{"id":247329,"date":"2023-02-28T06:12:24","date_gmt":"2023-02-27T22:12:24","guid":{"rendered":"\/\/m.iemloyee.com\/?p=247329"},"modified":"2023-02-27T11:12:50","modified_gmt":"2023-02-27T03:12:50","slug":"angew-chem-int-ed-%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e7%ac%bc%e5%8a%9f%e8%83%bd%e7%9a%84%e7%a7%81%e4%ba%ba%e5%ae%9a%e5%88%b6%ef%bc%88%e6%89%8b%e6%80%a7%e3%80%81aie%e5%92%8ccpl","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=247329","title":{"rendered":"Angew. Chem. Int. Ed.: \u91d1\u5c5e\u6709\u673a\u7b3c\u529f\u80fd\u7684\u201c\u79c1\u4eba\u5b9a\u5236\u201d\uff08\u624b\u6027\u3001AIE\u548cCPL\uff09"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u91d1\u5c5e\u6709\u673a\u7b3c\uff08MOC\uff09\uff0c\u5373\u901a\u8fc7\u6709\u673a\u914d\u4f53\u4e0e\u91d1\u5c5e\u79bb\u5b50\u914d\u4f4d\u5f62\u6210\u7684\u5177\u6709\u53ef\u8c03\u7684\u51e0\u4f55\u5f62\u72b6\u3001\u5c3a\u5bf8\u548c\u72ec\u7279\u9650\u57df\u7a7a\u8154\u7684\u8d85\u5206\u5b50\u6750\u6599\u3002\u5176\u901a\u8fc7\u529f\u80fd\u5316\u6240\u5f97\u4ea7\u7269\u5728\u8bf8\u5982\u50ac\u5316\u3001\u5206\u5b50\u8bc6\u522b\u3001\u8367\u5149\u8c03\u63a7\u3001\u836f\u7269\u91ca\u653e\u53ca\u751f\u7269\u533b\u836f\u7b49\u65b9\u9762\u8868\u73b0\u51fa\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u4f46\u662f\uff0c\u6784\u7b51MOC\u7684\u914d\u4f53\u5f80\u5f80\u9700\u8981\u5728\u82db\u523b\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\u8fdb\u884c\u590d\u6742\u7e41\u7410\u7684\u6709\u673a\u5408\u6210\u64cd\u4f5c\uff0c\u8fd9\u4e00\u5b9a\u7a0b\u5ea6\u9650\u5236\u4e86\u529f\u80fd\u6027MOC\u7684\u53d1\u5c55\u3002\u5728\u6e29\u548c\u53cd\u5e94\u6761\u4ef6\u4e0b\u8fdb\u884c\u540e\u5408\u6210\u4fee\u9970\uff08PSM\uff09\u4e3aMOC\u529f\u80fd\u5316\u63d0\u4f9b\u4e86\u53ef\u80fd\uff0c\u4f46\u662fPSM\u8fc7\u7a0b\u4e2d\u5f88\u5bb9\u6613\u5f15\u8d77MOC\u4f53\u7cfb\u4e2d\u7684\u52a8\u6001\u76f8\u4e92\u4f5c\u7528\uff0c\u8fdb\u800c\u7834\u574fMOC\u7684\u7ed3\u6784\u3002\u76ee\u524d\u53d1\u5c55MOC\u7684\u529f\u80fd\u5316\u4fee\u9970\u7684\u666e\u9002\u6027\u65b9\u6cd5\u8fd8\u5b58\u5728\u6311\u6218\uff0c\u8fd9\u5f88\u5927\u7a0b\u5ea6\u9650\u5236\u4e86MOC\u6750\u6599\u7684\u6784\u7b51\u548c\u5e94\u7528\u5f00\u53d1\u3002<\/p>\n

