{"id":245987,"date":"2023-01-17T06:00:02","date_gmt":"2023-01-16T22:00:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=245987"},"modified":"2023-01-16T16:27:06","modified_gmt":"2023-01-16T08:27:06","slug":"%e8%b7%9f%e5%82%ac%e5%8c%96%e8%be%83%e5%8a%b2%ef%bc%81%e6%b8%a9%e5%b7%9e%e5%a4%a7%e5%ad%a6%e9%99%88%e9%94%a1%e5%ae%892022%e5%b9%b4%e7%a0%94%e7%a9%b6%e6%88%90%e6%9e%9c%e9%9b%86%e9%94%a6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=245987","title":{"rendered":"\u8ddf\u50ac\u5316\u8f83\u52b2\uff01\u6e29\u5dde\u5927\u5b66\u9648\u9521\u5b892022\u5e74\u7814\u7a76\u6210\u679c\u96c6\u9526"},"content":{"rendered":"<p>2022\u5e74\uff0c\u6e29\u5dde\u5927\u5b66\u9648\u9521\u5b89\/\u90ed\u5927\u8425\u8bfe\u9898\u7ec4\u7684\u4e3b\u8981\u7814\u7a76\u5de5\u4f5c\u96c6\u4e2d\u5728\u80fd\u6e90\u7535\u50ac\u5316\u3001\u9502-\u786b\u7535\u6c60\u3001\u94a0\u7535\u6c60\u4ee5\u53ca\u56fa\u4f53\u7535\u89e3\u8d28\u7b49\u80fd\u6e90\u5b58\u50a8\u548c\u8f6c\u5316\u9886\u57df\uff0c\u53d1\u8868Angew\u3001ACS Nano\u3001AFM\u53ca\u5176\u4ed6research \u6587\u7ae0\u3002\u5185\u5bb9\u5982\u4e0b\uff1a<\/p>\n<p><strong>Part 1 Li-S<\/strong><strong>\u7535\u6c60<\/strong><\/p>\n<p><strong>1<\/strong><strong>\u3001<\/strong><strong>Angew. Chem. Int. Ed.<\/strong><strong>\uff1a\u6709\u673a\u5c0f\u5206\u5b50\u52a0\u901f\u591a\u786b\u5316\u7269\u7684\u50ac\u5316\u8f6c\u5316<\/strong><\/p>\n<p>\u9502\u786b\u7535\u6c60\uff08LSBs\uff09\u4f5c\u4e3a\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u65b0\u578b\u7535\u5316\u5b66\u7535\u6e90\uff0c\u5177\u6709\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u3001\u6210\u672c\u4f4e\u3001\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\u3002\u7136\u800c\uff0cLSBs\u7684\u5546\u4e1a\u5316\u4ecd\u7136\u53d7\u5230\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u6548\u5e94\u548c\u7f13\u6162\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u963b\u788d\uff0c\u8fd9\u4f1a\u5bfc\u81f4\u6d3b\u6027\u6750\u6599\u7684\u4e0d\u53ef\u9006\u635f\u5931\u3001\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u8150\u8680\u4ee5\u53ca\u7535\u6c60\u5185\u963b\u7684\u589e\u52a0\uff0c\u6700\u7ec8\u5bfc\u81f4\u7535\u6c60\u77ed\u8def\uff0c\u5faa\u73af\u5bff\u547d\u548c\u4f4e\u5e93\u4ed1\u6548\u7387\u3002\u5e78\u8fd0\u7684\u662f\uff0c\u6709\u673a\u5206\u5b50\u6539\u6027\u78b3\u57fa\u4e2d\u95f4\u5c42\u7684\u5f00\u521b\u6027\u7814\u7a76\u5de5\u4f5c\uff0c\u4ee5\u7f13\u89e3\u78b3\u6750\u6599\u6781\u6027\u5dee\u7684\u95ee\u9898\uff0c\u589e\u5f3a\u7269\u7406\u548c\u5316\u5b66\u5438\u9644\uff0c\u6539\u5584\u591a\u786b\u5316\u7269\u50ac\u5316\u8f6c\u5316\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u800c\u4e0d\u5f71\u54cd\u5176\u78b3\u6750\u6599\u4f18\u52bf\uff08\u5feb\u901f\u4f20\u8d28\u548c\u7535\u8377\u8f6c\u79fb\u7b49\uff09\u3002\u7136\u800c\uff0c\u6709\u673a\u5206\u5b50\u901a\u8fc7\u7b80\u5355\u7684\u91cd\u7ec4\u8fdb\u5165\u57fa\u4f53\u4ecd\u7136\u4f1a\u5728\u6709\u673a\u7535\u89e3\u8d28\u4e2d\u635f\u5931\u3002\u6b64\u5916\uff0c\u50ac\u5316\u8f6c\u5316\u7684\u673a\u5236\u5c1a\u4e0d\u6e05\u6670\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u548c\u5f00\u53d1\u4e0e\u78b3\u6750\u6599\u7d27\u5bc6\u7ed3\u5408\u7684\u65b0\u578b\u6709\u673a\u5206\u5b50\u5bf9\u4e8e\u52a0\u901f\u591a\u786b\u5316\u7269\u7684\u50ac\u5316\u8f6c\u5316\u3001\u6291\u5236\u7a7f\u68ad\u6548\u5e94\u548c\u4fdd\u6301\u5176\u7ed3\u6784\u7a33\u5b9a\u6027\u81f3\u5173\u91cd\u8981\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245988\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1-1.png\" alt=\"\" width=\"878\" height=\"718\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1-1.png 878w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1-1-300x245.