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\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

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\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

    \n
  1. \u672c\u6587\u901a\u8fc7\u8109\u51b2\u7535\u6c89\u79ef\u5408\u6210\u4e86\u542b\u6709Fe\u3001Co\u3001Ni\u3001Cu\u548cMo\u7684\u9ad8\u71b5\u5408\u91d1\u3002<\/li>\n
  2. H-FeCoNiCuMo\u5bf9\u5168pH\u8303\u56f4\u7684\u6c34\u89e3\u5177\u6709\u50ac\u5316\u4f5c\u7528\u3002\u5728\u78b1\u6027HER\u548cOER\uff0c\u4ee5\u53ca\u9178\u6027HER\u4e2d\u8868\u73b0\u51fa\u8d85\u4f4e\u7684\u03b710<\/sub>\uff0c\uff08\u03b7x<\/sub>\u7684\u5b9a\u4e49\u4e3a\u8fbe\u5230x mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u6240\u9700\u7684\u8fc7\u7535\u4f4d\uff09\u3002<\/li>\n
  3. \u4f5c\u8005\u901a\u8fc7\u673a\u7406\u5206\u6790\u5728\u539f\u5b50\u5c3a\u5ea6\u4e0a\u89e3\u91ca\u4e86\u8be5\u50ac\u5316\u5242\u5177\u6709\u5353\u8d8a\u6027\u80fd\u7684\u5185\u5728\u539f\u56e0\u3002<\/li>\n<\/ol>\n

    \u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

    \"\"\u56fe<\/strong>1.<\/strong> H-FeCoNiCuMo\u7684\u5236\u5907\u5de5\u827a\u53ca\u5176\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81\u3002\u00a9 2023 Applied Catalysis B.<\/strong><\/p>\n

    \u5982\u56fe<\/strong>1<\/strong>A\u6240\u793a\uff0c\u91c7\u7528\u5408\u9002\u914d\u6bd4\u7684\u524d\u9a71\u4f53\u7535\u89e3\u8d28\uff0c\u901a\u8fc7\u8109\u51b2\u7535\u6d41\u7535\u6c89\u79ef\u6cd5\u5728\u6ce1\u6cab\u954d\u9aa8\u67b6\u8868\u9762\u6c89\u79efFe Co Ni Cu Mo\u9ad8\u71b5\u5408\u91d1\uff0c\u5236\u5907H-FeCoNiCuMo\u7535\u6781\u3002\u4f5c\u4e3a\u5bf9\u6bd4\uff0c\u4f5c\u8005\u8fd8\u5236\u4f5c\u4e86\u76f8\u5e94\u76844\u79cd\u91d1\u5c5e\u5143\u7d20\u7684\u4e2d\u71b5\u5408\u91d1\uff08MEA\uff09\u7535\u6781\u3002\u56fe<\/strong>1<\/strong>B\u663e\u793a\u5236\u5907\u7684HEA\u5177\u6709\u4e09\u7ef4\u6811\u679d\u72b6\u7ed3\u6784\u3002\u901a\u8fc7\u56fe<\/strong>1<\/strong>C\u53d1\u73b0 Fe Co Ni Cu Mo\u9ad8\u71b5\u5408\u91d1\u5177\u6709\u5355\u4e00\u7684\u9762\u5fc3\u7acb\u65b9\uff08FCC\uff09\u76f8\uff0c\u8fd9\u8868\u660e\u5236\u5907\u7684HEA\u662f\u539f\u5b50\u7ea7\u5747\u5300\u6df7\u5408\u7684\u3002\u901a\u8fc7\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u955c\uff08HRTEM\uff09\u786e\u5b9a\u5176\u6676\u9762\u95f4\u8ddd\u4e3a0.21\u2009nm \uff08111\uff09\u6676\u9762\u548c0.181\u2009nm \uff08220\uff09\u6676\u9762\u3002\u6839\u636eVegard\u89c4\u5219\u4f30\u7b97\u7684\u6676\u683c\u5e38\u6570\u4e3a0.366\u2009nm\uff0c\u8fd9\u4e0e\u56fe<\/strong>1<\/strong>E\u4e2dXRD\u6d4b\u5f97\u76840.363\u2009nm\u975e\u5e38\u543b\u5408\uff0c\u901a\u8fc7\u56fe<\/strong>1<\/strong>D\u7684\u5143\u7d20mapping\u56fe\u8c31\u53ef\u4ee5\u53d1\u73b05\u79cd\u5143\u7d20\u5206\u5e03\u5747\u5300\u3002<\/p>\n