\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u671f\uff0c\u66a8\u5357\u5927\u5b66\u5468\u5c0f\u5e73<\/strong>\/<\/strong>\u674e\u4e39\u6559\u6388\u56e2\u961f<\/strong>\u53d1\u5c55\u4e86\u4e00\u79cd\u901a\u7528\u7684\u91d1\u5c5e\u6709\u673a\u7b3cPdn<\/sub>L2n<\/sub>\uff08n=2 \u621612\uff09\u7684\u540e\u5408\u6210\u4fee\u9970\u529f\u80fd\u5316\u65b9\u6cd5\u3002\u501f\u52a9\u84bd\u548c\u9a6c\u6765\u9170\u4e9a\u80fa\u57fa\u56e2\u53ef\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u53d1\u751f[4+2] Diels-Alder\u73af\u52a0\u6210\u53cd\u5e94\u7684\u7279\u70b9\uff0c\u5728\u9884\u5408\u6210\u542b\u6709\u84bd\u57fa\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\u4e0a\u6709\u6548\u63a5\u679d\u5404\u79cd\u5b98\u80fd\u56e2\uff08\u5982\u73af\u5df1\u57fa\u3001\u03b1-\u82ef\u4e59\u57fa\u3001\u624b\u6027\u8054\u8418\u915a\u3001\u56db\u82ef\u57fa\u4e59\u70ef\u57fa\u548c\u8298\u53d6\u4ee3\u57fa\uff09\uff0c\u5b9e\u73b0\u4e86\u5bf9Pdn<\/sub>L2n<\/sub>\u578bMOC\u6750\u6599\u7684\u529f\u80fd\u5b9a\u5236\u3002\u5177\u4f53\u5730\uff0c\u73af\u5df1\u57fa\u4fee\u9970\u7684MOC\u7684\u6eb6\u89e3\u5ea6\u5f97\u5230\u4e86\u6781\u5927\u7684\u6539\u5584\uff1b\u624b\u6027\u8054\u8418\u915a\uff08BINOL\uff09\u4fee\u9970\u7684MOC\u5177\u6709\u624b\u6027\u548c\u6d53\u5ea6\u4f9d\u8d56\u7684\u5706\u4e8c\u8272\u6027\uff08CD\uff09\uff1b\u56db\u82ef\u57fa\u4e59\u70ef\u57fa\u4fee\u9970\u7684MOC\u8868\u73b0\u51fa\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\uff08AIE\uff09\u7279\u6027\u3002\u66f4\u6709\u8da3\u7684\u662f\uff0c\u901a\u8fc7\u5206\u6b65\u540e\u5408\u6210\u4fee\u9970\u65b9\u6cd5\uff0c\u53ef\u4ee5\u5728MOC\u4e0a\u540c\u65f6\u4fee\u9970\u4e24\u79cd\u4e0d\u540c\u7c7b\u578b\u7684\u5b98\u80fd\u56e2\uff08\u4f8b\u5982\uff0c\u624b\u6027BINOL\u548c\u975e\u624b\u6027\u53d1\u8272\u56e2\u8298\uff09\uff0c\u8fd9\u53ef\u4ee5\u4f7f\u975e\u624b\u6027\u8298\u53d1\u8272\u56e2\u5728\u624b\u6027BINOL\u57fa\u56e2\u7684\u8bf1\u5bfc\u4e0b\u4ea7\u751f\u5706\u504f\u632f\u53d1\u5149\uff08CPL\uff09\u7279\u6027\u3002\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\u4ee5\u201cTailor-Made Pdn<\/sub>L2n<\/sub> Metal-Organic Cages via Covalent Post-Synthetic Modification<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aAngewandte Chemie-International Edition<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

    \n
  1. \u501f\u52a9\u84bd\u548c\u9a6c\u6765\u9170\u4e9a\u80fa\u57fa\u56e2\u53ef\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u53d1\u751f[4+2] Diels-Alder\u73af\u52a0\u6210\u53cd\u5e94\u7684\u7279\u70b9\uff0c\u5f00\u53d1\u4e86\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u901a\u7528\u578b\u529f\u80fd\u5316\u9014\u5f84\u3002<\/li>\n
  2. \u5b9e\u73b0\u4e86\u5bf9\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u529f\u80fd\u5316\u5b9a\u5236\uff0c\u6210\u529f\u83b7\u5f97\u4e86\u5206\u522b\u5177\u6709\u4e0d\u540c\u6eb6\u89e3\u6027\u3001\u5706\u4e8c\u8272\u6027\u3001\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u7279\u6027\u53ca\u5706\u504f\u632f\u53d1\u5149\u7279\u6027\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\u3002<\/li>\n<\/ol>\n