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe1-1-768x628.png 768w\" sizes=\"(max-width: 878px) 100vw, 878px\" \/><\/p>\n<p>\u4e3a\u6b64\uff0c\u8bfe\u9898\u7ec4<strong>\u5f00\u53d1\u4e86\u4e00\u79cd\u4e09\uff08\u7f9f\u4e19\u57fa\uff09\u81a6\u5171\u4ef7\u6539\u6027\u7f9f\u57fa\u5316\u591a\u58c1\u78b3\u7eb3\u7c73\u7ba1\u4f5c\u4e3a\u5148\u8fdb\u9502\u786b\u7535\u6c60\u7684\u529f\u80fd\u5c42<\/strong>\u3002\u4e09\uff08\u7f9f\u4e19\u57fa\uff09\u81a6\uff08THPP\uff09\u4f5c\u4e3a\u9502\u786b\u7535\u6c60\u529f\u80fd\u63d2\u5c42\u4e2d\u7684\u6d3b\u6027\u7269\u8d28\uff0c\u80fd\u591f\u5feb\u901f\u5c06\u6db2\u76f8\u591a\u786b\u5316\u9502\uff08Li<sub>2<\/sub>S<sub>n<\/sub>, 4\u2264n\u22648\uff09\u50ac\u5316\u8f6c\u5316\u56fa\u76f8\u786b\u5316\u9502\uff08Li<sub>2<\/sub>S\uff09\uff0c\u4ece\u800c\u6709\u6548\u6291\u5236\u591a\u786b\u5316\u7269\u7a7f\u68ad\u6548\u5e94\u3002\u540c\u65f6\u80fd\u591f\u8bf1\u5bfc\u9502\u8d1f\u6781\u8868\u9762\u5f62\u6210\u7a33\u5b9a\u7684\u56fa\u4f53\u7535\u89e3\u6db2\u4e2d\u95f4\u76f8\uff08SEI\uff09\u5c42\uff0c\u8fdb\u800c\u51cf\u5c11\u9502\u8d1f\u6781\u679d\u6676\u7684\u5f62\u6210\u3002\u4ece\u800c\u4f7f\u672c\u5de5\u4f5c\u4e2d\u8bbe\u8ba1\u7684\u9502\u786b\u7535\u6c60\u5177\u6709\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u957f\u671f\u7a33\u5b9a\u6027\u3002\u5373\u4f7f\u5728\u4f4e\u6e29\u4e0b\uff0c1700\u6b21\u5faa\u73af\u7684\u5bb9\u91cf\u8870\u51cf\u7387\u4e5f\u4ec5\u4e3a\u6bcf\u5faa\u73af0.036%<strong>\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245989\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2.png\" alt=\"\" width=\"1269\" height=\"1018\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2-300x241.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2-768x616.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe2-1024x821.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<p>Bin Yang, Daying Guo*, Peirong Lin, Ling Zhou, Jun Li, Guoyong Fang, Jinyi Wang, Huile Jin, Xi\u2019an Chen*, and Shun Wang*, Hydroxylated Multi-walled Carbon Nanotubes Covalently Modified with Tris(hydroxypropyl) Phosphine as a Functional Interlayer for Advanced Lithium-Sulfur Batteries. Angew. Chem. Int. Ed., 2022, 61, 202204327.<\/p>\n<p>https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202204327.<\/p>\n<p><strong>2\u3001Adv. Funct. Mater.: \u5355\u539f\u5b50<\/strong><strong>\u94bc\u63d0\u9ad8\u9502\u786b\u7535\u6c60\u53cd\u5e94\u52a8\u529b\u5b66<\/strong><\/p>\n<p>\u9502\u786b\u7535\u6c60\uff08LSB\uff09\u5177\u67092600 Wh kg<sup>-1<\/sup>\u7684\u6781\u9ad8\u6bd4\u80fd\u91cf\u548c1675 mAh