{"id":246130,"date":"2023-01-20T06:00:50","date_gmt":"2023-01-19T22:00:50","guid":{"rendered":"\/\/m.iemloyee.com\/?p=246130"},"modified":"2023-01-19T17:26:14","modified_gmt":"2023-01-19T09:26:14","slug":"science%ef%bc%9a%e4%b8%80%e7%bb%b4%e5%88%b0%e4%b8%89%e7%bb%b4%e7%9a%84%e6%8b%93%e6%89%91%e7%bc%a9%e5%90%88%e5%ae%9e%e7%8e%b0%e6%96%b0%e5%9e%8b%e8%b6%85%e5%a4%a7%e5%ad%94%e5%88%86%e5%ad%90%e7%ad%9b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=246130","title":{"rendered":"Science\uff1a\u4e00\u7ef4\u5230\u4e09\u7ef4\u7684\u62d3\u6251\u7f29\u5408\u5b9e\u73b0\u65b0\u578b\u8d85\u5927\u5b54\u5206\u5b50\u7b5b\u7684\u5408\u6210"},"content":{"rendered":"<p><strong>\u7814\u7a76\u80cc\u666f<\/strong><\/p>\n<p>\u6cb8\u77f3\u5206\u5b50\u7b5b\uff08zeolite\uff09\u662f\u4e00\u7c7b\u7ed3\u6676\u6027\u5fae\u5b54\u7845\u94dd\u9178\u76d0\uff0c\u5177\u6709\u5b54\u5f84\u5206\u5e03\u5747\u4e00\u3001\u5b54\u9053\u7ed3\u6784\u89c4\u6574\u3001\u6d3b\u6027\u4e2d\u5fc3\u53ef\u8c03\u3001\u6bd4\u8868\u9762\u79ef\u5927\u3001\u7a33\u5b9a\u6027\u597d\u7b49\u7279\u6027\uff0c\u4f5c\u4e3a\u50ac\u5316\u5242\u3001\u5438\u9644\u5242\u3001\u79bb\u5b50\u4ea4\u6362\u5242\u5728\u4f20\u7edf\u5316\u5de5\u3001\u73af\u5883\u9886\u57df\u4ee5\u53ca\u65b0\u5174\u50a8\u80fd\u3001\u5149\u7535\u5668\u4ef6\u3001\u751f\u7269\u533b\u7528\u3001\u71c3\u6599\u7535\u6c60\u3001\u751f\u7269\u8d28\u8f6c\u5316\u7b49\u9886\u57df\u6709\u7740\u91cd\u8981\u7684\u5e94\u7528\uff0c\u5c24\u5176\u662f\u4f5c\u4e3a\u50ac\u5316\u5242\u5728\u77f3\u6cb9\u70bc\u5236\u3001\u77f3\u6cb9\u5316\u5de5\u3001\u7164\u5316\u5de5\u3001\u65e5\u7528\u5316\u5de5\u7b49\u65b9\u9762\u6709\u7740\u6781\u5176\u91cd\u8981\u7684\u5e94\u7528\u3002\u4f8b\u5982\uff0c\u4e0a\u4e16\u7eaa90\u5e74\u4ee3\u6210\u529f\u5f00\u53d1\u7684\u8d85\u7a33Y\u5927\u5b54\u5206\u5b50\u7b5b\uff0c\u7531\u4e8e\u5177\u6709\u8f83\u5927\u7684\u5b54\u9053\u7ed3\u6784\uff0c\u5c06\u5176\u5e94\u7528\u5728\u539f\u6cb9\u88c2\u89e3\u8fc7\u7a0b\u5f15\u53d1\u4e86\u201c\u70bc\u6cb9\u5de5\u4e1a\u6280\u672f\u9769\u547d\u201d\uff0c\u76ee\u524d\u5de5\u4e1a\u4e0a\u6025\u9700\u5f00\u53d1\u51fa\u5177\u6709\u66f4\u5927\u5b54\u9053\u7cfb\u7edf\u7684\u4e09\u7ef4\u7a33\u5b9a\u8d85\u5927\u5b54\u5206\u5b50\u7b5b\u6750\u6599\u3002\u7531\u4e8e\u5206\u5b50\u7b5b\u6676\u5316\u673a\u7406\u4e0d\u660e\u6670\uff0c\u6c34\u70ed\u5408\u6210\u96be\u4ee5\u5b9e\u73b0\u5b9a\u5411\u63a7\u5236\uff0c\u5728\u4eba\u5de5\u5408\u6210\u6cb8\u77f3\u5206\u5b50\u7b5b80\u4f59\u5e74\u7684\u7814\u7a76\u5386\u53f2\u4e2d\uff0c\u4e09\u7ef4\u7a33\u5b9a\u8d85\u5927\u5b54\u7845\u9178\u76d0\u5206\u5b50\u7b5b\u7684\u5408\u6210\u4e00\u76f4\u662f\u5206\u5b50\u7b5b\u9886\u57df\u5185\u5b5c\u5b5c\u4ee5\u6c42\u7684\u76ee\u6807\uff0c\u7136\u800c\u6570\u5341\u5e74\u6765\u9c9c\u6709\u7a81\u7834\uff0c\u8fd9\u4e5f\u662f\u5f53\u524d\u5206\u5b50\u7b5b\u5408\u6210\u9886\u57df\u6240\u9762\u4e34\u7684\u4e00\u9879\u6781\u5927\u6311\u6218\u3002\u5206\u5b50\u7b5b\u7684\u5b54\u5f84\u51b3\u5b9a\u4e86\u80fd\u5728\u5176\u5b54\u9053\u4e2d\u6269\u6563\u548c\u53cd\u5e94\u7684\u5206\u5b50\u5c3a\u5bf8\u3002\u867d\u7136\u5c0f\u7684\u5b54\u9053\u80fd\u591f\u4fc3\u8fdb\u53cd\u5e94\u548c\u5438\u9644\u9009\u62e9\u6027\uff0c\u4f46\u5bf9\u4e8e\u5176\u4ed6\u5e94\u7528\uff0c\u5982\u5904\u7406\u77f3\u6cb9\u5927\u5206\u5b50\u6216\u6709\u673a\u6c61\u67d3\u7269\u7684\u5438\u9644\u548c\u53cd\u5e94\uff0c\u5219\u9700\u8981\u5177\u6709\u8f83\u5927\u5b54\u9699\u7684\u8d85\u5927\u5b54\u3001\u5177\u6709\u9ad8\u7a33\u5b9a\u6027\u7684\u5206\u5b50\u7b5b\u3002\u5408\u6210\u65b0\u578b\u62d3\u6251\u7ed3\u6784\u7684\u5206\u5b50\u7b5b\u662f\u5206\u5b50\u7b5b\u7814\u7a76\u9886\u57df\u7684\u91cd\u8981\u5185\u5bb9\uff0c\u5927\u90e8\u5206\u5206\u5b50\u7b5b\u662f\u901a\u8fc7\u6c34\u70ed\u6216\u6eb6\u5242\u70ed\u76f4\u63a5\u5408\u6210\u800c\u5f97\u5230\u3002\u5c11\u6570\u5206\u5b50\u7b5b\u5219\u53ef\u4ee5\u901a\u8fc7\u7145\u70e7\u5176\u4e8c\u7ef4\u5c42\u72b6\u524d\u9a71\u4f53\u83b7\u5f97\uff0c\u8fd9\u79cd\u7145\u70e7\u662f\u4e0d\u6539\u53d8\u5c42\u7ed3\u6784\u7684\u62d3\u6251\u7f29\u5408\u8fc7\u7a0b\u3002\u5c42\u72b6\u524d\u9a71\u4f53\u53ef\u4ee5\u76f4\u63a5\u5408\u6210\uff0c\u4e5f\u53ef\u4ee5\u901a\u8fc7ADOR\uff08assembly-disassembly-organization-reassembly\uff0c\u7ec4\u88c5-\u5206\u89e3-\u91cd\u6574-\u518d\u7ec4\u88c5\uff09\u8fc7\u7a0b\u5206\u89e3\u67d0\u4e9b\u542b\u9517\u5206\u5b50\u7b5b\u7ed3\u6784\u5f97\u5230\u3002\u867d\u7136\u5c42\u72b6\u524d\u9a71\u4f53\u4e3a\u5206\u5b50\u7b5b\u5408\u6210\u5e26\u6765\u4e86\u65b0\u7684\u53ef\u80fd\uff0c\u4f46\u6240\u5408\u6210\u7684\u5206\u5b50\u7b5b\u4e3b\u8981\u662f\u5c0f\u5b54\u5206\u5b50\u7b5b\u7ed3\u6784\u7c7b\u578b\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u51e0\u5341\u5e74\u5e7f\u6cdb\u4e14\u7cfb\u7edf\u7684\u5206\u5b50\u7b5b\u5408\u6210\u7814\u7a76\u5c1a\u672a\u53d1\u73b0\u53ef\u4ee5\u4ece\u4e00\u7ef4\uff081D\uff09\u94fe\u72b6\u7845\u9178\u76d0\u5206\u5b50\u7b5b\u524d\u9a71\u4f53\u5411\u4e09\u7ef4\uff083D\uff09\u5206\u5b50\u7b5b\u7684\u62d3\u6251\u7ed3\u6784\u8f6c\u5316\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u6210\u679c\u7b80\u4ecb<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u65af\u5fb7\u54e5\u5c14\u6469\u5927\u5b66\/\u5317\u4eac\u5927\u5b66\u7684\u9ece\u5efa\u535a\u58eb\u3001\u897f\u73ed\u7259\u9a6c\u5fb7\u91cc\u6750\u6599\u7814\u7a76\u6240Miguel