{"id":247773,"date":"2023-03-01T06:00:24","date_gmt":"2023-02-28T22:00:24","guid":{"rendered":"\/\/m.iemloyee.com\/?p=247773"},"modified":"2023-02-27T15:39:27","modified_gmt":"2023-02-27T07:39:27","slug":"%e4%b8%ad%e7%a7%91%e5%a4%a7%e7%ab%a0%e6%a0%b9%e5%bc%basmall%ef%bc%9a%e6%b0%ae%e6%8e%ba%e6%9d%82%e7%a1%ab%e5%8c%96%e7%89%a9%e5%bc%82%e8%b4%a8%e7%bb%93%e6%9e%84%e5%ae%9e%e7%8e%b0%e9%ab%98%e6%80%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=247773","title":{"rendered":"\u4e2d\u79d1\u5927\u7ae0\u6839\u5f3aSmall\uff1a\u6c2e\u63ba\u6742\u786b\u5316\u7269\u5f02\u8d28\u7ed3\u6784\u5b9e\u73b0\u9ad8\u6027\u80fd\u5c3f\u7d20\u6c27\u5316\u8f85\u52a9\u8282\u80fd\u5236\u6c22"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u6c22\u6c14\uff08H2<\/sub>\uff09\u4f5c\u4e3a\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u80fd\u6e90\u8f7d\u4f53\uff0c\u662f\u66ff\u4ee3\u4f20\u7edf\u5316\u77f3\u71c3\u6599\u7684\u7406\u60f3\u9009\u62e9\uff0c\u5176\u4e2d\u5229\u7528\u53ef\u6301\u7eed\u80fd\u6e90\u9a71\u52a8\u7684\u7535\u89e3\u6c34\u5236\u6c22\u6280\u672f\u56e0\u5176\u96f6\u6c61\u67d3\u548c\u96f6\u78b3\u6392\u653e\u800c\u5907\u53d7\u5173\u6ce8\u3002\u5c3d\u7ba1\u5982\u6b64\uff0c\u7531\u4e8e\u9634\u6781\u548c\u9633\u6781\u53cd\u5e94\u7684\u9ad8\u80fd\u52bf\u5792\uff0c\u5c24\u5176\u662f\u9633\u6781\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u8fc7\u7a0b\u7684\u56fa\u6709\u52a8\u529b\u5b66\u7f13\u6162\uff0c\u7535\u5316\u5b66\u6c34\u5206\u89e3\u8fc7\u7a0b\u4ecd\u7136\u9762\u4e34\u8f6c\u6362\u6548\u7387\u8f83\u4f4e\u7684\u56f0\u5883\uff0c\u5bfc\u81f4\u5728\u5927\u89c4\u6a21H2<\/sub>\u751f\u4ea7\u8fc7\u7a0b\u4e2d\u9700\u8981\u5927\u91cf\u7535\u529b\u3002\u56e0\u6b64\uff0c\u7814\u7a76\u4eba\u5458\u5df2\u7ecf\u53d1\u5c55\u51fa\u4e86\u4e24\u79cd\u6709\u6548\u7684\u7b56\u7565\u6765\u514b\u670d\u8fd9\u4e00\u4e3b\u8981\u74f6\u9888\uff1a1\uff09\u5f00\u53d1\u9ad8\u6027\u80fd\u548c\u4f4e\u6210\u672c\u7684\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u50ac\u5316\u5242\u4ee5\u52a0\u901f\u9634\u6781\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u4ece\u800c\u964d\u4f4eHER\u8fc7\u7535\u52bf\uff1b2\uff09\u7528\