g<sup>-1<\/sup>\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff0c\u662f\u5f53\u524d\u53ef\u5145\u7535\u9502\u79bb\u5b50\u7535\u6c60\u7684\u672a\u6765\u4e4b\u661f\u3002\u7136\u800c\u53ef\u6eb6\u6027\u4e2d\u95f4\u4ea7\u7269\u591a\u786b\u5316\u7269\u7684\u201c\u7a7f\u68ad\u201d\u6548\u5e94\uff0c\u5bfc\u81f4\u5355\u8d28\u786b\u7684\u5229\u7528\u7387\u4f4e\u3001\u53cd\u5e94\u52a8\u529b\u5b66\u6162\u3001\u5faa\u73af\u5bff\u547d\u5dee\u548c\u5e93\u4f26\u6548\u7387\u4f4e\uff0c\u4ece\u800c\u9650\u5236\u4e86LSB\u7684\u5546\u4e1a\u5316\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u5408\u7406\u8bbe\u8ba1\u6d3b\u6027\u7269\u8d28\u786b\u7684\u5bbf\u4e3b\u8f7d\u4f53\uff0c\u6709\u6548\u5730\u6291\u5236\u591a\u786b\u5316\u7269\u9502\uff08LiPS\uff09\u7684\u7a7f\u68ad\uff0c\u5e76\u63d0\u9ad8\u786b\u7684\u7f13\u6162\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u4ecd\u7136\u662f\u9502\u786b\u7535\u6c60\u9762\u4e34\u7684\u4e3b\u8981\u6311\u6218\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245990\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3.png\" alt=\"\" width=\"1269\" height=\"1145\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3-300x271.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3-768x693.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe3-1024x924.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u57fa\u4e8e\u6b64\uff0c<strong>\u8bfe\u9898\u7ec4<\/strong>\u5728\u65b0\u9896\u78b3\u7403\u7ed3\u6784\u8bbe\u8ba1\uff08<em>J. Mater. Chem. A<\/em>, <strong>2017,<\/strong> 5, 18193-18206.\uff09\u548c\u6c2e\u63ba\u6742\u82b1\u578b\u78b3\u7eb3\u7c73\u7403\uff08<em>J. Mater. Chem. A<\/em>, <strong>2017<\/strong>, 5, 6245-6256\uff09\u7684\u57fa\u7840\u4e0a<strong>\u5f00\u53d1\u4e86\u4e00\u79cd\u5355\u539f\u5b50\u94bc\u4ee5\u56db\u6c2e\u914d\u4f4d\uff08<\/strong><strong>Mo-N<sub>4<\/sub><\/strong><strong>\uff09\u7684\u5f62\u5f0f\u951a\u5b9a\u5728<\/strong><strong> N <\/strong><strong>\u63ba\u6742\u78b3\u7eb3\u7c73\u82b1\u4e0a\u4f5c\u4e3a\u9502\u786b\u7535\u6c60\u786b\u9634\u6781\uff0c\u663e\u8457\u63d0\u9ad8\u7535\u6c60\u6027\u80fd<\/strong><strong>\u3002<\/strong>\u5229\u7528\u72ec\u7279\u8bbe\u8ba1\u7684\u82b1\u578b\u7ed3\u6784\u78b3\u7403\u548c\u9ad8\u6d3b\u6027Mo-N<sub>4<\/sub>\u50ac\u5316\u4e2d\u5fc3\uff0c<strong>\u8868\u73b0\u51fa\u591a\u91cd\u56fa\u5b9a\u548c\u50ac\u5316\u591a\u786b\u5316\u7269\u4f5c\u7528\uff0c<\/strong>\u80fd\u591f\u5feb\u901f\u5c06\u6db2\u76f8\u591a\u786b\u5316\u9502\uff08Li<sub>2<\/sub>S<sub>n<\/sub>, 4\u2264n\u22648\uff09\u50ac\u5316\u8f6c\u5316\u56fa\u76f8\u786b\u5316\u9502\uff08Li<sub>2<\/sub>S\uff09\uff0c\u4ece\u800c\u6709\u6548\u6291\u5236\u591a\u786b\u5316\u7269\u7a7f\u68ad\u6548\u5e94\u3002\u57fa\u4e8e\u6b64\uff0c\u8fd9\u9879\u5de5\u4f5c\u4e2d\u8bbe\u8ba1\u7684LSBs\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u957f\u671f\u7a33\u5b9a\u6027\u3002 \u7279\u522b\u662f\u57285.1 mg cm<sup>-2<\/sup>\u7684\u9ad8\u8f7d\u786b\u4e0b\uff0c\u9762\u79ef\u6bd4\u5bb9\u91cf\u8fbe\u5230\u521d\u59cb\u5bb9\u91cf3.24 mAh cm<sup>-2<\/sup>\uff084.27 mA cm<sup>-2<\/sup>\uff09\uff0c\u7ecf\u8fc7400\u6b21\u5faa\u73af\u540e\u9762\u79ef\u6bd4\u5bb9\u91cf\u4fdd\u6301\u57283.17 mAh cm<sup>-2<\/sup>\uff0c\u8870\u51cf\u7387\u4ec5\u4e3a0.004%\u3002\u8fd9\u79cd\u901a\u8fc7\u5c06\u5355\u539f\u5b50\u50ac\u5316\u5242\u951a\u5b9a\u5728\u6c2e\u63ba\u6742\u78b3\u7eb3\u7c73\u7403\u4e0a\u7ed3\u6784\u8bbe\u8ba1\u7b56\u7565\u4e3a\u9502\u786b\u7535\u6c60\u5e94\u7528\u5e26\u6765\u5149\u660e\u7684\u672a\u6765\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245991\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4.png\" alt=\"\" width=\"1269\" height=\"906\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4-300x214.