    \"\"\u56fe<\/strong>2.<\/strong> \u4e2d\u71b5\u548c\u9ad8\u71b5\u5408\u91d1\u7684\u7535\u50ac\u5316\u6c34\u89e3\u6027\u80fd\u6bd4\u8f83\u3002\u00a9 2023 Applied Catalysis B.<\/strong><\/p>\n

    \u4f5c\u8005\u57281M KOH\u548c0.5M H2<\/sub>SO4<\/sub>\u4e2d\u7814\u7a76\u4e86HEA\u7535\u6781\u7684HER\u7535\u50ac\u5316\u6027\u80fd\uff0c\u57281M KOH\u4e2d\u7814\u7a76OER\u6027\u80fd\u3002\u56fe<\/strong>2<\/strong>A\uff0cB\u663e\u793a\u4e86HEA\u548c\u5bf9\u7167\u6837\u54c1\u57281 M KOH\u4e2d\u4ee51 mV s-1<\/sup>\u7684\u626b\u901f\u4e0bHER\u548cOER\u6027\u80fd\u7684LSV\u66f2\u7ebf\u3002M-CoNiCuMo\u548cH-FeCoNiCuMo\u90fd\u53d6\u5f97\u4e86\u8d85\u4f4e\u7684\u8fc7\u7535\u4f4d\u3002\u90fd\u4f4e\u4e8e\u8fd1\u5e74\u6765\u62a5\u9053\u7684\u6027\u80fd\u4f18\u8d8a\u7684HER\u7535\u50ac\u5316\u5242\uff08\u56fe<\/strong>2<\/strong>G\uff09\u3002\u4f5c\u8005\u7814\u7a76\u53d1\u73b0Fe\u5728\u5408\u91d1\u4e2d\u5bf9\u78b1\u6027\u4ecb\u8d28\u4e2d\u7684HER\u8d77\u7740\u8d1f\u9762\u4f5c\u7528\uff0cH-FeCoNiCuMo\u4e2dFe\u7684\u5b58\u5728\u6291\u5236\u4e86Co\u3001Ni\u3001Cu\u548cMo\u4e4b\u95f4\u7684\u534f\u540c\u6548\u5e94\uff0c\u5bfc\u81f4H-FeCoNiCuMo\u7684\u6027\u80fd\u7565\u900a\u4e8eM-CoNiCuMo\u3002<\/p>\n

