{"id":246177,"date":"2023-01-30T06:37:44","date_gmt":"2023-01-29T22:37:44","guid":{"rendered":"\/\/m.iemloyee.com\/?p=246177"},"modified":"2023-01-29T20:37:59","modified_gmt":"2023-01-29T12:37:59","slug":"appl-catal-b-%ef%bc%9a%e9%ab%98%e6%95%88pd-c%e5%82%ac%e5%8c%96%e5%89%82%e7%94%a8%e4%ba%8e%e7%94%b2%e9%85%b8%e9%93%b5%e8%84%b1%e6%b0%a2%e4%b8%ad%e8%a1%a8%e9%9d%a2%e6%b0%a7%e5%ae%98%e8%83%bd%e5%9b%a2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=246177","title":{"rendered":"Appl. Catal. B.\uff1a\u9ad8\u6548Pd\/C\u50ac\u5316\u5242\u7528\u4e8e\u7532\u9178\u94f5\u8131\u6c22\u4e2d\u8868\u9762\u6c27\u5b98\u80fd\u56e2\u7684\u5f71\u54cd"},"content":{"rendered":"<p style=\"text-align: center;\"><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u968f\u7740\u80fd\u6e90\u9700\u6c42\u7684\u589e\u52a0\u548c\u5bf9\u73af\u5883\u5f71\u54cd\u7684\u65e5\u76ca\u5173\u6ce8\uff0c\u6c22\u80fd\u6e90\u56e0\u5176\u4e0d\u6392\u653e\u6c61\u67d3\u7269\u3001\u80fd\u91cf\u5bc6\u5ea6\u9ad8\uff08~33 kWh\/kg\uff09\u800c\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u5bf9\u4e8e\u6c22\u6c14\u7684\u50a8\u5b58\u548c\u8f93\u9001\uff0c\u4e00\u4e9b\u7814\u7a76\u4eba\u5458\u6b63\u5728\u5bf9\u6db2\u6001\u6709\u673a\u6c22\u8f7d\u4f53\uff08LOHCs\uff09\u8fdb\u884c\u7814\u7a76\uff0c\u5176\u4f18\u70b9\u662f\uff1a1)\u6709\u671b\u643a\u5e26\u66f4\u591a\u7684\u6c22\u6c14\uff1b2)\u66f4\u52a0\u7075\u6d3b\uff0c\u53ef\u4ee5\u4e0e\u73b0\u6709\u7684\u4ea4\u901a\u57fa\u7840\u8bbe\u65bd\u7d27\u5bc6\u7ed3\u5408\uff1b3)\u53ef\u4ee5\u5728\u4f4e\u538b\u548c\u63a5\u8fd1\u73af\u5883\u6e29\u5ea6\u7684\u6761\u4ef6\u4e0b\u643a\u5e26\u6c22\u6c14\u3002\u7532\u9178(H<sub>2<\/sub>CO<sub>2<\/sub>)\u548c\u7532\u9178\u76d0\u6eb6\u6db2(MHCO<sub>2<\/sub>, M=Na<sup>+<\/sup>\uff0c K<sup>+<\/sup>\uff0c NH<sup>4 +<\/sup>)\u662f\u5404\u79cdLOHCs\u4e2d\u975e\u5e38\u6709\u6548\u7684\u4ecb\u8d28\uff0c\u5c24\u5176\u662f\u7532\u9178\u94f5\u3002\u5728\u9002\u5f53\u7684\u50ac\u5316\u5242\u4f5c\u7528\u4e0b\u7532\u9178\u76d0\u6eb6\u6db2\u8131\u6c22\u53ef\u4ea7\u751f\u9ad8\u7eaf\u6c22\u3002\u524d\u671f\u7684\u7814\u7a76\u8868\u660e\uff0cPd\/C\u50ac\u5316\u5242\u5177\u6709\u8f83\u9ad8\u7684\u78b3\u9178\u6c22\u94f5\u52a0\u6c22\u548c\u7532\u9178\u94f5\u8131\u6c22\u6d3b\u6027\uff0c\u4f18\u4e8e\u5176\u4ed6\u8d35\u91d1\u5c5e\u57fa\u50ac\u5316\u5242(Ru\/C, Rh\/C, Pt\/C)\u3002\u800c\u8868\u9762O\u5b98\u80fd\u56e2\u53ef\u80fd\u5177\u6709\u4e0eN\u63ba\u6742\u57fa\u56e2\u76f8\u4f3c\u7684\u7279\u5f81\u3002\u4f8b\u5982\uff1a1)N\u63ba\u6742\u78b3\u6750\u6599\u4e2d\u5b58\u5728\u591a\u79cdN-C\u7ed3\u6784\u3002\u540c\u6837\uff0c\u78b3\u8f7d\u4f53\u4e0a\u4e5f\u5b58\u5728\u591a\u4e2aO\u5b98\u80fd\u56e2(\u7f9f\u57faO\u3001\u7fb0\u57faO\u3001\u7fa7\u57faO\u3001\u916f\u57faO\u7b49)\u30022)N\u63ba\u6742\u57fa\u56e2\u53ef\u4ee5\u589e\u52a0\u8f7d\u4f53\u8868\u9762Pd\u7684\u6d53\u5ea6\uff0c\u800cO\u5b98\u80fd\u56e2\u4e5f\u6709\u540c\u6837\u7684\u4f5c\u7528\u3002\u6709\u62a5\u9053\u79f0\uff0c\u8868\u9762O\u5b98\u80fd\u56e2\u5f62\u6210\u91d1\u5c5e\u524d\u9a71\u4f53\u548c\u91d1\u5c5e\u7684\u951