A. Camblor\u6559\u6388\u3001\u5409\u6797\u5927\u5b66\u9648\u98de\u5251\u6559\u6388\u548c\u4e8e\u5409\u7ea2\u9662\u58eb\u7b49\u62a5\u9053\u4e86\u4e00\u4f8b\u65b0\u578b\u7684\u4e09\u7ef4\u7a33\u5b9a\u8d85\u5927\u5b54\u7845\u9178\u76d0\u5206\u5b50\u7b5b\u6750\u6599ZEO-3\u3002\u8be5\u6750\u6599\u662f\u7531\u9648\u98de\u5251\u6559\u6388\u548c\u4e8e\u5409\u7ea2\u9662\u58eb\u8bfe\u9898\u7ec4\u6240\u5f00\u53d1\uff0c\u4ed6\u4eec\u9996\u5148\u5408\u6210\u4e86\u4e00\u79cd\u65b0\u9896\u76841D\u94fe\u72b6\u7845\u9178\u76d0\u6750\u6599ZEO-2\uff0cZEO-2\u7ecf\u9ad8\u6e29\u7145\u70e7\u76f4\u63a5\u53d1\u751f\u62d3\u6251\u7f29\u5408\u751f\u6210\u4e863D\u7a33\u5b9a\u7684\u5168\u8fde\u63a5\u8d85\u5927\u5b54\u5206\u5b50\u7b5bZEO-3\u3002\u9ece\u5efa\u535a\u58eb\u901a\u8fc7\u4f7f\u7528\u5148\u8fdb\u7684\u8fde\u7eed\u503e\u8f6c\u4e09\u7ef4\u7535\u5b50\u884d\u5c04\uff08cRED\uff09\u6280\u672f\u7ed3\u5408X-\u5c04\u7ebf\u7c89\u672b\u884d\u5c04\u62df\u5408\u7cbe\u4fee\u65b9\u6cd5\u6700\u7ec8\u786e\u5b9a\u4e86\u8fd9\u4e24\u79cd\u6750\u6599\u7684\u7cbe\u786e\u7ed3\u6784\u3002ZEO-3\u5177\u67093D\u5341\u516d\u5143\u73af\uff0816MR\uff09\u548c\u5341\u56db\u5143\u73af\uff0814MR\uff09\u7a7f\u63d2\u8d85\u5927\u5b54\u9053\u7ed3\u6784\uff08\u56fe1\uff09\uff0c\u662f\u9996\u4f8b\u5177\u6709\u4e0d\u4ee5F<sup>&#8211;<\/sup>\u79bb\u5b50\u53c2\u4e0e\u5408\u6210\u7684\u7eaf\u7845\u53cc\u56db\u5143\u73af\uff08D4R\uff09\u5355\u5143\u7684\u7eaf\u7845\u5206\u5b50\u7b5b\u3002\u8fd9\u79cd\u4ece1D\u94fe\u72b6\u7845\u9178\u76d0ZEO-2\u52303D\u5206\u5b50\u7b5bZEO-3\u7684\u8f6c\u5316\u662f\u4e00\u79cd\u5168\u65b0\u7684\u62d3\u6251\u7f29\u5408\u8def\u5f84\uff0c\u5b83\u7684\u53d1\u73b0\u4e3a\u6df1\u5165\u7814\u7a76\u5206\u5b50\u7b5b\u5408\u6210\u4e0e\u7ed3\u6784\u7684\u5173\u7cfb\u63d0\u4f9b\u4e86\u65b0\u7684\u7406\u89e3\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cA 3D Extra-Large Pore Zeolite Enabled by 1D-to-3D Topotactic Condensation of a Chain Silicate\u201d\u4e3a\u9898\u4e8e1\u670820\u65e5\u5728\u7ebf\u53d1\u8868\u4e8e\u56fd\u9645\u9876\u7ea7\u5b66\u672f\u520a\u7269Science\u6742\u5fd7\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u76f8\u5173\u7814\u7a76\u56e2\u961f2021\u5e74\u8fd8\u66fe\u62a5\u9053\u9996\u4f8b\u5177\u6709\u591a\u7ef4\u5ea6\u8d85\u5927\u5b54\u9053\u7ed3\u6784\u4e14\u7a33\u5b9a\u7684\u7845\u94dd\u9178\u76d0\u5206\u5b50\u7b5bZEO-1\uff08<em>Science<\/em> <strong>2021<\/strong>, <em>374<\/em>, 1605\uff09\u3002ZEO-1\u5df2\u88ab\u56fd\u9645\u5206\u5b50\u7b5b\u7ed3\u6784\u59d4\u5458\u4f1a\u6388\u4e88\u7ed3\u6784\u4ee3\u7801<strong>JZO<\/strong> (Jilin University-ZEO-1)\uff0cZEO-3\u7684\u7ed3\u6784\u4ee3\u7801\u4e5f\u6b63\u5728\u7533\u8bf7\u4e2d\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-246131\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1-7.png\" alt=\"\" width=\"1425\" height=\"1231\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1-7.png 1425w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1-7-300x259.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1-7-768x663.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1-7-1024x885.png 1024w\" sizes=\"(max-width: 1425px) 100vw, 1425px\" \/><\/p>\n<p>\u56fe1. ZEO-3\u7684\u8d85\u5927\u5b54\u9053\u7cfb\u7edf\uff08\u6765\u6e90\uff1aScience\uff09<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u8981\u70b9<\/strong><strong>1<\/strong><strong>\uff1a\u94fe\u72b6\u7845\u9178\u76d0\u524d\u9a71\u4f53\u7684\u5408\u6210\u4e0e\u7ed3\u6784<\/strong><\/p>\n<p>1D\u7845\u9178\u76d0\u524d\u9a71\u4f53ZEO-2\u662f\u4ee5\u4e09\u73af\u5df1\u57fa\u7532\u57fa\u93fb\uff08tricyclohexylmethylphosphonium\uff0ctCyMP\uff09\u4e3a\u6709\u673a\u6a21\u677f\u5242\u5408\u6210\u7684\u9488\u72b6\u6676\u4f53\uff0c\u5176\u590d\u6742\u7684\u94fe\u72b6\u7ed3\u6784\u662f\u901a\u8fc7\u8fde\u7eed\u503e\u8f6c\u4e09\u7ef4\u7535\u5b50\u884d\u5c04\uff08cRED\uff09\u6280\u672f\u786e\u5b9a\u7684\u3002ZEO-2\u5177\u6709<em>C<\/em>2\/<em>c<\/em>\u7a7a\u95f4\u7fa4\uff0c\u7ed3\u6784\u4e2d\u7684\u7845\u9178\u76d0\u94fe\u6cbf[001]\u65b9\u5411\u6392\u5217\uff0c\u6bcf\u6761\u94fe\u5728<em>ab<\/em>\u9762\u4e0a\u88ab\u56db\u6761\u76f8\u540c\u7684\u94fe\u5305\u56f4\uff08\u56fe2A\u548cC\uff09\uff0c\u800c\u5728\u94fe\u7684\u8fb9\u7f18\u5b58\u5728\u7531\u56db\u4e2a\u7845\u7f9f\u57fa\uff08Si-OH\uff09\u6216\u7845\u6c27\u8d1f\u79bb\u5b50\uff08Si-O<sup>&#8211;<\/sup>\uff09\u57fa\u56e2\u5f62\u6210\u