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    \u5982\u56fe<\/strong>2<\/strong>B\u6240\u793a\uff0cH-FeCoNiCuMo\u5728\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\u4e0d\u4ec5\u5c55\u793a\u51fa\u4f18\u5f02\u7684HER\u7279\u6027\uff0c\u540c\u65f6\u4e5f\u5c55\u793a\u51fa\u4e86\u4f18\u5f02\u7684OER\u7279\u6027\uff0c\u5b83\u7684\u03b710<\/sub>\u5c0f\u4e8e200 mV\uff0c\u03b7500<\/sub>\u5c0f\u4e8e300 mV\uff0c\u5c06\u5176\u4f5c\u4e3a\u78b1\u6027\u4ecb\u8d28\u4e2d\u6574\u4f53\u6c34\u89e3\u7684\u53cc\u529f\u80fd\u7535\u6781\uff0c\u5176\u6027\u80fd\u8d85\u8fc7\u4e86\u6240\u6709MEA\u7535\u6781\u548c\u5176\u4ed6\u5df2\u53d1\u8868\u6027\u80fd\u4f18\u5f02\u7684\u7535\u6781\uff08\u56fe<\/strong>2<\/strong>H\uff09\u3002Fe\u7684\u5b58\u5728\u867d\u7136\u4f7fH-FeCoNiCuMo\u5728\u78b1\u6027HER\u65b9\u9762\u900a\u8272\u4e8eM-CoNiCuMo\uff0c\u4f46\u5176\u5bf9\u4e8e\u78b1\u6027OER\u7684\u50ac\u5316\u662f\u81f3\u5173\u91cd\u8981\u7684\u3002\u57281\u4e2aHEA\u548c5\u4e2aMEA\u5bf9\u7167\u7535\u6781\u4e2d\uff0cM-FeCoNiMo\u5728\u8fc7\u7535\u4f4d\u65b9\u9762\u4e5f\u8868\u73b0\u51fa\u5353\u8d8a\u7684OER\u6027\u80fd\uff0c\u03b710<\/sub>\u548c\u03b7500<\/sub>\u4ec5\u7565\u900a\u8272\u4e8eH-FeCoNiCuMo\uff0c\u4f46\u660e\u663e\u4f18\u4e8e\u5176\u4ed6\u7684MEA\u7535\u6781\u3002\u8fd9\u610f\u5473\u7740Cu\u662f\u4e94\u79cd\u91d1\u5c5e\u5143\u7d20\u4e2d\u5bf9\u78b1\u6027OER\u76f8\u5bf9\u4e0d\u5229\u7684\u5143\u7d20\u3002\u4f5c\u8005\u53d1\u73b0\u901a\u8fc7\u52a0\u5165\u9002\u5f53Ni\u3001Co\u548cFe\u53ef\u4ee5\u589e\u5f3a\u7535\u6781OER\u6d3b\u6027\u3002\u9664\u4e86\u6700\u9ad8\u7684\u50ac\u5316\u6548\u7387\u5916\uff0cH-FeCoNiCuMo\u8fd8\u62e5\u6709\u6700\u9ad8\u7684\u50ac\u5316\u52a8\u529b\u5b66\u6548\u7387\u3001\u5e73\u5747\u5185\u5728\u6d3b\u6027\u548c\u7535\u8377\u8f6c\u79fb\u6548\u7387\uff08\u56fe<\/strong>2<\/strong>E\u53ca\u5176\u4ed6\u652f\u6491\u6750\u6599\uff09\u3002<\/p>\n

    \u7f3a\u9677\u7684\u5b58\u5728\u66f4\u5bb9\u6613\u4f7f\u5f97\u6837\u54c1\u5728\u9178\u6027\u73af\u5883\u4e2d\u88ab\u8150\u8680\u3002\u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u5c06H-FeCoNiCuMo\u57280.5 M H2<\/sub>SO4<\/sub>\u7684\u9ad8\u8150\u8680\u6027\u4ecb\u8d28\u4e2d\u5bf9\u5176HER\u6027\u80fd\u8fdb\u884c\u6d4b\u8bd5\u8bc4\u4f30\u3002H-FeCoNiCuMo\u8868\u73b0\u51fa\u5f02\u5e38\u4f18\u5f02\u7684\u50ac\u5316\u6548\u7387\uff0c\u5176\u03b710<\/sub>\u4e3a\u4e2a\u4f4d\u6570\uff0c\u03b7500<\/sub>\u63a5\u8fd1100 mV\uff0c\u4f18\u4e8e\u6240\u6709MEA\u7535\u6781\u4ee5\u53ca\u5176\u4ed6\u5df2\u53d1\u8868\u7684HER\u7535\u50ac\u5316\u5242\uff08\u56fe<\/strong>2<\/strong>C\uff09\u3002\u4e0e\u78b1\u6027HER\u76f8\u6bd4\uff0c\u5728\u9178\u6027HER\u4e2d\uff0cFe\u4e0d\u518d\u662fH-FeCoNiCuMo\u4e2d\u4e0d\u5229\u7684\u5143\u7d20\u3002H-FeCoNiCuMo\u62e5\u6709\u6700\u9ad8\u7684\u7535\u5316\u5b66\u6d3b\u6027\u8868\u9762\u79ef\u3001\u52a8\u529b\u5b66\u6548\u7387\u3001\u5e73\u5747\u5185\u5728\u6d3b\u6027\u548c\u7535\u8377\u8f6c\u79fb\u6548\u7387\uff08\u56fe<\/strong>2<\/strong>F\u53ca\u5176\u4ed6\u652f\u6491\u6750\u6599\uff09\u3002<\/p>\n