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4-768x548.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe4-1024x731.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<p>Daying Guo, Xu Zhang, Menglan Liu, Zhisheng Yu, Xi\u2019an Chen,* Bin Yang, Zhen Zhou,* and Shun Wang*, Single Mo\u2013N<sub>4<\/sub> Atomic Sites Anchored on N-doped Carbon Nanoflowers as Sulfur Host with Multiple Immobilization and Catalytic Effects for High-Performance Lithium\u2013Sulfur Batteries. Adv. Funct. Mater. 2022, 32, 2204458.<\/p>\n<p>https:\/\/onlinelibrary.wiley.com\/doi\/epdf\/10.1002\/adfm.202204458.<\/p>\n<p><strong>3<\/strong><strong>\u3001<\/strong><strong>J. Energy Chem.: <\/strong><strong>\u5f3a\u5185\u7535\u573a\u5b9e\u73b0\u9ad8\u6027\u80fd\u9502\u786b\u7535\u6c60<\/strong><\/p>\n<p>\u9502\u786b\u7535\u6c60\uff08LSBs\uff09\u5177\u67092600 W h kg<sup>-1<\/sup>\u7684\u6781\u9ad8\u6bd4\u80fd\u91cf\u548c1675 mA h g<sup>-1<\/sup>\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\u4f5c\u4e3a\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u65b0\u578b\u7535\u5316\u5b66\u7535\u6e90\uff0c\u5177\u6709\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u3001\u6210\u672c\u4f4e\u3001\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\u3002\u9057\u61be\u7684\u662f\uff0cLSBs\u7684\u5546\u4e1a\u5316\u4ecd\u7136\u53d7\u5230\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u6548\u5e94\u548c\u7f13\u6162\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u963b\u788d\uff0c\u8fd9\u4f1a\u5bfc\u81f4\u6d3b\u6027\u6750\u6599\u7684\u4e0d\u53ef\u9006\u635f\u5931\u3001\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u8150\u8680\u4ee5\u53ca\u7535\u6c60\u5185\u963b\u7684\u589e\u52a0\uff0c\u6700\u7ec8\u5bfc\u81f4\u7535\u6c60\u77ed\u8def\uff0c\u5faa\u73af\u5bff\u547d\u548c\u4f4e\u5e93\u4ed1\u6548\u7387\u3002\u91d1\u5c5e\u5316\u5408\u7269\u590d\u5408\u78b3\u57fa\u4e2d\u95f4\u5c42\u4f5c\u4e3a\u9694\u819c\u4fee\u9970\u5c42\u4e0d\u4ec5\u80fd\u591f\u7f13\u89e3\u78b3\u6750\u6599\u6781\u6027\u5dee\u7684\u95ee\u9898\uff0c\u800c\u4e14\u53ef\u4ee5\u589e\u5f3a\u7269\u7406\u548c\u5316\u5b66\u5438\u9644\uff0c\u6539\u5584\u591a\u786b\u5316\u7269\u50ac\u5316\u8f6c\u5316\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u800c\u4e0d\u5f71\u54cd\u9694\u819c\u7684\u5feb\u901f\u4f20\u8d28\u548c\u7535\u8377\u8f6c\u79fb\u7b49\u3002\u56e0\u6b64\uff0c\u78b3\u6750\u6599\u548c\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\u7684\u590d\u5408\u7269\u5728\u7535\u6c60\u5e94\u7528\u8fc7\u7a0b\u4e2d\u5177\u6709\u6355\u83b7\u548c\u8fdb\u4e00\u6b65\u8f6c\u5316\u591a\u786b\u5316\u7269\u7684\u53cc\u91cd\u529f\u80fd\uff0c\u8fd9\u610f\u5473\u7740\u8be5\u65b9\u6cd5\u662f\u6291\u5236\u591a\u786b\u5316\u7269\u7a7f\u68ad\u6548\u5e94\u7684\u53ef\u884c\u89e3\u51b3\u65b9\u6848\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245992\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5.png\" alt=\"\" width=\"1204\" height=\"907\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5.png 1204w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5-300x226.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5-768x579.