7684\u5355\u56db\u5143\u73af\uff08S4R\uff09\uff0c\u94fe\u95f4\u7684S4R\u7a0d\u6709\u9519\u5f00\u4f46\u6cbf[110]\u548c[1-10]\u65b9\u5411\u4e24\u4e24\u914d\u5bf9\u5f62\u6210\u4e86\u5927\u91cf\u6c22\u952e\u4ee5\u7a33\u5b9aZEO-2\u7684\u7ed3\u6784\uff08\u56fe2B\uff09\uff0c\u800ctCyMP\u9633\u79bb\u5b50\u5219\u4f4d\u4e8e\u94fe\u95f4\u7a7a\u9699\u3002ZEO-2\u7684\u9ad8\u5206\u8fa8<sup>29<\/sup>Si\u56fa\u4f53\u6838\u78c1\u8c31\u63ed\u793a\u4e86\u56db\u79cdQ<sup>3<\/sup>\u548c\u4e03\u79cdQ<sup>4<\/sup>\u7684Si\u4f4d\u70b9\uff08\u56fe2D\uff09\uff0c\u8fd9\u4e0e\u5176\u6676\u4f53\u7ed3\u6784\u6570\u636e\u4e00\u81f4\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-246132\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2-6.png\" alt=\"\" width=\"1425\" height=\"588\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2-6.png 1425w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2-6-300x124.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2-6-768x317.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2-6-1024x423.png 1024w\" sizes=\"(max-width: 1425px) 100vw, 1425px\" \/><\/p>\n<p>\u56fe2. ZEO-2\u7684\u7ed3\u6784\uff1a\uff08A\uff09\u6cbf[001]\u65b9\u5411\u7684\u94fe\uff1b\uff08B\uff09\u94fe\u95f4\u4e24\u4e2aS4R\u4e4b\u95f4\u7684\u6c22\u952e\uff1b\uff08C\uff09<em>ab<\/em>\u9762\u4e0a\u7684\u94fe\u6392\u5e03\uff1b\uff08D\uff09<sup>29<\/sup>Si\u56fa\u4f53\u6838\u78c1\u8c31\uff08\u6765\u6e90\uff1aScience\uff09<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u8981\u70b9<\/strong><strong>2<\/strong><strong>\uff1a<\/strong><strong>1D<\/strong><strong>\u94fe\u5411<\/strong><strong>3D<\/strong><strong>\u8d85\u5927\u5b54\u5206\u5b50\u7b5b\u7684\u62d3\u6251\u7ed3\u6784\u8f6c\u5316<\/strong><\/p>\n<p>\u9ad8\u6e29\u7145\u70e7ZEO-2\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u53bb\u9664tCyMP\uff0c\u6c22\u952e\u4f5c\u7528\u7684\u4e24\u4e2aS4R\u4e4b\u95f4\u8fd8\u4f1a\u8131\u6c34\u7f29\u5408\u5f62\u6210Si-O-Si\u6865\u53caD4R\uff08\u56fe3A\uff09\uff0c\u8fd9\u4e5f\u662f\u9996\u6b21\u5728\u4e0d\u542bF<sup>&#8211;<\/sup>\u79bb\u5b50\u7684\u7eaf\u7845\u5206\u5b50\u7b5b\u4f53\u7cfb\u4e2d\u5f97\u5230D4R\u3002\u7531\u6b64\uff0c1D\u7684ZEO-2\u524d\u9a71\u4f53\u62d3\u6251\u8f6c\u5316\u4e3a3D\u7eaf\u7845\u5206\u5b50\u7b5bZEO-3\uff0c\u9488\u72b6\u5f62\u8c8c\u5f97\u5230\u4fdd\u6301\uff0c\u800ctCyMP\u7145\u70e7\u6b8b\u7559\u7684\u78f7\u53ef\u4ee5\u901a\u8fc7\u9ad8\u6e29\u6c34\u6d17\u6216H<sub>2<\/sub>\u8fd8\u539f\u800c\u9664\u53bb\u3002ZEO-3\u7684\u7ed3\u6784\u4e5f\u662f\u901a\u8fc7cRED\u6280\u672f\u89e3\u6790\u7684\uff0c\u5b83\u4fdd\u6301\u4e86ZEO-2\u7684\u5bf9\u79f0\u6027\u548c\u94fe\u7684\u62d3\u6251\u7ed3\u6784\uff0c\u4f46\u76f8\u6bd4ZEO-2\uff0c\u5176\u6676\u80de<em>a<\/em>\u548c<em>b<\/em>\u8f74\u6536\u7f29\u4e8617%\u3001<em>c<\/em>\u8f74\u81a8\u80c0\u4e86\u4ec50.4%\u3002\u4e3a\u4e86\u83b7\u5f97\u66f4\u51c6\u786e\u7684\u6676\u80de\u548c\u539f\u5b50\u4f4d\u7f6e\uff08\u5305\u62ecZEO-2\u4e2d\u65e0\u5e8f\u7684tCyMP\uff09\uff0c\u7814\u7a76\u4eba\u5458\u5bf9ZEO-2\u548cZEO-3\u5f00\u5c55\u4e86\u540c\u6b65\u8f90\u5c04\u7c89\u672bX-\u5c04\u7ebf\u884d\u5c04\u7684\u7ed3\u6784\u7cbe\u4fee\u3002ZEO-3\u662f\u5168\u8fde\u63a5\u7684\u8d85\u5927\u5b54\u5206\u5b50\u7b5b\uff0c\u5177\u6709\u9996\u4f8b3D 16\u00d714\u00d714 MR\u7684\u5b54\u9053\u7cfb\u7edf\uff08\u56fe3B\u548cC\uff09\uff0c\u4e3a\u7a33\u5b9a\u7684\u8d85\u5927\u5b54\u5168\u8fde\u63a5\u7eaf\u7845\u5206\u5b50\u7b5b\u4e4b\u6700\uff0c\u5176<sup>29<\/sup>Si\u56fa\u4f53\u6838\u78c1\u8c31\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e861D\u52303D\u7684\u62d3\u6251\u7ed3\u6784\u8f6c\u5316\uff0c\u5373\u4ec5\u6709Q<sup>4<\/sup>\u7684Si\u4f4d\u70b9\uff08\u56fe3D\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-246133\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3-6.png\" alt=\"\" width=\"1425\" height=\"552\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3-6.png 1425w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3-6-300x116.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3-6-768x297.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3-6-1024x397.png 1024w\" sizes=\"(max-width: 1425px) 100vw, 1425px\" \/><\/p>\n<p>\u56fe3. ZEO-3\u7684\u7ed3\u6784\uff1a\uff08A\uff09D4R\u5355\u5143\uff1b\uff08B\uff09\u6cbf[110]\u548c[1-10]\u65b9\u5411\u768414MR\u5b54\u9053\uff1b\uff08C\uff09\u6cbf[001]\u65b9\u5411\u768416MR\u5b54\u9053\uff1b\uff08D\uff09<sup>29<\/sup>Si\u56fa\u4f53\u6838\u78c1\u8c31\uff08\u6765\u6e90\uff1aScience\uff09<\/p>\n<p>&nbsp;<\/p>\n<p>\u7403\u5dee\u7535\u955c\u518d\u6b21\u8bc1\u5b9e\u4e86ZEO-2\u548cZEO-3\u7684\u7ed3\u6784\uff08\u56fe4\uff09\u3002\u5728ZEO-2\u94fe\u95f4\u8fd8\u51fa\u73b0\u4e86\u5bf9\u5e94\u4e8etCyMP\u7684\u5fae\u5f31\u4fe1\u53f7\uff0c\u800c\u8be5\u4f4d\u7f6e\u5728\u62d3\u6251\u7ed3\u6784\u8f6c\u5316\u540e\u5c06\u6210\u4e3aZEO-3\u768414MR\u5b54\u9053\uff0c\u800cZEO-3\u768416MR\u548c14MR\u5b54\u9053\u6e05\u6670\u53ef\u89c1\uff0c\u6b64\u5916\u8fd8\u89c2\u5bdf\u5230\u4e86\u4e24\u79cd\u6750\u6599\u4e2d\u8f83\u5c0f\u76844\u30015\u548c6MR\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-246134\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4-6.png\" alt=\"\" width=\"1425\" height=\"483\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4-6.png 1425w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4-6-300x102.