    \"\"\u56fe<\/strong>3.<\/strong> H-FeCoNiCuMo\u968f\u7740\u8fd8\u539f\u7535\u4f4d\u589e\u52a0\u65f6\u5bf9\u5e94\u7684Mo FT-EXAFS\u5149\u8c31\u53ca\u5176\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u53d1\u751f\u7684\u534f\u540c\u4f5c\u7528\u793a\u610f\u56fe\u3002\u00a9 2023 Applied Catalysis B.<\/strong><\/p>\n

    \u4f5c\u8005\u901a\u8fc7\u539f\u4f4dXAS\u6765\u7814\u7a76H-FeCoNiCuMo\u5bf9HER\u7684\u53cd\u5e94\u673a\u5236\u3002\u5982\u56fe<\/strong>3<\/strong>A-E\u6240\u793a\uff0c\u4f5c\u8005\u5f97\u5230\u4e86H-FeCoNiCuMo\u76f8\u4f4d\u6821\u6b63\u7684FT-EXAFS\u5149\u8c31\u3002\u4ece\u8be5\u5149\u8c31\u53ef\u77e5\uff0cH-FeCoNiCuMo\u7684\u6240\u6709\u4e94\u79cd\u7ec4\u6210\u5143\u7d20\u90fd\u4e0d\u662f\u5355\u539f\u5b50\u72b6\u6001\uff0c\u800c\u662f\u9ad8\u71b5\u5408\u91d1\u72b6\u6001\uff0c\u6240\u6709\u4e94\u79cd\u7ec4\u6210\u5143\u7d20\u90fd\u968f\u673a\u5206\u5e03\u5728FCC\u6676\u4f53\u7ed3\u6784\u4e2d\uff0c\u5e76\u4e14\u5728HER\u4e2d\u4fdd\u6301\u8fd9\u79cd\u72b6\u6001\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u57281M KOH\u4e2d\uff0cCo\u548cCu\u7684\u76f8\u5e94FT-XANES\u5149\u8c31\u7684\u632f\u8361\u632f\u5e45\u968f\u7740\u8fd8\u539f\u7535\u4f4d\u7684\u589e\u52a0\u800c\u589e\u52a0\uff0c\u4f46\u57280.5M H2<\/sub>SO4<\/sub>\u4e2d\u4fdd\u6301\u4e0d\u53d8\u3002\u632f\u5e45\u7684\u589e\u52a0\u610f\u5473\u7740\u539f\u5b50\u914d\u4f4d\u7a0b\u5ea6\u7684\u63d0\u9ad8<\/strong>\uff0c\u8fd9\u8868\u660eCo\u548cCu\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u7684HER\u7684RDS\u8fc7\u7a0b\u4e2d\u4e0e\u5468\u56f4\u7269\u79cd\u53d1\u751f\u4e86\u7f13\u6162\u800c\u5f3a\u7684\u914d\u4f4d\u3002\u7136\u800c\uff0c\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\u7684Co\u548cCu\u4ee5\u53ca\u5728\u78b1\u6027\u548c\u9178\u6027\u4ecb\u8d28\u4e2d\u7684Fe\u3001Ni\u548cMo\uff0c\u90fd\u6ca1\u6709\u53d1\u751f\u8fd9\u79cd\u914d\u4f4d\u3002<\/p>\n