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe5-1024x771.png 1024w\" sizes=\"(max-width: 1204px) 100vw, 1204px\" \/><\/p>\n<p>\u4e3a\u6b64\uff0c<strong>\u8bfe\u9898\u7ec4<\/strong>\u5408\u7406\u8bbe\u8ba1\u5e76\u6784\u5efa\u4e86\u4e00\u79cd\u5177\u6709\u82b1\u72b6\u7ed3\u6784\u7684\u78b1\u5f0f\u78b3\u9178\u94cb\uff08Bi<sub>2<\/sub>O<sub>2<\/sub>CO<sub>3<\/sub>\uff09\u6750\u6599\uff0c\u5e76\u4f7f\u7528\u4e0e\u5bfc\u7535\u78b3\uff08DC\uff09\u6df7\u5408\u7684\u4f5c\u4e3aLSBs\u4e2d\u786b\u9634\u6781\u7684\u963b\u6321\u5c42\u3002\u5229\u4e8eBi<sub>2<\/sub>O<sub>2<\/sub>CO<sub>3<\/sub>\uff08BOC\uff09\u7eb3\u7c73\u82b1\u5185\u90e8\u7684\u5f3a\u7535\u573a\uff0c\u5728BOC\u8868\u9762\u8bf1\u5bfc\u5b8f\u89c2\u7535\u8377\uff0c\u5bfc\u81f4\u5916\u90e8\u73af\u5883\u4e2d\u7684\u5927\u91cf\u6781\u6027\u5206\u5b50\u88ab\u5316\u5b66\u5438\u9644\u5728\u8868\u9762\u4e0a\uff0c\u4ee5\u5c4f\u853d\u8fd9\u4e9b\u8868\u9762\u7535\u8377\uff0c\u4ece\u800c\u589e\u5f3a\u591a\u786b\u5316\u7269\u6355\u83b7\u7b56\u7565\u6765\u89e3\u51b3\u7a7f\u68ad\u6548\u5e94\u3002\u540c\u65f6\uff0c\u963b\u6321\u5c42\u5bf9\u591a\u786b\u5316\u7269\u8868\u73b0\u51fa\u5f3a\u70c8\u7684\u50ac\u5316\u4f5c\u7528\u3002\u4e3a\u6b64\uff0c\u6240\u8bbe\u8ba1\u7684\u63d2\u5c42\u819c\u5728\u5728\u9ad8\u7535\u6d41\u5bc6\u5ea65C\u65f6\uff0c\u5b9e\u73b0\u4e86713 mA h g<sup>-1<\/sup>\u7684\u9ad8\u6bd4\u5bb9\u91cf\u3002\u5728\u7535\u6d41\u5bc6\u5ea61 C\u65f6\uff0c\u5faa\u73af550\u5708\u4e4b\u540e\uff0c\u653e\u7535\u6bd4\u5bb9\u91cf\u7ef4\u6301\u5728719 mA h g<sup>-1<\/sup>\u9ad8\u53ef\u9006\u6027\u5bb9\u91cf\uff0c\u6bcf\u5708\u5faa\u73af\u4ec5\u8870\u51cf0.044%\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u57285.1 mg cm<sup>-2<\/sup>\u7684\u786b\u8f7d\u91cf\u4e0b\uff0c200\u6b21\u5faa\u73af\u540e\u9762\u79ef\u6bd4\u5bb9\u91cf\u4fdd\u6301\u57284 mA h cm<sup>\u2212<\/sup><sup>2<\/sup>\uff0c\u6bcf\u5708\u8870\u51cf\u7387\u4ec5\u4e3a0.056%\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245993\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe6.png\" alt=\"\" width=\"1269\" height=\"952\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe6.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe6-300x225.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe6-768x576.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe6-1024x768.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<p>Bin Yang<sup>1<\/sup>, Jinyi Wang<sup>1<\/sup>, Yuheng, Qi, Daying Guo*, Xueyu Wang, Guoyong Fang, Xi\u2019an Chen*, Shun Wang*, Strong internal electric field enhanced polysulfide trapping and ameliorates redox kinetics for lithium-sulfur battery, Journal of Energy Chemistry, DOI: 10.1016\/j.jechem.2022.10.045<\/p>\n<p><strong>\u5176\u4ed6\uff1a<\/strong><\/p>\n<p><strong>1<\/strong><strong>\u3001<\/strong><strong>Small:<\/strong> High Pseudocapacitance-Driven CoC<sub>2<\/sub>O<sub>4<\/sub> Electrodes Exhibiting Superior Electrochemical Kinetics and Reversible Capacities for Lithium-Ion and Lithium\u2013Sulfur Batteries.<\/p>\n<p>https:\/\/doi.org\/10.1002\/smll.202205887.<\/p>\n<p><strong>2<\/strong><strong>\u3001<\/strong><strong>Small<\/strong>\uff1aFlower-Like NiS<sub>2<\/sub>\/WS<sub>2<\/sub> Heterojunction as Polysulfide\/Sulfide Bidirectional Catalytic Layer for High-Performance Lithium\u2212Sulfur Batteries.