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 <\/p>\n

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\"\"<\/p>\n

 <\/p>\n

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 <\/p>\n

\u56db\u3001<\/b><\/strong>\u6570\u636e\u6982\u89c8<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1 <\/b><\/strong>\u00a0a) PFC-8\u548cPFC-8 350\u7684TGA\u66f2\u7ebf\uff0cb)PFC-8\u548cPFC-8 350\u7684\u6574\u4f53XPS\u5149\u8c31\uff0cc)PFC-8\u548cPFC-8 350\u7684\u9ad8\u5206\u8fa8\u7387N 1s XPS\u5149\u8c31\uff0cd)PFC-8\u548cPFC-8 350\u7684\u9ad8\u5206\u8fa8\u7387Ni 2p XPS\u5149\u8c31\uff0ce)PFC-8\u548cPFC-8 350\u7684 XRD\u66f2\u7ebf\uff0cf)PFC-8\u548cPFC-8 350\u5bf9\u5e94\u7684\u5cf0\u503c\u5f3a\u5ea6\u6bd4\u503c,g)\u548cj)PFC-8 350\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf,h)PFC-8\u6846\u67b6\u4e0d\u540c\u6676\u9762\u7684\u539f\u5b50\u7ed3\u6784\u56fe,<\/b><\/strong>\u00a0<\/b><\/strong>i)PFC-8\u6846\u67b6\u4e2d(110)\u6676\u9762\u56fe,k)PFC-8\u6846\u67b6\u4e2d(200)\u6676\u9762\u56fe,l)PFC-8\u6846\u67b6\u4e2d(020)\u6676\u9762\u56fe <\/b><\/strong>\u00a9 <\/b><\/strong>2022 Wiley-VCH GmbH<\/b><\/strong><\/p>\n

 <\/p>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

\u56fe2<\/b><\/strong>\u00a0<\/b><\/strong>\u00a0<\/b><\/strong>a)PFC-8\u548cPFC-8 350\u57285mVs<\/b><\/strong>-1<\/b><\/sup><\/strong>\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\uff0cb)PFC-8\u548cPFC-8 350\u7684\u901f\u7387\u6027\u80fd\u66f2\u7ebf\uff0cc)PFC-8 350 \u548cd)PFC-8\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684GCD\u66f2\u7ebf\uff0ce)Zn||PFC-8 350\u7535\u6c60\u5728\u4ece1\u52305mVs<\/b><\/strong>-1<\/b><\/sup><\/strong>\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\uff0cf\uff09\u5cf01\u3001g\uff09\u5cf02\u548ch\uff09\u5cf03\u7684log (i)\u548clog (v)\u4e4b\u95f4\u7684\u62df\u5408\u56fe\uff0ci) Ragone\u56fe\u6bd4\u8f83\u4e86Zn||PFC-8 350\u7535\u6c60\u4e0e\u5176\u4ed6\u78b1\u6027\u6c34\u7cfb\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u529f\u7387\u5bc6\u5ea6\u548c\u5bf9\u5e94\u80fd\u91cf\u5bc6\u5ea6\uff0cj)PFC-8\u548cPFC-8 350\u7535\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10Ag<\/b><\/strong>-1<\/b><\/sup><\/strong>\u4e0b\u7684\u5faa\u73af\u6027\u80fd <\/b><\/strong>\u00a9 <\/b><\/strong>2022 Wiley-VCH GmbH<\/b><\/strong><\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe3 \u00a0<\/b><\/strong>a)\u5145\u653e\u7535\u66f2\u7ebf\u548c\u76f8\u5e94\u7684<\/b><\/strong>\u6b63\u6781<\/b><\/strong>\u6536\u96c6\u9636\u6bb5\uff0cb)\u9ad8\u5206\u8fa8\u7387N 1s XPS\u8c31\uff0cc)\u9ad8\u5206\u8fa8\u7387Ni 2p XPS\u8c31\uff0cd)PFC-8 350 \u9634\u6781\u5728\u4e0d\u540c\u5145\u653e\u7535\u6df1\u5ea6\u4e0b\u7684FTIR\u66f2\u7ebf\uff0ce)PFC-8 350 \u9634\u6781\u7684\u4e24\u6b65\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u793a\u610f\u56fe <\/b><\/strong>\u00a9 <\/b><\/strong>2022 Wiley-VCH GmbH<\/b><\/strong><\/p>\n

\u00a0<\/b><\/strong><\/p>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

\u56fe4 <\/b><\/strong>\u00a0a-e)\u5438\u9644OH<\/b><\/strong>–<\/b><\/sup><\/strong>\u57fa\u56e2\u540e\u5177\u6709\u4e0d\u540c\u5207\u9762\u7684PFC-8\u677f\u7684\u539f\u5b50\u7ed3\u6784\u4fa7\u89c6\u56fe\uff0cf)OH<\/b><\/strong>–<\/b><\/sup><\/strong>\u5728\u4e0d\u540c\u8868\u9762\u4e0a\u7684\u5438\u9644\u80fd\uff0cg-i\uff09\u7531\u8fd9\u4e24\u4e2a\u5e73\u9762\u7ec4\u6210\u7684\uff08110\uff09\uff08020\uff09\u548c\uff08200\uff09\u5e73\u9762\u7684\u72b6\u6001\u56fe\u7684\u5bc6\u5ea6 <\/b><\/strong>\u00a9 <\/b><\/strong>2022 Wiley-VCH GmbH<\/b><\/strong><\/p>\n

\u00a0<\/b><\/strong><\/p>\n

\u4e94\u3001<\/b><\/strong>\u6210\u679c\u542f\u793a<\/b><\/strong><\/p>\n

MOFs\u4f5c\u4e3a\u4e00\u79cd\u5f88\u6709\u53d1\u5c55\u6f5c\u529b\u7684\u5145\u7535\u7535\u6c60\u7535\u6781\u6750\u6599\u8d8a\u6765\u8d8a\u88ab\u5e7f\u6cdb\u5e94\u7528\uff0c\u4f46\u5927\u591a\u6570\u90fd\u4ec5\u5c40\u9650\u4e8e\u76f4\u63a5\u4f7f\u7528\uff0c\u6ca1\u6709\u8fdb\u4e00\u6b65\u7684\u4f18\u5316\u6539\u6027\uff0c\u672c\u6587\u901a\u8fc7\u7b80\u5355\u7684\u70ed\u4fee\u9970\u7b56\u7565\u8c03\u8282\u4e3b\u66b4\u9732\u9762\uff0c\u4f7f\u5f97\u7535\u6c60\u8868\u73b0\u51fa\u826f\u597d\u7684\u901f\u7387\u6027\u80fd\u548c\u957f\u671f\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u4e3a\u8c03\u8282\u7535\u6c60\u7684MOF\u57fa\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u6253\u5f00\u4e86\u65b0\u7684\u5927\u95e8\uff0c\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

 <\/p>\n

\u539f\u6587\u8be6\u60c5<\/b><\/strong>\uff1a<\/b><\/strong>https:\/\/doi.org\/10.1002\/anie.202209794<\/p>\n

\u672c\u6587\u7531meiweifengmaozi\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"

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