4<\/sub>\/CNT\u7535\u6781\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u548c\u6c28\u4ea7\u7387\u3002 (e) \u80fd\u6e90\u6d88\u8017\u6bd4\u8f83\uff08kWh kg<sup>\u22121<\/sup>-N) \u5728\u65b9\u6848 A \u548c B \u4e2d\u3002\u00a92023 The Author(s)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-247948\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/8-1.png\" alt=\"\" width=\"685\" height=\"272\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/8-1.png 685w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/02\/8-1-300x119.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>8<\/strong> \u5df2\u62a5\u9053\u7684\u7535\u5316\u5b66\u785d\u9178\u76d0\u8fd8\u539f\u7684\u80fd\u8017\u6bd4\u8f83\u3002\u00a92023 The Author(s)<\/p>\n<p style=\"text-align: center;\"><span style=\"color: #0000ff;\"><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/span><\/p>\n<p><strong>\u00a0 \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u6210\u529f\u5730\u8bc1\u660e\u6c27\u5316\u8fd8\u539f\u7535\u5438\u9644\u5242\u548c\u7535\u50ac\u5316\u5242\u7684\u7ed3\u5408\u80fd\u591f\u5b9e\u73b0\u7a00\u785d\u9178\u76d0\u5e9f\u6c34\u7684\u8282\u80fd\u5206\u79bb\uff0c\u5e76\u5c06\u5176\u8f6c\u5316\u4e3a\u589e\u503c\u7684\u94f5\u3002\u4ece\u785d\u9178\u76d0\u4fee\u590d\u7684\u89d2\u5ea6\u6765\u770b\uff0c\u8fd9\u9879\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u3001\u65e0\u5316\u5b66\u7269\u7684\u9009\u62e9\u5de5\u827a\uff0c\u5b83\u7ed3\u5408\u4e86\u6c28\u751f\u6210\u7684\u597d\u5904\u3002\u4ece\u6c28\u5408\u6210\/\u5e9f\u7269\u4ef7\u683c\u7684\u89d2\u5ea6\u6765\u770b\uff0c\u8fd9\u4e2a\u65b9\u6cd5\u53ef\u4ee5\u76f4\u63a5\u5229\u7528\u7a00\u91ca\u785d\u9178\u76d0\u4f5c\u4e3a\u6c28\u751f\u4ea7\u7684\u539f\u6599\uff0c\u6f5c\u5728\u5730\u51cf\u5c11\u5bf9\u78b3\u5bc6\u96c6\u578bHaber-Bosch\u5de5\u827a\u7684\u9700\u6c42\uff0c\u5e76\u4e3a\u5316\u5b66\u539f\u6599\u6216\u80fd\u6e90\u8f7d\u4f53\u751f\u4ea7\u5efa\u7acb\u65b0\u7684\u7efc\u5408\u9014\u5f84\u3002\u4ece\u6839\u672c\u4e0a\u8bf4\uff0c\u8fd9\u9879\u7814\u7a76\u5de5\u4f5c\u5f3a\u8c03\u4e86\u7535\u5316\u5b66\u8f6c\u5316\u4e2d\u53cd\u5e94\u548c\u5206\u79bb\u4e00\u4f53\u5316\u7684\u6838\u5fc3\u91cd\u8981\u6027\uff0c\u5e76\u901a\u8fc7\u9009\u62e9\u6027\u7535\u5438\u9644\u514b\u670d\u56fa\u6709\u8f93\u8fd0\u9650\u5236\uff0c\u4e3a\u4f4e\u6d53\u5ea6\u5206\u5b50\u7684\u53cd\u5e94\u5206\u79bb\u63d0\u4f9b\u4e86\u4e00\u79cd\u5e7f\u4e49\u7b56\u7565\u3002<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5\uff1a<\/strong>https:\/\/doi.org\/10.1038\/s41467-023-36318-1<\/p>\n<p>\u672c\u6587\u7531K . L\u64b0\u7a3f\u3002<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u00a0 \u785d\u9178\u76d0\u7531\u4e8e\u5176\u6d41\u52a8\u6027\u3001\u6c34\u6eb6\u6027\u548c\u6301\u4e45\u6027\uff0c\u957f\u671f\u4ee5\u6765\u4e00\u76f4\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u5e7f\u6cdb\u5b58\u5728\u5bfc\u81f4\u5bcc\u8425\u517b\u5316\u548c\u85fb\u7c7b\u7e41\u6b96\u7684\u5927\u578b\u6c61\u67d3\u7269\u3002\u785d\u9178\u76d0\u6c61\u67d3\u4e3b\u8981\u662f\u7531\u6d3b\u6027\u6c2e\u80a5\u7684\u8fc7\u5ea6\u4f7f\u7528\u548c&#8230;<\/p>\n","protected":false},"author":48789,"featured_media":247941,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4830,3353,2569],"class_list":["post-247939","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-4830","tag-3353","tag-2569"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/247939"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/48789"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=247939"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/247939\/revisions"}],"predecessor-version":[{"id":248722,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/247939\/revisions\/248722"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/247941"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=247939"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=247939"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=247939"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}