a\u5b9a\u4f4d\u70b9\uff0c\u51b3\u5b9a\u4e86\u6d3b\u6027\u78b3\u4f5c\u4e3a\u50ac\u5316\u5242\u8f7d\u4f53\u6750\u6599\u7684\u6027\u80fd\u3002\u4f8b\u5982\uff0c\u8868\u9762\u9178\u6027\u7684O\u5b98\u80fd\u56e2\u964d\u4f4e\u4e86\u78b3\u7684\u758f\u6c34\u6027\uff0c\u5bfc\u81f4\u8868\u9762\u53ef\u63a5\u8fd1\u542b\u6c34\u91d1\u5c5e\u524d\u9a71\u4f53\uff0c\u800c\u9178\u6027\u8f83\u4f4e\u7684O\u5b98\u80fd\u56e2\u589e\u52a0\u4e86\u91d1\u5c5e\u524d\u9a71\u4f53\u4e0e\u8f7d\u4f53\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u7136\u800c\uff0cO\u5b98\u80fd\u56e2\u5982\u4f55\u901a\u8fc7Pd\/C\u50ac\u5316\u5242\u5f71\u54cd\u7532\u9178\u94f5\u8131\u6c22\u8fd8\u4e0d\u6e05\u695a\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u534e\u76db\u987f\u5dde\u7acb\u5927\u5b66\u5316\u5b66\u5de5\u7a0b\u4e0e\u751f\u7269\u5de5\u7a0b\u5b66\u9662\u6797\u9e3f\u98de\u6559\u6388\u56e2\u961f\u8054\u5408\u52b3\u4f26\u65af\u5229\u5f17\u83ab\u5c14\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u6750\u6599\u79d1\u5b66\u90e8Sneha A.\u00a0Akhade\u6559\u6388\u56e2\u961f\u7814\u7a76\u4e86\u78b3\u8f7d\u8868\u9762\u529f\u80fd\u5316\u94af\u50ac\u5316\u5242\u7528\u4e8e\u7532\u9178\u916f\u8131\u6c22\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u53caO\u5b98\u80fd\u56e2\u7684\u5f71\u54cd\u3002\u8be5\u9879\u7814\u7a76\u8868\u660e\uff0c O\u5b98\u80fd\u56e2\u5728\u5206\u6563Pd\u7eb3\u7c73\u9897\u7c92\u548c\u964d\u4f4e\u8131\u6c22\u6d3b\u5316\u80fd\u65b9\u9762\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u8868\u660e\uff0c\u5927\u591a\u6570O \u5b98\u80fd\u56e2\u589e\u5f3a\u4e86Pd\u6d3b\u6027\u4f4d\u70b9\u4e0a\u7532\u9178\u916f\u7684\u5438\u9644\u3002\u4f46C=O\u57fa\u56e2\u7684\u5b58\u5728\u6d88\u8017\u4e86\u8fd8\u539f\u5242\uff0c\u963b\u788d\u4e86\u91d1\u5c5ePd\u7684\u5f62\u6210\u3002Pd\u5411O\u5b98\u80fd\u56e2\u7684\u7535\u5b50\u8f6c\u79fb\u4e0d\u5229\u4e8e\u8131\u6c22\u3002\u5236\u5907\u7684Pd5\/re-ACA(\u7ecf\u9178\u6d17\u6da4\u7684\u8fd8\u539f\u6d3b\u6027\u78b3)\u8868\u73b0\u51fa\u663e\u8457\u7684\u6d3b\u6027\uff0c\u5176TOF\u503c\u4e3a13511 h<sup>\u2212<\/sup><sup>1<\/sup>\uff0c\u9ad8\u4e8e\u5546\u7528Pd\/C\u50ac\u5316\u5242\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cEfficient Pd on carbon catalyst for ammonium formate dehydrogenation: Effect of surface oxygen functional groups\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520a<strong><em>Applied Catalysis B: Environmental<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-246178\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/0-9.png\" alt=\"\" width=\"1582\" height=\"742\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/0-9.png 1582w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/0-9-300x141.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/0-9-768x360.