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4-6-768x260.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4-6-1024x347.png 1024w\" sizes=\"(max-width: 1425px) 100vw, 1425px\" \/><\/p>\n<p>\u56fe4. ZEO-2\u548cZEO-3\u7684\u7403\u5dee\u7535\u955c\u7167\u7247\uff1a\uff08A\uff09\u6cbf[110]\u5e26\u8f74\u7684ZEO-2\uff1b\uff08B\uff09\u6cbf[110]\u5e26\u8f74\u7684ZEO-3\uff1b\uff08C\uff09\u6cbf[001]\u5e26\u8f74\u7684ZEO-3\uff08\u6765\u6e90\uff1aScience\uff09<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u8981\u70b9<\/strong><strong>3<\/strong><strong>\uff1a\u62d3\u6251\u5206\u6790\u4e0e<\/strong><strong>Beta<\/strong><strong>\u5206\u5b50\u7b5b\u7684<\/strong><strong>\u03c3<\/strong><strong>\u7ed3\u6784\u62d3\u5c55<\/strong><\/p>\n<p>\u62d3\u6251\u7ed3\u6784\u5206\u6790\u8868\u660e\uff0cZEO-2\u7684\u94fe\u662f\u7531<em>mtw<\/em>\u3001<em>bea<\/em>\u548c<em>mor<\/em>\u7684\u590d\u5408\u6784\u7b51\u5355\u5143\uff08composite building unit\uff0cCBU\uff09\u5f62\u6210\u7684\uff0c\u5b83\u4eec\u53ef\u4ee5\u7ec4\u5408\u4e3a\u4e00\u4e2a\u66f4\u5927\u7684\u7ed3\u6784\u5355\u5143\uff0c\u800cZEO-3\u5728\u62d3\u6251\u4e0a\u4ec5\u6bd4ZEO-2\u591a\u51fa<em>d<\/em>4<em>r<\/em>\uff08\u5bf9\u5e94D4R\uff09\u7684CBU\uff08\u56fe5A\uff09\u3002\u5927\u7ed3\u6784\u5355\u5143\u6309\u7167+90\u00b0\u4e0e-90\u00b0\u4ea4\u66ff\u7684\u65cb\u8f6c\u8fde\u63a5\uff0c\u53ef\u4ee5\u6784\u6210ZEO-2\u7684\u94fe\uff08\u56fe5B\uff09\uff0c\u8be5\u94fe\u4e5f\u88ab\u53d1\u73b0\u4e8eBeta\u5206\u5b50\u7b5b\u7684\u591a\u578b\u4f53B\uff08BEB\uff0c\u975e\u516c\u8ba4\u4ee3\u7801\uff09\u4e2d\uff0c\u5373ZEO-2\u7684\u94fe\u901a\u8fc7\u5171\u4eabS4R\uff08\u800c\u975eZEO-3\u4e2d\u7684D4R\uff09\u7684\u8fde\u63a5\u53ef\u5f62\u6210BEB\u7684\u7ed3\u6784\uff08\u56fe5F\uff09\uff1b\u82e5\u5927\u7ed3\u6784\u5355\u5143\u603b\u662f\u6309\u7167+90\u00b0\u6216\u603b\u662f\u6309\u7167-90\u00b0\u7684\u65cb\u8f6c\u8fde\u63a5\uff0c\u5c06\u4ea7\u751f\u4e00\u4e2a\u624b\u6027\u94fe\uff08\u56fe5C\uff09\uff0c\u8be5\u94fe\u901a\u8fc7\u5171\u4eabS4R\u7684\u8fde\u63a5\u65b9\u5f0f\u5219\u80fd\u5f62\u6210Beta\u5206\u5b50\u7b5b\u7684\u624b\u6027\u591a\u578b\u4f53A\uff08<strong>BEA<\/strong>\uff0c\u7a7a\u95f4\u7fa4\u4e3a<em>P<\/em>4<sub>1<\/sub>22\u6216<em>P<\/em>4<sub>3<\/sub>22\uff09\uff08\u56fe5G\uff09\uff0c\u8be5\u94fe\u7531\u6b64\u53ef\u79f0\u4e3a<em>bea<\/em>\u94fe\u3002\u901a\u8fc7<em>d<\/em>4<em>r<\/em>\u7684\u8fde\u63a5\uff0c\u53ef\u4ee5\u5b9e\u73b01D ZEO-2\u94fe\u54113D ZEO-3\u5206\u5b50\u7b5b\u7684\u62d3\u6251\u8f6c\u53d8\uff08\u56fe5D\uff09\uff1b\u7c7b\u4f3c\u5730\uff0c<em>bea<\/em>\u94fe\u901a\u8fc7<em>d<\/em>4<em>r<\/em>\u7684\u8fde\u63a5\u5c06\u5bfc\u5411\u4e00\u4e2a\u624b\u6027\u7684\u3001\u5177\u67093D 16\u00d714\u00d714 MR\u8d85\u5927\u5b54\u9053\u7ed3\u6784\u7684\u5047\u60f3\u5206\u5b50\u7b5b\u03c3-<strong>BEA<\/strong>\uff08\u7a7a\u95f4\u7fa4\u540c\u6837\u4e3a<em>P<\/em>4<sub>1<\/sub>22\u6216<em>P<\/em>4<sub>3<\/sub>22\uff09\uff08\u56fe5E\uff09\u3002\u8fd9\u4e9b\u53d1\u73b0\u8868\u660e, ZEO-3\u4e0eBeta\u5206\u5b50\u7b5b\u5728\u7ed3\u6784\u4e0a\u9ad8\u5ea6\u5173\u8054\uff0cZEO-3\u548c\u03c3-<strong>BEA<\/strong>\u5206\u522b\u5bf9\u5e94BEB\u548c<strong>BEA<\/strong>\u5206\u5b50\u7b5b\u7684\u03c3\u7ed3\u6784\u62d3\u5c55\u3002\u7406\u8bba\u7814\u7a76\u8fd8\u8868\u660e\uff0cZEO-3\u548c\u03c3-<strong>BEA<\/strong>\u7684\u80fd\u91cf\u90fd\u63a5\u8fd1\u5df2\u77e5\u5206\u5b50\u7b5b\u7684\u80fd\u91cf-\u5bc6\u5ea6\u5173\u7cfb\uff0cZEO-3\u7684\u5408\u6210\u4e5f\u9884\u793a\u7740\u5047\u60f3\u03c3-<strong>BEA<\/strong>\u662f\u53ef\u884c\u7684\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-246135\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5-6.png\" alt=\"\" width=\"2175\" height=\"1920\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5-6.png 2175w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5-6-300x265.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5-6-768x678.