    \u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

    \"\"<\/p>\n

    \u793a\u610f\u56fe<\/strong>1. <\/strong>\u901a\u8fc7Diels-Alder\u73af\u52a0\u6210\u53cd\u5e94\u5bf9Pd12<\/sub>L24<\/sub>\u91d1\u5c5e\u6709\u673a\u7b3c\u8fdb\u884c\u5171\u4ef7\u540e\u5408\u6210\u4fee\u9970\u4ee5\u5f15\u5165\u5b9a\u5236\u5b98\u80fd\u56e2\u3002\u00a9Wiley-VCH<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>1.<\/strong>\uff08a\uff091\u53f7\u6837\u54c1\u76841<\/sup>H NMR\u548cDOSY\u8c31\u56fe\u3002\uff08b\uff091\u53f7\u6837\u54c1\u7684ESI-TOF\u8d28\u8c31\u56fe\u3002\u63d2\u56fe\u663e\u793am\/z = 1598.1909\u59049+\u5cf0\u7684\u6a21\u62df\uff08\u7ea2\u8272\uff09\u548c\u5b9e\u9a8c\uff08\u84dd\u8272\uff09\u540c\u4f4d\u7d20\u8d28\u8c31\u5cf0\uff0c\u5bf9\u5e94\u4e8e[Pd12<\/sub>(L1)24<\/sub>(OTf)15<\/sub>]9+<\/sup>\u3002\u00a9 Wiley-VCH<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>2. <\/strong>\u901a\u8fc7\u540e\u5408\u6210\u4fee\u9970\u7684\u65b9\u6cd5\u6784\u5efa\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\uff08a\uff091\u53f7\u6837\u54c1\u548c\uff08b\uff092\u53f7\u6837\u54c11<\/sup>H NMR\u8c31\u56fe\u3002\u901a\u8fc7\u6d88\u89e3\u91d1\u5c5e\u6709\u673a\u7b3c2\u53f7\u6837\u54c1\u83b7\u5f97\u7684\u914d\u4f53\uff08c\uff09L2\u548c\u914d\u4f53\uff08d\uff09L1\u76841<\/sup>H NMR\u8c31\u56fe\u3002\u7ea2\u8272\u865a\u7ebf\u5bf9\u5e94\u4e8e\u84bd\u73af\uff08Hf<\/sub>\uff09\u768410\u53f7\u4f4d\u6c22\u539f\u5b50\u5cf0\u3002\u84dd\u8272\u865a\u7ebf\u5bf9\u5e94\u4e8e\u4e0e\u84bd\u73af\uff08Hf<\/sub>\uff09\u76f8\u8fde\u7684\u4e9a\u7532\u57fa\u7684\u5cf0\u3002\u00a9 Wiley-VCH<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>3.<\/strong>\uff08a\uff091\u3001\uff08b\uff093\u3001\uff08c\uff094-R\u3001\uff08d\uff095\u548c\uff08e\uff096\u53f7\u4fee\u9970\u4e0d\u540c\u529f\u80fd\u57fa\u56e2\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\u6837\u54c1\u76841<\/sup>H NMR\u8c31\u56fe\u3002\u7ea2\u8272\u865a\u7ebf\u5bf9\u5e94\u4e8e\u84bd\u73af\uff08Hf<\/sub>\uff09\u768410\u53f7\u4f4d\u6c22\u539f\u5b50\u5cf0\u3002\u84dd\u8272\u865a\u7ebf\u5bf9\u5e94\u4e8e\u4e0e\u84bd\u73af\uff08Hf<\/sub>\uff09\u76f8\u8fde\u7684\u4e9a\u7532\u57fa\u7684\u5cf0\u3002\u00a9Wiley-VCH<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>4.<\/strong>\uff08a\uff091\u3001\uff08b\uff092\u3001\uff08c\uff093\u3001\uff08d\uff094-R\u3001\uff08e\uff095 \u548c\uff08f\uff096 \u53f7\u4fee\u9970\u4e0d\u540c\u529f\u80fd\u57fa\u56e2\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\u6837\u54c1\u7684\u5206\u5b50\u4f18\u5316\u6a21\u578b\u3002\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u529f\u80fd\u5316\u57fa\u56e2\u4ee5\u6df1\u7eff\u8272\u7a81\u51fa\u663e\u793a\u3002\u00a9 Wiley-VCH<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>5. <\/strong>CH2<\/sub>Cl2<\/sub>\u4e2d\u4e0d\u540c\u6d53\u5ea6\u76844-R\uff08\u7ea2\u8272\u5b9e\u7ebf\uff09\u548c4-S\uff08\u84dd\u8272\u5b9e\u7ebf\uff09\u6837\u54c1\u7684CD\u5149\u8c31\u3002\u7eff\u8272\u865a\u7ebf\u7bad\u5934\u8868\u793aCD\u4fe1\u53f7\u5728300 nm-350 nm\u8303\u56f4\u5185\u7684\u53d8\u5316\u8d8b\u52bf\u3002\u00a9Wiley-VCH<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>6.<\/strong>\uff08a\uff09\u6d53\u5ea6\u4e3a1.0\u00d710-6<\/sup> M\u76845\u53f7\u529f\u80fd\u5316\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\u6837\u54c1\u5728\u542b\u6709\u4e0d\u540c\u6b63\u5df1\u70f7\u6bd4\u4f8b\u7684CH2<\/sub>Cl2<\/sub> \/\u6b63\u5df1\u70f7\u6df7\u5408\u7269\u4e2d\u7684\u53d1\u5c04\u5149\u8c31 (\u03bbex<\/sub> = 350 nm)\u3002\uff08b\uff09\u5728365 nm\u6fc0\u53d1\u4e0b\uff0c5\u53f7\u6837\u54c1\u5728\u542b\u6709\u4e0d\u540c\u6b63\u5df1\u70f7\u6bd4\u4f8b\u7684CH2<\/sub>Cl2<\/sub> \/\u6b63\u5df1\u70f7\u6df7\u5408\u7269\u4e2d\u7684\u7167\u7247\u3002\u00a9Wiley-VCH<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>7.<\/strong>\uff08a\uff091\u53f7\u91d1\u5c5e\u6709\u673a\u7b3c\u6837\u54c1\u901a\u8fc7\u5206\u6b65\u540e\u5408\u6210\u4fee\u9970\u83b7\u5f97\u5177\u6709\u4e24\u79cd\u4e0d\u540c\u529f\u80fd\u57fa\u56e2\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u56fe\u793a\u3002\uff08b\uff097-R\u30017-R’\u30017-S\u548c7-S’\u5728\u6d53\u5ea6\u4e3a1\u00b410-5<\/sup> M\u7684DMSO\u6eb6\u6db2\u4e2d\u7684\uff08b\uff09CD\u5149\u8c31\u548c\uff08c\uff09\u5f52\u4e00\u5316\u53d1\u5c04\u5149\u8c31\u30027-R\u548c7-S\u7684\u6fc0\u53d1\u6ce2\u957f\u4e3a350 nm\uff0c7-R’\u548c7-S’\u7684\u6fc0\u53d1\u6ce2\u957f\u4e3a387 nm\u3002\uff08d\uff097-R\u548c7-S\u5728\u6d53\u5ea6\u4e3a1.0\u00d710-5 <\/sup>M\u7684DMSO\u6eb6\u6db2\u4e2d\u7684CPL\u5149\u8c31\uff08\u03bbex <\/sub>= 320 nm\uff09\u3002\u00a9Wiley-VCH<\/p>\n