    \u7814\u7a76\u4eba\u5458\u53d1\u73b0\uff0cNi\u548cMo\u5177\u6709\u6b63\u5411\u534f\u540c\u6548\u5e94\uff0c\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u901a\u8fc7Volmer-Tafel\u8def\u7ebf\u6709\u6548\u5730\u9a71\u52a8HER\u3002\u6b64\u5916\uff0cDFT\u6a21\u62df\u663e\u793a\uff0cCoCu\u5408\u91d1\u80fd\u591f\u8868\u73b0\u51fa\u4f4e\u7684H\u5438\u9644\u81ea\u7531\u80fd\uff0c\u4ee5\u5b9e\u73b0\u9ad8\u6548HER\u3002\u4ee5\u4e0a\u7814\u7a76\u8868\u660e\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u7528H-FeCoNiCuMo\u50ac\u5316HER\u53ef\u4ee5\u57fa\u4e8eNiMo\u548cCoCu\u5206\u7c7b\u8ba8\u8bba\u3002\u5206\u7c7b\u7684NiMo\u5bf9\uff0c\u8868\u793a\u4e3aDT<\/sub>\u57df\uff0c\u4ee5Volmer-Tafel\u8def\u7ebf\u8fdb\u884c\uff0c\u5206\u7c7b\u7684CoCu\u5bf9\uff0c\u8868\u793a\u4e3aDH<\/sub>\u57df\uff0c\u4ee5Volmer-Heyrovsky\u8def\u7ebf\u8fdb\u884c\u3002\u5bf9\u4e8e\u8fd9\u4e24\u6761\u8def\u7ebf\uff0cVolmer\u6b65\u9aa4\uff08\u56fe<\/strong>3<\/strong>F\u7070\u8272\u7bad\u5934\uff09\u901a\u8fc7\u6253\u7834H-O-H\u7684H-O\u952e\u5f62\u6210M-H*\u3002\u5728DH<\/sub>\u4e0a\uff0cM-H*\u901a\u8fc7\u6253\u7834H-O-H\u7684H-O\u952e\uff0c\u7ecf\u8fc7Heyrovsky\u6b65\u9aa4\uff08\u56fe<\/strong>3<\/strong>F\u68d5\u8272\u7bad\u5934\uff09\u751f\u6210H2<\/sub>\uff0c\u800c\u5728DT<\/sub>\u4e0a\uff0cM-H*\u9075\u5faaTafel\u6b65\u9aa4\uff08\u56fe<\/strong>3<\/strong>F\u7ea2\u8272\u7bad\u5934\uff09\uff0c\u901a\u8fc7\u5316\u5b66\u89e3\u5438\u91ca\u653eH2<\/sub>\u3002DT<\/sub>\u57df\u548cDH<\/sub>\u57df\u4e4b\u95f4\u7684\u534f\u540c\u4f5c\u7528\u4f7f\u5f97H-FeCoNiCuMo\u5bf9\u78b1\u6027HER\u53d6\u5f97\u6700\u4f4e\u7684Tafel\u659c\u7387\u3002\u6b63\u662f\u8fd9\u79cd\u534f\u540c\u4f5c\u7528\u4f7fH-FeCoNiCuMo\u548cM-CoNiCuMo\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u6bd4\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\u7684\u8fc7\u7535\u4f4d\u548cTafel\u659c\u7387\u8868\u73b0\u66f4\u597d\u3002\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u52a8\u529b\u5b66\u6a21\u5f0f\uff0c\u5373\u901a\u8fc7\u6c22\u539f\u5b50\uff08<\/strong>H*<\/strong>\uff09\u4ece<\/strong>DH<\/sub><\/strong>\u5230<\/strong>DT<\/sub><\/strong>\u7684\u8fc1\u79fb\uff0c\u5728<\/strong>DT<\/sub><\/strong>\u548c<\/strong>DH<\/sub><\/strong>\u57df\u4e4b\u95f4\u4ea7\u751f\u534f\u540c\u4f5c\u7528\uff08\u56fe<\/strong>3F<\/strong>\uff1b\u9ed1\u8272\u7bad\u5934\uff09<\/strong>\uff0c\u6765\u89e3\u91caH-FeCoNiCuMo\u548cM-CoNiCuMo\u83b7\u5f97\u7684\u8d85\u4f4eTafel\u659c\u7387\u7684\u5185\u5728\u673a\u5236\u3002<\/p>\n