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5-6-1024x904.png 1024w\" sizes=\"(max-width: 2175px) 100vw, 2175px\" \/><\/p>\n<p>\u56fe5. ZEO-2\u3001ZEO-3\u4e0eBeta\u5206\u5b50\u7b5b\u7684\u62d3\u6251\u5206\u6790\uff1a\uff08A\uff09\u5355\u72ec\u7684CBU\u53ca\u7531\u5176\u6784\u7b51\u7684\u5927\u7ed3\u6784\u5355\u5143\uff1b\uff08B\uff09ZEO-2\u7684\u94fe\uff1b\uff08C\uff09<em>bea<\/em>\u94fe\uff1b\uff08D\uff09ZEO-3\uff1b\uff08E\uff09\u03c3-<strong>BEA<\/strong>\uff1b\uff08F\uff09BEB\uff1b\uff08G<strong>\uff09<\/strong><strong>BEA<\/strong><strong>\uff08<\/strong>\u6765\u6e90\uff1aScience\uff09<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u8981\u70b9<\/strong><strong>4<\/strong><strong>\uff1a<\/strong><strong>ZEO-3<\/strong><strong>\u5206\u5b50\u7b5b\u7684\u6027\u8d28<\/strong><\/p>\n<p>\u4e09\u7ef4\u8d85\u5927\u5b54\u9053\u7ed3\u6784\u5bfc\u81f4ZEO-3\u5177\u6709\u975e\u5e38\u4f4e\u7684\u9aa8\u67b6\u5bc6\u5ea6\uff08FD\uff09\uff0c\u4e3a12.76\u4e2a\u56db\u9762\u4f53\u539f\u5b50\uff08T\uff09\/1000 \u00c5<sup>3<\/sup>\uff0c\u8fd9\u4f4e\u4e8e\u5176\u4ed6\u7a33\u5b9a\u7684\u3001\u4f4e\u9aa8\u67b6\u5bc6\u5ea6\u7684\u7845\uff08\u94dd\uff09\u9178\u76d0\u5206\u5b50\u7b5b\uff08\u5305\u62ec<strong>FAU<\/strong>\u3001<strong>EMT<\/strong>\u3001*<strong>BEA<\/strong>\u3001<strong>BEC<\/strong>\u3001<strong>ISV<\/strong>\u548c<strong>IWV<\/strong>\uff0c\u4ee5\u53ca\u6700\u8fd1\u62a5\u9053\u7684PST-2\u3001PST-32\u548cZEO-1\uff09\u3002\u4e8b\u5b9e\u4e0a\uff0cZEO-3\u6253\u7834\u4e86\u5206\u5b50\u7b5b\u9aa8\u67b6\u5bc6\u5ea6\u548c\u6700\u5c0f\u5143\u73af\u5c3a\u5bf8\u95f4\u5df2\u89c2\u6d4b\u5230\u7684\u8d8b\u52bf\uff1a\u5bf9\u4e8e\u5177\u6709\u5e73\u57474.25 MR\u6700\u5c0f\u5143\u73af\u7684\u5206\u5b50\u7b5b\uff0c\u5176\u9884\u6d4b\u7684\u6700\u5c0fFD\u4e3a13\uff0c\u8fd9\u6bd4ZEO-3\u66f4\u5927\uff1b\u4e0e\u542b\u67094\u548c5 MR\u7684\u5168\u8fde\u63a5\u7ed3\u6784\u5206\u5b50\u7b5b<strong>ISV<\/strong>\u548c<strong>IWV<\/strong>\u76f8\u6bd4\uff0cZEO-3\u7684FD\u4e5f\u6bd4\u5b83\u4eec15\u7684FD\u66f4\u5c0f\u3002ZEO-3\u7684\u7406\u8bba\u5bc6\u5ea6\u63a5\u8fd1\u6c34\uff0c\u4ec5\u4e3a1.27 g\/cm<sup>3<\/sup>\uff0c\u4e0d\u5230\u77f3\u82f1\uff082.65 g\/cm<sup>3<\/sup>\uff09\u5bc6\u5ea6\u7684\u4e00\u534a\u3002ZEO-3\u5728N<sub>2<\/sub>\u548cAr\u5438\u9644\u6d4b\u8bd5\u4e2d\u5c55\u73b0\u4e86\u8d85\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u5206\u522b\u4e3a989\u548c1032 m<sup>2<\/sup>\/g\uff0cAr\u5438\u9644\u5b9e\u9a8c\u5f97\u5230\u7684\u5e73\u5747\u5b54\u5f84\u4e3a10.8\u548c8.8 \u00c5\uff0c\u8fd9\u4e0e\u6676\u4f53\u5b66\u6570\u636e\u5339\u914d\u5f97\u5f88\u597d\u3002\u8fd9\u4e9b\u7ed3\u679c\u9a8c\u8bc1\u4e86ZEO-3\u975e\u5e38\u7a7a\u65f7\u7684\u9aa8\u67b6\u7ed3\u6784\u3002<\/p>\n<p>ZEO-3\u8d85\u5927\u7684\u5b54\u5f84\u5141\u8bb8\u5927\u5206\u5b50\u7684\u6269\u6563\u548c\u5438\u9644\uff0c\u53ef\u7528\u4e8e\u6325\u53d1\u6027\u6709\u673a\u7269\uff08VOCs\uff09\u7684\u5904\u7406\u3002\u5728\u9759\u6001\u5438\u9644\u5b9e\u9a8c\u4e2d\uff0cZEO-3\u5bf9\u7532\u82ef\u548c\u6c34\u84b8\u6c14\u7684\u9971\u548c\u5438\u9644\u91cf\u5747\u6bd4\u5b54\u5f84\u66f4\u5c0f\u7684Beta\u5206\u5b50\u7b5b\u66f4\u9ad8\uff08\u56fe6A\uff09\uff1b\u5728\u52a8\u6001\u7a7f\u900f\u5b9e\u9a8c\u4e2d\uff0cZEO-3\u5bf9\u7eaf\u7532\u82ef\u548c\u7532\u82ef\u4e0e\u6c34\u84b8\u6c14\u6df7\u5408\u7269\u8fd9\u4e24\u79cdVOCs\u7684\u7a7f\u900f\u65f6\u95f4\u5747\u957f\u4e8eBeta\u5206\u5b50\u7b5b\uff08\u56fe6B\uff09\uff0c\u8868\u660e\u66f4\u9ad8\u7684\u52a8\u6001\u5438\u9644\u91cf\uff1b\u8fd9\u4e24\u79cdVOCs\u5728ZEO-3\u5b54\u9053\u4e2d\u7684\u8131\u9644\u6e29\u5ea6\u4e5f\u4f4e\u4e8eBeta\u5206\u5b50\u7b5b\uff08\u56fe6C\uff09\u3002\u6b64\u5916\uff0cZEO-3\u5bf9\u4e0a\u8ff0VOCs\u7684\u5438\u9644\u7a33\u5b9a\u6027\u4e5f\u8981\u4f18\u4e8e\u5546\u4e1a\u7684UiO-66 MOFs\u6750\u6599\uff0c\u7ecf\u8fc7\u6570\u6b21\u5438\u8131\u9644\u518d\u751f\u5faa\u73af\u540eZEO-3\u5bf9VOCs\u7684\u5438\u9644\u91cf\u51e0\u65e0\u8870\u51cf\uff0c\u8868\u73b0\u6027\u80fd\u4f18\u5f02\u3002\u4f7f\u7528\u7532\u82ef\u4e0e\u6c34\u84b8\u6c14\u7684\u6df7\u5408\u7269\u66f4\u5177\u6709\u5de5\u4e1a\u5e94\u7528\u4ef7\u503c\uff0c\u76f8\u6bd4\u8f83\u4e8e\u4f20\u7edf\u4f7f\u7528\u7684\u5206\u5b50\u7b5b\u6750\u6599\uff0cZEO-3\u5177\u6709\u66f4\u5927\u7684\u5438\u9644\u5bb9\u91cf\uff0c\u4ee5\u53ca\u5176\u9ad8\u7a33\u5b9a\u6027\u4e5f\u4fdd\u8bc1\u4e86\u5176\u6f5c\u5728\u5546\u4e1a\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-246136\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe6-4.png\" alt=\"\" width=\"2175\" height=\"720\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe6-4.png 2175w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe6-4-300x99.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe6-4-768x254.