    \"\"<\/p>\n

    \u56fe<\/strong>8.<\/strong>\uff08a\uff09\u901a\u8fc7Diels-Alder\u53cd\u5e94\u5bf9Pd2<\/sub>L4<\/sub>\u578b\u91d1\u5c5e\u6709\u673a\u7b3c\u8fdb\u884c\u5171\u4ef7\u540e\u5408\u6210\u4fee\u9970\u7684\u793a\u610f\u56fe\u3002\uff08b\uff09\u529f\u80fd\u5316\u7684\u91d1\u5c5e\u6709\u673a\u7b3c8\u30019\u300110-R\u548c11\u53f7\u6837\u54c1\u76841<\/sup>H NMR\u8c31\u56fe\u3002\u7ea2\u8272\u865a\u7ebf\u5bf9\u5e94\u4e8e\u84bd\u73af\uff08Hf<\/sub>\uff09\u768410\u53f7\u4f4d\u6c22\u539f\u5b50\u5cf0\u3002\u84dd\u8272\u865a\u7ebf\u5bf9\u5e94\u4e8e\u4e0e\u84bd\u73af\uff08Hf<\/sub>\uff09\u76f8\u8fde\u7684\u4e9a\u7532\u57fa\u7684\u5cf0\u3002\u00a9Wiley-VCH<\/p>\n