    \"\"\u56fe<\/strong>4.<\/strong> MEAs\u548cHEA\u7684\u6574\u4f53\u6c34\u5206\u89e3\u6027\u80fd\u3002\u00a9 2023 Applied Catalysis B.<\/strong><\/p>\n

    \u5bf9\u4e8e\u5de5\u4e1a\u5e94\u7528\u6765\u8bf4\uff0c\u78b1\u6027\u7535\u89e3\u69fd\u5e94\u8be5\u5728\u4f4e\u7535\u538b\u4e0b\u8fdb\u884c\uff0c\u4ee5\u964d\u4f4e\u8fd0\u884c\u6210\u672c\u548c\u5ef6\u957f\u7535\u50ac\u5316\u5242\u7684\u5bff\u547d\u3002\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\uff0cH-FeCoNiCuMo\u5bf9HER\u548cOER\u90fd\u5177\u6709\u9ad8\u6548\u50ac\u5316\uff0c\u5e76\u4f5c\u4e3a\u4e00\u79cd\u51fa\u8272\u7684\u53cc\u529f\u80fd\u50ac\u5316\u5242\u7528\u4e8e\u78b1\u6027\u6574\u4f53\u6c34\u89e3\u3002H-FeCoNiCuMo\/\/H-FeCoNiCuMo\u8026\u5408\u53ea\u9700\u89811.416\u548c1.623 V\u7684\u8d85\u4f4e\u7535\u6c60\u7535\u538b\uff0c\u5c31\u80fd\u5206\u522b\u63d0\u4f9b10\u548c500 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u8d85\u8fc7\u4e86\u6240\u6709MEA\u8026\u5408\u4ee5\u53ca\u76ee\u524d\u53d1\u8868\u6027\u80fd\u9760\u524d\u7684\u53cc\u529f\u80fd\u7535\u50ac\u5316\u5242\uff08\u56fe<\/strong>4<\/strong>A\uff09\u3002\u901a\u8fc7\u56fe<\/strong>4<\/strong>B\u53ef\u4ee5\u53d1\u73b0\u5176\u53cd\u5e94\u52a8\u529b\u5b66\u6548\u7387\u975e\u5e38\u7a81\u51fa\u3002\u6700\u91cd\u8981\u7684\u662f\uff0cH-FeCoNiCuMo\/\/H-FeCoNiCuMo\u8026\u5408\u5728\u6076\u52a3\u7684\u5de5\u4f5c\u73af\u5883\u4e2d\u4ecd\u7136\u5341\u5206\u7a33\u5b9a\uff0c\u57281M KOH\u4e2d\u7684\u6c34\u89e3\u548c0.5M H2<\/sub>SO4<\/sub>\u4e2d\u7684HER\u4e2d\uff0c\u5728500 mA cm-2<\/sup>\u7684\u9ad8\u521d\u59cb\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u8fde\u7eed\u5de5\u4f5c100\u5c0f\u65f6\u540e\uff0c\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf\uff08i-t\uff09\u8870\u51cf\u4ec5\u4e3a2%\u548c1.5%\uff08\u56fe<\/strong>4<\/strong>D\uff0cE\uff09\u3002\u4f5c\u8005\u5c06H-FeCoNiCuMo\/H-FeCoNiCuMo\u8026\u5408\u7535\u6781\u653e\u7f6e\u572820wt%\u7684\u9ad8\u6d53\u5ea6KOH\u3001\u9ad8\u8fbe1500 mA cm-2<\/sup>\u7684\u8d85\u9ad8\u7535\u6d41\u5bc6\u5ea6\u548c70\u2103\u7684\u9ad8\u6e29\u73af\u5883\u4e0b\u8fdb\u4e00\u6b65\u68c0\u9a8c\u5176\u7535\u50ac\u5316\u6548\u7387\u548c\u7a33\u5b9a\u6027\u3002\u5982\u56fe<\/strong>4<\/strong> F\u6240\u793a\uff0c\u7535\u6781\u63d0\u4f9b500\u30011000\u30011500 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u6240\u9700\u7684\u7535\u6c60\u7535\u538b\u5206\u522b\u53ea\u67091.533\u30011.585\u548c1.627 V\uff0c\u8fdc\u4f4e\u4e8e\u5ba4\u6e29\u4e0b\u57281 M KOH\u4e2d\u8fbe\u5230\u9700\u8981\u7684\u7535\u538b\u3002<\/p>\n