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/0-9-1024x480.png 1024w\" sizes=\"(max-width: 1582px) 100vw, 1582px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>1\u3001\u8bc1\u660e\u4e86O\u5b98\u80fd\u56e2\u5728\u5206\u6563Pd\u7eb3\u7c73\u9897\u7c92\u548c\u964d\u4f4e\u8131\u6c22\u6d3b\u5316\u80fd\u65b9\u9762\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002<\/p>\n<p>2\u3001\u5236\u5907\u7684Pd5\/re-ACA\u8868\u73b0\u51fa\u663e\u8457\u6d3b\u6027\uff0cTOF\u503c\u4e3a13511 h<sup>\u2212<\/sup><sup>1<\/sup>\uff0c\u9ad8\u4e8e\u5546\u7528Pd\/C\u50ac\u5316\u52421.6\u500d\u3002<\/p>\n<p style=\"text-align: center;\"><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-246179\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/1-21.png\" alt=\"\" width=\"1022\" height=\"917\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/1-21.png 1022w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/1-21-300x269.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/1-21-768x689.png 768w\" sizes=\"(max-width: 1022px) 100vw, 1022px\" \/><\/p>\n<p>\u56fe1. a) Pd5\/ACA\uff1bb) Pd5\/ACA0.4\uff1bc) Pd5\/ACA8\uff1bd) Pd5\/re-ACA\u7684TEM\u56fe\u50cf\u3002 e)\u5bf9\u5e94\u5143\u7d20\u6620\u5c04\u548c\u80fd\u8c31(\u7ea2\u8272:\u78b3\uff0c\u7eff\u8272:\u6c27\uff0c\u6d45\u84dd\u8272:\u94af)\u3002f) Pd5\/re-ACA\uff1bg) Pd5\/ACA8\uff1bh, i) Pd5\/ACA0.4\u7684HRTEM\u56fe\u50cf\uff1b\u3002\u00a9 2022 Elsevier B.V.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-246180\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/2-21.png\" alt=\"\" width=\"858\" height=\"328\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/2-21.png 858w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/2-21-300x115.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/2-21-768x294.png 768w\" sizes=\"(max-width: 858px) 100vw, 858px\" \/><\/p>\n<p>\u56fe2. ACA\u3001re-ACA\u3001ACA0.4\u548cACA8\u7684a)TPD\u5149\u8c31\u548cb) ATR-IR\u5149\u8c31\uff1bc) Pd5\/ACA8\u3001Pd5\/re ACA8\u548cPd5\/re-ACA\u50ac\u5316\u5242\u7684\u6c22\u4f53\u79ef\u968f\u53cd\u5e94\u65f6\u95f4\u7684\u53d8\u5316\u3002\u00a9 2022 Elsevier B.V.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-246181\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/3-21.png\" alt=\"\" width=\"854\" height=\"595\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/3-21.png 854w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/3-21-300x209.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/3-21-768x535.png 768w\" sizes=\"(max-width: 854px) 100vw, 854px\" \/><\/p>\n<p>\u56fe3. Pd5\/ACA\u3001Pd5\/ACA0.4\u548cPd5\/re-ACA\u50ac\u5316\u5242\u7684XPS\u8c31a) O1 s\uff1bb) Pd 3d\u3002\u00a9 2022 Elsevier B.V.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-246182\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/4-20.png\" alt=\"\" width=\"846\" height=\"654\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/4-20.png 846w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/4-20-300x232.