u5176\u4ed6\u66f4\u5bb9\u6613\u53d1\u751f\u7535\u6c27\u5316\u7684\u6709\u673a\u5c0f\u5206\u5b50\u5982\u5c3f\u7d20\u3001\u80bc\u548c\u7532\u9187\u4ee3\u66ffOER\u3002\u5c3f\u7d20\u4f5c\u4e3a\u4e00\u79cd\u5e38\u89c1\u7684\u6c61\u67d3\u7269\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5de5\u4e1a\u548c\u751f\u6d3b\u6c61\u6c34\u4e2d\u3002\u901a\u8fc7HER\u548c\u5c3f\u7d20\u6c27\u5316\u53cd\u5e94\uff08UOR\uff09\u7684\u8026\u5408\uff0c\u53ef\u4ee5\u5b9e\u73b0H2<\/sub>\u751f\u4ea7\u548c\u5bcc\u5c3f\u6db2\u5e9f\u6c34\u65e0\u5bb3\u5904\u7406\uff0c\u8be5\u7ec4\u5408\u5c55\u73b0\u4e86\u5176\u5b9e\u9645\u5e94\u7528\u7684\u5de8\u5927\u6f5c\u529b\u3002\u7136\u800c\uff0cUOR\u7684\u53d1\u751f\u9700\u8981\u7ecf\u5386\u590d\u6742\u7684\u516d\u7535\u5b50\u8f6c\u79fb\u548c\u591a\u91cd\u4e2d\u95f4\u4f53\u7684\u5f62\u6210\/\u89e3\u5438\u8fc7\u7a0b\uff0c\u5c3d\u7ba1\u70ed\u529b\u5b66\u52bf\u80fd\u8f83\u4f4e\uff0c\u4f46\u4e5f\u53d7\u5230\u4e0d\u4ee4\u4eba\u6ee1\u610f\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\u7684\u9650\u5236\u3002\u56e0\u6b64\uff0c\u8feb\u5207\u9700\u8981\u7cbe\u786e\u8bbe\u8ba1\u548c\u5408\u6210\u6027\u80fd\u4f18\u826f\u7684HER\u548cUOR\u53cc\u529f\u80fd\u6027\u7535\u50ac\u5316\u5242\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/span><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u7ae0\u6839\u5f3a\u6559\u6388\u56e2\u961f\u901a\u8fc7\u9634\u79bb\u5b50\u63ba\u6742\u7b56\u7565\uff0c\u6210\u529f\u8bbe\u8ba1\u51fa\u4e86\u4e00\u79cd\u6c2e\u63ba\u6742\u786b\u5316\u7269\u5f02\u8d28\u7ed3\u6784\u7684\u53cc\u529f\u80fd\u50ac\u5316\u5242\uff08\u8868\u793a\uff1aN-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\uff09\u3002\u5728\u8f83\u4f4e\u7684\u8f93\u5165\u7535\u4f4d\u4e0b\u5b9e\u73b0\u4e86\u5c3f\u7d20\u6c27\u5316\u8f85\u52a9\u7535\u5316\u5b66\u4ea7\u6c22\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u201cConstruction of Nitrogen-Doped Biphasic Transition-Metal Sulfide Nanosheet Electrode for Energy-Efficient Hydrogen Production via Urea Electrolysis<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Small<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/span><\/p>\n