<\/p>\n<p>https:\/\/doi.org\/10.1002\/smll.202206926.<\/p>\n<p><strong>3<\/strong><strong>\u3001<\/strong><strong>Front. Chem.:<\/strong> A Review on the Construction of Carbon-Based Metal Compound Composite Cathode Materials for Room Temperature Sodium-Sulfur Batteries.<\/p>\n<p>https:\/\/doi.org\/10.3389\/fchem.2022.928429.<\/p>\n<p><strong>4<\/strong><strong>\u3001<\/strong><strong>Adv. Eng. Mater.\u00a0:<\/strong> Fluorinated Solid-State Electrolytes for Lithium Batteries: Interface Design and Ion Conduction Mechanisms.<\/p>\n<p>https:\/\/doi.org\/10.1002\/adem.202201390.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Part 2 <\/strong><strong>\u7535\u50ac\u5316<\/strong><\/p>\n<p><strong>1<\/strong><strong>\u3001<\/strong><strong>ACS Nano <\/strong><strong>\u539f\u5b50\u7f6e\u6362\u7b56\u7565\u6784\u7b51\u6790\u6c27\u53cd\u5e94\u50ac\u5316\u5242<\/strong><\/p>\n<p>\u7535\u89e3\u6c34\u662f\u4e00\u79cd\u9ad8\u6548\u3001\u6e05\u6d01\u7684\u5236\u5907\u9ad8\u7eaf\u6c22\u6280\u672f\u3002\u6c34\u5206\u89e3\u5305\u62ec\u4e24\u4e2a\u534a\u53cd\u5e94:\u6790\u6c22(HER)\u548c\u6790\u6c27(OER)\u3002\u5176\u4e2dOER\u662f\u4e00\u4e2a\u56db\u7535\u5b50\u8d28\u5b50\u8026\u5408\u53cd\u5e94\uff0c\u53cd\u5e94\u8fc7\u7a0b\u590d\u6742\uff0c\u9700\u8981\u66f4\u9ad8\u7684\u80fd\u91cf(\u66f4\u9ad8\u7684\u8d85\u7535\u52bf)\u6765\u514b\u670d\u53cd\u5e94\u80fd\u5792\u3002\u56e0\u6b64\uff0c\u7f13\u6162\u7684OER\u52a8\u529b\u5b66\u662f\u963b\u788d\u6c34\u5206\u89e3\u6574\u4f53\u5e94\u7528\u7684\u5173\u952e\u95ee\u9898\u4e4b\u4e00\u3002\u5f02\u8d28\u7ed3\u6784\u7684\u6784\u5efa\u662f\u8bbe\u8ba1\u50ac\u5316\u5242\u754c\u9762\u4ee5\u8fdb\u884c\u9ad8\u6548\u6790\u6c27\u53cd\u5e94(OER)\u7684\u6700\u6709\u524d\u9014\u7684\u7b56\u7565\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u901a\u8fc7\u5bf9\u672c\u4f53\u7684\u50ac\u5316\u5242\u539f\u5b50\u8fdb\u884c\u7cbe\u786e\u7f6e\u6362\u6784\u7b51\u5f02\u8d28\u754c\u9762\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245994\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe7.png\" alt=\"\" width=\"1127\" height=\"738\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe7.png 1127w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe7-300x196.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe7-768x503.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe7-1024x671.png 1024w\" sizes=\"(max-width: 1127px) 100vw, 1127px\" \/><\/p>\n<p>\u57fa\u4e8e\u6b64\uff0c<strong>\u8bfe\u9898\u7ec4<\/strong>\u901a\u8fc7\u539f\u5b50\u53d6\u4ee3\u7b56\u7565\u5236\u5907\u4e86\u8d1f\u8f7d\u5728\u67d4\u6027\u78b3\u7ea4\u7ef4\u5e03\u4e0a\u7684\u9488\u72b6\u5f02\u8d28\u7ed3\u6784Co<sub>1-x<\/sub>S\/Co(OH)F\uff0c\u5176\u4e2d\u786b\u539f\u5b50\u5728\u7535\u6c89\u79ef\u8fc7\u7a0b\u4e2d\u4eceCo(OH)F\u4e2d\u90e8\u5206\u53bb\u9664\u540e\u540c\u65f6\u63a5\u679d\u5230F\u7a7a\u4f4d\u4e0a\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u786b\u5316\u94b4\u5728Co(OH)F\u754c\u9762\u4e0a\u7684\u751f\u957f\u3002\u8fd9\u79cd\u5177\u6709\u8fd9\u79cd\u8bbe\u8ba1\u7684\u7535\u50ac\u5316\u5242\u5177\u6709\u4ee5\u4e0b\u4f18\u70b9\uff1a(1)\u539f\u5b50\u66ff\u4ee3\u5f15\u8d77\u7684\u6676\u683c\u7578\u53d8\u5bfc\u81f4\u6d3b\u6027\u4f4d\u589e\u52a0\uff1b(2)\u901a\u8fc7\u539f\u5b50\u7f6e\u6362\u7b56\u7565\u5728Co(OH)F\u8868\u9762\u6784\u5efa\u7684Co<sub>1-x<\/sub>S\u4f18\u5316\u4e86OER\u8fc7\u7a0b\u4e2d\u7684\u5438\u9644(OH)\u548c\u8131\u9644(O<sub>2<\/sub>)\u80fd\u91cf\uff1b(3)\u9488\u72b6\u7ed3\u6784\u5177\u6709\u5c16\u7aef\u589e\u5f3a\u7684\u5c40\u90e8\u7535\u573a\u6548\u5e94\u3002\u56e0\u6b64\uff0cCo<sub>1-x<\/sub>S\/Co(OH)F \/CC\u50ac\u5316\u5242\u8868\u73b0\u51fa\u975e\u5e38\u9ad8\u7684OER\u50ac\u5316\u6027\u80fd\uff0c\u572810 mA cm<sup>-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u548c71 mV dec<sup>-1<\/sup>\u7684Tafel\u659c\u7387\u4e0b\u8d85\u7535\u52bf\u4e3a269 mV\u3002\u4e0d\u5bf9\u79f0\u7535\u6781\u5728\u6574\u4e2a\u6c34\u5206\u89e3\u4e2d\u663e\u793a\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u901a\u8fc7DFT\u7406\u8bba\u8ba1\u7b97\u548c\u975e\u539f\u4f4d\u8868\u5f81\uff0c\u7814\u7a76\u4e86\u8fd9\u4e9b\u9ad8\u6548Co<sub>1-x<\/sub>S\/Co(OH)F\/CC\u50ac\u5316\u5242\u7684\u50ac\u5316\u673a\u7406\u3002\u8fd9\u79cd\u539f\u5b50\u53d6\u4ee3\u7b56\u7565\u663e\u793a\u4e86\u5bf9\u5176\u5b83\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269(\u91d1\u5c5e= Ni\u3001Mn\u3001Cu)\u7684\u666e\u9002\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245995\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe8.png\" alt=\"\" width=\"1037\" height=\"846\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe8.png 1037w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe8-300x245.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe8-768x627.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe8-1024x835.png 1024w\" sizes=\"(max-width: 1037px) 100vw, 1037px\" \/><\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<p>Qian Lin, Daying Guo,* Ling Zhou, Lin Yang, Huile Jin, Jun Li, Guoyong Fang, Xi\u2019an Chen,* and Shun Wang*, Tuning the Interface of Co<sub>1\u2212x<\/sub>S\/Co(OH)F by Atomic Replacement Strategy toward High-Performance Electrocatalytic Oxygen Evolution, ACS Nano 2022, 16, 15460\u221215470<\/p>\n<p>https:\/\/doi.org\/10.1021\/acsnano.2c07588.<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>2<\/strong><strong>\u3001<\/strong><strong>Adv. Mater.<\/strong> <strong>Interfaces<\/strong><strong>\u7efc\u8ff0<\/strong><strong>: <\/strong><strong>\u8fc7\u6e21\u91d1\u5c5e\u57fa\u7535\u50ac\u5316\u5242\u7528\u4e8e\u6d77\u6c34\u6c27\u5316<\/strong><\/p>\n<p>\u7535\u50ac\u5316\u6c34\u5206\u89e3\u662f\u4e00\u79cd\u6709\u6548\u7684\u7b56\u7565\uff0c\u53ef\u4ee5\u5c06\u98ce\u80fd\u3001\u592a\u9633\u80fd\u7b49\u95f4\u6b47\u6027\u80fd\u6e90\u8f6c\u5316\u4e3a\u53ef\u518d\u751f\u3001\u53ef\u6301\u7eed\u7684\u6c22\u80fd\u3002\u5168\u7403\u6de1\u6c34\u8d44\u6e90\u6781\u5176\u532e\u4e4f\u3002\u4e0e\u6de1\u6c34\u76f8\u6bd4\uff0c\u6d77\u6c34\u662f\u4e00\u79cd\u4e30\u5bcc\u4e14\u53ef\u6301\u7eed\u7684\u8d44\u6e90\uff0c\u5728\u7535\u50ac\u5316\u4e2d\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u6d77\u6c34\u6790\u6c27\u53cd\u5e94(OER)\u662f\u56db\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u8fd9\u5bfc\u81f4\u7f13\u6162\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u6b64\u5916\uff0c\u6d77\u6c34\u4e2d\u5404\u79cd\u5143\u7d20\u7684\u5b58\u5728\u53ca\u5176\u5bf9\u7535\u5316\u5b66\u7684\u5e72\u6270\u4f7f\u5f97\u6d77\u6c34\u4e2d\u7684OER\u6781\u5177\u6311\u