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/4-20-768x594.png 768w\" sizes=\"(max-width: 846px) 100vw, 846px\" \/><\/p>\n<p>\u56fe4. \u5546\u7528Pd\/C\u50ac\u5316\u5242\u548c\u5404\u79cdPd\/ACA\u50ac\u5316\u5242\u8131\u6c22\u6d3b\u6027\u7684\u6bd4\u8f83\u3002a)\u6c22\u4f53\u79ef\u968f\u53cd\u5e94\u65f6\u95f4\u7684\u53d8\u5316(80 <sup>\u25e6<\/sup>C)\uff1bB)\u7532\u9178\u76d0\u8131\u6c22\u53cd\u5e94\u6e29\u5ea6\u7684\u5f71\u54cd;c) Arrhenius\u56fe(\u4ece0\u52305\u5206\u949f\u7684\u5e73\u5747\u521d\u59cb\u53cd\u5e94\u901f\u7387)\u3002\u53cd\u5e94\u6761\u4ef6\uff1a0.05 g\u50ac\u5316\u5242\uff0c20 mmol\u7532\u9178\u94f5\uff0c1 atm\u6c2e\u6c14\uff0c40 min\u3002\u00a9 2022 Elsevier B.V.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-246183\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/5-17.png\" alt=\"\" width=\"850\" height=\"321\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/5-17.png 850w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/5-17-300x113.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/5-17-768x290.png 768w\" sizes=\"(max-width: 850px) 100vw, 850px\" \/><\/p>\n<p>\u56fe5. a) Pd5\/re-ACA, b) Pd5\/ACA8\u50ac\u5316\u5242\u4e0a\u7684\u539f\u4f4dATR-IR\u5149\u8c31\u4f5c\u4e3a\u5c062 M\u7532\u9178\u94f5\u6eb6\u6db2\u6f02\u6d17\u5230\u8c31\u5ba4\u540e\u8bb0\u5f55\u65f6\u95f4\u7684\u51fd\u6570\u3002\u5728\u6f02\u6d17\u524d\u8bb0\u5f55\u7a7a\u6c14\u4e2d\u7684\u53c2\u8003\u5149\u8c31\u3002\u00a9 2022 Elsevier B.V.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-246184\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/6-6.png\" alt=\"\" width=\"862\" height=\"323\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/6-6.png 862w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/6-6-300x112.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/6-6-768x288.png 768w\" sizes=\"(max-width: 862px) 100vw, 862px\" \/><\/p>\n<p>\u56fe6. a) Pd5\/ACA8\u3001Pd5\/re-ACA8\u548cPd5\/re-ACA\u50ac\u5316\u5242\u7684\u6c22\u4f53\u79ef\u968f\u53cd\u5e94\u65f6\u95f4\u7684\u53d8\u5316\uff1bb) ACA8\u548cre-ACA8\u78b3\u8f7d\u4f53\u7684TPD\u56fe\u3002\u00a9 2022 Elsevier B.V.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-246185\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/7-2.png\" alt=\"\" width=\"876\" height=\"247\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/7-2.png 876w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/7-2-300x85.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/7-2-768x217.png 768w\" sizes=\"(max-width: 876px) 100vw, 876px\" \/><\/p>\n<p>\u56fe7. \u5728Pd\u7eb3\u7c73\u9897\u7c92\u4e0a\uff0c\u6c22\u548c\u7532\u9178\u916f\u7684\u4ee3\u8868\u6027\u6784\u578b\u88ab\u675f\u7f1a\u5728\u9760\u8fd1\u8f7d\u4f53\u201c\u8fd1\u8f7d\u4f53\u201d\u548c\u8fdc\u79bb\u8f7d\u4f53\u201c\u8fdc\u8f7d\u4f53\u201d\u7684\u4f4d\u7f6e\u3002\u00a9 2022 Elsevier B.V.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-246186\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/8-1.png\" alt=\"\" width=\"872\" height=\"408\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/8-1.png 872w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/8-1-300x140.