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe6-4-1024x339.png 1024w\" sizes=\"(max-width: 2175px) 100vw, 2175px\" \/><\/p>\n<p>\u56fe6. ZEO-3\u5904\u7406VOCs\u7684\u6027\u80fd\uff1a\uff08A\uff09\u9759\u6001\u5438\u9644\uff1b\uff08B\uff09\u52a8\u6001\u5438\u9644\uff1b\uff08C\uff09\u8131\u9644\u66f2\u7ebf\uff08\u6765\u6e90\uff1aScience\uff09<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u5c0f\u7ed3<\/strong><\/p>\n<p>\u8be5\u5de5\u4f5c\u62a5\u9053\u4e86\u9996\u4f8b\u5177\u6709\u5168\u8fde\u63a5\u8d85\u5927\u5b54\u9053\u7a33\u5b9a\u7ed3\u6784\u7684\u7845\u9178\u76d0\u5206\u5b50\u7b5bZEO-3\uff0c\u5b83\u662f\u901a\u8fc71D\u94fe\u72b6\u7845\u9178\u76d0ZEO-2\u7684\u62d3\u6251\u7f29\u5408\u5f97\u5230\u7684\u3002ZEO-3\u7ed3\u6784\u72ec\u7279\uff0c\u4e0eBeta\u5206\u5b50\u7b5b\u6709\u4e00\u5b9a\u7684\u62d3\u6251\u76f8\u4f3c\u6027\uff0c\u7eaf\u7845\u8d85\u5927\u5b54\u7ed3\u6784\u4f7f\u5176\u5c55\u73b0\u51fa\u4f18\u5f02\u7684VOCs\u5904\u7406\u6027\u80fd\u3002ZEO-3\u7684\u7ed3\u6784\u7279\u5f81\uff0c\u5c24\u5176\u662f\u65e0F<sup>&#8211;<\/sup>\u7684\u7eaf\u7845D4R\u548c\u4f4e\u4e8e\u9884\u671f\u7684FD\uff0c\u660e\u663e\u4e0d\u540c\u4e8e\u76f4\u63a5\u5408\u6210\u7684\u5df2\u77e5\u5206\u5b50\u7b5b\u3002\u8fd9\u79cd\u4e00\u7ef4\u5230\u4e09\u7ef4\u7684\u62d3\u6251\u8f6c\u53d8\u8fc7\u7a0b\u9884\u793a\u7740\u4e00\u79cd\u65b0\u7684\u5206\u5b50\u7b5b\u6676\u5316\u673a\u5236\uff0c\u5bf9\u4f20\u7edf\u5206\u5b50\u7b5b\u6676\u5316\u673a\u7406\u63d0\u51fa\u4e86\u6311\u6218\uff0c\u5bf9\u5176\u8fdb\u884c\u6df1\u5165\u7814\u7a76\u5c06\u5bf9\u5206\u5b50\u7b5b\u65b0\u7ed3\u6784\u7684\u5408\u6210\u62d3\u5c55\u53ca\u6676\u5316\u673a\u7406\u7684\u8fdb\u4e00\u6b65\u9610\u660e\u90fd\u5177\u6709\u91cd\u8981\u7684\u7406\u8bba\u548c\u73b0\u5b9e\u610f\u4e49\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u8be5\u6210\u679c\u5408\u4f5c\u56e2\u961f\u8fd8\u6709\u4e2d\u56fd\u79d1\u5b66\u9662\u57ce\u5e02\u73af\u5883\u7814\u7a76\u6240\u9093\u534e\u526f\u7814\u7a76\u5458\u548c\u8d3a\u6cd3\u9662\u58eb\u3001\u9ebb\u7701\u5927\u5b66\u963f\u9ed8\u65af\u7279\u5206\u6821\u8303\u709c\u6559\u6388\u7b49\uff0c\u8be5\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u201c\u5206\u5b50\u7b5b\u50ac\u5316\u6750\u6599\u7684\u5206\u5b50\u5de5\u7a0b\u5b66\u201d\u57fa\u7840\u79d1\u5b66\u4e2d\u5fc3\u9879\u76ee\uff0822288101\uff09\u3001\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\uff082022YFA1503600\u30012021YFA1501202\uff09\u3001111\u8ba1\u5212\uff08B17020\uff09\u7b49\u9879\u76ee\u652f\u6301\u3002<\/p>\n<p><strong>\u7b2c\u4e00\u4f5c\u8005<\/strong>\uff1aJian Li\uff08\u9ece\u5efa\uff09\uff0cZihao Rei Gao\uff08\u9ad8\u5b50\u8c6a\uff09\uff0cQing-Fang Lin\uff08\u6797\u6e05\u82b3\uff09<\/p>\n<p><strong>\u901a\u8baf\u4f5c\u8005<\/strong>\uff1aJian Li\uff08\u9ece\u5efa\uff09\uff0cMiguel A. Camblor\uff0cFei-Jian Chen\uff08\u9648\u98de\u5251\uff09\uff0cJihong Yu\uff08\u4e8e\u5409\u7ea2\uff09<\/p>\n<p><strong>\u901a\u8baf\u5355\u4f4d<\/strong>\uff1aStockholm University, Anhui ZEO New Material Technology Co. Ltd., Peking University, Instituto de Ciencia de Materiales de Madrid, Bengbu Medical College, Jilin University<\/p>\n<p><strong>\u53c2\u8003\u6587\u732e<\/strong><\/p>\n<p>Jian Li<sup>*\u2020<\/sup>, Zihao Rei Gao<sup>\u2020<\/sup>, Qing-Fang Lin<sup>\u2020<\/sup>, Chenxu Liu, Fangxin Gao, Cong Lin, Siyao Zhang, Hua Deng, Alvaro Mayoral, Wei Fan, Song Luo, Xiaobo Chen, Hong He, Miguel A. Camblor<sup>*<\/sup>, Fei-Jian Chen<sup>*<\/sup>, Jihong Yu<sup>*<\/sup>. A 3D Extra-large Pore Zeolite Enabled by 1D-to-3D Topotactic Condensation of a Chain Silicate. <em>Science<\/em> <strong>2023<\/strong>, <em>379<\/em>(6629), DOI: 10.1126\/science.ade1771.<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/www.science.org\/doi\/10.1126\/science. ade1771<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u7814\u7a76\u56e2\u961f\u4ecb\u7ecd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-246137\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u4e8e\u5409\u7ea2.png\" alt=\"\" width=\"451\" height=\"637\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u4e8e\u5409\u7ea2.png 451w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u4e8e\u5409\u7ea2-212x300.png 212w\" sizes=\"(max-width: 451px) 100vw, 451px\" \/><\/p>\n<p><strong>\u4e8e\u5409\u7ea2\u9662\u58eb<\/strong><\/p>\n<p>\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\uff0c\u53d1\u5c55\u4e2d\u56fd\u5bb6\u79d1\u5b66\u9662\u9662\u58eb\uff0c\u6b27\u6d32\u79d1\u5b66\u9662\u5916\u7c4d\u9662\u58eb\uff0c\u745e\u5178\u7687\u5bb6\u79d1\u5b66\u9662\u5916\u7c4d\u9662\u58eb\uff0c\u5409\u6797\u5927\u5b66\u672a\u6765\u79d1\u5b66\u56fd\u9645\u5408\u4f5c\u8054\u5408\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\uff0c\u5409\u6797\u5927\u5b66\u5316\u5b66\u5b66\u9662\u6559\u6388\u3002<\/p>\n<p>\u73b0\u4efb\u7f8e\u56fd\u5316\u5b66\u4f1aJACS\u6267\u884c\u4e3b\u7f16\uff0c\u300a\u9ad8\u7b49\u5b66\u6821\u5316\u5b66\u5b66\u62a5\u300b\u548cChemical Research in Chinese Universities\u4e3b\u7f16\uff0cChemical Reviews\u3001Accounts of Chemical Research\u3001JACS-Au\u3001Advanced Materials\u3001Chem\u3001Matter\u3001ACS Nano\u3001National Science Review\u7b49\u56fd\u9645\u671f\u520a\u7f16\u59d4\/\u987e\u95ee\u7f16\u59d4\u3002\u62c5\u4efb\u4e2d\u56fd\u5316\u5b66\u4f1a\u526f\u7406\u4e8b\u957f\u3001\u4e2d\u56fd\u5316\u5b66\u4f1a\u5206\u5b50\u7b5b\u4e13\u4e1a\u59d4\u5458\u4f1a\u4e3b\u4efb\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u5206\u5b50\u7b5b\u7eb3\u7c73\u5b54\u6750\u6599\u7684\u5206\u5b50\u5de5\u7a0b\u5b66\u7814\u7a76\uff0c\u81f4\u529b\u4e8e\u5206\u5b50\u7b5b\u6750\u6599\u7684\u8bbe\u8ba1\u5408\u6210\u53ca\u5176\u5728\u80fd\u6e90\u3001\u73af\u5883\u53ca\u65b0\u5174\u9886\u57df\u7684\u5e94\u7528\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u5728 Science\u3001Nature\u3001Nat. Rev. Mater.