6218\u6027\u3002\u9274\u4e8e\u6b64\uff0c<strong>\u8bfe\u9898\u7ec4<\/strong>\u56de\u987e\u4e86\u8fc7\u6e21\u91d1\u5c5e\u57fa\u6d77\u6c34OER\u7535\u50ac\u5316\u6750\u6599\u7684\u6700\u65b0\u8fdb\u5c55\uff0c\u5305\u62ec\u6c22\u6c27\u5316\u7269\u3001\u6c27\u5316\u7269\u3001\u786b\u5c5e\u5316\u5408\u7269\u3001\u78f7\u5316\u7269\u548c\u6c2e\u5316\u7269\u7b49\u3002\u672c\u6587\u91cd\u70b9\u4ece\u7ed3\u6784\u8bbe\u8ba1\u3001\u673a\u7406\u7406\u89e3\u548c\u6027\u80fd\u589e\u5f3a\u7b49\u65b9\u9762\u7efc\u8ff0\u4e86\u662f\u5982\u4f55\u6d88\u9664\u7535\u89e3\u6d77\u6c34\u4e2dOER\u7684\u7ade\u4e89\u53cd\u5e94\u6790\u6c2f\u53cd\u5e94\u3002\u6700\u540e\uff0c\u4ecb\u7ecd\u4e86\u6d77\u6c34\u7535\u50ac\u5316OER\u9762\u4e34\u7684\u6311\u6218\u3001\u524d\u666f\u548c\u7814\u7a76\u65b9\u5411\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-245996\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe9.png\" alt=\"\" width=\"1269\" height=\"715\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe9.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe9-300x169.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe9-768x433.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2023\/01\/\u56fe9-1024x577.png 1024w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<p>Lin Yang, Ling Zhou, Mei Wang, Yuheng Qi, Daying Guo,* Haocheng Li, Xi\u2019an Chen,* and Shun Wang, Transition Metal-Based Electrocatalysts for Seawater<\/p>\n<p>Oxidation, Adv. Mater. Interfaces 2022, 9, 2201486.<\/p>\n<p>https:\/\/doi.org\/10.1002\/admi.202201486.<\/p>\n<p><strong>\u5176\u4ed6\uff1a<\/strong><\/p>\n<p><strong>1<\/strong><strong>\u3001<\/strong><strong>Small:<\/strong> A Tandem Interfaced (Ni<sub>3<\/sub>S<sub>2<\/sub>-MoS<sub>2<\/sub>)@TiO<sub>2<\/sub> Composite Fabricated by Atomic Layer Deposition as Efficient HER Electrocatalyst.<\/p>\n<p>https:\/\/doi.org\/10.1002\/smll.202201896.<\/p>\n<p>2\u3001<strong>Adv. Energy Sustainability Res.<\/strong>\uff1a Efficient Modulation of Electrocatalyst Interfaces by Atomic Layer Deposition: Fundamentals to Application.<\/p>\n<p>https:\/\/doi.org\/10.1002\/aesr.202200026.<\/p>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>2022\u5e74\uff0c\u6e29\u5dde\u5927\u5b66\u9648\u9521\u5b89\/\u90ed\u5927\u8425\u8bfe\u9898\u7ec4\u7684\u4e3b\u8981\u7814\u7a76\u5de5\u4f5c\u96c6\u4e2d\u5728\u80fd\u6e90\u7535\u50ac\u5316\u3001\u9502-\u786b\u7535\u6c60\u3001\u94a0\u7535\u6c60\u4ee5\u53ca\u56fa\u4f53\u7535\u89e3\u8d28\u7b49\u80fd\u6e90\u5b58\u50a8\u548c\u8f6c\u5316\u9886\u57df\uff0c\u53d1\u8868Angew\u3001ACS Nano\u3001&#8230;<\/p>\n","protected":false},"author":41672,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-245987","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245987"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/41672"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=245987"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245987\/revisions"}],"predecessor-version":[{"id":245997,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/245987\/revisions\/245997"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=245987"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=245987"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=245987"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}