    \u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

    \u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u7814\u7a76\u8868\u660e\uff0c\u7531\u7b49\u6469\u5c14Fe\u3001Co\u3001Ni\u3001Cu\u3001Mo\u7ec4\u6210\u7684\u65e0\u8d35\u91d1\u5c5e\u9ad8\u71b5\u5408\u91d1\uff08H-FeCoNiCuMo\uff09\u662f\u4e00\u79cd\u7a81\u7834\u6027\u7684\u6c34\u89e3\u7535\u50ac\u5316\u5242\u3002H-FeCoNiCuMo\u5408\u91d1\u5c55\u793a\u51fa\u539f\u5b50\u5c3a\u5ea6\u4e0a\u7684\u6700\u5927\u534f\u540c\u6548\u5e94\uff0c\u8868\u73b0\u51fa\u5353\u8d8a\u7684\u7535\u50ac\u5316\u6548\u7387\u548c\u7a33\u5b9a\u6027\u3002\u4f5c\u8005\u901a\u8fc7\u539f\u4f4dX\u5c04\u7ebf\u5438\u6536\u7814\u7a76\u63ed\u793a\u4e86\u5176\u5185\u5728\u7684\u4e00\u79cd\u65b0\u7684\u50ac\u5316\u73b0\u8c61\uff0c\u5373\u4e24\u79cd\u4e0d\u540c\u7684\u50ac\u5316\u673a\u5236\u540c\u65f6\u5728\u4e00\u79cd\u50ac\u5316\u5242\u7684\u4e0d\u540c\u6210\u5206\u4e0a\u53d1\u6325\u4f5c\u7528\uff0c\u672c\u6587\u4e2dCo\u548cCu\u4e0a\u7684Volmer-Heyrovsky\u8def\u7ebf\u548cNi\u548cMo\u4e0a\u7684Volmer-Tafel\u8def\u7ebf\u5206\u522b\u53d1\u6325\u4f5c\u7528\u3002\u8be5\u5de5\u4f5c\u5c55\u793a\u4e86\u4e00\u79cd\u901a\u8fc7\u5728\u539f\u5b50\/\u5206\u5b50\u5c3a\u5ea6\u4e0a\u8bbe\u8ba1\u591a\u7ec4\u5206\u50ac\u5316\u5242\u7684\u539f\u5b50\/\u5206\u5b50\u6df7\u5408\u7ec4\u5206\u4e4b\u95f4\u7684\u5f3a\u534f\u540c\u6548\u5e94\u6765\u8bbe\u8ba1\u7a81\u7834\u6027\u50ac\u5316\u5242\u7684\u65b0\u65b9\u6cd5\u3002<\/p>\n

    \u6587\u732e\u94fe\u63a5: Chun-Lung Huang, Yan-Gu Lin, Chao-Lung Chiang, Chun-Kuo Peng, Duraisamy Senthil Raja, Cheng-Ting Hsieh, Yu-An Chen, Shun-Qin Chang, Yong-Xian Yeh, Shih-Yuan Lu, Atomic scale synergistic interactions lead to breakthrough catalysts for electrocatalytic water splitting, Applied Catalysis B: Environmental, 2023, https:\/\/doi.org\/10.1016\/j.apcatb.2022.122016<\/a>.<\/p>\n

    \u672c\u6587\u7531MichstaBe\u5b59\u56fd\u6587\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"

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