\u3001J. Am. Chem. Soc.\u3001Angew. Chem. Int. Ed.\u3001Chem\u3001Adv. Mater.\u3001Natl. Sci. Rev.\u3001CCS Chem.\u7b49\u671f\u520a\u4e0a\u3002\u73b0\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u57fa\u7840\u79d1\u5b66\u4e2d\u5fc3\u9879\u76ee\uff0c\u662f\u9996\u6279\u201c\u5168\u56fd\u9ad8\u6821\u9ec4\u5927\u5e74\u5f0f\u6559\u5e08\u56e2\u961f\u201d\u8d1f\u8d23\u4eba\uff0c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u521b\u65b0\u7814\u7a76\u7fa4\u4f53\u5b66\u672f\u5e26\u5934\u4eba\u3001\u201c\u9ad8\u7b49\u5b66\u6821\u5b66\u79d1\u521b\u65b0\u5f15\u667a\u8ba1\u5212\u201d\u57fa\u5730\u8d1f\u8d23\u4eba\u3002\u66fe\u83b7\u5f97\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\u4e24\u9879\u3001\u56fd\u9645\u7eaf\u7cb9\u4e0e\u5e94\u7528\u5316\u5b66\u8054\u5408\u4f1a\uff08IUPAC\uff09\u5316\u5b66\u5316\u5de5\u6770\u51fa\u5973\u6027\u5956\u3001\u4f55\u6881\u4f55\u5229\u57fa\u91d1\u79d1\u5b66\u4e0e\u6280\u672f\u8fdb\u6b65\u5956\u4ee5\u53ca\u201c\u5168\u56fd\u6a21\u8303\u6559\u5e08\u201d\u7b49\u8363\u8a89\u79f0\u53f7\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-246138\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u9648\u98de\u5251.png\" alt=\"\" width=\"295\" height=\"403\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u9648\u98de\u5251.png 295w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u9648\u98de\u5251-220x300.png 220w\" sizes=\"(max-width: 295px) 100vw, 295px\" \/><\/p>\n<p><strong>\u9648\u98de\u5251\u6559\u6388<\/strong><\/p>\n<p>\u5409\u6797\u5927\u5b66\u5316\u5b66\u5b66\u9662\u201c\u5510\u6556\u5e86\u5b66\u8005\u201d\u9886\u519b\u6559\u6388A\u5c97\u3001\u8bfe\u9898\u7ec4\u7ec4\u957f\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u30012022\u5e74\u5165\u9009\u56fd\u5bb6\u7ea7\u201c\u56db\u9752\u201d\u4eba\u624d\uff0c\u5206\u522b\u4e8e2007\u5e74\/2010\u5e74\u672c\u79d1\/\u7855\u58eb\u6bd5\u4e1a\u4e8e\u4e2d\u56fd\u77ff\u4e1a\u5927\u5b66\u5e94\u7528\u5316\u5b66\u4e13\u4e1a\uff08\u5bfc\u5e08\uff1a\u9b4f\u8d24\u52c7\u6559\u6388\uff09\uff0c2014\u5e74\u535a\u58eb\u6bd5\u4e1a\u4e8e\u5357\u4eac\u5927\u5b66\u5316\u5b66\u4e13\u4e1a\uff08\u5bfc\u5e08\uff1a\u675c\u7ea2\u5bbe\u6559\u6388\uff09\uff0c\u4e4b\u540e\u81f3\u868c\u57e0\u533b\u5b66\u9662\u5de5\u4f5c\uff0c2022\u5e74\u52a0\u5165\u5409\u6797\u5927\u5b66\u5316\u5b66\u5b66\u9662\u4e8e\u5409\u7ea2\u9662\u58eb\u8bfe\u9898\u7ec4\u3002\u4e13\u6ce8\u4e8e\u65b0\u578b\u5927\u5b54\u548c\u8d85\u5927\u5b54\u5206\u5b50\u7b5b\u7684\u5408\u6210\u4e0e\u6027\u80fd\u7814\u7a76\uff0c\u8bfe\u9898\u7ec4\u957f\u671f\u6b22\u8fce\u6709\u5fd7\u4ece\u4e8b\u5206\u5b50\u7b5b\u5408\u6210\u4e0e\u5e94\u7528\u7814\u7a76\u7684\u7855\u535a\u7533\u8bf7\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-246139\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u9ece\u5efa.png\" alt=\"\" width=\"2160\" height=\"3040\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u9ece\u5efa.png 2160w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u9ece\u5efa-213x300.png 213w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u9ece\u5efa-768x1081.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u9ece\u5efa-728x1024.png 728w\" sizes=\"(max-width: 2160px) 100vw, 2160px\" \/><\/strong><\/p>\n<p><strong>\u9ece\u5efa\u535a\u58eb<\/strong><\/p>\n<p>\u5357\u4eac\u5927\u5b66\u7279\u8058\u7814\u7a76\u5458\uff08tenure-track\u526f\u6559\u6388\uff09\u3001\u8bfe\u9898\u7ec4\u7ec4\u957f\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff082\u6708\u4efd\u5f00\u5b66\u540e\u9074\u9009\u8bc4\u5ba1\uff09\u30012022\u5e74\u5165\u9009\u56fd\u5bb6\u7ea7\u9ad8\u5c42\u6b21\u4eba\u624d\u5f15\u8fdb\u8ba1\u5212\uff08\u9752\u5e74\u9879\u76ee\uff09\u30022013\u5e74\u91cd\u5e86\u5927\u5b66\u672c\u79d1\u6bd5\u4e1a\uff0c2018\u5e74\u5317\u4eac\u5927\u5b66\u65e0\u673a\u5316\u5b66\u4e13\u4e1a\u535a\u58eb\u6bd5\u4e1a\uff08\u5bfc\u5e08\uff1a\u5b59\u4fca\u826f\u6559\u6388\uff0c\u56fd\u5bb6\u6770\u9752\uff09\uff0c2018-2020\u5e74\u5728\u745e\u5178\u65af\u5fb7\u54e5\u5c14\u6469\u5927\u5b66\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff08\u5408\u4f5c\u5bfc\u5e08\uff1aXiaodong Zou\u6559\u6388\uff0c\u745e\u5178\u7687\u5bb6\u79d1\u5b66\u9662\u548c\u7687\u5bb6\u5de5\u7a0b\u9662\u4e24\u9662\u9662\u58eb\uff0c\u8bfa\u8d1d\u5c14\u5956\u5316\u5b66\u59d4\u5458\u4f1a\u59d4\u5458\uff0c\u5206\u5b50\u7b5b\u7ed3\u6784\u59d4\u5458\u4f1a\u59d4\u5458\uff09\uff1b2020-2022\u5e74\u5728\u745e\u5178\u7687\u5bb6\u7406\u5de5\u5b66\u9662\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff08\u5408\u4f5c\u5bfc\u5e08\uff1aMahiar