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/8-1-768x359.png 768w\" sizes=\"(max-width: 872px) 100vw, 872px\" \/><\/p>\n<p>\u56fe8. (a)\u7532\u9178\u76d0\u548c(b)\u6c22\u5728\u8868\u9762\u529f\u80fd\u5316\u78b3\u8f7d\u4f53\u8d1f\u8f7d\u7684Pd\u7eb3\u7c73\u9897\u7c92\u4e0a\u7684\u5438\u9644\u81ea\u7531\u80fd\u3002\u8bf8\u5982\u201c- O -\u201d\u7684\u6807\u7b7e\u8868\u793a\u8f7d\u4f53\u7684\u4fee\u9970\uff0c\u7eb3\u7c73\u9897\u7c92\u5927\u81f4\u76f8\u540c\u3002\u00a9 2022 Elsevier B.V.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-246187\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/9.png\" alt=\"\" width=\"500\" height=\"396\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/9.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/9-300x238.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p>\u56fe9. \u94af\u7eb3\u7c73\u9897\u7c92\u4e0e\u5404\u79cd\u6539\u6027\u77f3\u58a8\u70ef\u8f7d\u4f53\u4e4b\u95f4\u7684\u7535\u8377\u8f6c\u79fb\u3002\u6b63\u503c\u8868\u793a\u7535\u5b50\u4ece\u7eb3\u7c73\u9897\u7c92\u8f6c\u79fb\u5230\u8f7d\u4f53\u3002\u00a9 2022 Elsevier B.V.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-246188\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/10.png\" alt=\"\" width=\"853\" height=\"181\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/10.png 853w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/10-300x64.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/10-768x163.png 768w\" sizes=\"(max-width: 853px) 100vw, 853px\" \/><\/p>\n<p>\u56fe10. \u7eb3\u7c73\u7c92\u5b50\u8f7d\u4f53\u7535\u8377\u8f6c\u79fb\u7684\u7535\u8377\u5bc6\u5ea6\u7b49\u503c\u9762\u3002\u8fd9\u91cc\u663e\u793a\u7684\u7b49\u503c\u9762\u5bf9\u5e94\u7684\u7535\u8377\u5bc6\u5ea6\u5dee\u4e3a+ \/- 0.002 Bohr<sup>-3<\/sup>\u3002\u9ec4\u8272\u8868\u793a\u7535\u5b50\u8017\u7aed\u533a\u57df\uff0c\u9752\u8272\u8868\u793a\u7535\u5b50\u79ef\u805a\u533a\u57df\u3002\u00a9 2022 Elsevier B.V.<\/p>\n<p style=\"text-align: center;\"><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u8be5\u5de5\u4f5c\u7cfb\u7edf\u5730\u7814\u7a76\u4e86Pd\/C\u50ac\u5316\u5242\u4e0a\u542b\u6c27\u5b98\u80fd\u56e2\u5bf9\u7532\u9178\u94f5\u8131\u6c22\u7684\u5f71\u54cd\u3002\u5728Pd5\/re-ACA\u50ac\u5316\u5242\u4e0a\uff0c80 <sup>\u25e6<\/sup>C\u65f6TOF\u8fbe\u523013511 h<sup>\u22121<\/sup>\uff0c\u6bd4\u5546\u75285% Pd\/C\u50ac\u5316\u5242\u9ad81.6\u500d\u3002\u9ad8\u6d53\u5ea6HNO<sub>3<\/sub>\u5904\u7406\u53ef\u4ee5\u5728\u78b3\u8f7d\u4f53\u8868\u9762\u5f15\u5165\u66f4\u591a\u542b\u6c27\u5b98\u80fd\u56e2\uff0c\u7279\u522b\u662fC=O\u952e\u3002\u4e00\u65b9\u9762\uff0c\u8fd9\u4e9bO\u5b98\u80fd\u56e2\u6709\u5229\u4e8e\u5206\u6563\u78b3\u8f7d\u4f53\u4e0a\u7684Pd 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href=\"https:\/\/doi.org\/10.1016\/j.apcatb.2022.122015\">https:\/\/doi.org\/10.1016\/j.apcatb.2022.122015<\/a><\/p>\n<p>\u672c\u6587\u7531\u5c0f\u827a\u64b0\u7a3f<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u968f\u7740\u80fd\u6e90\u9700\u6c42\u7684\u589e\u52a0\u548c\u5bf9\u73af\u5883\u5f71\u54cd\u7684\u65e5\u76ca\u5173\u6ce8\uff0c\u6c22\u80fd\u6e90\u56e0\u5176\u4e0d\u6392\u653e\u6c61\u67d3\u7269\u3001\u80fd\u91cf\u5bc6\u5ea6\u9ad8\uff08~33 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