    \u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

    \u8be5\u5de5\u4f5c\u501f\u52a9\u84bd\u548c\u9a6c\u6765\u9170\u4e9a\u80fa\u57fa\u56e2\u53ef\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u53d1\u751f[4+2] Diels-Alder\u73af\u52a0\u6210\u53cd\u5e94\u7684\u9ad8\u6548\u6027\uff0c\u901a\u8fc7\u5171\u4ef7\u5408\u6210\u540e\u4fee\u9970\u9014\u5f84\u660e\u786e\u6784\u5efa\u4e86\u4e00\u7cfb\u5217\u529f\u80fd\u5316\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\uff0c\u5e76\u5177\u6709\u76f8\u5f53\u9ad8\u7684\u4ea7\u7387\u3002\u4e0e\u91d1\u5c5e\u6709\u673a\u7b3c\u6846\u67b6\u76f8\u6bd4\uff0c\u529f\u80fd\u5316\u4fee\u9970\u7684\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u5f97\u5230\u4e86\u663e\u8457\u8c03\u8282\uff0c\u5e76\u4e14\u83b7\u5f97\u4e86\u65b0\u7684\u529f\u80fd\uff08\u4f8b\u5982\uff0c\u6d53\u5ea6\u4f9d\u8d56\u7684\u5706\u4e8c\u8272\u6027\u3001AIE\u548c\u624b\u6027\u8bf1\u5bfc\u7684CPL\uff09\u3002\u901a\u8fc7\u540e\u5408\u6210\u4fee\u9970\u529f\u80fd\u5316\u7684\u65b9\u6cd5\u53ef\u4ee5\u8f7b\u677e\u5b9e\u73b0\u529f\u80fd\u5b9a\u5236\uff0c\u4e3a\u8bbe\u8ba1\u548c\u5408\u6210\u57fa\u4e8e\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u5148\u8fdb\u6750\u6599\u63d0\u4f9b\u4e86\u4e00\u4e2a\u901a\u7528\u7b56\u7565\u548c\u65b0\u7684\u5408\u6210\u5e73\u53f0\u3002<\/p>\n

     <\/p>\n

    \u539f\u6587\u8be6\u60c5\uff1a<\/strong>https:\/\/doi.org\/10.1002\/anie.202216977<\/a><\/p>\n

     <\/p>\n

    \u672c\u6587\u7531\u6750\u6599\u4eba\u8521\u4f73\u84c9\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

    \u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u91d1\u5c5e\u6709\u673a\u7b3c\uff08MOC\uff09\uff0c\u5373\u901a\u8fc7\u6709\u673a\u914d\u4f53\u4e0e\u91d1\u5c5e\u79bb\u5b50\u914d\u4f4d\u5f62\u6210\u7684\u5177\u6709\u53ef\u8c03\u7684\u51e0\u4f55\u5f62\u72b6\u3001\u5c3a\u5bf8\u548c\u72ec\u7279\u9650\u57df\u7a7a\u8154\u7684\u8d85\u5206\u5b50\u6750\u6599\u3002\u5176\u901a\u8fc7\u529f\u80fd\u5316\u6240\u5f97\u4ea7\u7269\u5728\u8bf8\u5982\u50ac\u5316\u3001\u5206\u5b50\u8bc6…<\/p>\n","protected":false},"author":49583,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2,67],"tags":[5001,5000,4999],"class_list":["post-247329","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","category-zhoubao","tag-5001","tag-5000","tag-4999"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/247329"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/49583"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=247329"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/247329\/revisions"}],"predecessor-version":[{"id":247938,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/247329\/revisions\/247938"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=247329"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=247329"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=247329"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}