Hamedi\u6559\u6388\uff09\u30022022\u5e7412\u6708\u52a0\u5165\u5357\u4eac\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u548c\u914d\u4f4d\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u3002\u76ee\u524d\u4e3b\u8981\u81f4\u529b\u4e8e\u65b0\u578b\u65e0\u673a\u529f\u80fd\u6750\u6599\u7684\u5f00\u53d1\uff0c\u591a\u5b54\u529f\u80fd\u6750\u6599\u3001\u81f4\u5bc6\u590d\u5408\u91d1\u5c5e\u6c27\u5316\u7269\u6750\u6599\u7684\u7ed3\u6784\u786e\u5b9a\u4e0e\u6784\u6548\u5173\u7cfb\uff0c\u7535\u5b50\u6676\u4f53\u5b66\u548cX\u5c04\u7ebf\u6676\u4f53\u5b66\u5728\u5fae\u7eb3\u6676\u4f53\u7ed3\u6784\u786e\u5b9a\u4e2d\u7684\u5e94\u7528\u7b49\u76f8\u5173\u7814\u7a76\u3002\u4e3b\u8981\u6210\u679c\u4ee5\u7b2c\u4e00\u6216\u8005\u5171\u540c\u901a\u8baf\u4f5c\u8005\u53d1\u8868\u5728Science\u3001Acc. Chem. Res.\u3001J. Am. Chem. Soc.\u3001Angew. Chem. Int. Ed.\u3001Nat. Commun.\u3001Adv. Energy Mater.\u3001ACS Nano\u7b49\u5316\u5b66\u548c\u6750\u6599\u9886\u57df\u9876\u7ea7\u671f\u520a\u4e0a\uff1b2019\u5e74\u83b7\u5f97\u56fd\u9645\u6676\u4f53\u5b66\u4f1a\uff08International Union of Crystallography\uff0cIUCr\uff09\u9881\u53d1\u7684\u9752\u5e74\u79d1\u5b66\u5bb6\u5956\uff08IUCr Young Scientists Award\uff09\u7b49\u3002<\/p>\n<p><strong>\u62db\u8058\u4fe1\u606f<\/strong><\/p>\n<p>\u9ece\u5efa\u8bfe\u9898\u7ec4\u56e0\u5de5\u4f5c\u9700\u8981\u8bda\u62db\u65e0\u673a\u529f\u80fd\u6750\u6599\uff08\u591a\u5b54\u6750\u6599\u548c\u590d\u5408\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u786b\u5316\u7269\uff09\u5408\u6210\u4e0e\u5e94\u7528\u65b9\u5411\u7684\u535a\u58eb\u540e\uff081-2\u540d\uff09\u53ca\u79d1\u7814\u52a9\u7406\uff08\u82e5\u5e72\uff09\uff0c\u6b22\u8fce\u5177\u6709\u65e0\u673a\u5316\u5b66\u3001\u6750\u6599\u5316\u5b66\u3001\u914d\u4f4d\u5316\u5b66\u7b49\u9886\u57df\u7814\u7a76\u7ecf\u5386\u7684\u9752\u5e74\u624d\u4fca\u52a0\u76df\u3002\u5f85\u9047\uff1a1. \u535a\u58eb\u540e\u4eab\u53d7\u5357\u4eac\u5927\u5b66\u535a\u58eb\u540e\u5404\u79cd\u798f\u5229\u5f85\u9047\uff08\u843d\u6237\u3001\u516c\u5bd3\u3001\u5b50\u5973\u5165\u5b66\u3001\u793e\u4fdd\u548c\u516c\u79ef\u91d1\u7b49\uff09\uff0c\u57fa\u7840\u5e74\u85aa20\u4e07\u8d77\uff0c\u7279\u522b\u4f18\u79c0\u8005\u5f85\u9047\u9762\u8bae\uff1b\u652f\u6301\u7533\u62a5\u5357\u4eac\u5927\u5b66\u3001\u6c5f\u82cf\u7701\u548c\u56fd\u5bb6\u5404\u4e2a\u5c42\u6b21\u535a\u58eb\u540e\u8ba1\u5212\uff0c\u5165\u9009\u8005\u57fa\u7840\u5e74\u85aa30\u4e07\u8d77\uff0c\u6700\u9ad8\u53ef\u8fbe60\u4e07\uff08\u8be6\u60c5\uff1ahttps:\/\/rczp.nju.edu.cn\/yjxlhbsh\/bshjj\/index.html\uff09\uff1b2. \u79d1\u7814\u52a9\u7406\u85aa\u8d44\u5f85\u9047\u9762\u8bae\u3002\u8868\u73b0\u4f18\u5f02\u7684\u4f18\u5148\u7559\u7ec4\u653b\u8bfb\u535a\u58eb\u5b66\u4f4d\u3002<\/p>\n<p>\u540c\u65f6\u8bfe\u9898\u7ec42023\u5e74\u6709\u5145\u88d5\u7684\u7855\u58eb\u7814\u7a76\u751f\u540d\u989d\uff08\u9700\u901a\u8fc7\u5357\u4eac\u5927\u5b66\u7855\u58eb\u751f\u7814\u7a76\u751f\u62db\u751f\u8003\u6838\uff09\u548c\u5c11\u91cf\u79d1\u7814\u535a\u58eb\u7814\u7a76\u751f\u540d\u989d\uff08\u8bfe\u9898\u7ec42024\u5e74\u53ca\u4e4b\u540e\u535a\u58eb\u7814\u7a76\u751f\u62db\u751f\u540d\u989d\u6bd4\u8f83\u5145\u88d5\uff09\uff0c\u6b22\u8fce\u8054\u7cfb\u62a5\u8003\u3002\u672c\u62db\u8058\u5e7f\u544a\u957f\u671f\u6709\u6548\uff0c\u6709\u610f\u8005\u8bf7\u5c06\u7b80\u5386\u548c\u4ee3\u8868\u6027\u8bba\u6587\u6216\u7814\u7a76\u8ba1\u5212\uff08\u4ec5\u535a\u58eb\u540e\u7533\u8bf7\u8005\uff09\u53d1\u9001\u81f3\u9ece\u5efa\u90ae\u7bb1\uff1ajian.li@nju.edu.cn\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7814\u7a76\u80cc\u666f \u6cb8\u77f3\u5206\u5b50\u7b5b\uff08zeolite\uff09\u662f\u4e00\u7c7b\u7ed3\u6676\u6027\u5fae\u5b54\u7845\u94dd\u9178\u76d0\uff0c\u5177\u6709\u5b54\u5f84\u5206\u5e03\u5747\u4e00\u3001\u5b54\u9053\u7ed3\u6784\u89c4\u6574\u3001\u6d3b\u6027\u4e2d\u5fc3\u53ef\u8c03\u3001\u6bd4\u8868\u9762\u79ef\u5927\u3001\u7a33\u5b9a\u6027\u597d\u7b49\u7279\u6027\uff0c\u4f5c\u4e3a\u50ac\u5316\u5242\u3001\u5438\u9644\u5242\u3001\u79bb&#8230;<\/p>\n","protected":false},"author":41672,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-246130","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/246130"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/41672"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=246130"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/246130\/revisions"}],"predecessor-version":[{"id":246142,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/246130\/revisions\/246142"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=246130"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=246130"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=246130"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}