1<\/strong>\u3001<\/strong>\u4f5c\u8005\u901a\u8fc7\u7535\u5316\u5b66\u6c89\u79ef\u548c\u6c28\u6c14\u9000\u706b\u5904\u7406\u7684\u65b9\u5f0f\u5236\u5907\u51fa\u6c2e\u63ba\u6742\u786b\u5316\u94b4\/\u786b\u5316\u954d\u5f02\u8d28\u7ed3\u7684\u590d\u5408\u7ed3\u6784<\/strong>\u3002<\/strong>N-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u5177\u6709\u72ec\u7279<\/strong>\u7684<\/strong>\u4e8c\u7ef4\u591a\u5b54\u7eb3\u7c73\u7247\u7ed3\u6784\u548c\u5b8c\u5168\u66b4\u9732\u7684\u6d3b\u6027\u4f4d\u70b9\u4ee5\u53ca<\/strong>N<\/strong>\u63ba\u6742\u5bf9\u7535\u5b50\u7ed3\u6784\u7684\u5f71\u54cd\u3002<\/strong><\/p>\n

2<\/strong>\u3001<\/strong>N-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u5728\u78b1\u6027\u7535\u89e3\u6db2\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684<\/strong>UOR<\/strong>\u548c<\/strong>HER<\/strong>\u6027\u80fd\uff0c\u4ec5\u9700<\/strong>1.47 V<\/strong>\uff08<\/strong>vs. RHE<\/strong>\uff09\u548c<\/strong>111 mV<\/strong>\u8fc7\u7535\u4f4d\u5c31\u80fd\u5206\u522b\u5b9e\u73b0<\/strong>400 mA\/cm2<\/sup><\/strong>\u548c<\/strong>\u00a010 mA\/cm2<\/sup><\/strong>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u5e76\u4e14\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u5e76\u4e14\u53ef\u4ee5\u7531\u5355\u8282\u5e72\u7535\u6c60\u76f4\u63a5\u9a71\u52a8\uff08\u5177\u6709\u7535\u538b<\/strong>\u22481.5 V<\/strong>\uff09\u3002<\/strong><\/p>\n

\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/span><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1 <\/strong>a) N-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\/NF\u7535\u6781\u7684\u5408\u6210\u793a\u610f\u56fe\u3002b) XRD\u56fe\u8c31\u3002c,d) SEM\u548ce,f) TEM\u56fe\u50cf\u3002g) HRTEM\u5206\u6790\u3002h)\u9ad8\u89d2\u5ea6\u73af\u5f62\u6697\u573a\u626b\u63cfTEM (HAADF-STEM)\u56fe\u53ca\u76f8\u5e94\u5143\u7d20\u6620\u5c04\u56fe\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2<\/strong> Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\/NF\u548cN-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u7684XPS\u8868\u5f81\u3002a) \u5168\u5149\u8c31\u548cb) Co 2p, c) Ni 2p, d) S 2p, e) N 1s\u7684\u9ad8\u5206\u8fa8\u7387\u5149\u8c31\u3002\u00a9 2023 Wiley<\/strong>\"\"<\/p>\n

\u56fe<\/strong>3<\/strong> N-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\/NF\u50ac\u5316\u5242\u7684\u7535\u5316\u5b66UOR\u548cHER\u6027\u80fd\u3002OER\u548cUOR\u7684a) \u6781\u5316\u66f2\u7ebf\u548cb)\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5bf9\u5e94\u7535\u4f4d\u3002c) \u57281 M KOH + 0.5 M\u5c3f\u7d20\u6eb6\u6db2\u4e2d\u5404\u79cd\u50ac\u5316\u5242\u7684UOR\u6781\u5316\u66f2\u7ebf\u3002d) \u4e0d\u540c\u50ac\u5316\u5242\u57281 M KOH\u4e2dHER\u7684\u6781\u5316\u66f2\u7ebf\u548ce) \u76f8\u5e94\u7684Tafel\u56fe\u3002f) N-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\/NF\u7684 2000\u6b21CV\u5faa\u73af\u524d\u540e\u7684\u6781\u5316\u66f2\u7ebf\u3002g) N-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\/NF\u7535\u6781\u5bf9UOR\u548cHER\u7684\u957f\u671f\u7a33\u5b9a\u6027\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4<\/strong> N-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\/NF\u7535\u6781\u7684\u5c3f\u7d20\u7535\u89e3\u6027\u80fd\u3002a) \u4f7f\u7528N-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\/NF\u4f5c\u4e3a\u9633\u6781\u548c\u9634\u6781\u7684\u5c3f\u7d20\u7535\u89e3\u69fd\u793a\u610f\u56fe\u3002\u5728\u5c3f\u7d20\u548c\u6c34\u7535\u89e3\u7684b) \u6781\u5316\u66f2\u7ebf\u548cc) \u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5bf9\u5e94\u7684\u7535\u6c60\u7535\u538b\u3002 d) \u5c3f\u7d20\u7535\u89e3\u4e2dH2<\/sub>\u7684\u7406\u8bba\u8ba1\u7b97\u91cf\u548c\u5b9e\u9a8c\u6d4b\u5b9a\u91cf\u3002e) \u5c3f\u7d20\u7535\u89e3\u7684\u957f\u671f\u7a33\u5b9a\u6027 (\u63d2\u56fe\u4e3aHER\u548cUOR\u6d4b\u8bd5\u524d\u540eN-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\/NF\u7535\u6781\u7684SEM\u56fe)\u3002f) \u7531\u989d\u5b9a1.5 V\u7535\u6c60\u63d0\u4f9b\u7535\u529b\u7684\u53cc\u7535\u6781\u5c3f\u7d20\u7535\u89e3\u7cfb\u7edf\u56fe\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5<\/strong> N-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\/NF\u7535\u6781UOR\u548cHER\u6d4b\u8bd5\u540e\u7684\u8868\u5f81\u3002 a) TEM, b) HRTEM\u56fe\uff0cc) UOR\u540eHAADF-STEM\u56fe\u50cf\u53ca\u76f8\u5e94\u5143\u7d20\u6620\u5c04\u3002d) TEM, e) HRTEM\u56fe\u50cf\uff0cf) HER\u540eHAADF-STEM\u56fe\u50cf\u53ca\u76f8\u5e94\u5143\u7d20\u6620\u5c04\u3002g) XRD\u56fe\u3002h) \u62c9\u66fc\u5149\u8c31\u3002\u7535\u89e3\u524d\u540ei) Ni 2p\u548cj) Ni 2p\u7684\u9ad8\u5206\u8fa8\u7387\u5149\u8c31\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>6<\/strong> a,b) Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u548cc,d) N-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u7684\u539f\u5b50\u7ed3\u6784\u6a21\u578b\u9876\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\u3002e) Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u548cN-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u7684HER\u5409\u5e03\u65af\u81ea\u7531\u80fd\u56fe\u3002f) Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u548cN-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u7684DOS\u56fe\u3002g, h) Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u548cN-Co9<\/sub>S8<\/sub>\/Ni3<\/sub>S2<\/sub>\u7684\u6c34\u548c\u5c3f\u7d20\u5438\u9644\u80fd\u56fe\u3002\u00a9 2023 Wiley<\/strong><\/p>\n

 <\/p>\n

\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/span><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u8be5\u5de5\u4f5c\u8bc1\u660e\u4e86\u6c2e\u63ba\u6742\u7684\u94b4\u954d\u57fa\u786b\u5316\u7269\u5bf9UOR\u548cHER\u5177\u6709\u9ad8\u6548\u7684\u50ac\u5316\u6027\u80fd\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8be5\u7814\u7a76\u4e0d\u4ec5\u63d0\u4f9b\u4e86\u4e00\u79cd\u9ad8\u6027\u80fd\u7684\u7535\u89e3\u6c34\u50ac\u5316\u5242\uff0c\u540c\u65f6\u4e5f\u9610\u8ff0\u4e86\u9634\u79bb\u5b50\u63ba\u6742\u63d0\u9ad8\u6d3b\u6027\u7684\u5185\u5728\u673a\u7406\uff0c\u4ece\u800c\u4e3a\u8fc7\u6e21\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\u5e94\u7528\u4e8e\u5c0f\u5206\u5b50\u6c27\u5316\u53cd\u5e94\u8f85\u52a9\u8282\u80fd\u5236\u6c22\u63d0\u4f9b\u4e86\u4e00\u5b9a\u7684\u8bbe\u8ba1\u601d\u8def\u548c\u53d1\u5c55\u65b9\u5411\u3002<\/strong><\/p>\n

\u00a0<\/strong><\/p>\n

\u539f\u6587\u8be6\u60c5\uff1a<\/strong>https:\/\/doi.org\/10.1002\/smll.202207425<\/a><\/p>\n

\u672c\u6587\u7531K . L\u64b0\u7a3f\u3002<\/p>\n

 <\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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